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1.
Transition metal dichalcogenides belong to the more developed class of materials for solid lubrication. However, the main limitation of these materials is the detrimental effect of air humidity causing an increase in the friction. In previous works, molybdenum diselenide has been shown to be a promising coating retaining low friction even in very humid environment. In this study, Mo–Se–C films were deposited by sputtering from a C target with pellets of MoSe2. Besides the evaluation of the chemical composition, the structure, the morphology, the hardness and the cohesion/adhesion, special attention was paid to the tribological characterization.The C content varied from 29 to 68 at.% which led to a progressive increase of the Se/Mo ratio. As a typical trend, the hardness increases with increasing C content. The coatings were tested at room temperature with different air humidity levels and at temperatures up to 500 °C on a pin-on-disc tribometer. The friction coefficient of Mo–Se–C coatings increased with air humidity from ~0.04 to ~0.12, while it was as low as 0.02 at temperature range 100–250 °C. The coatings were very sensitive to the elevated temperature being worn out at 300 °C due to adhesion problems at coating–titanium interface. 相似文献
2.
NiCr–Al2O3–SrSO4–Ag self-lubricating composites were prepared by powder metallurgy method and the tribological properties of composites were evaluated by a ball-on-disk tribometer against alumina ball at wide temperature range from the room temperature to 1,000 °C in air. The linear coefficient of thermal expansion was evaluated for investigation of thermal stability of composites. The tribo-chemical reaction films formed on the rubbing surfaces and their effects on the tribological properties of composites at different temperatures were addressed according to the surface characterization by SEM, XRD, and XPS. The results show that the NiCr–Al2O3 composite with addition of 10 wt% SrSO4 and 10 wt% Ag exhibits satisfying friction and wear properties over the entire temperature range from room temperature to 1,000 °C. The composition of the tribo-layers on the worn surfaces of the composites is varied at different temperatures. The synergistic lubricating effect of SrAl4O7, Ag, and NiCr2O4 lubricating films formed on worn surfaces were identified to reduce the friction coefficient and wear rate from room temperature to 800 °C. Meanwhile, at 1,000 °C, the SrCrO4 and NiAl2O4 was formed on the worn surfaces during sliding process, combining with the NiCr2O4, Al2O3, Cr2O3, Ag, and Ag2O, which play an important role in the formation of a continuous lubricating film on the sliding surface. 相似文献
3.
Mechanical and tribological properties of Cr–Nb double-glow plasma coatings deposited on Ti–Al alloy
Xiangfei Wei Pingze Zhang Dongbo Wei Hongyuan Zhao Chun Wang Tomasz Liskiewicz 《Tribology - Materials, Surfaces & Interfaces》2017,11(2):98-106
Double-glow plasma (DGP) coatings are recommended for metallic components to mitigate the damage induced by complex working conditions in previous studies. In this paper, Nb-rich (Cr–Nb4) and Cr-rich (Cr4–Nb) -alloyed layers were formed onto the Ti–Al substrate via a DGP process to enhance its wear resistance. Scratch and Nano-indentation tests were used to evaluate the mechanical properties of the coatings. The tribological behaviour of the coatings were investigated using a pin-on-disc tribometer by rubbing against the GCr15 ball. Results from surface analysis techniques showed that the coatings mainly comprised Cr, Nb and Cr2–Nb phases, and were well bonded to the substrate. The hardness of the Cr–Nb4 coating was 11.61GPa and the Cr4–Nb coating was 9.66 GPa which all higher than that of the uncoated Ti–Al which was 5.65 GPa. However, the critical load of the Cr4–Nb coating ~21.64 was higher than that of the Cr–Nb4 coating ~17.6. And the specific wear rate of Cr–Nb4 coating, Cr4–Nb coating and uncoated Ti–Al were 3.54 × 10?4, 0.01 × 10?4 and 1.53 × 10?4mm3 N?1 m?1, respectively. The low-wear mechanism of the coatings is discussed in detail in this paper. 相似文献
4.
Bronze–SiC–nickel coated graphite composites were fabricated by powder metallurgy technique (P/M). The tribological properties of composites sliding against AISI321 stainless steel pin were studied under sea water condition. The graphite is an effective solid lubricant in sea water environment. The SiC improved the hardness and tribological properties of composites. The friction coefficient of bronze–SiC–graphite composites increased with the increase of SiC. However, the specific wear rate of bronze–SiC–graphite composites decreased with increasing SiC. Bronze-2 wt% SiC-11.7 wt% nickel coated graphite composite showed the best tribological properties due to the synergistic effects of reinforcements. 相似文献
5.
