Application of exhaust gas fuel reforming in diesel and homogeneous charge compression ignition (HCCI) engines fuelled with biofuels

This paper documents the application of exhaust gas fuel reforming of two alternative fuels, biodiesel and bioethanol, in internal combustion engines. The exhaust gas fuel reforming process is a method of on-board production of hydrogen-rich gas by catalytic reaction of fuel and engine exhaust gas. The benefits of exhaust gas fuel reforming have been demonstrated by adding simulated reformed gas to a diesel engine fuelled by a mixture of 50% ultra low sulphur diesel (ULSD) and 50% rapeseed methyl ester (RME) as well as to a homogeneous charge compression ignition (HCCI) engine fuelled by bioethanol. In the case of the biodiesel fuelled engine, a reduction of NO_x emissions was achieved without considerable smoke increase. In the case of the bioethanol fuelled HCCI engine, the engine tolerance to exhaust gas recirculation (EGR) was extended and hence the typically high pressure rise rates of HCCI engines, associated with intense combustion noise, were reduced.     

The influence of hydrogen-enriched gas on the performance of lean NOx trap catalyst for a light-duty diesel engine

Modern diesel engines have improved engine fuel economy and significantly reduced nitrogen oxides (NO_x) and particulate matter (PM) emissions achieved by advances in both combustion and exhaust aftertreatment technologies. Recently, it has been shown that the vehicle emissions can be further improved by several catalytic systems including fuel reformers and aftertreatment systems, such as the Lean NO_x Trap (LNT). This NO_x removal system, called LNT, absorbs NO_x under lean exhaust gas conditions and releases NO_x under rich conditions. This technology can provide high NO_x conversion efficiency, but the right amount of reducing agent should be supplied into the catalytic converter under appropriate conditions.     

Evaluation of acetylene as a spark ignition engine fuel

In spite of its known shortcomings as a fuel for spark ignition engines, acetylene has been suggested as a possible alternative to petroleum-based fuels since it can be produced from non-petroleum resources (coal, limestone and water). Therefore, acetylene was evaluated in a single-cylinder engine to investigate performance and emission characteristics with special emphasis on lean operation for NO_x control. Testing was carried out at constant speed, constant airflow and MBT spark timing. Equivalence ratio and compression ratio were the primary variables. The engine operated much leaner when fuelled with acetylene than with gasoline. With acetylene, the engine operated at equivalence ratios as lean as 0·53 and 0·43 for compression ratios of 4 and 6, respectively. However, the operating range was very limited. Knock-induced preignition occurred either with compression ratios above 6 or with mixtures richer than 0·69 equivalence ratio. Both the indicated thermal efficiency and power output were less for acetylene fuelling than for gasoline. Acetylene combustion occurred at sufficiently lean equivalence ratios to produce very low NO_x and CO emissions. However, when the low NO_x levels were achieved hydrocarbon control was not improved over that with gasoline. Despite the potential for NO_x control demonstrated in this study of acetylene fuelling, difficulties encountered with engine knock and preignition plus well-known safety problems (wide flammability limits and explosive decomposition) associated with acetylene render this fuel impractical for spark ignition engines.     

Compact plasmatron-boosted hydrogen generation technology for vehicular applications

Onboard hydrogen generation using compact plasmatron devices could provide important new possibilities for reducing pollution from motor vehicles, making use of alternative fuels, and increasing engine efficiency. These improvements would involve the use of the plasmatron as a very small, rugged, rapid response and highly flexible means of electrical heating of gases. Plasmatron heating could be used to facilitate conversion of a wide range of hydrocarbon fuels into hydrogen-rich gas onboard a vehicle. Use of combinations of fuels is possible through potential transformation of a variety of fuels into hydrogen-rich gas. Another advantage of use of onboard plasmatron generation of hydrogen is that it could be used only when required and could be readily turned on and off. Preliminary experimental studies of plasmatron conversion of difficult-to-use alternative fuels (biofuels), iso-octane (representative of gasoline), and diesel fuel are described. Concepts for application to trucks and other heavy duty vehicles, sport utility vehicles and automobiles are discussed.     

