Advantages of nanocomposite coatings deposited by high power pulse magnetron sputtering technology

Recent advantages in PVD coatings for cutting tools enable high speed and dry machining with superior cutting parameters in commercial manufacturing sectors. For this reason hard coatings with high oxidation resistance and thermal stability are used for economically justifiable machining. In this regard nc-(Ti,Al)N/a-Si₃N₄ films were sputtered on tungsten carbide cutting tools and WC/Co samples by using the high power pulse magnetron sputtering (HPPMS) technology. Coating composition, microstructure and applied properties were investigated by using X-ray diffraction, scanning electron microscope and nanoindentation. The hardness value was about 29 GPa for a Si content of 3.3 at.%. The grain size was about 6 nm. As this study focuses on the thickness uniformity of the coatings, SEM pictures of the cross-section have been taken around the cutting edge to determine the deposition rate and the film growth. The coatings morphology has been compared to middle frequency and direct current sputtered nanocomposite (Ti,Al,Si)N films. The results demonstrate the enhanced HPPMS coatings properties, including a denser structure, a smoother surface and a favourable thickness uniformity.     

Adhesion phenomena in the secondary shear zone in turning of austenitic stainless steel and carbon steel

This paper aims to increase the understanding of the adhesion between chip and tool rake face by studying the initial material transfer to the tool during orthogonal machining at 150 m/min. Two types of work material were tested, an austenitic stainless steel, 316L, and a carbon steel, UHB 11. The tools used were cemented carbide inserts coated with hard ceramic coatings. Two different CVD coatings, TiN and Al₂O₃, produced with two different surface roughnesses, polished and rough, were tested. The influences of both tool surface topography and chemistry on the adhesion phenomena in the secondary shear zone were thus evaluated. Extensive surface analyses of the inserts after cutting were made using techniques such as Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), X-ray Photoelectron Spectroscopy (XPS), and Transmission Electron Microscopy (TEM). As expected, cutting in the stainless steel resulted in a higher amount of adhered material, compared to cutting in the carbon steel. Remnants of built-up layers were found on the surfaces of the 316L chips but not on the UHB 11 chips. Moreover, it was shown that for both materials the tool roughness had a profound effect, with the rougher surfaces comprising much higher amounts of adhered material than the polished ones. Non-metallic inclusions from both types of workpiece steels accumulate in the high temperature area on the inserts. The general tendency was that higher amounts of transferred material were found on the TiN coating than on the Al₂O₃ coating after cutting.     

Machining performance of pearlitic–ferritic nodular cast iron with coated carbide and silicon nitride ceramic tools

This paper concerns the fundamental cutting characteristics obtained in the turning of the pearlitic–ferritic nodular iron (EN-GJS-500-7 grade with UTS=500 MPa) when using carbide tools coated with single TiAlN and multilayer TiC/Ti(C,N)/Al₂O₃/TiN coatings, as well as silicon nitride (Si₃N₄) based ceramic tools. As a competitor, a P20 uncoated carbide grade was selected. The fundamental process readings include cutting and feed forces, the tool–chip interface temperature, Peclet number, friction coefficient and the tool–chip contact length as functions of cutting parameters. In particular, the measurements of cutting temperature were carried out using conventional tool–work thermocouple method and IR thermography. It is concluded based on many process characteristics that multilayer coated and ceramic tools can substantially improve the performance of nodular iron machining.     

Mathematical modeling of surface roughness for evaluating the effects of cutting parameters and coating material

The work presented in this paper examines the effects of cutting parameters (cutting speed, feed rate and depth of cut) onto the surface roughness through the mathematical model developed by using the data gathered from a series of turning experiments performed. An additional investigation was carried out in order to evaluate the influence of two well-known coating layers onto the surface roughness. For this purpose, the experiments were repeated for two CNMG 120408 (with an ISO designation) carbide inserts having completely the same geometry and substrate but different coating layers, in a manner that identical cutting conditions would be ensured. The workpiece material machined was cold-work tool steel AISI P20. Of the two types of inserts employed; Insert 1 possesses a coating consisting of a TiCN underlayer, an intermediate layer of Al₂O₃ and a TiN outlayer, all deposited by CVD; whilst Insert 2 is PVD coated with a thin TiAlN layer (3 ± 1 μm). The total average error of the model was determined to be 4.2% and 5.2% for Insert 1 and Insert 2, respectively; which proves the reliability of the equations established.     

