Electrical properties of Si p+-n junctions for sub-0.25μm CMOS fabricated by Ga FIB implantation

p⁺-n junction diodes for sub-0.25-μm CMOS circuits were fabricated using focused ion beam (FIB) Ga implantation into n-Si (100) substrates with background doping of N_b=(5-10)×10 ¹⁵ and N_b⁺=(1-10)×10¹⁷ cm^-3. Implant energy was varied from 2 to 50 keV at doses ranging from 1×10¹³ to 1×10¹⁵ cm^-2 with different scan speeds. Rapid thermal annealing (RTA) was performed at either 600 °C or 700°C for 30 s. Diodes fabricated on N_b⁺ with 10-keV Ga⁺ exhibited a leakage current (^I_R) 100× smaller than those fabricated with 50-keV Ga⁺. Tunneling was determined to be the major current transport mechanism for the diodes fabricated on N_b⁺ substrates. An optimal condition for I_R on N_b⁺ substrates was obtained at 15 keV/1×10¹⁵ cm^-2. Diodes annealed at 600°C were found to have an I_R 1000× smaller than those annealed at 700°C. I-V characteristics of diodes fabricated on N_b substrates with low-energy Ga⁺ showed no implant energy dependence. I-V characteristics were also measured as a function of temperature from 25 to 200°C. For diodes implanted with 15-keV Ga ⁺, the cross-over temperatures between I_diff and I_g-r occurred at 106°C for N_b ⁺ and at 91°C for N_b substrates     

High-energy (MeV) ion implantation and its device applications inGaAs and InP

The work performed to date on the implantation of megaelectronvolt (MeV) energy ions of shallow donor (Si, S), shallow acceptor (Be), compensation (B, O, N, Fe, Co, Ti), and rare-earth (Er) species in III-V GaAs and InP compounds is reviewed. The optimum annealing conditions, the resulting carrier concentrations, and the lattice quality of the material are discussed. For the buried implants, the lattice damage and the electrical properties of the material are almost independent of the implant energy. For MeV Be⁺ implants the outdiffusion of Be during annealing is not observed, unlike in the case of shallow keV Be ⁺ implants. The MeV energy Fe⁺ or Co⁺ implants performed at 200°C into n-type InP, and Ti implants into p-type InP gave thermally stable buried high-resistance layers. The performance of microwave devices like vertical p-i-n, varactor, and mixer diodes and an optical device like a heterostructure laser made using MeV energy ion implantation is discussed. The results of MeV implantation in obtaining interdevice isolation of multilayer structures like HBTs are also discussed     

Optimization of the germanium preamorphization conditions forshallow-junction formation

Shallow p⁺-n and n⁺-p junctions were formed in germanium preamorphized Si substrates. Germanium implantation was carried out over the energy range of 50-125 keV and at doses from 3×10¹⁴ to 1×10¹⁵ cm^-2. p ⁺-n junctions were formed by 10-keV boron implantation at a dose of 1×10¹⁵ cm^-2. Arsenic was implanted at 50 keV at a dose of 5×10¹⁵ cm^-2 to form the n⁺-p junctions. Rapid thermal annealing was used for dopant activation and damage removal. Ge, B, and As distribution profiles were measured by secondary ion mass spectroscopy. Rutherford backscattering spectrometry was used to study the dependence of the amorphous layer formation on the energy and dose of germanium ion implantation. Cross-sectional transmission electron microscopy was used to study the residual defects formed due to preamorphization. Complete elimination of the residual end-of-range damage was achieved in samples preamorphized by 50-keV/1×10¹⁵ cm^-2 germanium implantation. Areal and peripheral leakage current densities of the junctions were studied as a function of germanium implantation parameters. The results show that high-quality p⁺-n and n⁺-p junctions can be formed in germanium preamorphized substrates if the preamorphization conditions are optimized     

InP/InGaAs HBTs with n+-InP contacting layers grown byMOMBE using SiBr4

InP/InGaAs heterojunction bipolar transistors (HBTs) with low resistance, nonalloyed TiPtAu contacts on n⁺-InP emitter and collector contacting layers have been demonstrated with excellent DC characteristics. A specific contact resistance of 5.42×10^-8 Ω·cm², which, to the best of our knowledge, is the lowest reported for TiPtAu on n-InP, has been measured on InP doped n=6.0×10¹⁹ cm^-3 using SiBr₄. This low contact resistance makes TiPtAu contacts on n-InP viable for InP/InGaAs HBTs     

The effect of Co incorporation on electrical characteristics of n+/p shallow junction formed by dopant implantation into CoSi2 and anneal

