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1.
Microstructure and properties of carbon fiber sized with pickering emulsion based on graphene oxide sheets and its composite with epoxy resin
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The Graphene oxide (GO) sheets were used for preparing the epoxy resin Pickering emulsion. The particle size and the zeta potential of the Pickering emulsion were measured to evaluate its stability. The stable emulsion could be served as the film former of sizing agent for carbon fiber (CF). The effect of the Pickering emulsion stabilized by GO sheets on the properties of CF and the interfacial adhesion property of CF reinforced composite were investigated. Scanning electron microscopy (SEM) images showed that there existed a layer of sizing agent film with GO sheets evenly on the CF surface. Abrasion resistance and stiffness values of CF were tested and the results indicated that the sized CF conformed to the requirement of CF handleability. The interlaminar shear strength (ILSS) test indicated that the interfacial adhesion of the composite could be greatly improved. The fracture surfaces of CF composites were examined by SEM after ILSS tests. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42285. 相似文献
2.
Eslam Elkalla Chariya Kaewsaneha Abdelhamid Elaissari 《Polymer Engineering and Science》2019,59(Z1):E195-E199
The aim of this work is to present a facile Pickering emulsion polymerization method for the synthesis of submicron polystyrene/SiO2 core/shell composite particles. The commercial hydrophobic SiO2 nanoparticles were used as stabilizing agent for creating a stable oil‐in‐water emulsion. Although the adsorption of hydrophobic SiO2 nanoparticles in the emulsion system was unfavorable in terms of thermodynamics, by ultrasound treatment, self‐assembly of hydrophobic SiO2 nanoparticles effectively stabilized oil‐in‐water Pickering emulsions during polymerization. Using 3 wt.% SiO2 nanoparticles (based on styrene monomer) and 1:10 volume ratio of styrene monomer:water, the composite particles having average size of 790 nm and relatively narrow particles distribution were produced. With decreasing the volume ratio, smaller composite particles were created. Results from scanning electron microscope revealed that SiO2 nanoparticles were located exclusively at the surface of the polystyrene latex particles. The SiO2 content, determined by thermogravimetric analysis, was 12.6 wt.% in the composite particles. The route reported here may be used for the preparation of other composite nanostructures. POLYM. ENG. SCI., 59:E195–E199, 2019. © 2018 Society of Plastics Engineers 相似文献
3.
The influences of nano‐particles (nano‐sized CaCO3 and nano‐sized SiO2) on plasticizers volatility, solvent extraction stability, and exudation stability of flexible PVC were studied. The results showed that nano‐particles could reduce migration of plasticizers, thus improved the ability of anti‐migration of flexible PVC. Further more, nano‐sized SiO2 shows excellent property than nano‐sized CaCO3 in resistance migration of plasticizers. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
4.
To improve the interfacial adhesion between carbon fiber (CF) and poly(acrylonitrile‐butadiene‐styrene) (ABS) thermoplastic, an emulsion sizing whose film former was a terpolymer N‐phenylmaleimide‐styrene‐maleic anhydride (NSM)/ABS mixture was prepared. NSM, an efficient heat‐resistant modifier for ABS, could make the film former possess a superior heat resistance, which helped the sizing layer maintain integrity during the preparation of CF/ABS composite. Moreover, differential scanning calorimetry (DSC) results demonstrated that the glass transition temperature (Tg) of the NSM modified ABS achieved an improvement of 25.3°C. Particle size and distribution of the sizing agent were investigated to evaluate its stability. The FTIR spectrum obtained demonstrated that the chemical compositions of the sized CF got greatly changed and numerous functional groups appeared on sized CF. Abrasion resistance and fluffs of CF were tested and the results indicated that the sized CF obtained an appreciable enhancement in handleability. Interlaminar shear strength (ILSS) results revealed, after sizing, that the ILSS enhanced by 26.6%, due to the inserted sizing layer between CF and ABS matrix. POLYM. COMPOS., 37:2940–2949, 2016. © 2015 Society of Plastics Engineers 相似文献
5.