Thermal and thermo-mechanical properties of Ti–Al–N and Cr–Al–N coatings

Metastable Ti–Al–N and Cr–Al–N coatings have been proven to be an effective wear protection due to their outstanding mechanical and thermal properties. Here, a comparative investigation of mechanical and thermal properties, for Ti–Al–N and Cr–Al–N coatings deposited by cathodic arc evaporation with the compositions (c-Ti_0.52Al_0.48N, c/w-Ti_0.34Al_0.66N and c-Cr_0.32Al_0.68N) widely used in industry, has been performed in detail. The hardness of Ti_0.52Al_0.48N and Ti_0.34Al_0.66N coatings during thermal annealing, after initially increasing to the maximum value of ~ 34.1 and 38.7 GPa with T_a up to 900 °C due to the precipitation of cubic Al-rich and Ti-rich domains, decreases with further elevated T_a, as the formation of w-AlN and coarsening of precipitated phases. A transformation to Cr₂N and finally Cr via N-loss in addition to w-AlN formation during annealing of the Cr_0.32Al_0.68N coating occurs, and thus results in a continuous decrease in hardness. Among our coatings, the mixed cubic-wurtzite Ti_0.34Al_0.66N coating exhibits the highest thermal hardness, but the worst oxidation resistance. The Cr_0.32Al_0.68N coating shows the best oxidation resistance due to the formation of dense protective α-Al₂O₃-rich and Cr₂O₃-rich layers, with only ~ 1.4 μm oxide scale thickness, after thermal exposure for 10 h at 1050 °C in ambient air, whereas Ti–Al–N coatings are already completely oxidized at 950 °C.     

Improved properties of Ti-Al-N coating by multilayer structure

Multinary Ti-Al-N coatings are used for various applications where hard, wear and oxidation resistant materials are needed. Here, we prepare TiAlN/TiN nano-multilayer coatings with modulation period of ~ 20 nm in order to further improve the properties of Ti-Al-N coating. Annealing of both coatings up to 700 °C results in an increase in hardness due to the precipitation of cubic Al-rich domains by spinodal decomposition. Multilayer structure results in an increase in adhesion with substrates from ~ 72 N for Ti-Al-N single layer coating to 98 N for TiAlN/TiN nano-multilayer coating. Additionally, the interfaces of TiAlN/TiN nano-multilayer coating retard the outward diffusion of metal atoms (Al and Ti) and inward diffusion of O while exposing coatings in air atmosphere with elevated temperature, and thus improve its oxidation resistance. An improved machining performance regardless of continuous cutting and milling is obtained by TiAlN/TiN nano-multilayer coated inserts, which can be attributed to the combined effects of higher adhesion with substrates and better oxidation resistance.     

Structures and properties of TiAlCrN coatings deposited on Ti(C,N)-based cermets with various WC contents

In this paper, the Ti(C,N)-based cermets with various WC contents were used as the substrates of TiAlCrN coatings. The influence of WC addition on the structures and properties of the coatings was investigated. Besides, cutting tests on the coated cermet inserts were conducted under different conditions. The results indicated that the cermet substrates with finer grains provided more nucleation to the coatings. The grain size of the coating decreased with increasing WC contents in the substrate. W diffused from the substrates to coatings, which deteriorated the adhesion between TiAlCrN coatings and the cermet substrates. The coated cermet inserts presented better cutting performance, when WC was added to the substrates. However, the cutting performance of the coated cermet inserts was weaken when the addition of WC was more than 10 wt%.     