The impact of Co incorporation on the electrical characteristics has been investigated in n⁺/p junction formed by dopant implantation into CoSi₂ and drive-in anneal. The junctions were formed by As⁺ (30 or 40 keV, 1×10¹⁶ cm ^-2) implantation into 35 nm-thick CoSi₂ followed by drive-in annealing at 900°C for 30 s in an N₂ ambient. Deeper junction implanted by As⁺ at 40 keV was not influenced by the Co incorporation. However, for shallower junction implanted by As ⁺ at 30 keV, incorporation of Co atoms increased its leakage current, which were supposed to be dissociated from the CoSi₂ layer by silicide agglomeration during annealing. The mechanism of such a high leakage current was found to be Poole-Frenkel barrier lowering induced by high density of Co traps     

InP/InGaAs heterojunction bipolar transistors grown by gas-sourcemolecular beam epitaxy with carbon-doped base

The first N-p-n InP/InGaAs heterojunction bipolar transistors (HBTs) with p-type carbon doping in InGaAs are reported. P-type carbon doping in the InGaAs base has been achieved by gas-source molecular beam epitaxy (GSMBE) using carbon tetrachloride (CCl₄) as the dopant source. The resulting hole concentration in the base was 1×10¹⁹ cm^-3. HBTs fabricated using material from this growth method display good I-V characteristics with DC current gain above 500. This verifies the ability to use carbon doping to make a heavily p-type InGaAs base of an N-p-n HBT     

High-transconductance p-channel AlGaAs/GaAs HFETs with low-energyberyllium and fluorine co-implantation self-alignment

The fabrication and electrical characteristics of p-channel AlGaAs/GaAs heterostructure FETs with self-aligned p⁺ source-drain regions formed by low-energy co-implantation of Be and F are reported. The devices utilize a sidewall-assisted refractory gate process and are fabricated on an undoped AlGaAs/GaAs heterostructure grown by MOVPE. Compared with Be implantation alone, the co-implantation of F⁺ at 8 keV with 2×10¹⁴ ions/cm² results in a 3× increase in the post-anneal Be concentration near the surface for a Be⁺ implantation at 15 keV with 4×10¹⁴ ions/cm². Co-implantation permits a low source resistance to be obtained with shallow p⁺ source-drain regions. Although short-channel effects must be further reduced at small gate lengths, the electrical characteristics are otherwise excellent and show a 77-K transconductance as high as 207 mS/mm for a 0.5-μm gate length     

Deep-level dominated current-voltage characteristics of buriedimplanted oxide silicon-on-insulator

Current-voltage characteristics of Au contacts formed on buried implanted oxide silicon-on-insulator (SOI) structures are discussed, which indicate that the dominant transport mechanism is space-charge-limited current (SCLC) conduction in the presence of deep-level states. The deep-level parameters, determined using a simple analysis, appear to be sensitive to anneal conditions used and subsequent processing. Silicon implanted with 1.7×10¹⁸ cm^-2 oxygen ions at 150 keV following a 1200°C anneal for 3 h shows deep level 0.37 eV below the conduction band edge with a concentration of unoccupied traps of ~ 2×10¹⁵ cm^-3 . In contrast, arsenic ion implantation, in the 1200°C annealed material with a dose of 1.5×10¹² cm^-2 at 60 keV and activated by rapid thermal annealing (RTA), introduces a deep level 0.25 eV below the conduction band edge with an unoccupied trap concentration of ~6×10¹⁷ cm^-2     

Formation of cobalt silicided shallow junction using implantinto/through silicide technology and low temperature furnace annealing

This work investigates the shallow CoSi₂ contacted junctions formed by BF₂⁺ and As⁺ implantation, respectively, into/through cobalt silicide followed by low temperature furnace annealing. For p⁺n junctions fabricated by 20 keV BF₂⁺ implantation to a dose of 5×10¹⁵ cm^-2, diodes with a leakage current density less than 2 nA/cm² at 5 V reverse bias can be achieved by a 700°C/60 min annealing. This diode has a junction depth less than 0.08 μm measured from the original silicon surface. For n⁺p junctions fabricated by 40 keV As⁺ implantation to a dose of 5×10¹⁵ cm^-2, diodes with a leakage current density less than 5 nA/cm² at 5 V reverse bias can be achieved by a 700°C/90 min annealing; the junction depth is about 0.1 μm measured from the original silicon surface. Since the As⁺ implanted silicide film exhibited degraded characteristics, an additional fluorine implantation was conducted to improve the stability of the thin silicide film. The fluorine implantation can improve the silicide/silicon interface morphology, but it also introduces extra defects. Thus, one should determine a tradeoff between junction characteristics, silicide film resistivity, and annealing temperature     

