Liquid‐crystal photoaligning by azo dyes (Invited Paper)

Abstract— Liquid‐crystal (LC) photoalignment using azo dyes is described. It will be shown that this photoaligning method can provide a highly uniform alignment with a controllable pretilt angle and strong anchoring energy of the LC cell, as well as a high thermal and UV stability. The application of LC photoalignment to the fabrication of various types of liquid‐crystal displays, such as VAN‐LCDs, FLCDs, TN‐LCDs, and microdisplays, on glass and plastic substrates is also discussed. Azo‐dye photoaligned super‐thin polarizers and phase retarders are considered as new optical elements in LCD production, in particular for transflective displays.     

Photoalignment and photo‐patterning of planar and homeotropic liquid‐crystal‐display configurations

Abstract— Optical alignment and micro‐patterning of the alignment of liquid‐crystal displays (LCDs) by linear photopolymerization (LPP) technology renders high‐quality multi‐domain twisted‐nematic (TN) and supertwisted‐nematic (STN) displays with broad fields of view over wide temperature ranges feasible. The prerequisites are the generation of photo‐induced high‐resolution azimuthal alignment patterns with defined bias‐tilt angles 0° ≤ θ ≤ 90°. For the first time, LPP‐aligned single‐ and dual‐domain vertically aligned nematic LCDs (VAN‐LCDs) are presented. Dual‐domain VAN‐LCDs are shown to exhibit broad fields of view which are further broadened by combining the displays with LPP‐aligned optical compensators made of liquid‐crystal polymers.     

Review of various measurement methodologies of migration ion influence on LCD image quality and new measurement proposal beyond LCD materials

Nowadays, thin‐film transistor liquid crystal displays (TFT‐LCDs) have realized high reliability of display characteristics by improving liquid crystal (LC) materials and cell fabrication processes. In order to improve display reliability, measurement methodologies are important to see the progress of improvement of materials and processes; thus, our group has proposed voltage holding ratio (VHR), ion impurity, residual direct current (DC) and elastic constants for LC cells, and the optical anisotropy of an alignment layer on indium tin oxide (ITO) glass substrate for LCD industry. In case of an ion impurity, we have succeeded in measuring the ion impurity amount in TFT‐LCD. Furthermore, we have recently proposed ion impurity measurement methodology for beyond LCD applications that are organic light emitting diode (OLED) and organic photovoltaics (OPV). In this review, I introduce each measurement methodology for LCDs and beyond LCDs in detail.     

Novel super fast response vertical alignment‐liquid crystal display with extremely wide temperature range

We have developed a novel super fast response (SFR) thin‐film transistor liquid crystal display (TFT‐LCD) with an extremely wide temperature range. Nematic liquid crystal molecules with positive dielectric anisotropy are vertically aligned initially. Any gray‐to‐gray response is forcibly controlled by applying an electric field. Response times of the SFR TFT‐LCD are over several times shorter than those of conventional LCDs such as vertical alignment or in‐plane switching LCDs.     

Nano‐domains formation on photoalignment thin film by self‐organized dewetting

A novel discontinuous photoalignment surface with nano‐domains for liquid crystal is developed. The formation of the discontinuous structure is created by self‐organized dewetting, which is regarded as one of the most promising bottom‐up approaches to fabricate nano‐structure. Different dewetting conditions, such as surface roughness, thickness and viscosity, have been investigated. Such discontinuous photoalignment layer can be fabricated on top of another continuous alignment layer to form a new kind of heterogeneous nano‐structured alignment surface – stacked alignment layers. This heterogeneous alignment surface can be used to produce arbitrary pretilt angles for the liquid crystal display. Simulation model has been built to understand the dewetting mechanism. Experiments using photo‐aligned and photo‐polymerisable polymer have been done to verify the dewetting theory. The produced stacked alignment layers are proved to be robust. Moreover, the dewetting processing is a fully controllable process and is compatible with existing manufacturing techniques.     

