纳米Ag颗粒增强复合钎料蠕变性能的研究

制备纳米Ag颗粒增强的Sn-Cu基复合钎料.研究不同温度载荷下复合钎料钎焊接头的蠕变断裂寿命,并与Sn-0.7Cu基体钎料钎焊接头进行对比.此外,确定纳米Ag颗粒增强的Sn-Cu基复合钎料钎焊接头在不同温度和应力水平下的应力指数和蠕变激活能,建立复合钎料钎焊接头的稳态蠕变本构方程.结果表明,在不同的温度和应力下,与Sn-0.7Cu钎料钎焊接头相比,纳米Ag颗粒增强的Sn-Cu基复合钎料钎焊接头的蠕变断裂寿命均有所提高,且具有更高的蠕变激活能,说明复合钎料钎焊接头具有更优的抗蠕变性能.     

银镍金属微细颗粒对锡铅基复合钎料力学性能的影响

运用弥散强化原理，分别选用Ag颗粒和Ni颗粒作为增强体，以63Sn37Pb共晶钎料为基体，制成金属颗粒增强锡铅基复合钎料。在再流焊条件下，弥散分布的增强体与基体冶金结合，在增强体表层形成一薄层金属间化合物，从而使复合钎料蠕变性能大幅度提高。试验证明：在相同条件下，与基体钎料63Sn37Pb相比，5％Ag(体积分数，下同)和10％Ag颗粒增强锡铅基复合钎料蠕变寿命分别提高了8倍和6倍，同时抗拉强度和剪切强度均得到提高；5％Ni和10％Ni颗粒增强锡铅基复合钎料蠕变寿命分别提高了84倍和185倍，但剪切强度和延伸率均明显降低。     

纳米银颗粒增强复合钎料的研究

研究了纳米银颗粒增强锡铅基复合钎料的物理性能、工艺性能、力学性能和蠕变性能。通过在Sn-37Pb中加入不同含量的纳米银颗粒，测定比较复合钎料的性能，从而选择最佳加入量。结果表明，φ(Ag)=3％的纳米银颗粒的复合钎料综合性能最好，与Sn-37Pb共晶钎料相比，所加入的纳米银颗粒对住错起到了钉扎作用，从而提高了钎焊接头的蠕变寿命，其断裂形貌特征为延性和脆性混合断裂。     

增强颗粒对Sn0.7Cu基复合钎料铺展性能的影响

以Sn0.7Cu共晶钎料作为基体钎料,通过添加微细金属颗粒(1μmAg、1μmNi和8μmCu)形成颗粒增强复合钎料。研究了增强颗粒对复合钎料铺展性能的影响,优选出Sn0.7Cu基复合钎料的最佳增强体。研究表明:Ni(3vol%)颗粒增强Sn0.7Cu复合钎料铺展性能差;Cu(3vol%)颗粒增强复合钎料铺展性能不如Ag(3vol%)颗粒增强复合钎料;对于金属颗粒增强Sn0.7Cu基复合钎料,Ag颗粒为最佳增强体。     

锡铅稀土钎料合金的高温蠕变性能

本文对比分析了Ｓｎ６０Ｐｂ４０和Ｓｎ－Ｐｂ－０．０５ＲＥ两种钎料合金在多轴应力状态下蠕的裂规律,初步探讨了主控两种钎料合金蠕变断裂的力学因素,并从金属学角度初步探讨了两种钎料合金的蠕变断裂方式,着重分析了混合稀土对锡铅钎料合金蠕变性能的影响。     

增强颗粒Cu对锡铅基复合钎料铺展性能的影响

颗粒增强是提高合金性能的重要手段之一。增强体的不同含量对基体的性能会产生不同的影响。分析和讨论了Cu的不同体积分数对Cu颗粒增强的锡铅基复合钎料铺展性能的影响。试验结果表明：当Cu颗粒的体积分数小于1％时，随着Cu的体积分数的增加，复合钎料的铺展性能有所提高；当Cu的体积分数大于1％时，随着Cu颗粒体积分数的增加，复合钎料的铺展性能降低；当Cu颗粒的体积分数大于10％时，复合钎料的铺展性能急剧降低，且外观质量变差。     

