Fiber delivered two-color picosecond source through nonlinear spectral transformation for coherent Raman scattering imaging

We demonstrate a two-color, fiber-delivered picosecond source for coherent Raman scattering (CRS) imaging through nonlinear spectral transformation. The wavelength tunable picosecond pump is generated by nonlinear spectral compression of a prechirped femtosecond pulse in a fiber wavelength division multiplexer (WDM). The 1064-nm synchronized picosecond Stokes pulse is generated through pulse carving of a continuous wave laser, nonlinear spectral broadening in 100-m standard single-mode fiber, and subsequent dispersive compression with a fiber compressor. The pump and Stokes beams are combined and delivered by the fiber WDM. CRS imaging of mouse skin is performed to demonstrate the practicality of this source.     

Multimodal coherent anti-Stokes Raman spectroscopic imaging with a fiber optical parametric oscillator

We report on multimodal coherent anti-Stokes Raman scattering (CARS) imaging with a source composed of a femtosecond fiber laser and a photonic crystal fiber (PCF)-based optical parametric oscillator (FOPO). By switching between two PCFs with different zero dispersion wavelengths, a tunable signal beam from the FOPO covering the range from 840 to 930 nm was produced. By combining the femtosecond fiber laser and the FOPO output, simultaneous CARS imaging of a myelin sheath and two-photon excitation fluorescence imaging of a labeled axons in rat spinal cord have been demonstrated at the speed of 20 μs per pixel.     

Multiplicative and subtractive focal volume engineering in coherent Raman microscopy

Rigorous calculations are performed to study the effective reduction of the nonlinear excitation volumes when using phase-only masks to condition the pump and Stokes driving fields. Focal volume reduction was achieved using both a multiplicative operation of the excitation fields as well as a subtractive operation. Using a tunable optical bottle beam for the Stokes field, an effective reduction of the width of the excitation volume by a factor of 1.5 can be achieved in the focal plane. Further reduction of the focal volume introduces a rapid growth of sidelobes, which renders such volumes unsuitable for imaging applications. In addition, phase sensitive detection was found to provide information from selective sub-divisions of the engineered coherent anti-Stokes Raman scattering excitation volume. In the case of isolated nanoparticles, an apparent resolution improvement by a factor of 3 is demonstrated, and it is shown that the size of sub-diffraction-limited particles can be accurately determined using phase sensitive detection.     

Polarization-mode dispersion measurements in high-birefringence fibers by means of stimulated Raman scattering

A convenient technique for polarization-mode dispersion measurements in short lengths of high-birefringence fibers is reported. The technique is based on spectral interferometry with a frequency-doubled Nd:YAG laser, which is frequency shifted and broadened by self-stimulated Raman scattering in an optical fiber. The different Raman Stokes beams permit accurate measurements over a 40-nm wavelength range in the visible spectrum.     

Optical Properties of Copper-Doped Lithium Niobate Crystals

We have studied the optical properties of copper-doped lithium niobate crystals using semiconductor light-emitting diodes and lasers emitting in the visible and ultraviolet spectral regions as excitation sources. The results demonstrate that, at an excitation frequency approaching the frequency of electronic absorption in copper ions, there is discrete resonance Raman scattering in the form of a frequency comb. The observed Raman satellites of discrete light scattering are due to polar longitudinal A₁ optical modes of the lithium niobate single crystal. Under excitation by a light-emitting diode with a wavelength of 520 nm, we observe a sharp increase in discrete light scattering intensity in comparison with the photoluminescence excited by shorter wavelength excitation sources.     

Increased efficiency of vacuum ultraviolet generation by stimulated anti-stokes Raman scattering with stokes seeding

Stimulated anti-Stokes Raman scattering in molecular hydrogen allows for the generation of continuously tunable narrow-bandwidth radiation down to the transmission limit of vacuum ultraviolet (VUV) window materials. Simultaneous irradiation of UV-pump radiation (in this application, dye laser radiation of wavelength lambda = 372 nm) and of radiation whose wavelength corresponds to the first Stokes component allows a considerable increase in efficiency-by nearly 2 orders of magnitude in the far VUV. The additional Stokes radiation is generated in a simple manner during the passage of the unfocused pump radiation through a high-pressure Raman cell that precedes the VUV Raman cell.     

Enhanced Raman scattering in a colloidal crystal observed by a tunable laser light source

The Raman scattering intensity was measured for a colloidal crystal composed of polystyrene micro spheres and a polymer gel with a tunable continuous-wave dye laser as an excitation light source. Enhancement of the Raman scattering caused by both the electric field enhancement at the excitation frequency and the increase in the local photon density of states at the scattering frequency was expected. The observed Raman scattering intensity as a function of the excitation frequency showed a reasonable agreement with the theoretical prediction.     

