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1.
The deformation characteristics contributing to the superior cavitation erosion properties of HCP cobalt single crystals have
been determined. Results indicate that its erosion response is highly orientation sensitive. A homogeneous distribution of
and
glide occurs in {0110} crystals, whereas slip in the (0001) crystals is much more heterogeneous and consists mainly of
dislocations. Continued exposure to cavitation nucleates a large number of twins, predominantly on the
and
planes in the
and (0001) crystals respectively. The former twins are finer and more needle-like than the latter. The
crystals are also significantly more erosion resistant than the (0001) crystals. The twin density increases continuously
with cavitation exposure until a dense network of twins spans the entire exposed area. This fine-scale twinning is considered
responsible for the superior erosion resistance of the metal. 相似文献
2.
The boundary structure of {10
1}, {10
2}, {11
1} and, {11
2} twins in hexagonal-close-packed (hcp) metals and the interaction of crystal dislocations with the first two twin types
have been studied previously using atomic-scale computer simulation. The interaction of crystal dislocations with {11
1} and {11
2} twin boundaries is described here and compared with the results for {10
1} and {10
2} twins. These four twins are found to create barriers to the motion of crystal dislocations gliding on the basal plane,
and the strength of the barrier depends in a relatively complex manner on crystallographic parameters and details of the atomic
structures of the interfaces. In some circumstances, crystal dislocations can be transmitted through the twin boundary, thereby
creating twinning dislocations.
This article is based on a presentation made in the symposium entitled “Defect Properties and Mechanical Behavior of HCP Metals
and Alloys” at the TMS Annual Meeting, February 11–15, 2001, in New Orleans, Louisiana, under the auspices of the following
ASM committees: Materials Science Critical Technology Sector, Structural Materials Division, Electronic, Magnetic & Photonic
Materials Division, Chemistry & Physics of Materials Committee, Joint Nuclear Materials Committee, and Titanium Committee. 相似文献
3.
The competition of slip among
, and
slip modes of hcp metals has been analyzed geometrically in terms of a critical resolved shear stress, CRSS, criterion. Under
the action of an applied stress slip systems of one or more modes may be activated depending on the value of the CRSS and
on the orientation of the slip systems with respect to the applied stress. If the CRSS of a given slip mode should exceed
a limiting value relative to the CRSS of the other modes, however, the given mode becomes inoperative even under the most
favorably stressed conditions. It is found by an examination of the yield loci that basal slip is inoperative if α2 < cos θ; prism slip is inoperative if α2 < α1 sin θ; and pyramidal slip is inoperative if α2 > cos θ + α1 sin θ where
and
are, respectively, the ratios of CRSS for prism and pyramidal slips relative to basal slip, and ϕ is the angle between the
(0001) and
normals. Since the value of ϕ is a function ofc/a, the limiting values of α1 and α1 depend on thec/a ratio of the crystal structure. 相似文献
4.
Twins as barriers to basal slip in hexagonal-close-packed metals 总被引:2,自引:0,他引:2
The boundary structure of
,
,
, and
twins in hexagonal-close-packed (hcp) metals and the interaction of crystal dislocations with the first two twin types have
been studied previously using atomic-scale computer simulation. The interaction of crystal dislocations with
and
twin boundaries is described here and compared with the results for
and
twins. These four twins are found to create barriers to the motion of crystal dislocations gliding on the basal plane, and
the strength of the barrier depends in a relatively complex manner on crystallographic parameters and details of the atomic
structures of the interfaces. In some circumstances, crystal dislocations can be transmitted through the twin boundary, thereby
creating twinning dislocations.
This article is based on a presentation made in the symposium entitled “Defect Properties and Mechanical Behavior of HCP Metals
and Alloys” at the TMS Annual Meeting, February 11–15, 2001, in New Orleans, Louisiana, under the auspices of the following
ASM committees: Materials Science Critical Technology Sector, Structural Materials Division, Electronic, Magnetic & Photonic
Materials Division, Chemistry & Physics of Materials Committee, Joint Nuclear Materials Committee, and Titanium Committee. 相似文献
5.