Fast‐response study of polymer‐stabilized VA‐LCD

Abstract— Polymer stabilization is introduced in VA‐type LCDs, and fast response time can be achieved along with a high contrast ratio.¹ A small amount of reactive monomer is mixed with liquid crystal and forms a polymer layer above the alignment layer by using a UV process. The pre‐tilt angle of the liquid crystal is stabilized, and a faster response time can be realized when the bias pre‐tilt angle from 90° is increased. The properties of reactive monomers and liquid crystal and the conditions of the UV process were studied. Based on the application of the proper monomer and LC, and an optima UV process, a 65‐in. 240‐Hz full‐HD TFT‐LCD, with a faster response time and high contrast ratio, has been developed.     

O films with adjustable tilt of optical axis for LCD compensation

Abstract— A method of preparation of positive O films with the tilt angle of the optic axis continuously controlled in the range 0–90° is proposed. It is based on the use of reactive mesogens and alignment materials that provide a wide range of pretilt angles. The method developed allows for further improvement in the viewing‐angle characteristics of LCDs with O compensation films.     

Tuning the alignment of liquid crystals by means of nano‐structured surfaces (Invited Paper)

Abstract— The solid‐surface/liquid‐crystal interactions, defining the field‐free alignment of the liquid crystal in conventional liquid‐crystal displays, are playing a vital role in their optical appearance and performance. Nano‐scale changes in the solid‐surface structure induced by light have been recently shown to affect the anchoring strength and the easy‐axis direction. Fine tuning of the anchoring strength is also demonstrated by nano‐structuring of the Langmuir‐Blodgett monolayer employed as liquid‐crystal alignment layers promoting homeotropic orientation. On the basis of nano‐engineering of the surface alignment properties, two novel alignment concepts have been introduced: electrically commanded surfaces (ECS) and high‐performance alignment layers (HiPAL). Nano‐structured polymers related to these concepts have been designed, synthesized, and used as materials for alignment layers in LCDs. ECS materials belong to the category of active alignment materials designed to mediate switching of the liquid crystal, whereas the HiPAL materials make possible the control of the molecular tilt angle in a broad range, from 0° to 90°, and they seem to enable the control of the anchoring strength as well. The nano‐structured alignment materials are strong candidates for implementation in a new generation of advanced liquid‐crystal displays and devices.     

EO characteristics for a photoaligned VA‐1/4 π cell on a photopolymer layer

The generation of a liquid‐crystal (LC) tilt angle on a copolymer with chalconyl and cholesteryl moiety characteristics was performed, and the electro‐optical (EO) performance of the photoaligned vertical‐alignment (VA) 1/4 π cell by polarized UV exposure on a homeotropic photopolymer surfaces was studied. The LC tilt angles decreased as UV exposure time increased on the copolymer surfaces. A tilt angle of 87° in NLC was observed with an UV exposure of 3 min on the photoalignment‐2 surface. The LC tilt angle is attributed to increased chalcone moiety with increasing UV exposure time. Excellent voltage‐transmittance (V‐T) curves of the photoaligned VA 1/4 π cell by polarized UV exposure on the photopolymer surface for 3 min containing a cholesteryl moiety of 8% were obtained. The V‐T and response‐time characteristics can be improved by the presence of a cholesteryl moiety in the photopolymer.     

Properties of azo‐dye alignment layer on plastic substrates

Abstract— The alignment properties of the azo‐dye photo‐alignment material SD‐1/SDA‐2 on plastic substrates are investigated. Important liquid‐crystal cell parameters, such as azimuthal and polar anchoring energy, pretilt angle, voltage holding ratio, and the corresponding electro‐optical properties are presented. Excellent alignment with high anchoring energy can be achieved with a polarized UV dose less than 1.0 J/cm². A reflective six‐digit flexible passive‐matrix‐driven TN‐LCD for smart‐card applications showing excellent electro‐optical properties is demonstrated.     