Effects of hydrogenation of fossil fuels with hydrogen and hydroxy gas on performance and emissions of internal combustion engines

Energy security is an important consideration for development of future transport fuels. Among the all gaseous fuels hydrogen or hydroxy (HHO) gas is considered to be one of the clean alternative fuels. Hydrogen is very flammable gas and storing and transporting of hydrogen gas safely is very difficult. Today, vehicles using pure hydrogen as fuel require stations with compressed or liquefied hydrogen stocks at high pressures from hydrogen production centres established with large investments.Different electrode design and different electrolytes have been tested to find the best electrode design and electrolyte for higher amount of HHO production using same electric energy. HHO is used as an additional fuel without storage tanks in the four strokes, 4-cylinder compression ignition engine and two-stroke, one-cylinder spark ignition engine without any structural changes. Later, previously developed commercially available dry cell HHO reactor used as a fuel additive to neat diesel fuel and biodiesel fuel mixtures. HHO gas is used to hydrogenate the compressed natural gas (CNG) and different amounts of HHO-CNG fuel mixtures are used in a pilot injection CI engine. Pure diesel fuel and diesel fuel + biodiesel mixtures with different volumetric flow rates are also used as pilot injection fuel in the test engine. The effects of HHO enrichment on engine performance and emissions in compression-ignition and spark-ignition engines have been examined in detail. It is found from the experiments that plate type reactor with NaOH produced more HHO gas with the same amount of catalyst and electric energy. All experimental results from Gasoline and Diesel Engines show that performance and exhaust emission values have improved with hydroxy gas addition to the fossil fuels except NO_x exhaust emissions. The maximum average improvements in terms of performance and emissions of the gasoline and the diesel engine are both graphically and numerically expressed in results and discussions. The maximum average improvements obtained for brake power, brake torque and BSFC values of the gasoline engine were 27%, 32.4% and 16.3%, respectively. Furthermore, maximum improvements in performance data obtained with the use of HHO enriched biodiesel fuel mixture in diesel engine were 8.31% for brake power, 7.1% for brake torque and 10% for BSFC.     

Future fuels and mixture preparation methods for spark ignition automobile engines

Research in the automobile industry focuses on studies of spark ignition automobile engines especially of stratified charge engines, lean combustion concepts, engines fueled by alcohol/gasoline blends, alcohol engines, and engines with on-board gas generators fueled by a variety of liquid fuels. The goal of this work is the development of low-emission, high fuel-economy and high performance power systems for the early 1990s. The implementation of this objective makes it necessary for more information on future fuel characteristics. In addition proper mixture preparation methods must be applied to find solutions to specific problems such as NO_x formation and aldehyde emission, while maintaining good fuel economy and high engine efficiency. The goal of this paper is to discuss the most attractive approaches for improved preparation and distribution of the fuel-air mixture with respect to future fuels such as alcohol/gasoline blends and other alcohol fuels.     

Combustion performance and emission reduction characteristics of automotive DME engine system

This article is a condensed overview of a dimethyl ether (DME) fuel application for a compression ignition diesel engine. In this review article, the spray, atomization, combustion and exhaust emissions characteristics from a DME-fueled engine are described, as well as the fundamental fuel properties including the vapor pressure, kinematic viscosity, cetane number, and the bulk modulus. DME fuel exists as gas phase at atmospheric state and it must be pressurized to supply the liquid DME to fuel injection system. In addition, DME-fueled engine needs the modification of fuel supply and injection system because the low viscosity of DME caused the leakage. Different fuel properties such as low density, viscosity and higher vapor pressure compared to diesel fuel induced the shorter spray tip penetration, wider cone angle, and smaller droplet size than diesel fuel. The ignition of DME fuel in combustion chamber starts in advance compared to diesel or biodiesel fueled compression ignition engine due to higher cetane number than diesel and biodiesel fuels. In addition, DME combustion is soot-free since it has no carbon–carbon bonds, and has lower HC and CO emissions than that of diesel combustion. The NO_x emission from DME-fueled combustion can be reduced by the application of EGR (exhaust gas recirculation). This article also describes various technologies to reduce NO_x emission from DME-fueled engines, such as the multiple injection strategy and premixed combustion. Finally, the development trends of DME-fueled vehicle are described with various experimental results and discussion for fuel properties, spray atomization characteristics, combustion performance, and exhaust emissions characteristics of DME fuel.     