S. Tsuji 《Metallurgical and Materials Transactions A》1994,25(4):741-751
Mathematical relationships describing the multiphase binary diffusions are deduced under the condition that
in an infinite medium, and also under the condition that
and the fluxes of both the species occur in each other’s opposite direction through the surface in a semi-infinite medium,
where
are the interdiffusion coefficient and the partial molal volume of componenti in phasej, respectively, and are composition independent. Two graphical evaluation methods for obtaining the interdiffusion coefficients
for all the phases present in the diffusion zone have been developed in infinite and semi-infinite media. Concentration-distance
curves of both the components for an infinite medium and those curves and also mass change of the couple per unit area of
the surface before and after the diffusion anneal for a semi-infinite medium must be prepared to calculate an interdiffusion
coefficient for each phase. 相似文献
6.
Interactions between deformation twin and 120 deg-rotational domain boundary were studied by transmission electron microscopy
in a two-phase TiAl-based alloy with fully lamellar structure deformed at room temperature. Three types of the interaction
were observed, depending on the interaction geometry and crystallography faced by the incident twinning Shockleys. It was
found that the incident twinning shear could be accommodated into the barrier domain by a reaction involving emission of 1/2
{111}
B
slip in all the three types of interactions presumably since the slip required a small critical resolved shear stress (CRSS)
and was always favored by the pile-up stress. Several reaction schemes involving 1/2
{111}
B
slip for each type of the interactions were proposed by considering whether the reaction resulted in a reduced elastic energy
and if the dissociated dislocations were able to glide away to minimize the total elastic energy associated with a long-range
stress field of a pileup of the incident twinning partials. It is suggested that whether a reaction scheme is feasible would
depend on behavior of other product dislocation except 1/2
{111}
B
. 相似文献
7.
Ternary interdiffusion coefficients were measured in the Ni solid solution γ (fcc) phase of the Ni-Cr-Al system at 1100 and
1200 °C. Extensive use was made of both γ/γ and γ/γ + β (β-NiAl structure) diffusion couples. Two analysis techniques were
employed to calculate the interdiffusion coefficients. When the Matano planes for Al and Cr were not coincident, numerous
integral calculations were made to determine an average diffusion coefficient and to assess the effect of the noncoincidence
of the Matano planes. The results of the diffusivity measurements showed that
is approximately four times greater than
, while
and
are of the same magnitude. For all concentrations,
is two to three times greater than
. Both
and
increase with increasing Al concentration, whereas
and
show little concentration dependence on Cr alone. A ternary, finite-difference interdiffusion model was employed to predict
concentration profiles for the γ/γ couples utilizing the concentration dependence of the measured diffusivities. Good agreement
was observed between the predicted and measured concentration profiles for both 1100 and 1200 °C. 相似文献
8.
Growth morphology and number
per unit volume have been determined vs withdrawal velocity V over the range 0.1 to 4 mm/s for primary Mg2Si in a Bridgman-solidified hypereutectic Al-Mg-Si alloy. Primary Mg2Si shows a transition from irregular or regular polyhedral to dendritic with increasing V, and
increases with solidification cooling rate
according to the relationship
. These results are compared with corresponding ones for Al-Mg-Si alloy wedge castings and for primary silicon in hypereutectic
Al-Si alloys. 相似文献
9.
The development of the deformation texture in zirconium during rolling in sequential passes 总被引:1,自引:0,他引:1
E. Tenckhoff 《Metallurgical and Materials Transactions A》1978,9(10):1401-1412
Slip and twinning systems activated by rolling in sequential passes were observed on a coarse grained zirconium polycrystal.