Review Paper: Emerging vertical‐alignment liquid‐crystal technology associated with surface modification using UV‐curable monomer

Abstract— The recent development of polymer‐induced pretilt angle in multi‐domain vertical‐alignment liquid‐crystal (LC) structures is reviewed. To create a small but well‐defined pretilt angle, ～0.1 wt.% of a photo‐curable monomer was mixed in an LC host and a bias voltage was applied to reorient the LC directors within each domain. The monomers are polymerized near the substrate surfaces by UV exposure. The formed polymer layers change the surface pretilt angle of the LC from 90° to about 89° with a defined azimuthal orientation. Consequently, within each domain the LC reorientation direction responding to the external field is well‐defined which leads to faster rise time and higher transmittance. This new technology overcomes the long standing problems of conventional MVA devices and is therefore expected to play a dominant role in the future.     

Arbitrary pretilt and azimuth angles generation by stacked photoalignment layers

We report a method of fabricating a nano‐sized stack alignment layer. The stacked alignment layer consists of nano‐domains of vertical and planar alignment materials. Experiments reveal that photoalignment thin film can undergo dewetting and form discrete nano‐sized domains. Such self‐organized structure creates a discontinuous layer stacked on top of a continuous layer and hence produces an inhomogeneous alignment surface. With two or more different principle alignment directions, this new alignment layer is capable of producing multiple pretilt and azimuth angle domains on a single substrate.     

A 15‐in. XGA thresholdless antiferroelectric LCD addressed by TFTs and using the quasi‐dc driving method

Abstract— A 15‐in. TFT‐LCD with XGA resolution using thresholdless antiferroelectric liquid crystal (TLAF) has been developed. TLAF materials show V‐shaped switching and enable display of analog gray scale, wide viewing angle, and fast response. However, in the case that high‐resolution TFT‐LCDs using materials with large spontaneous polarization such as TLAF were driven by the conventional method, alternating current (ac) driving, the obtained contrast ratio was limited because of a sharp decline of holding voltage due to the growth of a depolarization field. In order to enhance the contrast ratio, a novel driving method referred to as quasi‐dc driving was proposed. In the quasi‐dc driving, the polarity of the applied voltage to liquid crystals inverts at certain intervals of several seconds. Moreover, the applied voltage and the charging time at the time of polarity inversion are increased more than the intended signals. By this method, the 15‐in. TFT‐LCD using TLAF with high contrast ratio (more than 100:1) and wide viewing angle was realized.     

Curved vertical‐alignment liquid crystal display with uniform brightness: From pixel design to verification

Curved liquid crystal display (LCD) suffers from an issue of uneven brightness among the vertical‐alignment LCD panels based on thin glass substrates. In this work, we investigated its origin through optical simulation and successfully realized uniform brilliance for 27‐inch curved LCD panels. The optical simulation revealed that the dark areas on the bending sides of the curved LCD panel originated from the reduced azimuth angle of the liquid crystals (LC) next to the ITO trunk. This issue could be resolved by decreasing the pretilt angle of the LC on the color filter side. Through developing pretilt angle tuning technologies, we experimentally verified that the uniform brilliance could be achieved for 27‐inch curved LCD panels with 900‐mm curvature on thin glass substrates.     

Energy‐efficient liquid‐crystal displays (e2‐LCDs) using a photonic‐crystal backlight system

