A catalytic burner using propane and toluene alternately for the drying of textile coatings

This study aims to develop a low‐temperature catalytic burner using propane and toluene alternately as a fuel and to apply it to the drying of acrylic coatings on textiles. Pt catalysts deposited on ceramic fibres (Al₂O₃) were employed. For propane, the diffusive catalytic burner was used. The combustion efficiency of the diffusive catalytic burner deteriorated rapidly when it was installed in a downward position. Two concepts of forced diffusion combustion and premixed combustion were introduced to improve the downward placed diffusive catalytic burner. The combustion efficiency was enhanced with these modifications, but the forced diffusion was preferred since premixed combustion raised the temperature of the catalyst above 700°C leading to sintering of the catalyst. For the toluene catalytic burner the premixed combustion mode was adopted. Its optimum operation conditions were obtained by analyzing the temperatures within the catalyst layer and by adjustment of the toluene mixture. Field tests were performed on the drying acrylic coatings using the catalytic burners. The results showed that the use of catalytic burners had several benefits such as energy savings and less pollutant emissions. Copyright © 1999 John Wiley & Sons, Ltd.     

Frontiers in combustion techniques and burner designs for emissions control and CO2 capture: A review

The use of fossil fuel is expected to increase significantly by midcentury because of the large rise in the world energy demand despite the effective integration of renewable energies in the energy production sector. This increase, alongside with the development of stricter emission regulations, forced the manufacturers of combustion systems, especially gas turbines, to develop novel combustion techniques for the control of NO_x and CO₂ emissions, the latter being a greenhouse gas responsible for more than 60% to the global warming problem. The present review addresses different burner designs and combustion techniques for clean power production in gas turbines. Combustion and emission characteristics, flame instabilities, and solution techniques are presented, such as lean premixed air‐fuel (LPM) and premixed oxy‐fuel combustion techniques, and the combustor performance is compared for both cases. The fuel flexibility approach is also reviewed, as one of the combustion techniques for controlling emissions and reducing flame instabilities, focusing on the hydrogen‐enrichment and the integrated fuel‐flexible premixed oxy‐combustion approaches. State‐of‐the‐art burner designs for gas turbine combustion applications are reviewed in this study, including stagnation point reverse flow (SPRF) burner, dry low NO_x (DLN) and dry low‐emission (DLE) burners, EnVironmental burners (including EV, AEV, and SEV burners), perforated plate (PP) burner, and micromixer (MM) burner. Special emphasis is made on the MM combustor technology, as one of the most recent advances in gas turbines for stable premixed flame operation with wide turndown and effective control of NO_x emissions. Since the generation of pure oxygen is prerequisite to oxy‐combustion, oxygen‐separation membranes became of immense importance either for air separation for clean oxy‐combustion applications or for conversion/splitting of the effluent CO₂ into useful chemical and energy products. The different carbon‐capture technologies, along with the most recent carbon‐utilization approaches towards CO₂ emissions control, are also reviewed.     

Development and characterization of a low-NOx partially premixed hydrogen burner using numerical simulation and flame diagnostics

The utilization of hydrogen as a fuel in free jet burners faces particular challenges due to its special combustion properties. The high laminar and turbulent flame velocities may lead to issues in flame stability and operational safety in premixed and partially premixed burners. Additionally, a high adiabatic combustion temperature favors the formation of thermal nitric oxides (NO). This study presents the development and optimization of a partially premixed hydrogen burner with low emissions of nitric oxides. The single-nozzle burner features a very short premixing duct and a simple geometric design. In a first development step, the design of the burner is optimized by numerical investigation (Star CCM+) of mixture formation, which is improved by geometric changes of the nozzle. The impact of geometric optimization and of humidification of the combustion air on NO_x emissions is then investigated experimentally. The hydrogen flame is detected with an infrared camera to evaluate the flame stability for different burner configurations. The improved mixture formation by geometric optimization avoids temperature peaks and leads to a noticeable reduction in NO_x emissions for equivalence ratios below 0.85. The experimental investigations also show that NO_x emissions decrease with increasing relative humidity of combustion air. This single-nozzle forms the basis for multi-nozzle burners, where the desired output power can flexibly be adjusted by the number of single nozzles.     