The friction and wear behaviors of the self‐lubricating Al2O3–20Ag20CaF2 disk against an Al2O3 pin pair have been investigated over a broad load range from 1 to 30 N and sliding velocities from 0.084 to 1 m/s at 650°C. Four typical wear modes have been identified and the wear mode map was constructed to illustrate the influence of load
and speed on the friction coefficient and wear rate. The results showed the effective self‐lubricating region (II) (continuous
lubricating film) is almost independent of sliding speed, and mainly dependent on the load. It is suggested that the plastic
deformation and plastic flow during sliding play an important role in the formation of the self‐lubricating film on the sliding
surface. Furthermore, the worn surface in the region (II) (continuous lubricating film) was found to be much softer than the
original surface and the distribution of Vickers hardness became more uniform due to the presence of the lubricating film
on the worn surface.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
6.
Effects of sintering aids and solid lubricants on tribological behaviours of CMC/Al2O3 pair at 650°C
Ten kinds of self-lubricating composites with different amounts of sintering aids and solid lubricants in Al2O3 matrix were fabricated by hot-pressed sintering. Their friction and wear behaviours in unlubricated sliding against Al2O3 were tested by using a pin-on-disk wear tester at 650°C. It was shown that the amount of sintering aids strongly affected
friction coefficient and wear rate of the Al2O3–20Ag20CaF2 composite, the appropriate amount of sintering aids was 10 wt% for beneficial effect on the reduction of wear at 650°C. Also
it was shown that the addition of equal quantities of Ag and CaF2 in Al2O3 matrix can promote the formation of the well-covered lubricating film, and effectively reduce the friction and wear. The
composite with 40 wt% of lubricants (20 wt% Ag, 20 wt% CaF2) presented an optimum tribological behavior at 650°C (friction coefficient μ is about 0.3, wear rates are about 4 x 10-6 mm3/N,m and 5 x 10-7 mm3/N,m for the disk and pin, respectively).
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
7.
R. Biswas A. S. Kuar S. K. Biswas S. Mitra 《The International Journal of Advanced Manufacturing Technology》2010,51(9-12):983-994
In micro-manufacturing, circularity of a drilled hole at entry and exit are important attributes which greatly influence the quality of a drilled hole. This study investigates the effect of five parameters in the circularity of drilled holes in pulsed Nd:YAG laser micro-drilling process. The drilling operation has been carried out on titanium nitride–alumina (TiN–Al2O3) composite, an important electroconductive ceramics suitable for wear and heating applications. The effect of various process parameters like lamp current, pulse frequency, pulse width, air pressure, and focal length of Nd:YAG laser micro-drilling on hole circularity at entry and exit has been investigated through response-surface-methodology-based experimental study. The parametric combination for optimal hole circularity at entry and exit has also been evaluated. 相似文献
8.
《Tribology - Materials, Surfaces & Interfaces》2013,7(3):125-131
AbstractIn the present study, the wear behaviour of Cu–Al2O3 composites and Cu–Al alloys has been investigated. The experiment involved casting of Cu–Al alloys with 0·37, 1, 2 and 3 wt-% of aluminium under inert gas atmosphere. The composites were produced by internal oxidation of alloys at 950°C for 10 h in presence of Fe2O3 and Al2O3 powders mixture. The microstructures of composites were studied using SEM and atomic force microscopy. To identify wear behaviour of specimens, dry sliding pin-on-disk wear tests were conducted according to ASTM G99-95a standard. The normal loads of 20, 30, and 40 N were applied on specimens during wear tests. The sliding speed and distances were selected as 0·5 m s–1 and 500, 1000 and 1500 m respectively. To specify the wear mechanisms, the worn surfaces of composites were examined by SEM equipped with EDX. According to wear test results, increasing applied load and sliding distance leads to more volume loss in all specimens. Composites represent better wear resistance in comparison to alloys. Additionally, increasing the volume fraction of alumina particles in composites enhances the wear resistance, especially under high applied load. The wear mechanisms are mainly abrasion, oxidation and delamination. 相似文献
9.
Sanjeev Bhandari Harpreet Singh Harmesh Kumar Kansal Vikas Rastogi 《Tribology Letters》2012,45(2):319-331
Slurry erosion performance of detonation gun (D-gun) spray ceramic coatings (Al2O3 and Al2O3–13TiO2) on CF8M steel has been investigated. Slurry collected from an actual hydro power plant was used as the abrasive media in
a high speed erosion test rig. Attempt has been made to study the effect of concentration (ppm), average particle size and
rotational speed on the slurry erosion behaviour of these ceramic-coated steels under different experimental conditions. The
analysis of eroded samples was done using SEM, XRD and stylus profilometry. The slurry erosion performance of the D-gun spray
Al2O3–13TiO2-coated steel has been found to be superior to that of Al2O3-coated steel. Both the coatings showed brittle fracture mechanism of material removal during the slurry erosion exposure. 相似文献
10.
