Influence of 15 and 80 nano-SiO2 particles addition on mechanical and physical properties of ternary blended concrete incorporating rice husk ash

This study demonstrates the effects of SiO₂ nanoparticles as additives with two different sizes of 15 and 80?nm on compressive strength and porosity of rice husk ash (RHA) blended concrete. Up to 20% of ordinary Portland cement (OPC) was replaced by RHA with average particle size of 5 micron. Also, SiO₂ nanoparticles were added to the above mixture at four different weight percentages of 0.5, 1.0, 1.5 and 2.0 and cured in lime solution. The results indicated that compressive strength of Portland cement–nano SiO₂–rice husk ash (PC–NS–RHA) ternary blended concrete was considerably increased. Moreover, the total amount of porosity decreased to a minimum with respect to the control concrete. This improvement was observed at all the curing ages and replacement levels, but there was a gain in the optimal point with 20% of RHA plus 2% of 80?nm SiO₂ particles at 90 days of curing.     

Particle size effect on the strength of rice husk ash blended gap-graded Portland cement concrete

Rice husk ash (RHA) has been used as a highly reactive pozzolanic material to improve the microstructure of the interfacial transition zone (ITZ) between the cement paste and the aggregate in high-performance concrete. Mechanical experiments of RHA blended Portland cement concretes revealed that in addition to the pozzolanic reactivity of RHA (chemical aspect), the particle grading (physical aspect) of cement and RHA mixtures also exerted significant influences on the blending efficiency. The relative strength increase (relative to the concrete made with plain cement, expressed in %) is higher for coarser cement. The gap-grading phenomenon is expected to be the underlying mechanism. This issue is also approached by computer simulation. A stereological spacing parameter (i.e., mean free spacing between mixture particles) is associated with the global strength of the blended model cement concretes. This paper presents results of a combined mechanical and computer simulation study on the effects of particle size ranges involved in RHA-blended Portland cement on compressive strength of gap-graded concrete in the high strength/high performance range. The simulation results demonstrate that the favourable results for coarser cement (i.e., the gap-graded binder) reflect improved particle packing structure accompanied by a decrease in porosity and particularly in particle spacing.     

Creep analysis of concrete containing rice husk ash

This paper presents an experimental study on the mechanical properties of concrete added with rice husk ash (RHA) as a supplementary cementitious material. The compressive strength, modulus of elasticity and creep were obtained experimentally from specimens with different RHA contents (0%, 10%, 15% and 20% of binder). The results show that the addition of RHA in concrete can improve both the compressive strength and modulus of elasticity and reduce the creep of concrete. The examination of pore micro-structure of hardened concrete using both the mercury intrusion porosimetry and scanning electron microscope techniques demonstrates that RHA particles can react with calcium hydroxide originated from cement hydration to produce additional C-S-H, which can fill voids and large pores and thus reduces the porosity related to capillary pores and voids. In addition, the release of absorbed water, which is retained in the small pores of RHA particles at early days, can improve cement hydration and thus reduce the porosity related to gel pores.     

Effect of grinding of low-carbon rice husk ash on the microstructure and performance properties of blended cement concrete

The effectiveness of unground low-carbon rice husk ash (URHA) as a pozzolan and the effect of grinding the URHA to finer fractions for use in portland cement system were investigated. The properties investigated include the setting time and calcium hydroxide depletion of rice husk ash (RHA) pastes; microstructure and flow behavior of RHA mortars; strength and durability of RHA concretes. Results from this investigation suggested that the URHA and ground RHA (GRHA) mixtures performed better than the control mixtures in all tests conducted except water demand and setting time. The URHA mixture revealed denser microstructure compared to the control mixture. The internal porosity created by the coarse RHA grains in the matrix and their inability to completely participate in pozzolanic reaction may be the reasons for the poorer performance of the URHA mixture than compared to the GRHA mixture. The effect of grinding the RHA to finer fractions either substantially or slightly improved all properties except final setting time. With the performance of the GRHA concrete somewhat similar to that of the SF concrete, the use of ground RHA can be concluded to provide acceptable performance in portland cement systems.     

