GF/MoS2改性PTFE密封唇片材料的力学及摩擦学性能

采用玻璃纤维(GF)微粉与MoS₂复合改性聚四氟乙烯(PTFE)密封唇片材料,考察复合材料的力学、干摩擦磨损性能及其磨损机理。结果表明:当GF质量分数为15%时,PTFE/GF试样的回弹率达到最大值92.5%,摩擦因数为0.29,相比纯PTFE有所增加,而磨损率大大降低,仅为1.8×10?6mm3/(N·m);在此基础上,当MoS₂添加量为5%时,PTFE/GF/MoS₂试样的回弹率略有降低,但仍然保持在90%以上,其摩擦因数为0.31,体积磨损率进一步降低到1.25×10?6mm3/(N·m)。磨损面SEM分析表明:纯PTFE呈现出严重的塑性变形和粘着磨损特征,而PTFE/GF主要表现为磨粒磨损行为;适当MoS₂含量的PTFE/GF/MoS₂试样在摩擦过程中磨粒磨损特征消失,仅有非常轻微的粘着磨损行为。     

Tribological Behaviours of PTFE Composites Filled with PEEK and Nano-ZrO_2 Based on Pin-on-Flat Reciprocating Friction Model

Nano-Zr O_2 and PEEK particles were synergistically filled in unfilled PTFE to improve the wear resistance and maintain a relatively low friction coefficient, and the materials were studied using a reciprocating sliding friction and wear tester. In the friction tests, the evolution of various tribological characteristics in both the contact interfaces and debris was observed, and the wear mechanism of the PTFE composites was investigated. The results showed that the wear rate of the PTFE composites synergistically filled with nano-Zr O_2 and PEEK was lower and its friction coefficient was slightly higher than that of the unfilled PTFE; the uniformity and continuity of the transfer film generated by the composite with nano-Zr O_2 and PEEK were the best, and the particle size of the debris was minimal in comparison to that in other sample systems.     

改性聚氨酯耐磨防腐涂层的研究

以改性聚氨酯、聚四氟乙烯、铜粉、二硫化钼、石墨为主要原料,研制了一种常温固化耐磨防腐涂层。通过正交试验和极差分析,优选出一组配方为:改性聚氨酯100份,聚四氟乙烯20.8份,铜粉10份,二硫化钼与石墨各4.2份,涂层的附着力为0级,硬度为3H,耐磨性为在3.3kg负荷作用下与钢轮对磨2500圈,弦长为6.46mm,并且涂层在10%的硫酸、60%的氢氧化钠、30%的氯化钠溶液中浸泡一个月后耐蚀性良好。     

青铜-聚四氟乙烯复合材料温压新工艺

填充聚四氟乙烯以其优异的性能,成为具有广泛应用前景的粒子改性复合材料,在聚四氟乙烯中加入青铜后克服了纯聚四氟乙烯的耐磨性差、热膨胀系数大等缺点,扩大了聚四氟乙烯的应用范围.填充聚四氟乙烯温压成型性能的主要工艺参数是烧结温度、烧结时间、预压压力,常规的压缩模塑成型法,周期长、性能差、表面精度和光洁度不高,本研究的温压成型工艺工序少、周期短、机械性能得到明显提高.     

Tribological Properties of Polytetrafluoroethylene Composites Filled with Rare Earths Modified Glass Fibers

1Introduction Polytetrafluoroethyleneisakindofperfectself lubri catingmaterialduetoitsverylowfrictioncoefficient,goodhightemperaturestabilityandchemicalstability.Yetitcannotbeusedasanti wearmaterialalonebecause ofitspoormechanicalproperties,badthermalconductivi tyandhighwearrate.Therefore,variousreinforcement andmodificationofPTFEhavebeentried,andthefric tionandwearpropertiesofPTFEcompositeshavebeen extensivelystudiedbymanyinvestigators[14].Glassfiberexhibitsahightensilestrengthandten sile…     