Nanosilica/polyarylene ether nitriles terminated with phthalonitrile (SiO2/PEN‐t‐Ph) composites were prepared by hot‐press approach. To ensure the nano‐SiO2 can disperse uniformly, the solution casting method combined with ultrasonic dispersion technology had been taken previously. The mass fraction of nano‐SiO2 particles was varied to investigate their effect on the thermal, mechanical, and dielectric properties of the nanocomposites. From scanning electron microscope images, it was found that the nanoSiO2 particles were dispersed uniformly in the PEN‐t‐Ph matrix when the addition of nano‐SiO2 was less than 16.0 wt%. However, when the mass fraction of nano‐SiO2 increased to 20.0 wt%, the nano‐SiO2 particles tend to self‐aggregate and form microns sized particles. Thermal studies revealed that nano‐SiO2 particles did not weaken the thermal stabilities of the PEN‐t‐Ph matrix. Mechanical investigation manifested that the SiO2/PEN‐t‐Ph nanocomposites with 12.0 wt% nano‐SiO2 loading showed the best mechanical performance with tensile strength of 108.2 MPa and tensile modulus of 2107.5 Mpa, increasing by 14% and 19%, respectively as compared with the pure PEN‐t‐Ph film. Dielectric measurement showed that the dielectric constant increased from 3.70 to 4.15 when the nano‐SiO2 particles varied from 0.0 to 20.0 wt% at 1 kHz. Therefore, such composite was a good candidate for high performance materials at elevated temperature environment. POLYM. COMPOS., 35:344–350, 2014. © 2013 Society of Plastics Engineers 相似文献
6.
Nano‐SiO2/PMMA‐PU composite particles with core‐shell structure via emulsion polymerization and their application in epoxy resin
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A novel method of nano‐SiO2/poly(methyl methacrylate)(PMMA)‐polyurethane(PU) composite particles modifying epoxy resin is reported. The composite particles with the obvious core‐shell structure were prepared by emulsion polymerization of PMMA and PU prepolymer on the surface of nano‐SiO2. The diameter of the composite particles was 50–100 nm with dark core SiO2 (30–60 nm) and light shell polymer of PMMA and PU (20–30 nm); moreover, PU was well distributed in PMMA with about 10 nm diameter. After nano‐SiO2 was encapsulated by PMMA and PU, the Si content on the surface decreased rapidly to 2.08% and the N content introduced by PU was about 1.27%. The ratio of polymer to original nano‐SiO2 (fp), the grafting ratio of polymer to original nano‐SiO2 (fr) and the efficiency grafting ratio of polymer (fe) were, respectively, about 116.7%, 104.4%, and 89.5%. The as‐prepared composite particles were an effective toughness agent to modify epoxy resin, and the impact strength of the modified epoxy resin increased to 46.64 kJ m?2 from 19.12 kJ m?2 of the neat epoxy resin. This research may enrich the field of inorganic nanoparticles with important advances toward the modification for polymer composite materials. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41919. 相似文献
7.
A core–shell nanosilica (nano‐SiO2)/fluorinated acrylic copolymer latex, where nano‐SiO2 served as the core and a copolymer of butyl acrylate, methyl methacrylate, and 2,2,2‐trifluoroethyl methacrylate (TFEMA) served as the shell, was synthesized in this study by seed emulsion polymerization. The compatibility between the core and shell was enhanced by the introduction of vinyl trimethoxysilane on the surface of nano‐SiO2. The morphology and particle size of the nano‐SiO2/poly(methyl methacrylate–butyl acrylate–2,2,2‐trifluoroethyl methacrylate) [P(MMA–BA–TFEMA)] core–shell latex were characterized by transmission electron microscopy. The properties and surface energy of films formed by the nano‐SiO2/P(MMA–BA–TFEMA) latex were analyzed by Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy/energy‐dispersive X‐ray spectroscopy, and static contact angle measurement. The analyzed results indicate that the nano‐SiO2/P(MMA–BA–TFEMA) latex presented uniform spherical core–shell particles about 45 nm in diameter. Favorable characteristics in the latex film and the lowest surface energy were obtained with 30 wt % TFEMA; this was due to the optimal migration of fluorine to the surface during film formation. The mechanical properties of the films were significantly improved by 1.0–1.5 wt % modified nano‐SiO2. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
8.