Face milling of the EN AB-43300 aluminum alloy by PVD- and CVD-coated cemented carbide inserts

Two commercially available WC-6Co cemented carbide substrates (Extramet EMT100 and Pramet H10), were industrially coated with PVD TiB₂ or CVD diamond. Subsequently, the coated inserts were submitted to dry sliding tests (slider on cylinder contact geometry) against the aluminum alloy EN AB-43300, for preliminary performance ranking and identification of basic wear mechanisms. The best substrate/coating combination (CVD-Diamond coated Extramet EMT100) was then tested in face milling EN AB-43300 with milling tool characterized by two different geometries (A and B), using PCD inserts as a reference for comparison. In milling tests, the influence of both insert geometry and cutting fluid feed rate were taken into account. The geometry of the tool was identified as the main parameter in influencing the tool performance. In particular, in the case of the A geometry, the relative flank wear of CVD coated tools increased abruptly during the test due coating detachment, whilst with the B geometry no catastrophic failure of the CVD coated insert was observed. The influence of Cutting Fluid Feed Rate (CFFR) also changed with tool geometry: in particular, with the B geometry, which allowed to obtain the best results with the CVD coated inserts, a decrease of CFFR from 100 to 25% did not affect significantly the wear resistance of CVD-coated inserts and allowed to maintain the roughness of the workpiece (R_a) below 0.6 μm, notwithstanding a slightly increased tendency towards the formation of Al-based transfer layers.     

Microstructure evolution and densification kinetics of Al2O3/Ti(C,N) ceramic tool material by microwave sintering

The microstructure evolution and densification kinetics of Al₂O₃/Ti(C,N) ceramic tool material during microwave sintering were studied. The density and grain growth significantly increases at the temperatures higher than 1400 °C. The calculated kinetics parameter n indicates that volume diffusion is the main densification mechanism when the sintering temperature is below 1300 °C, while grain boundary diffusion plays a leading role in the densification process when the sintering temperature is higher than 1300 °C. The grain growth activation energy of Al₂O₃/Ti(C,N) composite is 48.82 KJ/mol, which is much lower than those of monolithic Al₂O₃ in the microwave sintering and conventional sintering. The results suggested that the Al₂O₃/Ti(C,N) ceramic tool material with nearly full densification and fine grains can be prepared by two-step microwave sintering.     

Advanced coated ceramic tools for machining superalloys

The main limitation on the use of nickel-base superalloys, such as INCONEL 718, is the difficulty in conventional-type machining. The use of high cutting speed to achieve both machining adiabatic conditions and high productivity is necessary for their applications. This non-conventional type machining results in a short life-span of tools, even for those expensive ceramic ones with reinforced SiC whiskers (SiC_w) suitable for use at high cutting speeds. The aim of the paper is to present the results of a new idea proposed by the authors to obtain an increase in tool life at high cutting speed by minimizing the temperature effects on composite reinforcement mechanisms. The 2090 SiC whiskers reinforced A1₂O₃ tools were CrN and (Ti,AI)N coated using the PVD technique, and comparative machining tests on INCONEL 718 were carried out using uncoated and coated tools. After machining, the tools were observed with a scanning electron microscope (SEM), and EDAX (X-ray) semiquantitative analyses were performed. The behaviour of the CrN and (Ti,AI)N layers using various cutting conditions was analysed and different wear mechanisms along the tool chip contact length were observed. The cause and the mechanisms of wear were deduced and mathematic models linking tool life with process parameters were suggested.     

Effect of femtosecond laser pretreatment on wear resistance of Al2O3/TiC ceramic tools in dry cutting

A femtosecond pulsed laser (pulse width: 120 fs, wavelength: 800 nm and repetition rate: 500 Hz) was used for the pretreatment on the rake face of Al₂O₃/TiC ceramic cutting tools. The evolution of surface morphology of pretreated cutting tools irradiated with different pulse energies was measured by scanning electron microscope (SEM) and atomic force microscope (AFM). Dry cutting tests were carried out with these pretreated tools and conventional tools on hardened steel. The effect of pulse energy on the wear resistance of these pretreated tools was investigated. Results show that the cutting forces have no significant difference between laser pretreated tools and the conventional tool; the cutting temperatures of laser pretreated tools were slightly reduced compared with the conventional tool. Meanwhile, we found that the laser pretreated tools increased the adhesions of chips on the rake face, but they can significantly improve the wear resistance of the rake face; and laser pulse energy was found to have a profound effect on the wear resistance of the laser pretreated tools.     

