The antiwear and extreme pressure action mechanism of CeF3 in grease

Cerium (III) fluoride as an antiwear or extreme pressure additive has been used in grease and bonded solid film lubricant, but its action mechanism has not been clarified. In this paper, the tribological characteristics of lithium grease containing CeF₃, CaF₂, SbF₃, CeO₂ and graphite fluoride ((CF)_n) were evaluated with an SRV tester. The results show that pastes containing CaF₂ and (CF)_n give good antiwear and anti-friction performance, but do not possess extreme pressure properties. Adding CeO₂ to grease offers no benefit to the antiwear and anti-friction performance of the paste. Paste containing SbF₃ has poor lubricating properties. XPS analysis shows that the good antiwear and extreme pressure properties of paste containing CeF₃ can be attributable to the formation of a physically adherent film and a chemical reaction film on the rubbing surface. Thermogravimetry shows that CeF₃ acts as an agent for the slow release of the fluorine element.     

Indigenously developed,fully automated semi-adiabatic calorimeter for heat capacity measurements on small samples (0.5–2 g) in temperature range 10–300 K

Design, fabrication and performance evaluation of a low temperature semi-adiabatic heat-pulse calorimeter for heat capacity measurement on small samples from 10 to 300 K has been presented. Automation has been brought in by indigenously developed data acquisition system (DAS) in ‘C’ language using LabWindows/CVI platform. A simple algorithm for identifying the attainment of thermal equilibrium in the calorimeter has been proposed and successfully implemented. Several useful sub-routines, enabling uninterrupted operation of calorimeter and continued measurement of reliable heat capacity data over the operational temperature range have been discussed. Performance of the calorimeter has been tested with oxygen-free high conducting copper (OFHC) and two other materials namely potassium di-hydrogen phosphate (KH₂PO₄) and Fe₃PO₇. Comparison of results with reported values have shown overall ±2% accuracy.     

The effect of LaF3 nanocluster modified with succinimide on the lubricating performance of liquid paraffin for steel-on-steel system

LaF₃ nanocluster modified with succinimide was prepared. The effect of the modified LaF₃ nanocluster on the lubricating performance of liquid paraffin for steel-on-steel sliding system was investigated on a four-ball machine. The morphology of LaF₃ and its lubricating mechanisms as additive in liquid paraffin were studied by means of transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). It was found that LaF₃ nanocluster modified with succinimide as an additive in liquid paraffin increased the load-carrying capacity and had good antiwear and friction-reduction behaviour. The XPS analysis of the worn steel surfaces indicated that a boundary lubricating film consisting of physically adsorbing film (succinimide) and tribochemically reacting film (lanthanum oxide and ferrous fluoride) was generated during the friction process. This contributed to improving the lubricating performance of liquid paraffin.     

氟化石墨在润滑方面的应用研究

氟化石墨作为石墨的改性材料,润滑性能优良。文中详细介绍了氟化石墨在作为固体润滑剂,润滑涂料方面的应用。     

In situ TEM studies of micron‐sized all‐solid‐state fluoride ion batteries: Preparation,prospects, and challenges

Trustworthy preparation and contacting of micron‐sized batteries is an essential task to enable reliable in situ TEM studies during electrochemical biasing. Some of the challenges and solutions for the preparation of all‐solid‐state batteries for in situ TEM electrochemical studies are discussed using an optimized focused ion beam (FIB) approach. In particular redeposition, resistivity, porosity of the electrodes/electrolyte and leakage current are addressed. Overcoming these challenges, an all‐solid‐state fluoride ion battery has been prepared as a model system for in situ TEM electrochemical biasing studies and first results on a Bi/La_0.9Ba_0.1F_2.9 half‐cell are presented. Microsc. Res. Tech. 79:615–624, 2016. © 2016 Wiley Periodicals, Inc.     

Refractive index sensor based on fiber loop ring-down spectroscopy

An optical fiber refractive index sensor based on fiber loop ring-down spectroscopy and a tapered fiber was fabricated using an ordinary single mode fiber with an arc fusion splicer. The performance of the sensor was controlled by the parameters of the tapered fiber. A fiber loop ring-down spectroscopy system was employed to enhance the sensitivity and demodulate the transmission spectrum. The results showed that a sensor with a waist diameter of 14 m and a length of 1.2 mm had good optical performance. By monitoring the ring-down time of the system, relatively high sensitivity of 411.576 s/ RIU was achieved with refractive index values from 1.333 to 1.412. This sensor offers few interferences, high sensitivity, easy fabrication, and low cost.     