Increasing the efficiency of radiant burners by using polymer membranes

Gas-fired radiant burners are used to convert fuel chemical energy into radiation energy for various applications. The radiation output of a radiant burner largely depends on the temperature of the combustion flame. In fact, the radiation output and, thus, the radiant efficiency increase to a great extent with flame temperature. Oxygen-enriched combustion can increase the flame temperature without increasing fuel cost. However, it has not been widely applied because of the high cost of oxygen production. In the present work, oxygen-enriched combustion of natural gas in porous radiant burners was studied. The oxygen-enriched air was produced passively, using polymer membranes. The membranes were shown to be an effective means of obtaining an oxygen-enriched environment for gas combustion in the radiant burners. Two different porous radiant burners were used in this study. One is a reticulated ceramic burner and the other is a ceramic fibre burner. The experimental results showed that the radiation output and the radiant efficiency of these burners increased markedly with rising oxygen concentrations in the combustion air. Also investigated were the effects of oxygen enrichment on combustion mode, and flame stability on the porous media.     

Catalytic combustion of hydrogen for residential heat supply application

Hydrogen can be converted to thermal energy by combustion or to electricity energy by fuel cells. Considering the stringent requirements for safety from fire hazards and elimination of pollutants, the flameless catalytic combustion of hydrogen is favorable over conventional flame combustion for residential heat supply application. This paper reported an industrial‐scale heat acquisition system based on hydrogen catalytic combustion. The 1 wt% Pt‐loaded glass fiber felts prepared by an impregnation process were used as the combustion catalyst, and a catalytic combustion burner with a capacity of 1 kW was designed. It was found that 100% hydrogen conversion rate could be obtained during the stable combustion stage, and the stable combustion could be achieved by adjusting hydrogen flow rate. The change in H₂/air ratio would influence the initial combustion stage but has little impact on the stable combustion stage. A heat efficiency of 80% for hot water supply was obtained based on the present catalytic hydrogen combustion burner. Copyright © 2016 John Wiley & Sons, Ltd.     

Fuel‐lean VOCs combustion in a porous burner stacked with alumina balls: A case for ethylene combustion

A porous burner stacked in turn with 3‐ and 9‐mm alumina pellets was established to perform C₂H₄ combustion experiments by acquiring the flammable limits, temperature variation characteristics, combustion wave velocity, pollutant emissions, and treatment efficiency. The burner operated well at equivalence ratios within 0.3 to 0.7. Larger alumina pellets widened the burner's lower flammable limit. As the flame propagated downstream, the higher premixed gas flow velocity and larger alumina pellets, the higher combustion wave velocity, whereas the circumstances were opposite as the flame spread upstream. The combustion temperature increased with the equivalence ratio and premixed gas flow velocity. In response to the effect of the alumina pellet dimension, 3‐mm alumina pellets corresponded to higher combustion temperatures, lower CO emissions, and higher treatment efficiency than those less than 9‐mm conditions.     

Study on nonpremixed methane/air combustion from flame structure and NOX emission aspect for different burner head structures

In the present study, the air turbulator, which is a part of a nonpremixed burner, is investigated numerically in terms of its effects on the diffusion methane flame structure and NO_X emissions. A computational fluid dynamics (CFD) code was used for the numerical analysis. At first, four experiments were conducted using natural gas fuel. In the experimental studies, the excess air ratio was taken constant as 1.2, while the fuel consumption rate was changed between 22 and 51 Nm³/h. After the experimental studies, the CFD studies were carried out. Pure methane was taken as fuel for the simulations. The nonpremixed combustion model with the steady laminar flamelet model (SFM) approach was used in the combustion analyses. Methane‐air extinction mechanism with 17 species and 58 reactions was used for the simulations. The results obtained from the CFD studies were confronted with the measurements of the flue gas emissions in the experimental studies. Then, a modified burner head was analysed numerically for the different air turbulator blade numbers and angles. The CFD results show that increasing the air turbulator blade number and angle causes the thermal NO emissions to be reduced in the flue gas by making the flame in the combustion chamber more uniform than the original case. This new flame structure provides better mixing of the fuel and combustion air. Thus, the diffusion flame structure in the combustion chamber takes the form of the partially premixed flame structure. The maximum reduction in the thermal NO emissions in the flue gas is achieved at 38% according to the original case.     