Comparative engine performance and emission analysis of CNG and gasoline in a retrofitted car engine

A comparative analysis is being performed of the engine performance and exhaust emission on a gasoline and compressed natural gas (CNG) fueled retrofitted spark ignition car engine. A new 1.6 L, 4-cylinder petrol engine was converted to the computer incorporated bi-fuel system which operated with either gasoline or CNG using an electronically controlled solenoid actuated valve mechanism. The engine brake power, brake specific fuel consumption, brake thermal efficiency, exhaust gas temperature and exhaust emissions (unburnt hydrocarbon, carbon mono-oxide, oxygen and carbon dioxides) were measured over a range of speed variations at 50% and 80% throttle positions through a computer based data acquisition and control system. Comparative analysis of the experimental results showed 19.25% and 10.86% reduction in brake power and 15.96% and 14.68% reduction in brake specific fuel consumption (BSFC) at 50% and 80% throttle positions respectively while the engine was fueled with CNG compared to that with the gasoline. Whereas, the retrofitted engine produced 1.6% higher brake thermal efficiency and 24.21% higher exhaust gas temperature at 80% throttle had produced an average of 40.84% higher NO_x emission over the speed range of 1500–5500 rpm at 80% throttle. Other emission contents (unburnt HC, CO, O₂ and CO₂) were significantly lower than those of the gasoline emissions.     

在汽油机上实施HCCI的技术策略

均质混合气压燃(HCCI)燃烧方式，是一种克服常规柴油机和汽油机缺点、集常规汽油机和柴油机优点于一体的新概念燃烧。本文分析了汽油机实施HCCI的可行性，介绍了HCCI发动机实用化所面临的问题，提出了双工作模式的折衷方案：在中低负荷工况实施HCCI，而在大负荷工况和冷起动工况恢复常规发动机工作方式。推荐可变压缩比(VCR)方案、可变废气再循环率(EGR)方案、可变排气门关闭时刻方案，以及废气再循环滚流分层充气方案等。为尽快在汽油机上实施HCCI燃烧方式指出了技术方向。     

Investigation of a hydrogen-assisted combustion system for a light-duty diesel vehicle

Two sets of experiments were conducted to investigate the effects of adding gaseous hydrogen to the intake of compression–ignition (CI) engines fueled with 20% bio-derived/80% petroleum-derived diesel fuel (B20). A 1.3 L, 53 kW CI engine coupled to an eddy-current engine dynamometer was tested first. Data were collected on engine operating parameters, fuel consumption, concentration of total oxides of nitrogen (NO_x) in the exhaust, and exhaust temperature. Eight steady-state operating points were tested with hydrogen flow rates equivalent to 0%, 5%, and 10% of the total fuel energy. In a second set of experiments, the stock gasoline engine of a 2005 Chevrolet Equinox was replaced with a 1.3 L, 66 kW CI engine, and urban drive cycles were run on a chassis dynamometer. The drive cycles were repeated with 0%, 5% and 10% of the fuel energy coming from the fumigated hydrogen. In both experiments, the addition of hydrogen did not result in discernable differences in engine efficiency. In the vehicle testing, there were no noticeable differences in drivability. There were modest reductions in NO_x emissions and increases in exhaust temperature with hydrogen addition. This investigation demonstrates that fumigating relatively small amounts of hydrogen into the intake of a modern diesel engine results in only modest changes in combustion efficiency and emissions with no detrimental effects on vehicle performance or drivability. This strategy can be used to partially offset the use of petroleum-based fuels in light-duty transportation vehicles.     