At least five independent deformation modes are activated; slip and twinning systems occur simultaneously. For low degrees
of deforma-tion the main slip system is prism slip
, even when the orientation is not favorable. The lattice rotations caused by slip proceed gradually with increasing defor-mation;
they are relatively small although the strain achieved can be large. On the other hand, twinning causes spontaneous, large-scale
lattice rotations, even for low degrees of deformation. The type of twinning depends largely on the crystallographic orientation
of the matrix. For basal pole orientations of the undeformed grains in the area 0 to 50 deg from the normal direction
twinning becomes preferentially operative. For basal pole orientations of the undeformed grains in the area 50 to 90 deg
from the normal direction, however,
twinning becomes preferentially operative. In both orientation areas as a complementary system
twinning is operative. For all deformation sys-tems their operation is independent of the azimutal position of the basal
pole in these areas. The lattice rotations alter the orientation of the crystallites in such a way that the basal poles all
become aligned more or less in the direction of the deforming compres-sive force. For higher degrees of deformation pyramidal
slip with a (c + a) type Burgers Vector can explain why this preferred orientation is maintained as final position, which
for zirconium shows a split of basal poles of ±30 to 50 deg towards the transverse direc-tion. The method of following the
complicated interactions between different slip and twinning systems in a stepwise deformed, coarse grained sheet by 1) trace
analysis of the deformation modes, 2) by correspondingly derived lattice rotations, and 3) by texture measurements leads to
an explanation of the texture development in zirconium. It is dis-cussed on the basis of basal pole rotations. 相似文献
10.
Electron-backscattered diffraction (EBSD) has been used to investigate the texture evolution during tensile deformation at
temperatures between 673 and 773 K of a coarse-grained commercial AZ31 magnesium alloy. A weak (0001) fiber texture was initially
present in the hot-rolled magnesium alloy plate. The [0001] directions of the grains spread 0 to 45 deg around the normal
direction (ND) of the magnesium alloy plate. This pre-existing weak texture evolved during tensile deformation into a strong
texture close to the {0001} 〈1
00〉. The [0001] directions of the grains rotated toward the orientations perpendicular to the tension axis of the samples,
indicating that the 〈11
0〉 slip system appeared to be the most active slip system, especially in the early stages of deformation. The EBSD Schmid-factor
analysis revealed that, however, with an increase in strain and the rotation of the (0001) slip plane, the {11
2} 〈11
〉 slip system appeared to be more favorable. The {1
00} 〈11
0〉 and {1
01} 〈11
0〉 slip systems remained favored throughout the strains investigated, indicating that {1
00} and {1
01} are two important slip planes for cross slip using the 〈11
0〉 slip vector. It is found that the misorientation across one coarse grain (as high as 38.2 deg) is accommodated by low-angle
grain boundaries (LAGBs). The formation of these LAGBs may be an intermediate stage of the coarse grain refinement that occurred
during deformation.
This article is based on a presentation made in the symposium entitled “Processing and Properties of Structural Materials,”
which occurred during the Fall TMS meeting in Chicago, Illinois, November 9–12, 2003, under the auspices of the Structural
Materials Committee. 相似文献
11.
S. Skolianos T. Z. Kattamis Y. R. Chung H. D. Merchant 《Metallurgical and Materials Transactions A》1987,18(7):1179-1190
Dendritic monocrystals of Al-4.5 wt pct Cu-2 wt pct Mn were directionally solidified at 0.20 m/h under a thermal gradient
of 3 × 103 K/m. Crystal pulling was stopped for various lengths of time prior to quenching the remaining liquid, thus making it possible
to evaluate the transformation and coarsening kinetics of dispersed intermetallic phases, Al6Mn and Al20Cu2Mn3, as a function of temperature. Coarsening of Al6Mn intermetallic particles surrounded by liquid (Type II) follows an average particle size
relationship much closer than it does a
relationship. This suggests that convection plays no important role in coarsening. For coarsening of Al6Mn particles in a solid matrix (Type I) the relationship
fits the experimental measurements reasonably well. Coarsening kinetics studies were extended to intermetallic particle sizes
an order of magnitude finer than those occurring in directionally solidified alloy, in order to derive information required
by an on-going project on the effect of intermetallic phase geometry on corrosion behavior. Jt was found that coarsening of
Al20Cu2Mn3 particles contained in a melt-spun ribbon follows a
relationship, as predicted by Kirchner for grain-boundary diffusion-controlled ripening. Finally, coarsening of Al6Mn particles surrounded by liquid indium film and contained in a plastically deformed matrix follows a
relationship, as predicted by LSW theory for liquid diffusion-controlled ripening. Shortening the time required to obtain
coarse intermetallic particles during a homogenization treatment is important in deep drawing.