多孔介质稳焰器对旋流火焰振荡燃烧特性影响的试验研究

为研究多孔介质稳焰器孔密度变化对贫预混旋流火焰振荡燃烧特性的影响,通过光电倍增管测量全局火焰热释放率,采用双麦克风方法测量旋流器入口速度脉动,获得不同孔密度多孔介质稳焰器火焰传递函数;并通过高速相机测量不同孔密度多孔介质稳焰器振荡火焰结构的变化。试验结果表明：多孔介质能够改变燃烧室声模态,有效抑制燃烧振荡,但孔密度对受迫燃烧火焰热释放率和压力脉动影响具有非线性;高频入口扰动对火焰响应特性影响较弱,火焰受迫响应呈现低通滤波特性;火焰传递函数增益峰值对应入口激励频率存在差异,但相位分布斜率基本一致;多孔介质导致火焰向稳焰器中心轴线聚拢,相干结构更加明显;宽频扰动范围内的火焰张角分布趋势与火焰传递函数增益曲线的分布趋势相反。     

Hydrogen substitution of natural-gas in premixed burners and implications for blow-off and flashback limits

Two multi-perforated premixed burners, designed for natural gas, are fueled with increasing hydrogen content to assess the limits of H₂ substitution and investigate potential risks associated to it. The burners feature a different design, which affects flame stabilization and heat exchange between the fresh mixture and the hot burner walls. First, results are presented by means of stability maps that were collected at constant power and over a wide range of equivalence ratio, from pure methane-air to pure hydrogen-air mixtures. The impact of hydrogen addition on blow-off and flashback limits is then analyzed. On one side, it is observed that hydrogen addition increases blow off resistance, extending the operating range towards ultra-lean conditions. On the other side, hydrogen raises the thermal load on the burner favoring flashback. It is shown that the competition between the bulk velocity at the burner outlet and the laminar burning velocity is not a reliable parameter to predict flashback occurrence, while the thermal state of the burner represents a determining factor. An analysis of the thermal transient reveals a strict correspondence between the onset of flashback for a given mixture composition and the burner surface temperature. Results highlight the challenges linked to the design of fuel-flexible systems, pointing out practical limits of H₂ substitution in burners designed for operation with natural gas.     

Experimental study of the combustion efficiency and formation of NOx in an industrial pulverized coal combustor

With horizontal bias combustion burners, experiments have been carried out on a 670 t h^?1, corner‐fired, pulverized‐coal fired boiler burning bituminous coal. At 200 MWe load, the furnace excess O₂ remains stable. The different horizontal fuel biases are obtained by changing the tilt angle of all the Louvre enrichers' regulating blades. The tilt angles of the blades are 0, 15, 24, 32°; the result is that the enriching ratios of the fuel‐rich primary air increase from 2.2 to 2.6 at No. 2 corner, and from 1.2 to 4.2 at No. 3 corner. The gas temperature increases in the burner region. The application of the horizontal bias combustion burners results in a reduction in NO_x formation from 545.7 mg Nm^?3 (O₂=6%) to 287.9 mg Nm^?3, and a substantial reduction in carbon in ash content from 5.24 to 2.48%. The boiler operated stably at a load of 80 MWe without auxiliary fuel oil. Copyright © 2004 John Wiley & Sons, Ltd.     

多孔介质中预混火焰猝熄及自稳定性研究

分析了多孔介质中预混火焰的猝熄效应,试验测定了一系列工况下泡沫陶瓷的猝熄直径和自稳定范围,为多孔介质燃烧器的开发设计提供了依据。通过分析发现,猝熄直径受到多个参数的影响,包括：混合气体的流速u、预混气体的层流火焰传播速度SL、燃烧室空管Re、预混气体的导温系数a、当量比φ以及多孔介质固体温度Ts。通过对多孔介质中燃烧的自稳定性试验研究,发现了多孔介质燃烧器中火焰稳定极限(吹脱极限和回火极限)与多孔介质平均孔径和气流速度及燃烧当量比的关系。     

Investigation of flame characteristics using various design parameters in a pulverized coal burner for oxy‐fuel retrofitting

In oxy‐coal combustion for carbon capture and storage, oxygen and recirculated CO₂ are used as oxidizers instead of air to produce CO₂‐rich flue gas. Owing to differences between the physical and chemical properties of CO₂ and N₂, the development of a burner and boiler system based on fundamental understanding of the flame type, heat transfer, and NOx emission is required. In this study, computational fluid dynamic analysis incorporating comprehensive coal conversion models was performed to investigate the combustion characteristics of a 30 MWth tangential vane swirl pulverized coal burner. Various burner design parameters were evaluated, including the influence of the burner geometry on the swirl strength, direct O₂ injection, and O₂ concentrations in the primary and secondary oxidizers. The flame characteristics were sensitive to the oxygen concentration in the primary oxidizer. The performance of direct O₂ injection around the primary oxidizer with low O₂ concentration was dependent on the mixing of the fuel and oxidizer. The predictions showed that swirl number adjustment and careful direct oxygen injection design are essential for retrofitting air‐firing pulverized coal burners as oxy‐firing burners.     