洪水作用下滑坡稳定性变化研究

每次大的洪水过后,河流两岸通常将会有大量滑坡的产生,而目前对洪水作用过程中滑坡复活研究较少,本文基于极限分析理论建立了洪水作用下曲线形滑面滑坡复活模型,研究了洪水作用过程中不同参数对滑坡稳定性影响情况,结果发现：随着地表水升高稳定性系数升高,随着地下水位升高滑坡稳定系数降低,滑坡在地下水与土体内摩擦角折减双重作用下,滑坡在内摩擦角15°-25度范围内有一个复活破坏过程;随着冲刷深度增加稳定性系数降低,随着边坡高度增加,冲刷深度对稳定性系数影响减小;相对于其他参数,冲刷深度与内摩擦角对稳定性系数影响大。     

刀具-岩石摩擦过程中的闪温分析

摩擦表面闪温对刀具材料性能产生着重要影响。针对刀具摩擦表面的微凸体建立了导热微分方程,系统分析了影响微凸体温度的影响因素。在提出摩擦表面接触系数的概念的基础上推导出了干摩擦条件下刀具闪温的解析计算模型并分析了水射流条件对闪温计算的影响。给出了基于均匀分布模型和概率分布模型的摩擦表面接触系数和水射流参与下满足动力润滑条件的摩擦系数等计算参数的确定方法。计算分析与红外测温实验的结果表明：刀具与岩石的摩擦闪温严重依赖两摩擦面的接触系数和各自表面微凸体分布情况;给出的摩擦面闪温计算模型比传统计算方法更接近实验测量值,更适用与工程中对材料安全性要求较高的场合应用。     

任意卷吸速度矢量点接触摩擦系数简化计算方法

针对弧齿锥齿轮和准双曲面齿轮传动的空间点接触摩擦系数求解复杂问题,考虑油膜入口区温升与中心油膜厚度以及接触区温升与摩擦系数间的耦合关系,提出任意卷吸速度矢量点接触的摩擦系数简化计算方法. 基于所提方法分析在不同工况下的点接触中心油膜厚度和摩擦系数,并将油膜厚度和摩擦系数与文献实验数据进行对比. 结果表明：在高速工况下,入口区温升和接触区温升显著,忽略温升影响将使油膜厚度和摩擦系数预测结果偏大;卷吸速度夹角对油膜厚度影响较大,对摩擦系数影响相对较小;在任意卷吸速度夹角工况下,点接触油膜厚度和摩擦系数预测结果与文献实验结果一致,验证摩擦系数简化计算方法的可靠性.     

超细羽绒粉体的表面疏水化改性

采用γ-巯丙基三甲氧基硅烷(KH590)、苯基异氰酸酯(PI)和十八烷基异氰酸酯(ODI)对超细羽绒粉体进行表面疏水化改性,制备了不同改性剂处理的超细羽绒粉体.通过FTIR、TG、水接触角实验、吸湿性实验研究了改性前后羽绒粉体的结构、热稳定性以及亲疏水性能.结果表明:PI和ODI可以化学结合在羽绒粉体表面,改性后的超细羽绒粉体保留了良好的吸湿性能,表面由亲水性变为疏水性,且初始热降解温度提高了约4-7℃;KH590偶联剂处理对羽绒粉体的热稳定性、吸湿性以及亲疏水性没有明显影响.PI和ODI改性是改善超细羽绒粉与非极性基体(如聚丙烯等)界面性能,提高非极性纤维材料吸湿性的有效方法,且对于这类复合材料的热加工是有利的.     

金属镍和聚四氟乙烯微粒复合电沉积的研究(Ⅲ)——复合膜的性能

由电沉积法得到的金属镍和高分子聚四氟乙烯（ＰＴＦＥ）复合膜层具有优良的减摩、自润滑性能．对所研制的金属镍和高分子聚四氟乙烯复合膜层的硬度、摩擦性能、形貌观察等进行了测试．实验结果表明镍聚四氟乙烯镀层有较低的滑动摩擦系数,在同样条件下,与镍镀层相比,其滑动摩擦系数下降三分之一左右．     

碳纤维增强摩擦材料的摩擦表面层

利用D-MS摩擦磨损试验机研究了碳纤维增强摩擦材料的摩擦磨损性能,并利用扫描电镜和能谱仪对其表面结构和微区成分进行了观察和测定,对热重分析试验的结果和摩擦磨损性能试验的结果进行了分析。结果表明:碳纤维摩擦材料在100～300℃内随温度升高摩擦磨损性能无明显降低,摩擦因数有所提高。碳纤维摩擦材料摩擦表面可分为富铁层、热力疏松层、变形强化层三层。摩擦表面工作层对材料表面获得稳定的摩擦磨损性能起重要作用。碳纤维的高导热性对材料的摩擦表面层结构有重要影响,它有利于减少热影响表面层深度,在本试验条件下,摩擦热影响表面层的深度约为0.55mm。     