Formerly Graduate Student, Department of Metallurgy, University of Connecticut, Storrs, CT 06268 相似文献
12.
Martensitic transformation in a series of Zr−Ti alloys has been studied by transmission electron microscopy. A transition
in morphology and substructure was observed with increasing additions of titanium. The 5 wt pct Ti alloy was found to be predominantly
dislocated lath martensite while the 10 wt pct Ti alloy showed mainly a twinned plate morphology. Twins within the martensite
plates could be classified into two categories, namely, thick
twins and thin twins mainly on
planes and, to a lesser extent, on
and
planes. In the case of the thick
twins, the specific variant of the twin plane was always found to correspond to a plane of the {110}bcc type, which is a mirror plane in the parent bcc crystal. When the specific variant of the composition plane was not parallel
to a mirror plane, the twins were observed to be very thin. Evidence of slip within individual twin bands pointed to the operation
of a multiple shear inhomogeneous deformation. Observations concerning
deformation twins due to impingement effect are also discussed in this paper. 相似文献
13.
The effects of four types of incompability on stresses generated in seven iso-axial bicrystals of 70-30 alpha brass subjected
to tension were examined by finite element methods. The distribution of applied stress and resolved shear stresses was determined.
The applied stress, {
}, was higher at the interior than at the surface, while the resolved shear stresses were generally higher at the surface.
For both applied {
} and resolved shear stresses, the largest stresses occurred at the bicrystal boundaries. The effect of end constraints on
a [213] oriented single crystal was found to create nonuniform stresses and strains, and an explanation for this behavior
was proposed. The effect of orientation on the magnitude of grain boundary resolved shear stress, {
}, and the relative extent (volume fraction) of enhanced grain boundary resolved shear stress,V
gb, were determined. The highest values of {
} andV
gb were reached in different portions of the stereographic triangle. The elastic interactions producing this behavior were too
complex to permit a simple interpretation.
TZI-KANG CHEN formerly Graduate Student at Polytechnic University 相似文献
14.
The deformation behavior of a Burgers oriented α-β-Ti-13Mn bimetallic bicrystal was studied at two plastic strains, 0.52 and
2.08 pct. Two single crystals, α and β, each corresponding to the orientation of its respective bicrystal component were also
investigated. The stress axes were
and [1218]β. The interface planes were
and
and lay in the x’-z’ plane. The deformation behavior of the a component differed from that of the a single crystal because
of plastically induced stresses,T
y’z’
,T
x’z’
,T
x’y’
, and σ
x’x’
. Prismatic slip and
twinning were found in the single crystal α whereas the bicrystal revealed additionally pyramidal andc + a slip, the latter at the interface. Slip on the front and back surfaces was different and both thec + a and twinning systems acted to maintain compatibility. Slip in the β single crystal and the β bicrystal component were quite
similar. However, there were differences in the intensity and amount of primary slip, (231)
, on the front and back surfaces. The diminished amount of (231)
slip on the back surface was due to plastically induced stresses, and on the front surface the primary slip cross slipped
to
slip which triggeredc + a slip in α. On the back surface the dominant slip system was
which acted in response to the plastically induced stresses. An approximate calculation revealed that the interface deformation
zone had about twice the flow stress of the average bicrystal stress.