Abstract— Cholesteric liquid crystals automatically form one‐dimensional photonic crystals. For a photonic crystal in which light‐emitting moieties are embedded, unique properties such as microcavity effects and simultaneous light emission and light reflection can be expected. Three primary‐color photonic‐crystal films were prepared based on cholesteric liquid crystal in which fluorescent dye is incorporated. Microcavity effects, i.e., emission enhancement and spectrum narrowing, were observed. Two types of demonstration liquid‐crystal displays (LCDs) were fabricated using the prepared photonic‐crystal films in a backlight system. One is an area‐color LCD in which a single photonic‐crystal layer is used for each color pixel and the other is a full‐color TFT‐LCD in which three stacked photonic‐crystal layers are used as light‐conversion layers. The area‐color LCD was excited by using 365‐nm UV light, and the full‐color TFT‐LCD was excited by using 470‐nm blue LED light. Because of the photonic crystal's unique features that allow it to work as light‐emitting and light‐reflecting layers simultaneously, both LCDs demonstrate clear readable images even under strong ambient light, such as direct‐sunlight conditions, under which conventional displays including LCDs and OLED displays cannot demonstrate clear images. In particular, an area‐color LCD, which eliminated color filters, gives clear images under bright ambient light conditions even without backlight illumination. This fact suggests that a backlight system using novel photonic‐crystal layers will be suitable for energy‐efficient LCDs (e²‐LCDs), especially for displays designed for outdoor usage.     

A new vertical‐alignment LC mode with high‐transmittance and fast‐response‐time features

Abstract— A novel pixel design for vertical‐alignment LCDs with superior transmittance has been developed. The new liquid‐crystal mode, refered to as the hole‐induced vertical‐alignment mode (Hi‐VA), uses a via hole of an organic layer on a TFT substrate to achieve multi‐domain alignment. Compared to the conventional design, the Hi‐VA mode has a transmittance of up to 135% with a contrast ratio of 2000:1. Moreover, the new structure is free from ITO patterning or protrusion on the color‐filter side, which makes the fabrication process simple and low cost.     

Robust flexible LCDs with paintable technology

Abstract— In this article, second‐generation liquid‐crystal displays (LCDs) made by Paintable LCD technology is presented. With this technology, LCDs are manufactured by a sequence of simple coating and UV curing processes. Since the process can be carried out on plastic substrates and the stack of optical layers is only tens of micrometers thick, the resulting LCDs are ultra‐thin and flexible.     

Liquid‐crystal displays using printed plastic TFT backplanes

Abstract— In this paper, we present results from a new liquid crystal over plastic printed thin‐film‐transistor (TFT) display. The display demonstrator shows that the processing incompatibilities between the plastic TFT backplane and the liquid‐crystal materials can be addressed to make a stable twisted‐nematic structure. New fabrication processes such as the photo‐alignment of liquid crystals have made it possible to create a new generation of displays, which pave the way towards fully integrated plastic liquid‐crystal‐display technologies.     

Control of the pretilt angle for liquid crystal alignment using novel electrospray deposition methods with two capillaries

The electrospray deposition (ESD) method is an established film‐forming technique. To control the pretilt angle on films, we developed two novel ESD methods for spraying two kinds of solutions containing alignment materials. One method is a simultaneous spraying method, while the other is a time‐divided spraying method. When we used the simultaneous‐spraying ESD method, we observed numerous fine liquid crystal (LC) domains with a diameter of approximately 10 µm in the LC cell. These LC domains were substantially smaller than those of LCs fabricated using the conventional ESD method. However, the pretilt angle could not be controlled over a wide range because multiple parameters could not be simultaneously controlled to achieve a stable spray. Using the time‐division ESD method, we controlled the pretilt angle over a wide range from 5° to 40°, with tiny domains. As a demonstration, we fabricated a 270° super‐twisted nematic mode cell using this method.     

Nano‐structured liquid‐crystal alignment layers (Invited Paper)

Abstract— The alignment of liquid crystal by nano‐structured surfaces is investigated. It is shown that reliable pretilt angles of any value between 0° and 90° can be produced with these surfaces. The physics and properties of such alignment layers are studied using a variety of techniques. The anchoring energy and temperature stability of the alignment are also measured. Dependence on various processing conditions is also characterized. It is shown that these nano‐structured alignment layers are useful for the production of high pretilt angles needed for a variety of applications.