低雷诺数旋翼翼型设计及气动仿真

研究了低雷诺数下薄圆弧旋翼的翼型,考虑其对高气动性能、高结构强度和便于制造和轻量化的要求,提出一种具有上凸结构的薄圆弧翼型。通过在翼型上表面增加凸起结构,增加部分弦长的翼型厚度并安装加强筋来提高翼型延展向的结构强度;设计出了最大厚度为4.3%、圆弧均匀厚度为2.5%、最大弯度为5.5%和均匀弯度为4.5%的薄圆弧翼型。采用基于二维定常、不可压缩Navier-Stoke方程的数值仿真方法计算了该翼型在雷诺数为40,000~100,000,迎角为-4°~12°下的气动性能,并获得了该翼型上下表面的压力系数分布线和速度矢量图。采用该翼型制作了直径为40cm,质量为15g,桨距为15.7cm的碳纤维旋翼;在悬停状态下完成了它的升力和结构强度试验。实验结果显示其性能满足使用要求。目前,研制的旋翼已成功地应用于某型多旋翼飞行器。     

Microhardness and SEM after CO2 laser irradiation or fluoride treatment in human and bovine enamel

Background: It remains uncertain as to whether or not CO₂ laser is able to hinder demineralization of enamel. The possibility to use bovine instead of human teeth on anticariogenic studies with laser has not yet been determined. Purpose: To compare the ability of CO₂ laser and fluoride to inhibit caries‐like lesions in human enamel and to test whether a similar pattern of response would hold for bovine enamel. Study Design: Ninety‐six enamel slabs (2 × 2 × 4 mm) (48 from bovine and 48 from human teeth) were randomly distributed according to surface treatment (n = 12): CO₂ laser, 5% sodium fluoride varnish (FV), 1.23% acidulated phosphate fluoride (APF) gel, or no treatment (control). Specimens were subjected to a 14‐day in vitro cariogenic challenge. Microhardness (SMH) was measured at 30 μm from the surface. For ultrastructural analysis, additional 20 slabs of each substrate (n = 5) received the same treatment described earlier and were analyzed by SEM. Results: ANOVA and Tukey test ascertained that CO₂ laser promoted the least mineral loss (SMH = 252^a). Treatment with FV resulted in the second highest values (207^b), which was followed by APF (172^c). Untreated specimens performed the worst (154^d). SEM showed no qualitative difference between human and bovine teeth. APF and control groups exhibited surfaces covered by the smear layer. A granulate precipitate were verified on FV group and fusion of enamel crystals were observed on lased‐specimens. Conclusions: CO₂ laser may control caries progression more efficiently than fluoride sources and bovine teeth may be a suitable substitute for human teeth in studies of this nature. Microsc. Res. Tech. 73:1030–1035, 2010. © 2010 Wiley‐Liss, Inc.     

Developing a Hybrid Programmable Logic Controller Platform for a Flexible Manufacturing System

In this article, we present the design and implementation of a flexible manufacturing system (FMS) control platform based on a programmable logic controller (PLC) and a personal computer (PC)-based visual man-machine interface (MMI) and data acquisition (DAS) unit. The key aspect of an FMS is its flexibility to adapt to changes in a demanding process operation. The PLC provides feasible solutions to FMS applications, using PC-based MMI/DAS, whereby PLCs are optimized for executing rapid sequential control strategies. PCs running MMI/DAS front-ends make intuitive operation interfaces, full of powerful graphics and reporting tools. Information from the PC can be distributed through a company's local area network or web using client-server technologies. Currently, with the convergence of underlying microprocessor technology and software programming techniques, many users find that PLCs provide a cost-effective solution to real-time control in small- to medium-sized process plants, especially when combined with supervisory PCs using hybrid systems. The major work of this article demonstrates that PLCs are responsive to rapid and repetitious control tasks, using PCs that present the flow of information automation and accept operator instructions, thereby providing the user a tool to modify and monitor the process as the requirements change.     

CO2 laser emission modes to control enamel erosion

Considering the importance and prevalence of dental erosion, the aim of this in vitro study was to evaluate the influence of different modes of pulse emission of CO₂ laser associated or not to acidulated phosphate fluoride (APF) 1.23% gel, in controlling enamel erosion by profilometry. Ninety‐six fragments of bovine enamel were flattened and polished, and the specimens were subjected to initial erosive challenge with hydrochloric acid (pH = 2). Specimens were randomly assigned according to surface treatment: APF 1.23% gel and gel without fluoride (control), and subdivided according to the modes of pulse CO₂ laser irradiation: no irradiation (control), continuous, ultrapulse, and repeated pulse (n = 12). After surface treatment, further erosive challenges were performed for 5 days, 4 × 2 min/day. Enamel structure loss was quantitatively determined by a profilometer, after surface treatment and after 5 days of erosive challenges. Two‐away ANOVA revealed a significant difference between the pulse emission mode of the CO₂ laser and the presence of fluoride (P ≤ 0.05). The Duncan's test showed that CO₂ laser irradiation in continuous mode and the specimens only received fluoride, promoted lower enamel loss than that other treatments. A lower dissolution of the enamel prisms was observed when it was irradiated with CO₂ laser in continuous mode compared other groups. It can be concluded that CO₂ laser irradiation in continuous mode was the most effective to control the enamel structure loss submitted to erosive challenges with hydrochloric acid. Microsc. Res. Tech. 78:654–659, 2015. © 2015 Wiley Periodicals, Inc.     