Formerly a Graduate Student in the Department of Physical and Engineering Metallurgy at Polytechnic Institute of New York,
Brooklyn, NY 相似文献
15.
Sungsoo Kim 《Metallurgical and Materials Transactions A》2006,37(1):59-68
Recently, it was proven that delayed hydride cracking (DHC) is accompanied by deformation twinning through the texture analysis
of a fractured surface. Thus, in order to understand the operation of deformation twinning, the texture variations by rolling
were investigated using Zr-2.5 pct Nb alloy with {11
0} 〈10
0〉 texture. It was observed that deformation twinning was operated predominantly in the range of a 5 to 15 pct strain. The
basal poles were rotated in the normal direction of a rolling plane with the strain, and the (0002) texture was fully reversed
after 15 pct strain. This finding was established to be due to the operation of the {10
2} and {11
1} twinning systems through the analysis of the inverse pole figure. It appeared that the degree and easiness of the twinning
operation was affected by changing the direction of compression during rolling with respect to the initial {11
0} 〈10
0〉 texture. The contribution of deformation twinning to strain was quantitatively calculated using the change in the basal
pole components.
This article is based on a presentation made in the symposium entitled “Processing and Properties of Structural Materials,”
which occurred during the Fall TMS meeting in Chicago, Illinois, November 9–12, 2003, under the auspices of the Structural
Materials Committee. 相似文献
16.
Ando Shinji Gotoh Takushi Tonda Hideki 《Metallurgical and Materials Transactions A》2002,33(13):823-829
The core structures of 〈c+a〉 dislocations in hexagonal-close-packed (hcp) metals have been investigated by molecular dynamics (MD) simulation using a
Lennard-Jones-type pair potential. The 〈c+a〉 edge dislocation has two types of core at 0 K; one is a perfect dislocation (type A), and the other has two 1/2 〈c+a〉 partials (type B). Type A transforms to type B by abruptly increasing temperature from 0 K to 293 K, while type B is stable
in temperature range from 0 K to 293 K. In contrast, type A extends parallel to (0001) at 30 K, and this extended core is
still stable at 293 K. These results suggest that the 〈c+a〉 edge dislocation glides on the
as two 1/2 〈c+a〉 partial dislocations and becomes sessile, due to changes of the core structure. The 〈c+a〉 screw dislocation spreads over two
planes at 0 K. The core transforms into a unsymmetrical structure at 293 K, which is spread over
and
, and core spreading occurs parallel to
at 1000 K. A critical strain to move screw dislocations depends on the sense of shear strain. The dependence of the yield
stress on the shear direction can be explained in terms of these core structures.
This article is based on a presentation made in the symposium entitled “Dect Properties and Mechanical Behavior of HCP Metals
and Alloys” at the TMS Annual Meeting, February 11–15, 2001, in New Orleans, Louisiana, under the auspices of the following
ASM committees: Materials Science Critical Technology Sector, Structural Materials Division, Electronic, Magnetic & Photonic
Materials Division, Chemistry & Physics of Materials Committee, Joint Nuclear Materials Committee, and Titanium Committee. 相似文献
17.
The interface migration rate behavior during recrystallization of a deformed
iron single crystal is considered in detail. A spheroidal growth, site-saturated nucleation model of recrystallization is
developed for iron which quantitatively takes into account the effect of concurrent recovery in the deformed regions ahead
of the advancing recrystallization interfaces. The recovery kinetics model incorporated into the growth model was devised
based on the experimental data of Michalak and Paxton.[10] Explanations are advanced for the nonlinear growth of grains during
recrystallization of iron. Deformation-induced stored energy gradients are proposed to explain the aspects of nonlinear growth
not accounted for by recovery and are introduced into the growth model also. A localized shear band deformation mechanism
developed by Harataniet al.[14] is used to rationalize the presence of stored energy gradients in the deformed
iron single crystal. 相似文献
18.