摆动式水平浓淡风煤粉燃烧器在670 t/h锅炉的应用研究

我厂2号锅炉(DG 670/13.7-8A)为四角切圆布置,一、二次风间隔布置,分上下两组,设计煤种为晋中贫煤.在实际运行中,煤质不稳定,锅炉着火和燃烧稳定性差.采用"摆动式水平浓淡风煤粉燃烧器"技术对燃烧器改造后,燃烧效率提高0.84%、在300 t/h时能稳定燃烧、炉膛无结渣,锅炉参数稳定.     

催化燃烧炉近零污染排放和高辐射效率利用的研究

在催化燃烧炉中,对贫天然气/空气混合物在镀贵金属（铂）蜂窝状支撑物横端面上燃烧进行研究.燃气与空气之间的比例关系对系统的辐射效率有相当大的影响,随着天然气与空气比的增大,燃烧系统的辐射效率降低.对于所测天然气,此催化燃烧过程可达到近零污染排放.     

Porous burners for lean-burn applications

We review research on lean methane combustion in porous burners, with an emphasis on practical aspects of burner design and operation and the application of the technology to real-world problems. In particular we focus on ‘ultra-lean’ combustion, where the methane concentration is actually at or below the lean flammability limit for a free flame (5% methane by volume in air). Porous burners are an advanced combustion technology whereby a premixed fuel/air mixture burns within the cavities of a solid porous matrix. They are capable of burning low-calorific value fuels and very lean fuel/air mixtures that would not normally be flammable, potentially allowing the exploitation of what would otherwise be wasted energy resources. Possible lean-burn applications include the reburn of exhaust gases from existing combustion systems, and the mitigation of fugitive methane emissions. Porous burners operate on the principle that the solid porous matrix serves as a means of recirculating heat from the hot combustion products to the incoming reactants. This results in burning velocities higher than those for a free flame, as well as extended lean flammability limits. Burner performance is also characterised by low emissions of combustion related pollutants and stable operation over a wide range of fuel concentrations and flow rates. Stable combustion of methane/air mixtures below the conventional lean limit has been observed by a number of researchers; in one study the combustion of a mixture with a fuel concentration of only 1% was reported. A number of design considerations are important as regards optimising burner performance for lean-burn applications. Foremost among these is the selection of a suitable material for the porous matrix. Possibilities include packed beds of alumina spheres or saddles, and reticulated foams made of silicon carbide or high temperature metal alloys. Other potentially significant design issues include the length of the porous bed, the use of ‘multi-section’ designs where different porous materials are used in each section, the incorporation of external heat exchangers to supplement the heat recirculation provided by the porous matrix, and the ability to operate the burner at elevated pressures. There is an extensive body of research relating to porous burners, comprising experimental and numerical investigations. However the majority of previous studies have been directed towards the use of porous burners for radiant heating applications rather than for the combustion of low-calorific value fuels. Consequently there is a lack of reliable data relating specifically to ultra-lean combustion. We identify specific areas where further research is required to progress this field. These include the influence on burner performance of the design considerations listed above, the stability of the combustion process to fluctuations in fuel concentration and flow rate, the development of reliable models specifically for ultra-lean combustion in practical burners, and the investigation of issues relating to scale-up and commercial application.     

Characterization of confined hydrogen-air jet flame in a crossflow configuration using design of experiments

Hydrogen combustion has many industrial applications and development of new hydrogen burners is required to fulfil new demands. A novel configuration of hydrogen burner utilizing crossflow injection of fuel jets into swirling combustion air is characterized empirically in this work. It is intended as a first step in the development of new burner technologies having reduced emission levels and improved efficiency. Experiments were designed using the full factorial design method. Operating parameters were varied simultaneously and the NO_X emissions from the flame stabilized on the burner were measured. Statistical analysis of the experimental data showed that overall equivalence ratio is the dominant factor and lower NO_X emissions are observed at low equivalence ratios, irrespective of the burner power level. The analysis yielded an empirical relationship among NO_X emission, overall equivalence ratio, and power level that is useful in the design activity for a future combustion system based on the proposed configuration.     