Chloride penetration and carbonation in concrete with rice husk ash and chemical activators

The use of industrial or agricultural by-product substitutions for cement has greatly contributed to sustainable development practices. The joint use of chemical activators has produced improvements in the mechanical properties of concrete but there are still few studies attempting to investigate the influence of activators on carbonation and chloride penetration. This study investigated the influence of chemical activators K₂SO₄, Na₂SO₄, Na₂SiO₃ on compressive strength, chloride penetration and carbonation of concrete mixtures with rice husk ash. Results indicate that the use of these activators has beneficial effects on initial strength and reduces chloride penetration. The mixture prepared with 20% rice husk ash and 1% K₂SO₄ as a chemical activator showed the lowest carbonation coefficients, which were in fact lower than the values found in the reference sample.     

An application of blended fly ash and residual rice husk ash for producing green building bricks

The present study investigates the possibility of using a blended class-F fly ash (FA) and residual rice husk ash (RHA) in the production of green building bricks through the application of densified mixture design algorithm (DMDA) in order to provide a new use for solid waste materials. This study uses unground rice husk ash (URHA) as a partial fine aggregate substitution (10–40%) in the studied cementitious mixtures. Solid bricks of 220 × 105 × 60 mm in size were prepared under forming pressure of 25–35 MPa, a curing temperature of 90 °C, and a relative humidity of 50%, for tests that assessed: compressive strength, flexural strength, bulk density, void volume, and water absorption. The test results showed that all brick samples demonstrated excellent properties. Compressive strength and flexural strength ranged, respectively, between 20.2–33 MPa and 5.4–6.9 MPa. Additionally, up to 30% of URHA content, the values of water absorption and void volume ranged, respectively, between 8.8–15.7% and 1.5–2.1%. All of these values not only conformed well to the requirements of the Vietnamese codes but also demonstrated great potential for using a blended FA–RHA in producing green building bricks.     

Hardened properties of self-consolidating high performance concrete including rice husk ash

This paper mainly presents the key hardened properties of self-consolidating high performance concrete (SCHPC). Various SCHPCs were produced with different water/binder (W/B) ratios, rice husk ash (RHA) contents, and air contents. The required filling ability and air content were achieved in all freshly mixed SCHPCs. The hardened SCHPCs were tested for compressive strength, ultrasonic pulse velocity, water absorption, total porosity, and true electrical resistivity. The effects of W/B ratio, RHA content, and air content on these hardened properties were observed. Test results revealed that the compressive strength, ultrasonic pulse velocity, and electrical resistivity increased whereas the water absorption and total porosity decreased with lower W/B ratio and higher RHA content. In addition, the air content decreased the compressive strength, ultrasonic pulse velocity, water absorption, and total porosity but increased the electrical resistivity. Based on the overall effects of rice husk ash, the optimum RHA content for SCHPC has been defined.     

Use of ultrafine rice husk ash with high-carbon content as pozzolan in high performance concrete

Rice husk ash (RHA) has been generated in large quantities in rice producing countries. This by-product can contain non-crystalline silica and thus has a high potential to be used as cement replacement in mortar and concrete. However, as the RHA produced by uncontrolled burning conditions usually contains high-carbon content in its composition, the pozzolanic activity of the ash and the rheology of mortar or concrete can be adversely affected. In this paper the influence of different grinding times in a vibratory mill, operating in dry open-circuit, on the particle size distribution, BET specific surface area and pozzolanic activity of the RHA is studied, in order to improve RHA’s performance. In addition, four high-performance concretes were produced with 0%, 10%, 15%, and 20% of the cement (by mass) replaced by ultrafine RHA. For these mixtures, rheological, mechanical and durability tests were performed. For all levels of cement replacement, especially for the 20%, the ultra-fine RHA concretes achieved superior performance in the mechanical and durability tests compared with the reference mixture. The workability of the concrete, however, was reduced with the increase of cement replacement by RHA.     