K. Kakehi 《Metallurgical and Materials Transactions A》1999,30(5):1249-1259
The effect of crystallographic orientation and aging heat treatment at 850 °C on the creep rupture strength of single crystals
of a nickel-based superalloy was examined at 700 °C in detail. Initial tensile orientations were selected over a wide range
on the standard stereographic triangle. The {111}〈112〉-type slip systems were found to be operative during the creep deformation.
The creep behavior was found to be greatly influenced by the additional aging at 850 °C for 20 hours. It was found that the
effect of the aging at 850 °C was quite different between orientations favored for the
slip system and those favored for the (111)
slip system and that the creep deformation mechanisms of these two slip systems were different. In the orientations favored
for
slip systems, in the single-aged specimens, a small mean surface-to-surface spacing due to hyperfine γ′ precipitates in the matrix channel promoted the
slip and the primary creep. As a result of the additional aging at 850 °C, the hyperfine γ′ precipitates were dissolved into the matrix, and the resultant large mean surface-to-surface spacing between the cuboidal
precipitates inhibited extensive shearing of the γ-γ′ structure by the
slip system. As a result, the creep strengths of these orientations were increased in double-aged specimens; however, the
low ductility associated with the difficulty of secondary noncoplanar slip did not enlarge rupture lifetime in the double-aged
[001] specimen. In the orientations favored for the (111)
slip system, creep deformation occurred by twinning shear through γ and γ′ precipitates, and a distinct effect of the aging at 850 °C was not observed. In the multiple orientation of the {111}
-type slip systems, i.e., the
and
orientations, hyperfine precipitates improved creep strength because they prevented dislocations from gliding in the matrix
channel in the single-aged specimens. 相似文献
19.
Recrystallization kinetics in a (111)[1
0] iron single crystal deformed 70 pet by rolling were characterized experimentally at temperatures between 500°C and 600°C
by means of quantitative metallography. A Laplace transform method was applied to the time-dependent global microstructural
properties, volume fraction, interface area per unit volume, and the largest intercept-free length (recrystallized grain)
to separate nucleation and interface migration effects from the overall recrystallization kinetics. A comprehensive nucleation
and growth model was derived from analysis of the microstructural data. The model consisted of the following salient features:
(a) nucleation was random and approximately site-saturated with zero incubation time at all temperatures; (b) the recrystallized
grains grew three-dimensionally in the shape of prolate spheroids; and (c) interface migration rates were highly anisotropic,
the grains growing at an approximately constant rate in one dimension and at a strongly decreasing rate in the other two dimensions.
The present findings were compared to a similar earlier study of a deformed iron (111)[
2] single crystal. The time dependencies of the interface migration rates were rationalized in terms of a deformation-induced,
nonuniform distribution of stored energy and an orientation-dependent grain boundary mobility. 相似文献
20.
Interdiffusion coefficient matrices,
have been experimentally measured at 31 points in the αδFe phase field of the Fe-Cr-AI ternary equilibrium phase diagram
at 900 °C (1173 K). Analyses of the computed matrices were carried out by subjecting each measured -Dn
ij to two consistency tests comprised of Onsager’s and Kirkaldy’s relations. Good consistency with these relationships was obtained
in the central region of the ternary phase field, but there were significant deviations near the phase boundaries. These may
beattributable to systematic uncertainties in the analytical procedure. The results indicate that
falls quickly with increasing CCr, with CAl > 0.2, but is not a strong function of CAl. Conversely,
is not a strong function of CAl but decreases with increasing CCr.
formerly with the Lawrence Berkeley Laboratories of the University of California, Berkeley
At the time of this research, Dr. Stringer was on sabbatical leave at the Lawrence Berkeley Laboratories, Department of Materials
Science and Mineral Engineering, University of California, Berkeley, CA 94720. 相似文献