The history of hard CVD coatings for tool applications at the University of Technology Vienna

The history of chemical vapour deposition (CVD) started in the 19th century with the production of lamp filaments and by the Mond process for the nickel production. In the 20th century Van Arkel deposited metals from the gas phase for application in lamp industry.TiC was the first hard coating deposited by CVD in the 1950s. Nearly 20 years later Krupp Widia introduced the first commercial TiC coating on hardmetal tools.Prof. Richard Kieffer started with TiN deposition by the CVD process in the 1970s at the “Technischer Hochschule Wien” and Prof. Benno Lux continued with Al₂O₃- and diamond coatings.In the following years CVD processes for TiN, Ti(C,N), ZrC, (Ti,Zr)C, TiB₂, Al₂O₃, Ta_xC, Cr_xC_y, diamond, BN and BCN were investigated at the University of Technology Vienna.The depositions of new crystalline solid solutions (mixed crystals), nano-crystalline materials and nano-crystalline mixtures of phases have been research topics so far.     

Machining performance and decomposition of TiAlN/TiN multilayer coated metal cutting inserts

The wear resistance of metal cutting inserts coated with metastable Ti_0.34Al_0.66N/TiN multilayers was tested in continuous turning of an AISI 316L stainless steel. The multilayers had periods of 25 + 50, 12 + 25 and 6 + 12 nm (Ti_0.34Al_0.66N + TiN) with a total multilayer stack thickness of 2 μm. Inserts coated with monolithic TiN and Ti_0.34Al_0.66N deposited under similar conditions were used as references. The multilayer coated inserts show a decrease of wear with decreased multilayer period, both on the rake and flank face. The wear on the rake face was lower on all the multilayer coated tools compared to the references. Scanning transmission electron imaging and energy dispersive spectroscopy elemental mapping of a worn multilayer coating show decomposition of the Ti_0.34Al_0.66N to domains rich of Al and Ti. High resolution transmission electron micrography shows preserved epitaxy between the TiN and Ti_0.34Al_0.66N layers. The improved wear resistance of the multilayer coated inserts is discussed in terms of an improved thermal stability of the multilayer stacks.     

A comparative study of two kinds of Y and Al modified silicide coatings on an Nb–Ti–Si based alloy prepared by pack cementation technique

Two kinds of Y and Al modified silicide coatings on an Nb–Ti–Si based alloy were prepared by pack cementation technique. The microstructure and oxidation behavior of both coatings were studied. Both coatings had a multiple layer structure, but the outer layers were composed of either Y- and Al-doped (Nb,X)Si₂ or Y-doped (Nb,X)₃Si₅Al₂ + (Nb,X)Si₂ phases, respectively. The former coating could protect the substrate alloy from oxidation at 1250 °C for 100 h, but the latter coating could only endure for less than 20 h. The scale formation mechanisms and microstructural changes of both coatings upon oxidation have been illustrated.     

Finite element modelling of the thermo-mechanical behavior of coatings under extreme contact loading in dry machining

During metal cutting processes, intensive friction and high temperature generated at the tool chip interface affect the cutting zone of the tool, by inducing damage and wear. To improve the cutting tool's life, thin hard coatings, synthesized by physical or chemical vapor deposition (PVD or CVD) techniques, are often used as protective layers. In this work, numerical/theoretical analysis of dry machining has been performed to study the impact of different coating layers on the machining process. Four cases are considered: an uncoated tool made of tungsten carbide (WC-Co) and coated tungsten carbides in three different configurations. The first one is made of one layer namely TiN, the second one (hypothetical carbide insert) is composed of two layers (Al₂O₃ and TiN), and the last one has three layers (TiCN, Al₂O₃ and TiN). The workpiece material is an AISI 316L stainless steel. All cutting conditions are fixed in order to highlight the effect of coatings independently from others influencing parameters. The analysis has shown the impact of the different configurations of coatings on the temperature level inside the tool and on its surface, on the pressure and also on the cutting and feed forces.     