A review of ammonia as a compression ignition engine fuel

During the past decades, the diesel engine has been through times of upheaval, boom and bust. At the beginning of the century, almost 50% of the new vehicle registrations in the European market were diesel-powered. However, the news of deadly diesel NO_x emissions supported by the diesel emission scandals caused a shock to the diesel engine market, and the sustainability of the diesel engine is currently in dispute.Recently major automotive manufacturers announced the development of diesel-powered vehicles with negligible NO_x emissions. Moreover, the NO_x emissions production is of lower concern for heavy-duty, marine or power generations applications where the implementation of advanced aftertreatment systems is feasible. However, despite the tackle of NO_x emissions, the decarbonisation of the automotive, marine and power generation markets is mandatory for meeting greenhouse gas emissions targets and limiting global warming.The decarbonisation of the diesel engine can be achieved by the implementation of a carbon-free fuel such as ammonia. This paper provides a detailed overview of ammonia as a fuel for compression ignition engines. Ammonia can be combusted with diesel or any other lower autoignition temperature fuel in dual-fuel mode and lead to a significant reduction of carbon-based emissions. The development of advanced injection strategies can contribute to enhanced performance and overall emissions improvement. However, ammonia dual-fuel combustion currently suffers from relatively high unburned ammonia and NO_x emissions because of the fuel-bound nitrogen. Therefore, the implementation of aftertreatment systems is required. Hence, ammonia as a compression ignition fuel can be currently seen as a feasible solution only for marine, power generation and possibly heavy-duty applications where no significant space constraints exist.     

Comparison between direct and indirect (prechamber) spark ignition in the case of a cogeneration natural gas engine,: part II: engine operating parameters and turbocharger characteristics

In the first paper (part I), prechamber ignition in cogeneration natural gas engines has been shown to significantly intensify and accelerate the combustion process, offering a further potential to reduce the exhaust gas emissions while keeping efficiency at a high level. This second part discusses the influence of the engine operating parameters (spark timing and load) and the turbocharger characteristics with the objective of evaluating the potential to reduce the exhaust gas emissions, particularly the CO emissions, below the Swiss limits (NO_X and CO emissions: 250 and 650 mg/m_N³, 5% O₂, respectively), without exhaust gas after treatment. The advantage of using an unscavenged prechamber is conditioned by a significant delay of the spark timing in order to generate substantial gas jets. This results in a large decrease in peak cylinder pressure and in an important reduction of NO_X, CO and THC emissions. Minimum emissions are achieved at a spark timing of about 8° CA_BTDC. In comparison with the direct ignition, the prechamber ignition yields approximately 40% and 55% less CO and THC emissions, respectively. However, this also leads to about 2%-point lower fuel conversion efficiency. The optimisation of the turbocharger results in a recovery of about 1%-point in fuel conversion efficiency, but a consequent change in the exhaust manifold gas dynamics attenuates the reduction in THC emissions. At the rated power output (150 kW), the prechamber ignition operation fulfils the Swiss requirements for exhaust gas emissions and still achieves a fuel conversion efficiency higher than 36.5%.     

Parallel induction: a simple fuel control method for hydrogen engines

A simple, low-pressure fuel control system for hydrogen engines is explained. Data are provided showing the performance of the system on two hydrogen engines, a Mitsubishi 2.4-1, spark-ignition engine in a bus and a Caterpillar 7-l. diesel from a mining vehicle converted to spark ignition. Both engines were turbocharged with aftercooling and utilize excess combustion air to limit NO_x emissions.     

Combustion and emission characteristics of a two-stroke diesel engine operating on alcohol

Though, as a renewable energy resource, alcohol fuel has many advantages in China, it is difficult for diesel engines to operate on alcohol due to its low cetane number and high latent heat of vaporization. This paper proposes an approach to its ignition problem by combining internal exhaust gas recirculation (EGR) with injection of small diesel fuel. Based on this approach, a two-stroke single-cylinder diesel engine was developed. Preliminary studies demonstrated that the engine can run on alcohol with almost zero level of smoke and low exhaust gas temperature, and that the engine operating on alcohol has lower nitrogen oxide (NO_x) emissions and 2–3% higher effective thermal efficiency than that operating on diesel fuel in moderate and high load zones.     