The relationship between extraordinary optical transmission and surface-enhanced Raman scattering in subwavelength metallic nanohole arrays

Nanohole arrays in an Ag film were used as a substrate for surface-enhanced Raman scattering in the optical range. Extraordinary optical transmission and local field enhancement in Ag nanohole arrays were theoretically simulated using three-dimensional finite difference time domain method. The periodicity of the holes was adjusted to control the transmission intensity and electric field intensity. The calculation results show that the peak position of transmission red-shifts as the periodicity increases, while the peak intensity decreases linearly. The electric field is localized in a very small region at the edges of the holes, which means the surface-enhanced Raman scattering originates only from a small number of molecules located in the edge regions. The electric field intensity changes with the excitation wavelength in a similar trend to the transmission intensity. Both the electric field intensity and transmission intensity reach their maximum value at the frequency of surface plasmon resonance. The structure that gives resonant transmission provides the maximum surface-enhanced Raman scattering signal. Controllable and predictable surface-enhanced Raman scattering can be produced by using this novel nanostructure. The structure can be optimized to get the maximum surface-enhanced Raman scattering signal at a certain excitation wavelength through numerical simulations.     

Frequency domain modeling of reradiation in highly scattering media

We present a straightforward procedure for frequency domain modeling of reradiation in a highly scattering medium with an arbitrary, finite three-dimensional geometry. We use a finite difference numerical solver to determine the fluence distribution at the excitation wavelength, which is then coupled to the emission wavelength with an array of equivalent reradiating sources. We then calculate the fluence distribution at the emission wavelength with a second, independent numerical simulation with new optical parameters appropriate to the emission wavelength, using the distributed reradiating sources as the excitation. We compare three-dimensional simulations of a fluorophore distributed in a scattering medium with experimental data. We also compare simulations of the Raman reradiation of small diamonds in a scattering medium with experiment.     

S-band multiwavelength ring Brillouin/Raman fiber laser with 20 GHz channel spacing

We propose and demonstrate a tunable S-band multiwavelength Brillouin/Raman fiber laser (MBRFL) with a tuning range of between 1490 to 1530 nm. The proposed MBRFL is designed around a 7.7 km long dispersion compensating fiber in a simple ring configuration, acting as a nonlinear medium for the generation of multiple wavelengths from stimulated Brillouin scattering (SBS) and also as a nonlinear gain medium for stimulated Raman scattering (SRS) amplification. A laser source with a maximum power of 12 dBm acts as the Brillouin pump (BP), while two 1420 nm laser diodes with a total power of 26 dBm act as the Raman pumps (RPs). The MBRFL can generate a multiwavelength comb consisting of even and odd Stokes at an average power of -12 dBm and -14 dBm respectively, and by separating the even and odd Stokes outputs, a 20 GHz channel spacing is obtained between two consecutive wavelengths. Due to the four-wave mixing (FWM) effect, anti-Stokes lines are also observed. The multiwavelength comb generated is not dependent on the BP, thus providing high stability and repeatability and making it a highly potential source for many real-world applications. This is the first time, to the knowledge of the authors, that a tunable MBRFL has been developed using SRS to obtain gain in the S-band region.     

Coherent population trapping in an rf-optical double resonance experiment in a neon discharge

We observed radio-frequency (rf) induced transparency for a probe optical field in an rf-optical double resonance experiment in a neon discharge. The origin of the transparency is coherent population trapping at Zeeman sublevels of the lower level of an optical transition of neon. Stokes and anti-Stokes optical fields were generated due to stimulated Raman scattering of both the radio-frequency field on the probe-induced optical coherence and the probe field on the Zeeman coherence.     

Planar Spontaneous Raman-Scattering Spectroscopy for Reacting Jet-Flow Diagnostics Using Lyot–Ehman Tunable Filter

The spatial-density distribution in burning a premixed methane–air swirling turbulent jet has been studied by measuring the intensity of the Stokes branch of spontaneous Raman scattering for vibrational–rotational transitions in nitrogen. An optical system comprising a Nd:YAG laser and the liquid-crystalline Lyot–Ehman tunable filter has been created and tested by measuring the temperature and density fields in a cone-shaped laminar flame. It has been established that the difference of data obtained using the Stokes component of Raman scattering in nitrogen and its ratio to the anti-Stokes component does not exceed 5% in a temperature range from 300 to 1800 K.     

Surface-enhanced Raman spectroscopy biosensors: excitation spectroscopy for optimisation of substrates fabricated by nanosphere lithography

In the 28 years since its discovery, surface-enhanced Raman scattering (SERS) has progressed from model system studies of pyridine on a roughened silver electrode to state-of-the-art surface science studies and real-world sensing applications. Each year, the number of SERS publications increases as nanoscale material design techniques advance and the importance of trace analyte detection increases. To achieve the lowest limits of detection, both the relationship between surface nanostructure and laser excitation wavelength and the analyte-surface binding chemistry must be carefully optimised. This work exploits the highly tunable nature of nanoparticle optical properties to establish the optimisation conditions. Two methods are used to study the optimised conditions of the SERS substrate: plasmon-sampled and wavelength-scanned surfaced Raman excitation spectroscopy (SERES). The SERS enhancement condition is optimised when the energy of the localised surface plasmon resonance of the nanostructures lies between the energy of the excitation wavelength and the energy of the vibration band of interest. These optimised conditions enabled the development of SERS-based sensors for the detection of a Bacillus anthracis biomarker and glucose in a serum-protein matrix.     