多孔阵列阳极氧化铝膜润滑性能的Stribeck研究

为了研究阳极氧化铝膜的多孔结构对其润滑性能的影响,分别制备了光滑表面氧化铝膜,40 nm孔径、90 nm孔径多孔表面氧化铝膜.用接触角测试仪测试了水、机油与3种表面的接触角;在不同润滑条件下,用摩擦磨损试验机UMT-2测试了3种氧化铝膜与GCrl5钢面接触的润滑性能.结果表明:多孔结构氧化铝膜增强了材料的亲水性能和亲油性能,90 nm孔径氧化铝膜表现出超亲油特征;水润滑和机油润滑条件下,速度从0.016 m/s增至0.32 m/s过程中,光滑氧化铝表面只能形成边界润滑区域,多孔表面得到了包含边界润滑、混合润滑和流体润滑的完整的Stibeck曲线.机油润滑条件下,40 nm孔径的膜达到最小摩擦系数的临界速度为0.28 m/s,最小摩擦系数为0.083,90 nm孔径的膜达到最小摩擦系数的临界速度仅为0.2 m/s,最小摩擦系数减小为0.023;机油润滑条件下,90 nm孔径的氧化铝膜板的Stribeck曲线,谷底区域更宽.     

Tribological Properties of Polyvinyl Mcohol Hydrogel Reinforced with Nanometer Hydroxy Apatite

As a potential artificial cartilage material,the friction and wear properties of nano-hydroxy apatite(HA)particles filled poly(vinyl alcohol)hydrogel(PVA-H)composites sliding against stainless steel disk under water lubrication condition were studied by using a four ball tester.The worn surfaces were investigated by using a scanning electron microscope(SEM)to determine the wear mechanisms.Experimental results show that filling HA to PVA-H will slightly increase the friction coefficient of composites with the increasing of HA content under water lubrication condition.Meanwhile,HA particles can greatly reduce the wear mass loss of the PVA-H composites and enhance the load carrying capacity,the wear loss of the 1 wt% HA reinforced PVA-H composites can be decreased by 30 percent under 2.0 MPa to 50 percent under 0.5 MPa contact pressure.We also found that 2 wt% HA content of composites increase the wear mass loss under the same condition.SEM examination shows that the worn surface of low HA containing(1 wt%)composites are much smoother than that of pure PVA-H or high HA containing(2 wt%)composites under 1.5 MPa contact pressure.It is also found that there are big hole and big reunited HA particles in the surface of 2 wt% HA containing composites,which leads to deterioration of the surface of samples under higher loads in water lubrication.These results may be useful in the tribological design of artificial articular cartilage material.     

Tribological Properties of Polyvinyl Alcohol Hydrogel Reinforced with Nanometer Hydroxy Apatite

As a potential artificial cartilage material, the friction and wear properties of nano-hydroxy apatite （HA） particles filled poly （vinyl alcohol） hydrogel （PVA-H） composites sliding against stainless steel disk under water lubrication condition were studied by using a four ball tester. The worn surfaces were investigated by using a scanning electron microscope （SEM） to determine the wear mechanisms. Experimental results show that filling HA to PVA-H will slightly increase the friction coefficient of composites with the increasing of HA content under water lubrication condition. Meanwhile, HA particles can greatly reduce the wear mass loss of the PVA-H composites and enhance the load carrying capacity, the wear loss of the 1 wt% HA reinforced PVA-H composites can be decreased by 30 percent under 2.0 MPa to 50 percent under 0.5 MPa contact pressure. We also found that 2 wt% HA content of composites increase the wear mass loss under the same condition. SEM examination shows that the worn surface of low HA containing （1 wt%） composites are much smoother than that of pure PVA-H or high HA containing （2 wt%） composites under 1.5 MPa contact pressure. It is also found that there are big hole and big reunited HA particles in the surface of 2 wt% HA containing composites, which leads to deterioration of the surface of samples under higher loads in water lubrication. These results may be useful in the tribological design of artificial articular cartilage material.     