Self compacting concrete from uncontrolled burning of rice husk and blended fine aggregate

This paper presents an experimental study on the development of normal strength Self compacting concrete (SCC) from uncontrolled burning of rice husk ash (RHA) as a partial replacement to cement and blended fine aggregate whilst maintaining satisfactory properties of SCC. Experiments on the fresh and hardened state properties have been carried out on RHA based SCC from uncontrolled burning. The dosages of RHA are limited to 0%, 20%, 30% and 40% by mass of the total cementitious material in the concrete. The experiments on fresh state properties investigate the filling ability, the passing ability and the segregation resistance of concrete. The experiments on hardened state properties investigate the compressive and the splitting tensile strengths. The water absorption level of the concrete with changing RHA levels has also been monitored. The experimental studies indicate that RHA based SCC developed from uncontrolled burning has a significant potential for use when normal strength is desired.     

Properties of geopolymer with seeded fly ash and rice husk bark ash

In the present work, compressive strength of inorganic polymers (geopolymers) produced of seeded fly ash and rice husk bark ash has been investigated. Different specimens made from a mixture of fly ash and rice husk bark ash in fine and coarse form were subjected to compressive strength tests at 7 and 28 days of curing. The curing regime was different: one set of the specimens were cured at room temperature until reaching to 7 and 28 days and the other sets were oven cured for 36 h at the range of 40-90 °C and then cured at room temperature until 7 and 28 days. The results indicate that in both 7 and 28 days regimes, the highest strengths are related to the specimens by SiO₂/Al₂O₃ ratio equals 2.99 cured at 80 °C. For these specimens, those contained finer fly ash particles show more compressive strength. Thermogravimetric analysis and Fourier transform infrared spectroscopy both also are in agreement with the obtained results from compressive strength tests. In addition, SEM micrographs of the specimens show that the finer the particle size of the utilized ashes, the denser the microstructure which confirms the results obtained by the strength tests.     

Mechanical properties of roller compacted concrete containing rice husk ash with original and recycled asphalt pavement material

This study focused on the effects of rice husk ash (RHA) on the mechanical properties of roller compacted concrete (RCC) designed with original and reclaimed asphalt pavement (RAP) materials. The RCC mixes were produced by partial substitution of cement with RHA at varying amounts of 3% and 5%. Four aggregate combinations including the mix with original aggregate, coarse RAP + fine original aggregate, coarse original aggregate + fine RAP and total RAP were considered. The main experimental design consisted of the compressive strength and three points bending tests. Bending test was used to measure the modulus of rupture, material’s energy absorbency and analyse the fatigue response of RCC mixes. All tests were performed after 7, 28 and 120 days curing except the fatigue test that performed on 120 days specimens. Adding RHA resulted in higher optimum moisture content (OMC) and lower maximum dry density. Furthermore, adding RAP with different dimensions reduced the OMC and maximum dry density. The material’s flexibility improved upon replacing 3% cement by RHA. However, the energy absorbency reduced by increasing the RHA content to 5%. The fatigue life of RCC mixes containing RAP material was lower than the conventional one. Furthermore, replacing the coarse aggregate by RAP led to higher fatigue life than the fine aggregate. There was a strong relationship (R² > 0.90) between the energy absorbency and fatigue response of RCC mixes. At higher stress ratios of 0.72, the mix with higher energy absorbency behaved better under repeated loadings. Besides, a reverse relationship was found between the fatigue life and material porosity. Adding 3% RHA reduced the porosity especially after 120 days curing and improved the fatigue resistance. However, the addition of RHA to 5% resulted in higher porosities and lower fatigue lives.     

Properties of autoclaved aerated concrete incorporating rice husk ash as partial replacement for fine aggregate

This study examines the effects of rice husk ash (RHA) on the physical, mechanical and microstructural properties of autoclaved aerated concrete (AAC) produced at a temperature of 180 °C for 8 h and 18 h. The RHA was used as an aggregate at various replacement ratios. The results demonstrated that RHA substitution for sand reduces compressive strength and unit weight. In terms of the microstructure, the highly reactive silica in RHA strongly affected the tobermorite transformation. At 8 h of autoclaving time, the lath-like and plate-like tobermorite formed in mixtures containing up to 50% RHA was replaced by a glass-like, silica-rich CSH structure at increased replacement ratios. However, extended processing had no significant effect on these properties, which indicates that the substitution of RHA for sand has a tendency to reduce the autoclaving time or autoclaving temperature required.     