Optical fiber distributed acoustic sensing based on the self-interference of Rayleigh backscattering

In order to detect the weak underwater acoustic signal, a Distributed Acoustic Sensing (DAS) scheme based on the self-interference of Rayleigh backscattering is presented. Rayleigh backscattered light which contains a phase change induced by acoustic signal along the sensing fiber which is a standard telecom single-mode fiber is split and fed into an imbalance Michelson interferometer. With the self-interference of two Rayleigh backscattered beams, the phase change is amplified theoretically compared with phase-sensitive OTDR. We designed an experiment to prove the scheme, and successfully restored the acoustic information, meanwhile, the DAS system has preliminary realized around the acoustic phase sensitivity of −151 dB (re rad/μPa) at 600 Hz, and the minimum detectable acoustic pressure of 6 Pa in the experiment.     

环氧基氟化石墨耐磨涂料的研究

以环氧树脂为黏接剂,采用酰胺类固化剂,并以氟化石墨为润滑剂,SiC为耐磨填料,制备一种常温固化的耐磨涂料。用红外光谱(FT-IR)、X射线衍射(XRD)、扫描电镜(SEM)分析氟化石墨的结构和性质,用光学显微镜(OM)观测润滑剂和填料在涂料中的分散情况,探索涂料中氟化石墨和SiC的含量与涂层力学性能、摩擦性能和热性能的关系。结果表明:氟化石墨层间距为0.71 nm,晶型结构不规则,表面能较低,其润滑性能优于石墨;通过一定的工艺SiC和氟化石墨均匀地分散在涂料中;含SiC和氟化石墨的涂膜具有较好的力学性能;当SiC和氟化石墨质量分数为20%和5%时,涂层耐磨性能较好;SiC和氟化石墨使涂膜的耐热性有所改善。     

Role of Nano-YbF3-Treated Carbon Fabric on Improving Abrasive Wear Performance of Polyetherimide Composites

A method for surface treatment of carbon fabric with nano-particles of rare earth salt (ytterbium fluoride–YbF₃) was tried first time in the authors’ laboratory to enhance the fiber–matrix interface, and has been reported here. In this article authors have reported on the performance evaluation of composites developed from the four fabrics treated with various doses viz. 0, 0.1, 0.3, and 0.5 wt% of YbF₃. The abrasive wear performance of these composites was evaluated by abrading the composites against silicon carbide abrasive paper under varying loads. The treated fabric composites exhibited lower coefficient of friction and higher wear resistance as compared with untreated fabric composite. A linear correlation between ILSS (interlaminar shear strength) and wear resistance was observed. Both were the highest for 0.3% dosing of fabric. Since it was also desirable to compare the efficiency of this novel method of treatment of carbon fibers with conventional one, a few results of composites with plasma-treated carbon fabric were compared with the nano-particle-treated fabric composites. It was concluded that the latest method improved the abrasive wear resistance of composites almost two times more than the plasma-treated composites. Fiber–matrix interface was strengthened because of the treatment as observed from SEM studies, ILSS, and matrix pick-up studies. Increased roughness of fiber surface was observed in topographical analysis by SEM. Effect of treatment on fiber was also observed by adhesion test and fiber tow tension test. SEM studies of worn surfaces were performed to understand wear mechanisms.     

The mechanism of synergism between ZDDP and CeF3 additives

The interaction of zinc dialkyldithiophosphate (ZDDP) with cerium fluoride and cerium dioxide in lithium grease has been studied for friction, wear, and EP characteristics on a four-ball and SRV tester. The combination of ZDDP and cerium trifluo-ride has been shown to be beneficial in reducing wear, especially over a long period of friction and with increasing EP load. The test results show that adding cerium dioxide to lithium grease does not improve the antiwear and friction performance of the paste. The analytical results of X-ray photoelectron spectrum (ESCA, XPS) reveal that ZDDP inhibits the decomposition of cerium fluoride and improves its film-forming property. The wear scar reaches a minimum at an atomic concentration ratio of 3P:2Zn:1S:25F, and an atomic concentration ratio of 2S:2P:1Zn:4F gives the highest EP load. The scratch test results show that combining ZDDP with cerium trifluoride improves the tenacity of the surface film. The stabilisation of cerium trifluoride by ZDDP is proposed.     