Natural-gas fueled spark-ignition (SI) and compression-ignition (CI) engine performance and emissions

Natural gas is a fossil fuel that has been used and investigated extensively for use in spark-ignition (SI) and compression-ignition (CI) engines. Compared with conventional gasoline engines, SI engines using natural gas can run at higher compression ratios, thus producing higher thermal efficiencies but also increased nitrogen oxide (NO_x) emissions, while producing lower emissions of carbon dioxide (CO₂), unburned hydrocarbons (HC) and carbon monoxide (CO). These engines also produce relatively less power than gasoline-fueled engines because of the convergence of one or more of three factors: a reduction in volumetric efficiency due to natural-gas injection in the intake manifold; the lower stoichiometric fuel/air ratio of natural gas compared to gasoline; and the lower equivalence ratio at which these engines may be run in order to reduce NO_x emissions. High NO_x emissions, especially at high loads, reduce with exhaust gas recirculation (EGR). However, EGR rates above a maximum value result in misfire and erratic engine operation. Hydrogen gas addition increases this EGR threshold significantly. In addition, hydrogen increases the flame speed of the natural gas-hydrogen mixture. Power levels can be increased with supercharging or turbocharging and intercooling. Natural gas is used to power CI engines via the dual-fuel mode, where a high-cetane fuel is injected along with the natural gas in order to provide a source of ignition for the charge. Thermal efficiency levels compared with normal diesel-fueled CI-engine operation are generally maintained with dual-fuel operation, and smoke levels are reduced significantly. At the same time, lower NO_x and CO₂ emissions, as well as higher HC and CO emissions compared with normal CI-engine operation at low and intermediate loads are recorded. These trends are caused by the low charge temperature and increased ignition delay, resulting in low combustion temperatures. Another factor is insufficient penetration and distribution of the pilot fuel in the charge, resulting in a lack of ignition centers. EGR admission at low and intermediate loads increases combustion temperatures, lowering unburned HC and CO emissions. Larger pilot fuel quantities at these load levels and hydrogen gas addition can also help increase combustion efficiency. Power output is lower at certain conditions than diesel-fueled engines, for reasons similar to those affecting power output of SI engines. In both cases the power output can be maintained with direct injection. Overall, natural gas can be used in both engine types; however further refinement and optimization of engines and fuel-injection systems is needed.     

Synthesis gas generation on-board a vehicle: Development and results of testing

The present work is focused on the development of energy-efficient internal combustion engines with minimized CO, CO₂, CH and NO_x emissions. In frame of this concept, a method for hydrogen-rich gas generation onboard a vehicle and, in particular, its application as an additive to the engine fuel was suggested and tested experimentally. For practical realization of the method, the catalysts for hydrocarbon fuel reforming to synthesis gas were created, compact under-hood mounted synthesis gas generator was designed, and integrated ICE-synthesis gas generator control system was developed. The tests proved fuel economy in city cycle and considerable decrease of CO, CO₂, CH and NO_x emissions. The prospects of the technology for the development of energy-efficient environmentally benign engines are analyzed.     

Determination of ecological efficiency in internal combustion engines: The use of biodiesel

This paper evaluates and quantifies the environmental impact from the use of some renewable fuels and fossils fuels in internal combustion engines. The following fuels are evaluated: gasoline blended with anhydrous ethyl alcohol (anhydrous ethanol), conventional diesel fuel, biodiesel in pure form and blended with diesel fuel, and natural gas. For the case of biodiesel, its complete life cycle and the closed carbon cycle (photosynthesis) were considered. The ecological efficiency concept depends on the environmental impact caused by CO₂, SO₂, NO_x and particulate material (PM) emissions. The exhaust gases from internal combustion engines, in the case of the gasoline (blended with alcohol), biodiesel and biodiesel blended with conventional diesel, are the less polluting; on the other hand, the most polluting are those related to conventional diesel. They can cause serious problems to the environment because of their dangerous components for the human, animal and vegetable life. The resultant pollution of each one of the mentioned fuels are analyzed, considering separately CO₂, SO₂, NO_x and particulate material (PM) emissions. As conclusion, it is possible to calculate an environmental factor that represents, qualitatively and quantitative, the emissions in internal combustion engines that are mostly used in urban transport. Biodiesel in pure form (B100) and blended with conventional diesel as fuel for engines pollute less than conventional diesel fuel. The ecological efficiency for pure biodiesel (B100) is 86.75%; for biodiesel blended with conventional diesel fuel (B20, 20% biodiesel and 80% diesel), it is 78.79%. Finally, the ecological efficiency for conventional diesel, when used in engines, is 77.34%; for gasoline, it is 82.52%, and for natural gas, it is 91.95%. All these figures considered a thermal efficiency of 30% for the internal combustion engine.     