A styrene‐acrylic/SiO2 nanoparticle composite emulsion was prepared by using SiO2 nanoparticles as seeds. The effect of factors such as the level of nano‐SiO2, reaction temperature and ultrasound treatment of nano‐SiO2 on the stability of the polymerization reaction was investigated. Water‐resistance of the emulsion was measured. The level of nano‐SiO2 in the emulsion was determined by inductively coupled plasma (ICP) spectrometry. The particle morphology of the emulsion with nano‐SiO2 was observed with transmission electron microscopy (TEM). The kinetics of the polymerization was also studied at various temperatures and various levels of nano‐SiO2. They showed that the level of nano‐SiO2 and reaction temperature had a great influence on the monomer conversion, particle size, coagulum content and viscosity of the emulsion. Nano‐SiO2 treated by ultrasonics can increase the coagulum content greatly, but it does not improve the water resistance of the emulsion. The level of nano‐SiO2 in the emulsion was lower than the theoretical value. The reaction kinetics indicated that the level of nano‐SiO2 had less influence on the reaction rate than the reaction temperature. Even a small amount of nano‐SiO2 can decrease the reaction rate. Copyright © 2004 Society of Chemical Industry 相似文献
9.
A series of the surface‐functionalized nano‐SiO2/polybenzoxazine (PBOZ) composites was produced, and an attempt was made to improve the toughness of PBOZ material, without sacrificing other mechanical and thermal properties. A benzoxazine functional silane coupling agent was synthesized to modify the surface of nano‐SiO2 particles, which were then mixed with benzoxazine monomers to produce the nano‐SiO2‐PBOZ nanocomposites. The notched impact strength and the bending strength of the nano‐SiO2‐PBOZ nanocomposites increase 40% and 50%, respectively, only with the addition of 3 wt % nano‐SiO2. At the same load of nano‐SiO2, the nano‐SiO2‐PBOZ nanocomposites exhibit the highest storage modulus and glass‐transition temperature by dynamic viscoelastic analysis. Moreover, the thermal stability of the SiO2/PBOZ nanocomposites was enhanced, as explored by the thermogravimetric analysis. The 5% weight loss temperatures increased with the nano‐SiO2 content and were from 368°C (of the neat PBOZ) to 379°C or 405°C (of the neat PBOZ) to 426°C in air or nitrogen with additional 3 wt % nano‐SiO2. The weight residue of the same nanocomposite was as high as 50% in nitrogen at 800°C. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
10.
Pickering emulsion polymerization has attracted considerable attention in material fabrication due to its unique surfactant-free
character and versatile association of oil, water and particles for a large set of materials. In this study, SiO2 modified with Methacryloxypropyltrimethoxysilane (MPTMS) was employed to prepare Pickering emulsion, and subsequently covalently-bonded
polystyrene/SiO2(PS/SiO2) composites were synthesized by Oil-in-water Pickering emulsion polymerization. Optical micrograph, contact angle, thermogravimetric
analysis (TGA), Fourier transform infrared spectra (FT-IR), scanning electron microscope (SEM) and dynamic laser scattering
(DLS) were employed to characterize the modified SiO2, Pickering emulsion and prepared composites. It was found that prepared composites possess ragged surface morphology and
SiO2 concentration has an important effect on the morphology of as-prepared composites. In addition, covalent bond between PS
core and SiO2 shell was evidenced by FT-IR. 相似文献
11.