Effects of Ti addition on microstructure homogenization and wear resistance of wide-band laser clad Ni60/WC composite coatings

Ni60/WC composite coatings were fabricated by wide-band laser cladding. The effects of Ti addition on microstructure homogenization and coating properties were investigated. Coating microstructure, phase constitution, microhardness and wear resistance were studied and grading analysis of in-situ synthesized ceramic particles was carried out. Results indicated that ceramics particles of Cr₅B₃ and M₂₃C₆ (M represents for Cr and W) carbides were in-situ synthesized in original Ni60-20WC coatings. With Ti addition, dissolution of original WC was facilitated and lots of TiC particles were synthesized instead of M₂₃C₆ carbides. Furthermore, the block Cr₅B₃ particles were greatly homogenized due to the net structure formed by dispersive TiC particles. With Ti addition, D50 of particle size decreased from 8.94 μm to 4.45 μm and particle morphologies were transformed from star-like shapes to uniform square blocks. Microhardness distribution became more uniform with average value decreased from 799 ± 89 HV_0.2 to 744 ± 77 HV_0.2. Due to the homogenized ceramic particles, wear resistance of coatings with Ti addition was enhanced to 2.6 times that of the original coatings.     

Effect of C2H2 gas flow rate on synthesis and characteristics of Ti–Si–C–N coating by cathodic arc plasma evaporation

The influences of C₂H₂ gas flow rate on the synthesis, microstructure, and mechanical properties of the Ti–Si–C–N films were investigated. Quaternary Ti–Si–C–N coatings were deposited on WC-Co substrates using Ti and TiSi (80:20 at.%) alloy target on a dual cathodic arc plasma evaporation system. The Ti–Si–C–N coatings were designed with Ti/TiN/TiSiN as an interlayer to enhance the adhesion strength between the top coating and substrate. The Ti–Si–C–N coatings were deposited under the mixture flow of N₂ and C₂H₂. Composition analysis showed that as the C₂H₂ gas flow increased, the Ti, Si and N contents decreased and the carbon content increased in the coatings. The results showed the maximum nanohardness of approximately 40 GPa with a friction coefficient of 0.7 was obtained at the carbon content of 28 at.% (C₂H₂ = 15 sccm). However, as the C₂H₂ gas flow rate increased from 15 to 40 sccm (carbon content from 25.2 to 56.3 at.%), both the hardness and friction coefficient reduced to 20 GPa and 0.3, respectively. Raman analysis indicated the microstructure of the deposited coating transformed from Ti–Si–C–N film to TiSi-containing diamond-like carbon films structure, which was strongly influenced by the C₂H₂ flow rate and is demarcated at a C₂H₂ flow of 20 sccm. The TiSi-containing diamond-like carbon films reveal low-friction and wear-resistant nature with an average friction coefficient between 0.3 and 0.4, lower than both TiSiN and Ti–Si–C–N films.     

Thermal stability of Al1−xInxN (0 0 0 1) throughout the compositional range as investigated during in situ thermal annealing in a scanning transmission electron microscope

The thermal stability of Al_1?xIn_xN (0 ? x ? 1) layers was investigated by scanning transmission electron microscopy (STEM) imaging, electron diffraction, and monochromated valence electron energy loss spectroscopy during in situ annealing from 750 to 950 °C. The results show two distinct decomposition paths for the layers richest in In (Al_0.28In_0.72N and Al_0.41In_0.59N) that independently lead to transformation of the layers into an In-deficient, nanocrystalline and a porous structure. The In-richest layer (Al_0.28In_0.72N) decomposes at 750 °C, where the decomposition process is initiated by In forming at grain boundaries and is characterized by an activation energy of 0.62 eV. The loss of In from the Al_0.41In_0.59N layer was initiated at 800 °C through continuous desorption. No In clusters were observed during this decomposition process, which is characterized by an activation energy of 1.95 eV. Finally, layers richest in Al (Al_0.82In_0.18N and Al_0.71In_0.29N) were found to resist thermal annealing, although the initial stages of decomposition were observed for the Al_0.71In_0.29N layer.     