Influence of operating parameters on performance and emissions for a compression-ignition engine fueled by hydrogen/diesel mixtures

Hydrocarbon exhaust emissions are mainly recognized as a consequent of carbon-based fuel combustion in compression ignition (CI) engines. Alternative fuels can be coupled with hydrocarbon fuels to control the pollutant emissions and improve the engine performance. In this study, different parameters that influence the engine performance and emissions are illustrated with more details. This numerical work was carried out on a dual-fuel CI engine to study its performance and emission characteristics at different hydrogen energy ratios. The simulation model was run with diesel as injected fuel and hydrogen, along with air, as inducted fuel. Three-dimensional CFD software for numerical simulations was implemented to simulate the direct-injection CI engine. A reduced-reaction mechanism for n-heptane was considered in this work instead of diesel. The Hiroyasu-Nagel model was presented to examine the rate of soot formation inside the cylinder. This work investigates the effect of hydrogen variation on output efficiency, ignition delay, and emissions. More hydrogen present inside the engine cylinder led to lower soot emissions, higher thermal efficiency, and higher NO_x emissions. Ignition timing delayed as the hydrogen rate increased, due to a delay in OH radical formation. Strategies such as an exhaust gas recirculation (EGR) method and diesel injection timing were considered as well, due to their potential effects on the engine outputs. The relationship among the engine outputs and the operation conditions were also considered.     

The effect of clove oil and diesel fuel blends on the engine performance and exhaust emissions of a compression-ignition engine

Diesel engines provide the major power source for transportation in the world and contribute to the prosperity of the worldwide economy. However, recent concerns over the environment, increasing fuel prices and the scarcity of fuel supplies have promoted considerable interest in searching for alternatives to petroleum based fuels. Based on this background, the main purpose of this investigation is to evaluate clove stem oil (CSO) as an alternative fuel for diesel engines. To this end, an experimental investigation was performed on a four-stroke, four-cylinder water-cooled direct injection diesel engine to study the performance and emissions of an engine operated using the CSO–diesel blended fuels. The effects of the CSO–diesel blended fuels on the engine brake thermal efficiency, brake specific fuel consumption (BSFC), specific energy consumption (SEC), exhaust gas temperatures and exhaust emissions were investigated. The experimental results reveal that the engine brake thermal efficiency and BSFC of the CSO–diesel blended fuels were higher than the pure diesel fuel while at the same time they exhibited a lower SEC than the latter over the entire engine load range. The variations in exhaust gas temperatures between the tested fuels were significant only at medium speed operating conditions. Furthermore, the HC emissions were lower for the CSO–diesel blended fuels than the pure diesel fuel whereas the NO_x emissions were increased remarkably when the engine was fuelled with the 50% CSO–diesel blended fuel.     

Experimental study of the performances of a modified diesel engine operating in homogeneous charge compression ignition (HCCI) combustion mode versus the original diesel combustion mode

Homogeneous charge compression ignition (HCCI) combustion mode provides very low NO_x and soot emissions; however, it has some challenges associated with hydrocarbon (HC) emissions, fuel consumption, difficult control of start of ignition and bad behaviour to high loads. Cooled exhaust gas recirculation (EGR) is a common way to control in-cylinder NO_x production in diesel and HCCI combustion mode. However EGR has different effects on combustion and emissions, which are difficult to distinguish. This work is intended to characterize an engine that has been modified from the base diesel engine (FL1 906 DEUTZ-DITER) to work in HCCI combustion mode. It shows the experimental results for the modified diesel engine in HCCI combustion mode fueled with commercial diesel fuel compared to the diesel engine mode. An experimental installation, in conjunction with systematic tests to determine the optimum crank angle of fuel injection, has been used to measure the evolution of the cylinder pressure and to get an estimate of the heat release rate from a single-zone numerical model. From these the angle of start of combustion has been obtained. The performances and emissions of HC, CO and the huge reduction of NO_x and smoke emissions of the engine are presented. These results have allowed a deeper analysis of the effects of external EGR on the HCCI operation mode, on some engine design parameters and also on NO_x emission reduction.