This article aims to study the effect of the sizing materials type on the mechanical, thermal, and morphological properties of carbon fiber (CF)‐reinforced polyamide 6,6 (PA 6,6) composites. For this purpose, unsized CF and sized CFs were used. Thermogravimetric analysis was performed, and it has been found that certain amounts of polyurethane (PU) and PA sizing agents decompose during processing. The effects of sizing agent type on the mechanical and thermomechanical properties of all the composites were investigated using tensile, Izod impact strength test, and dynamic mechanical analysis. Tensile strength values of sized CF‐reinforced composites were higher than that of unsized CF‐reinforced composites. PA and polyurethane sized CF‐reinforced composites exhibited the highest impact strength values among the other sized CF‐reinforced composites. PU and PA sized CF‐reinforced composites denoted higher storage modulus and better interfacial adhesion values among the other sizing materials. Scanning electron microscope studies indicated that CFs which were sized with PU and PA have better interfacial bonding with PA 6,6 matrix among the sized CFs. All the results confirmed that PA and PU were suitable for CF's sizing materials to be used for PA 6,6 matrix. POLYM. COMPOS., 34:1583–1590, 2013. © 2013 Society of Plastics Engineers 相似文献
12.
A kind of hydrophilic nano‐SiO2 was applied to poly(ethylene terephthalate)/polyamide‐6 (PA‐6) blends. Melt‐blended composites were prepared at various component ratios and different nano‐SiO2 levels. Mechanical, morphological, dynamic mechanical, and thermal tests were carried out to characterize the properties, morphology, and compatibilization of the composites. Increased impact strength, tensile strength, and modulus were observed by adding nano‐SiO2 particles in the blends. The nano‐SiO2 particles were found to be preferentially dispersed in PA‐6, resulting in an increase of glass transition temperature and crystallization of PA‐6. The mechanism of morphology and properties changes was discussed based on the selective dispersion of nano‐SiO2 particles in the blends. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2288–2296, 2007 相似文献
13.
Nowadays, solvent‐free, one‐part cyanoacrylate adhesive is widely used in medicine and dentistry. According to a literature survey done by the authors, there are few papers concentrated on the role of nano‐sized particles on the thermal behavior of cyanoacrylate glue. Thus the main goal of the current research focused on clarifying the role of nano‐sized SiO2 on the thermal behavior of cyanoacrylate. Thermal behavior of all materials including cyanoacrylate and its nanocomposites was studied by using Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) methods. The results of DSC analysis showed that an increase in the amount of nano‐sized SiO2 results in decreases in the duration of cyanoacrylate curing, energy release during polymerization, and incubation time of polymerization. Furthermore, the results of TGA tests illustrated that the weight loss of cyanoacrylate strongly depends on the contents of both caffeine and SiO2. In fact, an increase in nano‐sized SiO2 content increases the degradation temperature of cyanoacrylate. J. VINYL ADDIT. TECHNOL., 2010. © 2010 Society of Plastics Engineers 相似文献
14.
Ternary composites of polypropylene (PP), polydimethylsiloxane (PDMS) elastomer, and nano‐SiO2, prepared with three different mixing sequences, were studied for dispersion morphology and its effect on the crystallization of PP and the mechanical properties. The mixing sequence produced a significant effect on the dispersion morphology and, thereby, on the mechanical properties of the composites. A two‐step mixing sequence, in which nano‐SiO2 was added in the second step to the PP/PDMS binary system, produced a significant encapsulation of nano‐SiO2 by PDMS, and this, in turn, resulted in the poor modulus and impact strength of the composite. A one‐step mixing sequence of all three components produced a separated dispersion of PDMS and nano‐SiO2 phases in the PP matrix with the occurrence of a fine band of nano‐SiO2 particles at the boundaries of the PDMS domains and the presence of some nano‐SiO2 filler particles inside the PDMS domains. This one‐step mixing sequence produced an improvement in the tensile modulus but a decrease in the impact strength with increasing nano‐SiO2 content. In the third sequence of mixing, which involved a two‐step mixing sequence through the addition of PDMS in the second step to the previously prepared PP/nano‐SiO2 binary system, the morphology of the dispersion showed separately dispersed PDMS and nano‐SiO2 phases with a loose network of nano‐SiO2 particles surrounding the PDMS domains. This latter series of ternary composites had the highest impact strength and exhibited high shear deformation under tensile and impact conditions. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
15.