Characterization studies of pulse magnetron sputtered hard ceramic titanium diboride coatings alloyed with silicon

The composition, structure and mechanical properties of pulsed-DC unbalanced magnetron sputtered Ti–Si–B thin films—hard coatings with the potential for excellent thermal stability and oxidation resistance—are investigated and reported in this paper. Fully dense, hard (19–37 GPa) Ti–Si–B coatings were deposited at substrate bias voltages (V_s) ranging from floating potential to −150 V which resulted in substrate temperatures of ∼90–135 °C. We found that variation of substrate biasing conditions critically affected film composition, structure and resultant mechanical properties. For instance, concentration of Si in films decreased from 18.4 at.% to 3.8 at.% as V_s was increased from floating potential to −150 V; composition profile analysis of the near-surface region of films (0–10 nm) revealed them to be rich in Si with significant differences among specimens produced at different substrate bias conditions. Variation of substrate biasing conditions provided coating structures that ranged from completely amorphous at floating substrate potential to nanocrystalline at V_s = −50 to −100 V and crystalline nanocolumnar at V_s = −150 V. We found that each of the structures obtained exhibited different specific values of hardness and elastic modulus, which is also in a good agreement with results reported for other coatings possessing similar micro- and nano-structures. Film structure was analyzed in detail by conventional and analytical transmission electron microscopy. Coatings that exhibited the highest values of hardness (37 GPa) were found to possess features such as crystalline nanocolumnar grains a few nanometres in diameter and disordered intergranular regions of different chemical composition, thus qualifying as nanocomposite films. Results of this work allowed relationships to be drawn between deposition parameters and Ti–Si–B coating composition, structure and mechanical properties. Qualitatively similar relationships are also expected for other biased plasma-assisted physical vapour deposited transition-metal-based ceramic coatings alloyed with Si (e.g. Ti–Si–N, Cr–Si–N, Cr–Al–Si–N).     

Synthesis and characterization of super hard,self-lubricating Ti–Si–C–N nanocomposite coatings

Quaternary super hard Ti–Si–C–N coatings with different carbon contents were deposited on high-speed steel substrates by pulsed direct current plasma-enhanced chemical vapor deposition (PECVD) technology, using a gaseous mixture of TiCl₄/SiCl₄/N₂/H₂/CH₄/Ar. A variety of technologies have been employed to characterize the coatings, including X-ray diffraction, scanning and transmission electron microcopies, X-ray photoelectron spectroscopy, energy dispersive X-ray analysis, automated load–depth sensing and pin-on-disc. The super hard Ti–Si–C–N coatings were found to have unique nanocomposite structures composed of nanocrystallite and amorphous nc-Ti(C,N)/a-Si₃N₄/a-C and/or nc-Ti(C,N)/nc-TiSi₂/nc-Si/a-Si₃N₄/a-C, depending on the carbon contents in the coatings. The friction coefficient of the Ti–Si–C–N coatings with a higher carbon content (nc-Ti(C,N)/a-Si₃N₄/a-C nanocomposites) were found to be much lower than those of the Ti–Si–N coatings both at room and elevated temperatures, suggesting the formation of a graphite-like lubricious phase of amorphous carbon. However, they are still super hard (32–48 GPa) in spite of the carbon incorporation. This is due to a strong, thermodynamically driven and diffusion-rate-controlled (spinodal) phase segregation that leads to the formation of a stable nanostructure by self-organization. The energy difference between the grain boundary and the crystallite/amorphous phase interface hinders grain boundary mobility, leading to a gradual decrease in the grain size of the nanocrystallites. As a result, nanocomposite Ti–Si–C–N coatings with high hardness and a low friction coefficient can be produced. The coatings are foreseen to have high potential in dry and high-speed cutting tool applications, thus providing for cleaner, healthier and more pleasant machining conditions.