Raman shifter optimized for lidar at a 1.5 microm wavelength

A Raman shifter is optimized for generating high-energy laser pulses at a 1.54 microm wavelength. A forward-scattering design is described, including details of the multiple pass and nonfocused optical design, Stokes injection seeding, and internal gas recirculation. First-Stokes conversion efficiencies up to 43%--equivalent to 62% photon conversion efficiency--were measured. Experimental results show output average power in excess of 17.5 W, pulse energies of 350 mJ at 50 Hz, with good beam quality (M2<6). Narrow bandwidth and tunable output is produced when pumping with a single longitudinal mode Nd:YAG laser and seeding the process with a Stokes wavelength narrowband laser diode.     

Generation of 224-nm radiation by stimulated Raman scattering of ArF excimer laser radiation in a mixture of H2 and D2

Raman shifting of tunable ArF excimer laser radiation in a mixture of H(2) and D(2) produces tunable radiation in the 224-nm region as a result of Stokes shifting the frequency of the fundamental radiation (193 nm) once in both H(2) and D(2). At a total pressure of 25 bars, a 19% H(2) in D(2) mixture is found to provide a maximum conversion efficiency (2.5%) to the 224-nm range. Both fundamental and 224-nm radiation were used to record laser-induced fluorescence excitation spectra of nitric oxide produced in an oxyacetylene flame. From the excitation spectra, we determined the tuning range of the 224-nm radiation to be 270 cm(-1) with a linewidth of 0.9 cm(-1), which is similar to the fundamental laser radiation. We derived the exact Raman shift of the generated radiation by comparing both excitation spectra which was found to be 7142.3(5) cm(-1).     

Fabry–Perot Cavity Control for Tunable Raman Scattering

The Fabry–Perot (FP) resonator is an intuitive and versatile optical structure owing to its uniqueness in light-matter interactions, yielding resonance with a wide range of wavelengths as it couples with photonic materials encapsulated in a dielectric cavity. Leveraging the FP resonator for molecular detection, a simple geometry of the metal-dielectric-metal structure is demonstrated to allow tuning of the enhancement factors (EFs) of surface-enhanced Raman scattering (SERS). The optimum near-field EF from randomly dispersed gold nano-gaps and dynamic modulation of the far-field SERS EF by varying the optical resonance of the FP etalon are systematically investigated by performing computational and experimental analyses. The proposed strategy of combining plasmonic nanostructures with FP etalons clearly reveals wavelength matching of FP resonance to excitation and scattering wavelengths plays a key role in determining the magnitude of the SERS EF. Finally, the optimum near-field generating optical structure with controlled dielectric cavity is suggested for a tunable SERS platform, and its dynamic SERS switching performance is confirmed by demonstrating information encryption through liquid immersion.     

Influence of scattering on transmission through long-period fiber gratings and tunable microstructure fibers

Controlled optical scattering within or around an optical fiber provides a potentially useful mean for adjusting its transmission characteristic. This approach can complement conventional methods based on the establishment of well-defined variations in the index of refraction of the core or the cladding of the fiber. We describe the use of a highly scattering submonolayer of nanoparticles deposited onto the fiber surface for adjusting the resonance wavelength, depth, and width of an in-fiber long-period grating filter. We also introduce a polymer-dispersed liquid-crystal material that has a thermally tunable scattering cross section and can be incorporated into the channels of a microstructure optical fiber; this system may provide the means for a fiber-based scattering switch.     

Raman and fluorescent scattering matrix of spherical microparticles

In this paper, we have investigated the main properties of the Raman and fluorescent matrix of scattering by microspheres using the matrix scattering formalism. The coherent and incoherent inelastic scattering of incident light by a microsphere is described by the Stokes parameters. We demonstrate the main symmetry properties of the coherent and incoherent Raman and fluorescent scattering matrices. Numerical results are presented to illustrate the Raman scattering efficiency, cross-phase coefficient, and some other parameters of scattering by microspheres.     

Tunable optical frequency comb generation in a periodically poled lithium niobate waveguide based on stimulated Brillouin scattering

We propose and demonstrate a technique for the generation of an optical frequency comb (OFC) in a periodically poled lithium niobate (PPLN) waveguide based on stimulated Brillouin scattering. A single continuous wave laser is sent to a multi-wavelength Brillouin erbium fibre laser for generating a set of coherent and phase-locked multi-wavelength spectral lines. They are injected into a PPLN waveguide to obtain an OFC. We investigate the influence of the cavity structure on the OFC property in our two different schemes. The number of comb lines is affected by the 980 pump current and Brillouin pump power. The OFCs are tunable in a large range by changing their central wavelength.