The purpose of this study was to improve the physical properties and to expand the application range of starch‐based blend films added nano‐sized TiO2/poly(methyl methacrylate‐co‐acrylamide) (PMMA‐co‐AM). Starch‐based blend films were prepared by using corn starch, polyvinyl alcohol (PVA), nano‐sized PMMA‐co‐AM, nano‐sized TiO2/PMMA‐co‐AM particles, and additives, i.e., glycerol (GL) and citric acid (CA). Nano‐sized PMMA‐co‐AM was synthesized by emulsion polymerization and TiO2 nanoparticles were also prepared by using sol–gel method. Nano‐sized TiO2/PMMA‐co‐AM particles were synthesized by wet milling for 48 h. The morphology and crystallinity of TiO2, nano‐sized PMMA‐co‐AM and TiO2/PMMA‐co‐AM particles were investigated by using the scanning electron microscope (SEM) and X‐ray diffractometer (XRD). In addition, the functional groups of the TiO2/PMMA‐co‐AM particles were characterized by IR spectrophotometry (FTIR). The physical properties such as tensile strength (TS), elongation at break (%E), degree of swelling (DS), and solubility (S) of starch‐based films were evaluated. It was found that the adding of nano‐sized particles can greatly improve the physical properties of the prepared films. The photocatalytic degradability of starch/PVA/nano‐sized TiO2/PMMA‐co‐AM composite films was evaluated using methylene blue (MB) and acetaldehyde (ATA) as photodegradation target under UV and visible light. The degree of decomposition (C/C0) of MB and ATA for the films containing TiO2 and CA was 0.506 and 0.088 under UV light irradiation and 0.586 (MB) and 0.631 (ATA) under visible light irradiation, respectively. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
16.
Study on the preparation and thermal shrinkage properties of nano‐SiO2/UHMWPE/HDPE blend microporous membranes
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Nano‐SiO2/UHMWPE/HDPE blend microporous membranes (NBMs) with different content of nano‐SiO2 particles were prepared via thermally induced phase separation process. Thermogravimetric analysis was used to investigation of the amount of nano‐SiO2 particles reserved in NBMs. This approach showed that about 59% of total content of nano‐SiO2 particles reserved in NBMs. The formation and development of the interface pores were studied by scanning electron microscopy. NBMs performance was characterized by a variety of metrics including thermal shrinkage, melting and crystallization behavior, porosity and pore diameter, and permeability. The results indicated that nano‐SiO2 particles served as nucleating agent increasing the crystalline of NBMs. The comprehensive properties of NBMs were optimum when the content of nano‐SiO2 particles was 1%. Compared with pure HDPE separators, NBMs exhibit higher porosity and lower thermal shrinkage due to its high crystalline and the enrichment of UHMWPE chains. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41321. 相似文献
17.
Improved interfacial adhesion in carbon fiber/epoxy composites through a waterborne epoxy resin sizing agent
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A series of self‐emulsified waterborne epoxy resin (WEP) emulsions were used as surface sizing for carbon fibers (CFs) to improve the interfacial adhesion between the CF and epoxy matrix. In this work, the hydrogenated bisphenol‐A epoxy resin (HBPAE) was modified by polyethylene glycol (PEG) with molecular weights of 400, 800, 1000, 1500, 2000, 4000, and 6000 g/mol. The properties of the WEP emulsion were examined by Fourier transform infrared spectroscopy, dynamic light scattering, and transmission electron microscopy. The surface characteristics of sized CFs were evaluated using scanning electron microscopy, atomic force microscopy, and X‐ray photoelectron spectroscopy. Afterwards, CF/EP composites were prepared and their fracture surface and interlaminar shear strength (ILSS) were examined. The results indicated that PEG2000 modified HBPAE sizing had the optimum emulsion stability and film‐forming ability. Meanwhile, the results also demonstrated that a continuous and uniform sizing layer was formed on the surface of CFs and the surface sizing was excellent in improving the chemical activity of CFs. Compared with unsized CFs, the O1s/C1s composition ratio was observed to increase from 11.51% to 33.17% and the ILSS of CF/EP composites increased from 81.2 to 89.7 MPa, exhibiting better mechanical property than that of commercial Takemoto S64 sized CFs. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44757. 相似文献
18.