钎焊温度对Cu基非晶钎料钎焊WCuCrZr合金接头性能影响

为了实现降低ITER装置中W/CuCrZr合金钎焊温度的目的,采用甩带技术制备了成分为Cu47Ti33Zr11Ni8Si1(at.%)的宽10mm、厚80μm的均匀连续非晶合金箔带,将此铜基非晶合金作为新型钎料应用于W/CuCrZr合金的钎焊。使用光学显微镜、扫描电镜、X射线衍射仪和显微硬度计测试了接头显微结构、物相组成和显微硬度,对比了不同钎焊温度对接头性能的影响。结果表明：钎焊温度为900℃时,获得的钎焊接头界面接合良好、对母材影响小并且钎缝具有较高的硬度;将铜基非晶钎料应用于W/CuCrZr合金钎焊可以有效的降低钎焊温度。     

CuMnNiSi钎料钎焊不锈钢接头组织性能研究

采用新型的Cu-Mn-Ni-Si钎料真空钎焊2Cr13不锈钢,研究了钎焊温度和保温时间对接头组织和室温力学性能的影响.结果表明:钎焊接头组织由钎缝中心区Cu-Mn基固溶体和钎缝界面反应区的(Fe,Ni,Mn)- Si化合物组成.随着钎焊温度的增加,钎缝界面处化合物层厚度减小,Cu-Mn基固溶体相应增多,接头室温剪切强度随之增加,在钎焊时间15min、钎焊温度1050℃时达到321 MPa.在钎焊温度1000℃时,接头室温剪切强度随着钎焊保温时间的延长先增加后降低,在钎焊保温时间30min时取得最大值305 MPa.     

63Sn37Pb钎焊接头稳态蠕变本构方程的建立

采用高温蠕变测试装置，以简化的Dorn公式为基础．对63Sn37Pb微型单搭接钎焊接头蠕变应变进行了测试．确定了应力指数、蠕变激活能以及相关常数。建立了63Snd7Pb钎焊接头稳态蠕变本构方程，描述了稳态蠕变速率与应力和温度相关性。结果表明，钎焊接头应力指数和激活能均低于钎料本身的应力指数和激活能．说明钎料本身蠕变行为并不能完全代表钎焊接头的蠕变行为。     

颗粒增强复合钎料钎焊TiAl合金接头界面结构及性能

采用纳米Si3N4颗粒增强的AgCuTi复合钎料(AgCuTiC)实现了TiAl合金的钎焊连接.利用SEM,EDS及XRD等分析方法确定了TiAl/AgCuTiC/TiAl接头的典型界面结构为TiAl/AlCu2Ti/Ag(s,s)+TiN+ Al4Cu9+Ti5Si3.结果表明,钎焊过程中从TiAl母材溶入液相钎料的活性钛与复合钎料中纳米Si3N4颗粒发生反应,在钎缝中形成了细小的颗粒状TiN,Ti5Si3及Al4Cu9化合物增强的银基复合材料组织.银基复合材料的形成不仅提高了钎缝自身的强度,而且通过降低钎缝的线膨胀系数缓解了接头残余应力,并最终改善了钎焊接头的性能.当采用增强相含量为3％的AgCuTiC钎料在880℃保温5min条件下钎焊时,接头室温平均抗剪强度最高为278 MPa,比采用AgCuTi钎料提高40％.     

Influence of stress on the creep behavior of Cu particle enhancement SnPb based composite solder joints

1. Introduction Mechanical fracture of solder joints is a major cause of failure and it decreases the reliability in electronic systems. With the increased functionality, miniaturization of electronic components, broad op-eration temperature ranges, and increased stress re-quirement, good mechanical properties are de-manded on solder joints. The eutectic tin-lead solder, which has a low melting point (183°C), plays an important role in SMT (surface mount technology). The working temperature…     

The influence of temperature on creep behavior of Cu particle enhanced SnPb based composite soldered joints

Creep property of solder alloys is one of the important factors to affect the reliability of soldered joints in SMT(surface mount technology). Particle-enhancement is a way to improve the properties of solder alloys and has caused much more attention than before. Temperatures applied to soldered joints are one of the primary factors of affecting creep properties of particle enhancement composite soldered joints. In this paper single shear lap creep specimens with a 1 mm2 cross-sectional area were fabricated using Cu particle enhancement 63Sn37Pb based composite soldered joints and 63Sn37Pb eutectic soldered joints to examine the influence of temperature on creep behavior of soldered joints. Results indicated that the creep resistance of soldered joints of Cu particle enhancement 63Sn37Pb based composite soldered joint was generally superior to that of the conventional 63Sn37Pb soldered joint. At the same time, creep rupture life of the composite soldered joint was declined with increasing temperature and drop faster than that of the conventional 63Sn37Pb eutectic soldered joint.     