High quality SiO2/Si interfaces of poly-crystallinesilicon thin film transistors by annealing in wet atmosphere

A new post-metallization annealing technique was developed to improve the quality of metal-oxide-semiconductor (MOS) devices using SiO ₂ films formed by a parallel-plate remote plasma chemical vapor deposition as gate insulators. The quality of the interface between SiO₂ and crystalline Si was investigated by capacitance-voltage (C-V) measurements. An H₂O vapor annealing at 270°C for 30 min efficiently decreased the interface trap density to 2.0×10¹⁰ cm^-2 eV^-1, and the effective oxide charge density from 1×10 ¹² to 5×10⁹ cm^-2. This annealing process was also applied to the fabrication of Al-gate polycrystalline silicon thin film transistors (poly-Si TFT's) at 270°C. In p-channel poly-Si TFT's, the carrier mobility increased from 60-400 cm² V^-1 s^-1 and the threshold voltage decreased from -5.5 to -1.7 V     

High-performance InGaAs junction field-effect transistor with P/Beco-implanted gate

InGaAs junction field-effect transistors (JFETs) are fabricated in metalorganic chemical-vapor-deposition (MOCVD)-grown n-InGaAs and semi-insulating Fe:InP layers on n⁺-InP substrate with a P/Be co-implanted p⁺ self-aligned gate. The device exhibits a transconductance of 245 mS/mm (intrinsic transconductance of 275 mS/mm) at zero gate bias and good pinch-off behavior for a gate length of 0.5 μm. The effective electron velocity is deduced to be 2.8×10⁷ cm/s, equal to the theoretical prediction     

Formation of 0.05-μm p+-n and n+-pjunctions by very low (<500 eV) ion implantation

The current-voltage (I-V) characteristics of ultrashallow p⁺ -n and n⁺-p diodes, obtained using very-low-energy (<500-eV) implantation of B and As, are presented. the p⁺-n junctions were formed by implanting B⁺ ions into n-type Si (100) at 200 eV and at a dose of 6×10¹⁴ cm^-2, and n⁺-p junctions were obtained by implanting As⁺ ions into p-type (100) Si at 500 eV and at a dose 4×10¹² cm^-2. A rapid thermal annealing (RTA) of 800°C/10 s was performed before I-V measurements. Using secondary ion mass spectrometry (SIMS) on samples in-situ capped with a 20-nm ²⁸Si isotopic layer grown by a low-energy (40 eV) ion-beam deposition (IBD) technique, the depth profiles of these junctions were estimated to be 40 and 20 nm for p⁺-n and n⁺-p junctions, respectively. These are the shallowest junctions reported in the literature. The results show that these diodes exhibit excellent I-V characteristics, with ideality factor of 1.1 and a reverse bias leakage current at -6 V of 8×10^-12 and 2×10^-11 A for p⁺-n and n⁺-p diodes, respectively, using a junction area of 1.96×10^-3 cm²     

Hot-electron InGaAs/InP heterostructure bipolar transistors withfT of 110 GHz

A hot-electron InGaAs/InP heterostructure bipolar transistor (HBT) is discussed. A unity-current-gain cutoff frequency of 110 GHz and a maximum frequency of oscillation of 58 GHz are realized in transistors with 3.2×3.2-μm² emitter size. Nonequilibrium electron transport, with an average electron velocity approaching 4×10⁷ cm/s through the thin (650 Å) heavily doped (p=5×10¹⁹ cm^-3) InGaAs base and 3000-Å-wide collector space-charge region, results in a transit delay of 0.5 ps corresponding to an intrinsic cutoff frequency of 318 GHz     

Pulse annealing of implanted InP with minimal phosphorus loss

Electron pulse annealing has been used to activate implanted layers in InP without the phosphorus loss dominance in earlier work. Reduced pulse energies were employed at which the phosphorus loss could be curtailed but which necessitated supplemental thermal heating of the substrate for activation. Relatively shallow implants (75 keV, 4 × 10¹⁴Si+cm^-2) so annealed show minimum yields of ∼ 5% from backscattering and are doped to over 10¹⁹cm^-3with mobilities of 500 cm²V^-1sec^-1.     