11.
Wear behavior of the HVOF deposited Cr3C2–NiCr and WC–Co coatings on Fe-base steels were evaluated by the pin-on-disc mechanism. The constant normal load applied to the pin was 49 N and sliding distance was 4500 m with velocity of 1 m/s, at ambient temperature and humidity. The specific wear rate of WC–Co coating was 3 mm3/N m and Cr3C2–NiCr coating was 5.3 mm3/N m. SEM/EDAX and XRD techniques were used to analyze the worn out surface and wear debris. The Fe2O3 was identified as the major phase in the wear debris. The wear mechanism is mild adhesive wear in nature. 相似文献
12.
Alumina-carbon nanofibres (CNFs) and silicon carbide–CNFs nanocomposites with different volume fraction of CNFs (0–100 vol.%) were obtained by spark plasma sintering. The effect of CNFs content on the tribological behaviour in dry sliding conditions on the ceramic–carbon nanocomposites has been investigated using the ball-on-disk technique against alumina balls. The wear rate of ceramic–CNFs nanocomposites decreases with CNFs increasing content. The friction coefficient of the Al2O3/CNFs and SiC/CNFs nanocomposites with high CNFs content was found to be significantly lower compared to monolithic Al2O3 and SiC due to the effect of CNFs and unexpectedly slightly lower than CNFs material. The main wear mechanism in the nanocomposite was abrasion of the ceramic and carbon components which act in the interface as a sort of lubricating media. The experimental results demonstrate that the addition of CNFs to the ceramic composites significantly reduces friction coefficient and wear rate, resulting in suitable materials for unlubricated tribological applications. 相似文献
13.
A simple compact device for three-coordinate positioning of the tip of a scanning tunneling microscope, which is intended for operation in ultrahigh vacuum and a temperature range from room to helium (4.2 K) temperature. The nanopositioner contains two independent stepping piezoelectric motors. One of them is intended for bringing the tip to a sample (the Z axis) and the other, for positioning the tip in the sample plane (X, Y). The positioning accuracies at T = 4.2 K along the Z axis and in the plane of the sample (X, Y) are up to 10 and 40 nm, respectively. The maximum amplitudes of control pulses are ±250 and 140 V for the Z piezoelectric motor and the (X, Y) positioner, respectively (at 4.2 K). The device is manufactured from nonmagnetic materials and allows heating to 150°C for operation in ultrahigh vacuum. 相似文献
14.
In this work, one ternary Al–40Zn–3Cu and seven quaternary Al–40Zn–3Cu–(0.25–5)Si alloys were synthesized by permanent mould
casting. Their microstructure, mechanical and lubricated wear properties were investigated using appropriate test apparatus
and techniques. As the silicon content increased the hardness of the alloys increased, but their elongation to fracture decreased.
Tensile strength of the alloys decreased with increasing silicon content following a sharp decrease and a slight increase.
Among the silicon-containing quaternary alloys the highest and the lowest tensile strength values (348 and 305 MPa) were obtained
with the Al–40Zn–3Cu–2Si and Al–40Zn–3Cu–5Si alloys, respectively, while the base alloy (Al–40Zn–3Cu) exhibited a tensile
strength of 390 MPa. However, the volume loss due to wear of the alloys increased with increasing silicon content after showing
an initial increase and a sharp decrease. The lowest wear loss was obtained with the alloy containing approximately 2% Si
which has the highest tensile strength among the quaternary alloys containing more than 0.25% Si. Wear surfaces of the alloys
were characterized mainly by smearing indicating that adhesion is the dominant wear mechanism for the experimental alloys. 相似文献
15.
A. Shahi M. Heydarzadeh Sohi D. Ahmadkhaniha M. Ghambari 《The International Journal of Advanced Manufacturing Technology》2014,75(9-12):1331-1337
Possibility of the formation of Al–Al3Ni composite layers on commercial pure aluminium plates by friction stir processing (FSP) has been studied. It is believed that the hot working nature of FSP can effectively promote the exothermic reaction between Al and added Ni powder to produce Al3Ni intermetallic compounds in the aluminium matrix. In this study, the effects of the rotational and traverse speed of the tool as well as the number of FSP passes on the in situ formation of Al3Ni in aluminum matrix were examined. Besides, the microstructure and microhardness of the fabricated surface layers were also studied. The results showed that the ratio of tool rotational speed to traverse speed (ω/υ) is the main controlling parameter of the heat generated during FSP and hence the reaction between aluminium and nickel. Increasing the number of FSP passes also promoted the reaction between Ni and Al and improved the distribution of Al3Ni compounds, too. The composite layer achieved by six passes of FSP showed the highest hardness, which was almost twice of that of the base metal. 相似文献
16.