透波性Si3N4陶瓷铣削过程刀具-工件摩擦特性

透波性Si_3N_4陶瓷是制造天线窗的主要材料之一,铣削过程中刀具-工件摩擦特性与加工表面形貌紧密相关.本文以透波性Si_3N_4陶瓷铣削加工为研究对象,通过分析加工过程中刀具-工件接触关系得到摩擦接触区域主要集中于切削刃后刀面与工件表面;探究了不同加工机理下接触区域摩擦机理,塑性域加工摩擦机理为粘着摩擦、刀具表面粗糙度波峰犁沟摩擦和陶瓷粉末滚动摩擦,脆性域加工还包含碎裂型陶瓷颗粒犁沟摩擦;在此基础上应用已有的微观表面形态与表面接触的摩擦力及摩擦系数理论给出了Si_3N_4陶瓷与铣刀材料的摩擦系数计算公式;通过实验对分析结果进行了验证.结果表明:透波性Si_3N_4陶瓷加工机理转变的临界切深值大于0.3 mm且小于0.4 mm;摩擦系数计算公式最大误差率为20.46%,能在一定程度上反映加工过程中摩擦特性演化规律;加工机理初始转变阶段,摩擦系数值降低,且摩擦系数对表面粗糙度影响呈现三阶多项式分布规律.该研究为提高透波性Si_3N_4陶瓷铣削加工表面质量提供了参考.     

化学复合镀Ni-P-PTFE镀层性能的研究

化学复合镀Ni－P－PTFE镀层具有低的摩擦系数和自润滑性能．通过销环试验机测得镀层的摩擦系数;展现随着镀层中PTFE含量的增加,镀层摩擦系数先降低后稍有提高．PTFE含量为9wt％时,摩擦系数最低．对硬度及磨损率的测试,得出随着PTFE含量的增加,镀层硬度显著下降,在振动干摩擦磨损条件下的耐磨性也降低。     

The Wear Process of PTFE Coatings Under Vacuum Conditions

The wear process of PTFE coatings sliding against GCrlS-bearing steel ball under vacuum conditions was investigated, and the hardness of the PTFE coatings on both sides of wear track was measured. The experimental results showed that the friction coefficient of the PTFE coatings increases with the increase of sliding distance under different sliding velocities. And the friction coefficient of the PTFE coatings increases with the increase of sliding distance under different sliding loads. The wear rate of PTFE coatings decreases with the increase of sliding distance. And the majority of the wear produced during the whole wear process of PTFE coatings sliding against GCr-15 steel ball comes from the early period of friction. The hardness of PTFE coatings on both sides of wear track increases as the distance increases and distributes symmetrically around the wear track. Scanning electron microscope （SEM） was utilized to investigate the worn surface of PTFE coating, h was found that the worn surface of PTFE coating is characterized by sever plastic deformation and spalling of the PTFE coating. The edge of wear track is characterized by micro cracking.     

散体材料变截面桩复合地基极限承载力研究

以鼓胀破坏理论为基础，同时考虑桩土接触面上的摩擦，利用土压力理论，探讨了散体材料变截面桩及其复合地基极限承载力的计算方法。通过算例，讨论了桩型及桩土接触面上的摩擦角对散体材料桩及其复合地基极限承载力的影响。     

散体材料变截面桩复合地基极限承载力研究

以鼓胀破坏理论为基础,同时考虑桩土接触面上的摩擦,利用土压力理论,探讨了散体材料变截面桩及其复合地基极限承载力的计算方法。通过算例,讨论了桩型及桩土接触面上的摩擦角对散体材料桩及其复合地基极限承载力的影响。     

填充聚四氟乙烯的某些性能研究

对9种成分的填充聚四氟乙烯进行了机械性能和热性能的测试。结果表明:与纯聚四氟乙烯相比,填充聚四氟乙烯的抗压、抗弯强度和硬度增高;抗拉强度、断裂伸长率和线膨胀系数则降低;摩擦磨损性能明显改善.填充聚四氟乙烯的性能改变与填充剂的成分配比及其结晶度有关。X射线结晶度的测量结果表明,填充聚四氟乙烯的结晶度亦随填充剂的結晶性质不同而变化.