全彩发光二极管交通诱导屏光纤传输系统

设计了光纤传输系统以实现交通诱导屏图像数据的远距离实时传输。针对原光端机的诸多缺点,提出了传输系统的设计方案,构建了完整的系统结构。依据以太网相关传输协议对物理层和数据链路层的设计思想进行了分析,给出了系统中重要模块的设计方法,并对内存寻址和带宽估计进行了精确计算。测试结果表明:利用单芯光纤可完成最大分辨率为1 024pixel×768pixel,刷新频率为60Hz的图像源的实时传输,最大传输速率达1.5Gbps,距离为5～10km。与原传输方案相比,该方案减少了额外光端机设备,光纤利用率提高了80%,并利用接收端级联减少了光纤铺设成本。系统能够满足城市交通指挥中心对诱导屏实时信号的传输要求,传输性能可靠,已应用于现行交通诱导系统中。     

对后向离心风机圆弧叶片的新认识

通常认为圆弧叶片的加工简单,但流动性能差,在后向离心风机已很少应用, 但近来发现,有些圆弧叶片能有85％以上的整机全压效率.为此,本文对4个不同型号的后向离心风机采用圆弧叶片和现在常用的等当量扩张角流型叶片进行整机性能数值预估对比,结果表明:上凸圆弧叶片性能良好,但下凹圆弧叶片性能差.     

Experimental study of crystal anisotropy based on ultra-precision cylindrical turning of single-crystal calcium fluoride

To realize ultimately efficient signal processing, it is necessary to replace electrical signal processing circuits with optical ones. The optical micro-resonator, which localizes light at a certain spot, is an essential component in optical signal processing. Single-crystal calcium fluoride (CaF₂) is the most suitable material for a highly efficient optical micro-resonator. The CaF₂ resonator can only be manufactured by ultra-precision machining processes, because its crystal anisotropy does not allow the application of chemical etching. However, the optical micro-resonator's performance depends definitely on the surface integrity.This study investigated the relationship between surface quality after ultra-precision machining and crystal anisotropy. Firstly, crack initiation was investigated on the (1 0 0), (1 1 0), and (1 1 1) planes using the micro-Vickers hardness test. Secondly, brittle-ductile transition was investigated by orthogonal cutting tests. Finally, cutting performance of cylindrical turning was evaluated, which could be a suitable method for manufacturing the CaF₂ resonator. The most difficult point in cylindrical turning of CaF₂ is that the crystalline plane and cutting direction vary continuously. In order to manufacture the CaF₂ optical micro-resonator more efficiently, analysis was conducted on crack initiation and surface quality of all crystallographic orientations from the perspective of slip system and cleavage.     

油气水三相流产出剖面光纤持气率计响应规律的实验研究

为进一步研究油气水三相流产出剖面测井中光纤持气率计在高含水情况下的响应规律,在大庆油田多相流实验装置上进行了动态实验研究。实验结果表明,当油的流量一定,高含水的情况下,气量在5~10m3/d变化时测量持气率值与实际持气率值之间误差变化较大。气量大于10m3/d时误差变化较小,说明该仪器适合测量气量在10m3/d以上的混合流体。此结果对光纤持气率计的进一步优化设计提供了实验依据。     

空间差分干涉的光纤分布式水下声波测量

为了实现大范围的水下微弱声波探测,提出了一种基于后向瑞利散射空间差分干涉的光纤分布式声波检测(DAS)技术。声波振动引起单模传感光纤中后向瑞利散射光的变化,将含有声波信息的后向瑞利散射光注入到非平衡迈克尔逊干涉仪,调节干涉仪的臂长差实现不同长度的相邻空间段的后向瑞利散射光干涉,然后采用3×3耦合器解调技术解调出相位信息,实现声波信号的测量。实验搭建了一套基于DAS技术的水下声波测量系统,该系统不仅能够实时准确定位两个声波位置,还能还原声波的幅值、频率、相位等信息,并且实现了1kHz情况下的-148.8dB(re rad/μPa)水下声压相位灵敏度,100~1 500Hz频率的频响平坦度在1.2dB之内。实验结果证实DAS技术能够实时快速地实现多个声波信息的定量测量。     

多路温度测量系统在室温控制中的应用

温度控制一直是一个很重要的控制对象,由于控制对象的大滞后性等特征,因此对温度的精确控制及处理也是一个难点。本设计以温度检测为研究对象,通过合理利用数据采集技术和无线通信技术,提出了基于单片机与无线传输模块为核心的多路温度测量系统,并对该系统的硬件与软件进行了较为全面的理论设计。本系统着重论述了温度数据的采集、转换、无线通信、数码显示等电路设计环节,并利用C51软件对系统各个环节进行程序监控。通过本系统的设计,较好的实现了温度检测的智能化和数字化要求,并能够产生较好的实际应用价值及经济效果。