Murakami G Sakai K Homma T Yoshioka K Yoshikawa I Ichimaru S Takenaka H 《The Review of scientific instruments》2011,82(3):033106
We briefly report on the performance and stability of periodic multilayer mirrors containing Y(2)O(3) and Al layers designed for normal incidence reflection at the He-II emission line (30.4 nm). We found that Y(2)O(3)∕Al multilayer coatings had higher reflectivity (24.9%) at 30.4 nm and significantly lower reflectivity (1.3%) at 58.4 nm than the conventional coatings such as Mo∕Si. Furthermore, we investigated the temporal stability of the Y(2)O(3)∕Al multilayer coatings. Our sample was kept under vacuum, dry N(2) purge, and normal atmosphere for over three months, and there were no measurable changes in the reflectivity. These results suggest that we can use Y(2)O(3)∕Al multilayer coatings as standard mirrors for the He-II radiation. 相似文献
17.
In this work, thin films deposited by pulsed DC magnetron sputtering of [Ti–Al/Ti–Al–N] n and [Ti–Cr/Ti–Cr–N] n multilayers of nanometric periods were analyzed by AFM in contact mode to measure values of lateral and normal forces. From these measurements, the coefficient of friction (COF) of these materials in contact with the AFM tip was calculated. Measurements were made with three types of silicon tips, diamond-coated, Pt–Cr-coated, and bare silicon. Significant differences between the tip materials in contact with the samples, which affected the COF, were observed. The effect of the environmental layer of water covering the surface sample and the tip appears as the most important factor affecting the tribology behavior of the tip-sample contact. For diamond-coated and bare silicon tips there is an additional adherence force increasing the normal load. But for tips platinum–chromium-coated there is a repulsive force due to this water layer, which behaves as a lubricant layer before a threshold load. 相似文献
18.
Permyakov G. L. Trushnikov D. N. Ol’shanskaya T. V. Shchitsyn Yu. D. Kartashev M. F. Hassel T. 《Russian Engineering Research》2022,42(10):1061-1064
Russian Engineering Research - Al–Mg alloy samples are produced by multilayer surfacing according to various strategies, with and without interlayer deformation. The samples undergo tensile... 相似文献
19.
A. Fathy A. Sadoun M. Abdelhameed 《The International Journal of Advanced Manufacturing Technology》2014,73(5-8):1049-1056
This paper studied the combined effects of matrix-to-reinforcement particle size ratio (PSR) and SiC volume fraction on the mechanical properties of extruded Al–SiC composites. A powder metallurgy technique (PM) of cold pressing at 500 MPa followed by hot extrusion at 580 °C was adopted to produce Al/SiC composite. Aluminum powder of size 60 μm and silicon carbide with different sizes, i.e., 50, 20, and 8 μm, were used. Three different volume fractions of SiC were employed, i.e., 5, 10, and 15 %, for each investigated size using a constant extrusion ratio of 14.36. The effect of matrix-to-reinforcement PSR on the reinforcement spatial distribution, fabricability, and resulting mechanical properties of a PM-processed Al/SiC composite were investigated. It has been shown that small ratio between matrix to reinforcement particle size resulted in more uniform distribution of the SiC particles in the matrix. As the PSR increases, the agglomerations and voids increase and the reinforcement particulates seem to have nonuniform distribution. In addition, the agglomerations increased as the volume fraction of the SiC increased. It has also been shown that homogenous distribution of the SiC particles resulted in higher yield strength, ultimate tensile strength, and elongation. Yield strength and ultimate tensile strength of the composite reinforced by PSR (1.2) are higher than those of composite reinforced by PSR (7.5), while the elongation shows opposite trend with yield strength and ultimate tensile strength. 相似文献
20.
A. Fathy A. A. Megahed 《The International Journal of Advanced Manufacturing Technology》2012,62(9-12):953-963
In this work, artificial neural networks (ANNs) technique was used in the prediction of abrasive wear rate of Cu–Al2O3 nanocomposite materials. The abrasive wear rates obtained from series of wear tests were used in the formation of the data sets of the ANN. The inputs to the network are load, sliding speed, and alumina volume fraction. Correlation coefficients between the experimental data and outputs from the ANN confirmed the feasibility of the ANNs for effectively model and predict the abrasive wear rate. The comparison between the ANNs and the multi-variable regression analysis results showed that using ANNs technique is more effective than multi-variable regression analysis for the prediction of abrasive wear rate of Cu–Al2O3 nanocomposite materials. Optimization of the training process of the ANN using genetic algorithm (GA) is performed and the results are compared with the ANN trained without GA. Sensitivity analysis is also done to find the relative influence of factors on the wear rate. It is observed that load and alumina volume fraction effectively influence the wear rate. 相似文献