The influence of temperature enhanced SnPb based on creep behavior of Cu particle composite soldered joints

Creep property of solder alloys is one of the important factors to affect the reliabdity of soldered joints in SMT （surface mount technology）. Particle-enhancement is a way to improve the properties of solder alloys and has caused much more attention than before. Temperatures applied to soldered joints are one of the primary factors of affecting creep properties of particle enhancement composite soldered joints. In this paper single shear lap creep specimens with a 1 mm^2 cross-sectional area were fabricated using Cu particle enhancement 63Sn37 Pb based composite soldered joints and 63Sn37 Pb eutectic soldered joints to examine the influence of temperature on creep behavior of soldered joints. Results indicated that the creep resistance of soldered joints of Cu particle enhancement 63Sn37Pb based composite soldered joint was generally superior to that of the conventional 63Sn37Pb soldered joint. At the same time, creep rupture life of the composite soldered joint was declined with increasing temperature and drop faster than that of the conventional 63Sn37 Pb eutectic soldered joint.     

Creep behavior on Ag particle reinforced SnCu based composite solder joints

1 Introduction The EU had issued the WEEE mandate that aimed to prohibit the use of SnPb solders by 2006. Under the pressure of legislation and trade competitions, large electronic manufacturers and research institutes studied substitutes for SnPb solders…     

SnCu钎焊接头稳态蠕变本构方程建立

以搭接面积为1 mm2微型单搭接钎焊接头为研究对象,采用新型高温蠕变测试装置,测定了Sncu钎焊接头应力指数n和蠕变激活能Q,构建了稳态蠕变本构方程,探讨了蠕变变形机制.结果表明,在低温高应力下,SnCu共晶钎料钎焊接头应力指数为8.73,激活能在59.1～63.2 kJ/mol,位错攀移运动主要受位错管道扩散机制控制;在高温低应力区,Sncu共晶钎料钎焊接头应力指数为6.45,激活能在88.4～97.5 kJ/mol,位错攀移运动主要由晶格自扩散机制控制.     

基于纳米压痕法的无铅BGA焊点的循环力学行为

采用纳米压痕法通过循环加载卸载方式研究了最大载荷、循环次数及保载时间对Sn-3.0Ag-0.5Cu和Sn-0.3Ag-0.7Cu 2种钎料BGA焊点循环性能的影响.结果表明,Sn-Ag-Cu系无铅BGA焊点的循环性能具有很大的载荷依赖性,随着最大载荷的增加,BGA焊点的损伤累积增加且前几周循环中损伤累积很大,其后逐渐减小并趋于稳定;循环次数增加,使BGA焊点抵抗变形的能力稍有降低;保载时间增加,蠕变位移不断增加,蠕变和疲劳共同作用会加速焊点失效;Sn-0.3Ag-0.7Cu钎料BGA焊点的能量损耗大于Sn-3.0Ag-0.5Cu钎料BGA焊点.     

Sn-Pb共晶钎料在铜基板及金属间化合物基板上的润湿动力学

对锡-铅共晶钎料63Sn-37Pb在Cu基板及Cu-Sn金属间化合物表面层基板上的反应润湿动力学特性进行研究.结果表明:63Sn-37Pb钎料在Cu基板上的铺展特性随界面反应过程中液态钎料中Sn组元的消耗而变化;钎料熔化后的初始铺展符合简单流体规律,随后在Sn组元充足的条件下钎料以稳定速率铺展;随着Sn组元的不断消耗,润湿机制呈现界面活性元素扩散控制的反应铺展特征;63Sn-37Pb在Cu-Sn IMC表面层基板上呈现出非常好的铺展能力,远优于其在Cu基板上的铺展.     

基于蠕变模型倒装芯片焊点疲劳寿命预测

焊点可靠性预测研究多采用有限元仿真与单一精度近似模型相结合的模式,存在仿真时间长、效率低、准确性差等问题,为此,提出了一种基于变可信度近似模型的球栅阵列(ball grid array,BGA)焊点可靠性预测与优化方法.首先, 对不同网格细化方案进行收敛性验证,分别设计高/低精度样本点进行有限元仿真;其次,基于Co-Kriging模型融合高/低精度仿真数据进行焊点可靠性预测;最后,将预测结果与单一精度近似模型进行对比分析,并采用遗传算法优化模型获得对应结构参数.结果表明,在更少的仿真成本下,变可信度模型的预测效果更好,在同等预测精度下,变可信度模型高精度样本点数量仅为单一精度模型的1/4,相比高精度神经网络预测模型,在寻优过程中收敛更快.