A filtered-laminar-flame PDF sub-grid scale closure for LES of premixed turbulent flames. Part I: Formalism and application to a bluff-body burner with differential diffusion

A sub-grid scale closure for Large Eddy Simulation (LES) of turbulent combustion based on physical-space filtering of laminar flames is discussed. Applied to an unstructured grid, the combustion LES filter size is not fixed in this novel approach devoted to LES with refined meshes, but calibrated depending on the local level of unresolved scalar fluctuations. The context is premixed or stratified flames, the derived model relies on four balance equations for mixture fraction and its variance, and a progress variable and its variance. The proposed formalism is based on a presumed probability density function (PDF) derived from the filtered flames. Closures for the terms of the equations that are unresolved over LES grids are achieved through the PDF. The method uses flamelet tabulated detailed chemistry and is first applied to the simulation of laminar flames (1D and 2D) over various grids for validation, before simulating a turbulent burner studied experimentally by Sweeney et al. (2012). Since this burner also features differential diffusion effects, the numerical model is modified to account for accumulation of carbon in the recirculation zone behind the bluff-body. A differential diffusion number based on the gradient of residence times is proposed, in an attempt to globally quantify differential diffusion effects in burners.     

An experimental study on the high frequency oscillatory combustion in tubular flame burners

In this study, high frequency oscillatory combustion in tubular flame burner was experimentally investigated using large scale 8- and 12-in. diameter tubular flame burners. The conditions for the high frequency oscillatory combustion were determined, and the pressure fluctuations were measured, on which spectral analyses were made. The results showed that a smooth laminar tubular flame could be established, however, high frequency combustion sound was emitted from the 8- and 12-in. burners when the air flow rates exceeded 650 and 1200 m³/h, respectively. Pressure fluctuation measurements and spectral analyses showed that high frequency pressure fluctuations occurred simultaneously during the high frequency oscillation. The flame images were also obtained with a high speed video camera. The flame surface was found to be notably corrugated and the symmetry was broken during the oscillation. By assuming that the tubular flame burner is a simple tube, the natural frequencies of the burners were determined using the fundamental theory of the acoustic resonance in a cylindrical cavity, and the experimental peak frequencies in the spectra were compared with the natural frequencies. As a result, it was found that the high frequency oscillations in both the burners were identified as the tangential/radial mode acoustic resonant oscillations. It was further found that the tangential first mode of oscillation, which had an asymmetric structure, preceded the higher modes of oscillation which indicated that the mode dominated the occurrence of the high frequency oscillation. To verify the occurrence of the tangential first mode oscillation, the pressure fluctuations were measured with two pressure sensors installed at opposed locations. The results showed that the phase of the oscillation was 180° difference, and the asymmetric structure confirmed the occurrence of the tangential first mode of oscillation.     

Development of energy efficient porous medium burners on surface and submerged combustion modes

Two compact premixed LPG burners based on submerged and surface combustion modes in porous medium (abbreviated as MSB and SSB respectively) are developed and their combustion and emission characteristics are compared to those of the CB (conventional burner). The preheating and reaction zones of MSB are made from porcelain form and Alumina spheres of 30 mm size, respectively, and the corresponding zones in SSB are made from Alumina (Al₂O₃) foams of pore densities 26 ppcm and 8 ppcm. NO_x emission is reduced by 76% and 75% by the use of MSB and SSB, respectively, compared with the CB, with acceptable CO and SO₂ emissions. For a thermal load of 0.62 kW, the thermal efficiencies of CB, MSB and SSB are estimated to be 47%, 59% and 71%, respectively.     

Influence of hydrogen addition to pipeline natural gas on the combustion performance of a cooktop burner

Displacing pipeline natural gas with renewable hydrogen is a promising way to reduce the emission of carbon dioxide, which is a major greenhouse gas. However, due to significantly differing characteristics of hydrogen and natural gas, such as flame speed, adiabatic flame temperature and stability limits, the combustion performance of hydrogen/natural gas mixture differs from pure natural gas. From the perspective of residential end users, a key question is: how much hydrogen can be injected into the pipeline natural gas without influencing the performance of the residential burners? A representative cooktop burner is selected to study the influence of hydrogen addition on the combustion and cooking performance. Flashback limits, ignition time, flame characteristics, cooking performance, combustion noise, burner temperature, and various emissions (NO, NO₂, N₂O, CO, unburned hydrocarbon (UHC), NH₃) are evaluated for different levels of hydrogen addition. According to the experimental results, the combustion performance of the cooktop burner is not significantly affected with up to about 15% hydrogen addition by volume, which shows the feasibility of utilizing hydrogen on existing cooking appliances without any modification. The experiment methodologies and results in this study will serve as a reference for future test and emission regulation standards on domestic burners.