Introducing nanoparticles onto the surface of carbon fibers (CFs) is a useful method for enhancing the quality of fiber-matrix interface. In this work, a liquid sizing agent containing functionalized silica nanoparticles (SiO2) was well prepared to improve interfacial strength and mechanical properties of composites. In order to enhance the dispersion of SiO2 nanoparticles in sizing agent, SiO2 nanoparticles were chemically grafted with 3-aminopropyltriethoxysilane (APS), and then silanized silica (SiO2-APS) was introduced into the interphase by a conventional sizing process as well. Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA) confirmed the successful preparation of SiO2-APS. Scanning electron microscopy (SEM) showed that a uniform distribution of SiO2-APS on the fiber surface and the increased surface roughness. The sized fibers (CF/SiO2-APS) exhibited a high surface free energy and good wettability based on a dynamic contact angle testing. Interfacial microstructure and mechanical properties of untreated and sized CFs composites were investigated. Simultaneous enhancements of interlaminar shear strength (ILSS) and impact toughness of CF/SiO2-APS composites were achieved, increasing 44.79% in ILSS and 31.53% in impact toughness compared to those of untreated composites. Moreover, flexural strength and modulus of composites increased by 32.22 and 50.0% according to flexural test. In addition, the hydrothermal aging resistance of CF/SiO2-APS composites has been improved significantly owing to the introduced Si-O-Si bonds at the interface. 相似文献
19.
Preparation and property investigation of crosslinked alginate/silicon dioxide nanocomposite films
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Manli Yang Yanzhi Xia Yingxia Wang Xihui Zhao Zhixin Xue Fengyu Quan Cunzhen Geng Zhihui Zhao 《应用聚合物科学杂志》2016,133(22)
Crosslinked nanocomposite films of sodium alginate (SA) and silicon dioxide (SiO2) with different SiO2 loading values were prepared by in situ synthesis. Biocomposite films were produced by solution casting and solvent evaporation with glycerol as the plasticizer and calcium chloride as the crosslinking agent. The effects of the addition of nano silicon dioxide (nano‐SiO2) in SA on the microstructural, physical, mechanical, and optical properties of the nanocomposite films were characterized. The results show that nano‐SiO2 was dispersed homogeneously in the SA matrix; it thereby formed a strong interfacial interaction between the nano‐SiO2 particles and the matrix. The transparency of the bionanocomposite films was enhanced. Thermogravimetric analysis also revealed that nano‐SiO2 improved the thermal stability of the SA films. The incorporation of SiO2 further reduced the water vapor permeability and swelling degree and significantly increased the tensile strength and elongation, which are parameters important for packaging industries. Finally, the lower light transmission of UV light from 200 to 250 nm indicated that SA/SiO2 nanocomposite films could potentially be used to prevent lipid damage by UV light in food conservation. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43489. 相似文献
20.
Poly(vinyl chloride‐co‐vinyl acetate) (PVVA)/nano‐SiO2 composite resin was prepared by radical suspension polymerization of the monomers in the presence of fumed nano‐SiO2 particles premodified with γ‐methylacryloxypropyl trimethoxysilane. The cool dioctyl phthalate absorption percentage, granule porosity, and specific surface area of the composite resin were enhanced through incorporation of nano‐SiO2 into the PVVA. Scanning electron microscope pictures showed the resin had higher porosity. PVVA/nano‐SiO2 composite resin was mixed with pure PVC resin to form a mixture sample (polymer‐composite blend [PCB]) and the mixture was fused in the torque rheometer. The rheological test results indicated that, at a certain nano‐SiO2 content, the fusion speed of PCB was accelerated and the fusion temperature of PCB was decreased, owing to nano‐SiO2 dispersed evenly in the polymer matrix. When excessive nano‐SiO2 was loaded, the fusion torque, the fusion time, and the fusion temperature of PCB were all increased. These properties are correlative to the dispersive density of nano‐SiO2 in the polymer matrix. This study also demonstrated that the introduction of small amounts of nano‐SiO2 into the resin increased the impact strength and tensile strength of PCB simultaneously. J. VINYL ADDIT. TECHNOL., 20:230–236, 2014. © 2014 Society of Plastics Engineers 相似文献