Simple crystal growth of Si-Ge alloy by ion implantation andsequential rapid thermal anneal

The single crystal growth of Si-Ge alloy was studied in germanium implanted silicon substrate. Ge⁺ ions were implanted on 〈100〉, p-type silicon substrate at a dose of 10¹⁶ cm^-2. As implanted samples were annealed sequentially at a temperature of 700-1000°C for different times in an RTA system to crystallise the amorphous layer. The SNMS technique was used to determine the compositional analysis, and RBS in the channelling mode was performed to characterise the samples     

Ion-implanted high microwave power indium phosphide transistors

Encapsulated rapid thermal annealing (RTA) has been used in the fabrication of indium phosphide (InP) power metal-insulator-semiconductor field-effect transistors (MISFETs) with ion-implanted source, drain, and active channel regions. The MISFETs had a gate length of 1.4 μm. Six to ten gate fingers per device, with individual gate finger widths of 100 or 125 μm, were used to make MISFETs with total gate widths of 0.75, 0.8, or 1 mm. The source and drain contact regions and the channel region of the MISFETs were fabricated using silicon implants in semi-insulating InP at energies from 60 to 360 keV with doses from 1×10¹² to 5.6×10¹⁴ cm^-2. The implants were activated using RTA at 700°C for 30 s in N₂ or H₂ ambients using a silicon nitride encapsulant. The high-power, high-efficiency MISFETs were characterized at 9.7 GHz, and the output microwave power density for the RTA conditions used was as high as 2.4 W/mm. For a 1-W input at 9.7 GHz gains up to 3.7 dB were observed, with an associated power-added efficiency of 29%. The output power density was 70% greater than that reported for GaAs MESFETs     

Ultrahigh fT and fmax new self-alignmentInP/InGaAs HBT's with a highly Be-doped base layer grown by ALE/MOCVD

We report on a new self-alignment (SA) process and microwave performance of ALE/MOCVD grown InP/InGaAs heterojunction bipolar transistors (HBT's) with a base doping concentration of 1×10² 0 cm^-3. We obtained f_T of 161 GHz and f_max of 167 GHz with a 2×10 μm emitter. These high values indicate the best performance of InP/InGaAs HBT's ever reported, in so far as we know. These values were attained by reducing the base resistance using ALE/MOCVD and base-collector capacitance using a new SA process. These results indicate the great potential of these devices for ultrahigh-speed application     

Effects of neutral buried p-layer on high-frequency performance ofGaAs MESFETs

Fully ion-implanted n⁺ self-aligned GaAs MESFETs with Au/WSiN refractory metal gates have been fabricated by adopting neutral buried p-layers formed by 50-keV Be-implantation. S-parameter measurements and equivalent circuit fittings are discussed. When the Be dose is increased from 2×10¹² cm^-2 to 4×10¹² cm^-2, the maximum value of the cutoff frequency with a 0.2-μm gate falls off from 108 to 78 GHz. This is because a neutral buried player makes the intrinsic gate-source capacitance increase markedly, while its influence on gate-drain capacitance and gate-source fringing capacitance is negligible. The maximum oscillation frequency recovers, however, due primarily to the drain conductance suppression by the higher-concentration buried p-layer. An equivalent value of over 130 GHz has been obtained for both 0.2-μm-gate GaAs MESFETs     

Electrical properties of Ga-implanted Si p+-n shallowjunctions fabricated by low-temperature rapid thermal annealing

p⁺-n shallow-junction diodes were fabricated using on-axis Ga⁶⁹ implantation into crystalline and preamorphized Si, at energies of 25-75 keV for a dose of 1×10¹⁵/cm ², which is in excess of the dosage (2×10¹⁴/cm²) required to render the implanted layer amorphous. Rapid thermal annealing at 550-600°C for 30 s resulted in the solid-phase epitaxial (SPE) regrowth of the implanted region accompanied by high Ga activation and shallow junction (60-130 nm) formation. Good diode electrical characteristics for the Ga implantation into crystalline Si were obtained; leakage current density of 1-1.5 nA/cm² and ideality factor of 1.01-1.03. Ga implantation into preamorphized Si resulted in a two to three times decrease in sheet resistance, but a leakage current density orders of magnitude higher     

4H-SiC MOSFETs utilizing the H2 surface cleaningtechnique

The H₂ cleaning technique was examined as the precleaning of the gate oxidation for 4H-SiC MOSFETs. The device had a channel width and length of 150 and 100 μm, fabricated on the p-type epitaxial layer of 3×10¹⁶ cm^-3. The gate oxidation was performed after the conventional RCA cleaning, and H₂ annealing at 1000°C. The obtained channel mobility depends on the pre-cleaning process strongly, and was achieved 20 cm²/N s in the H₂ annealed sample. The effective interface-state density was also measured by the MOS capacitors fabricated on the same chips, resulting 1.8×10¹² cm^-2 from the photo-induced C-V method