High temperature capture of CO2 on lithium-based sorbents from rice husk ash

Highly efficient Li(4)SiO(4) (lithium orthosilicate)-based sorbents for CO(2) capture at high temperature, was developed using waste materials (rice husk ash). Two treated rice husk ash (RHA) samples (RHA1 and RHA2) were prepared and calcined at 800°C in the presence of Li(2)CO(3). Pure Li(4)SiO(4) and RHA-based sorbents were characterized by X-ray fluorescence, X-ray diffraction, scanning electron microscopy, nitrogen adsorption, and thermogravimetry. CO(2) sorption was tested through 15 carbonation/calcination cycles in a fixed bed reactor. The metals of RHA were doped with Li(4)SiO(4) resulting to inhibited growth of the particles and increased pore volume and surface area. Thermal analyses indicated a much better CO(2) absorption in Li(4)SiO(4)-based sorbent prepared from RHA1 (higher metal content sample) because the activation energies for the chemisorption process and diffusion process were smaller than that of pure Li(4)SiO(4). RHA1-based sorbent also maintained higher capacities during the multiple cycles.     

Performance and properties of mortar mixed with nano-CuO and rice husk ash

This paper presents an experimental study on a new mixture scheme of mortar. Unlike most of existing work, the present study investigates nano-CuO (NC), and its combined effects with cement replacement i.e., rice husk ash (RHA) on durability performance, as well as strength and permeability properties of mortars. Comprehensive observations of both the performance and properties improvements on RHA-containing mortar specimens were determined with the addition of NC. To this end, a series of tests for examining the strength both directly (compressive strength) and indirectly (Ultrasonic Pulse Velocity), electrical resistivity, chloride permeability, water absorption and microstructure characteristics (i.e., SEM micrographs, Mercury intrusion porosimetry (MIP) & capillary analyses) of mortar specimens were performed. A relationship between the Rapid chloride permeability test (RCPT) and electrical resistivity was also studied in order to recommend an alternative method for quality control in the presence of RHA and NC. Finally, a mixture scheme which provides relatively satisfactory properties improvement with positive environment credential is suggested.     

Use of rice husk ash in sandcrete blocks for masonry units

Different mix proportions of sand, cement and rice husk ash (RHA) were studied for use in sandcrete blocks. Optimum water/(cement+RHA) ratios were determined at different mix proportions. Compressive strengths of various mix proportions at 7, 28 and 60 days were also determined. The optimum water/(cement+RHA) ratio increased with rice husk ash contents. Test results showed that up to 40% RHA could be added as a partial replacement for cement without any significant change in compressive strength at 60 days. Compressive strengths of various mix proportions were compared with British Statutory minimum compressive strengths of bricks for various walls and it was found that sandcrete blocks of 1∶5 mortar mixes with 40% RHA (by weight of cement) could be used in both load and non-load bearing walls.     

X-ray diffraction analysis of silicon prepared from rice husk ash

Polycrystalline silicon has been prepared by metallothermal reduction of rice husk ash, which contains a considerable amount of amorphous silica. Acid-leached rice husk was burnt at a temperature of 620° C to obtain rice husk ash (RHA). RHA was then reduced with magnesium and major impurities were minimized or removed by an acid leaching process. The end-product was analysed using X-ray diffraction and mass spectrometric techniques. It was found that the powdered silicon obtained from magnesium reduction of RHA had a very low impurity concentration indicating that rice husk, which is an agricultural waste, is a potential source of metallurgical and solar-grade silicon.     

Application of rice husk ash in brick aggregate concrete to improve the permeability and resistance against acid and sulfate attack

Brick-aggregate-concrete with a greater permeability is susceptible to decay at a faster rate under the action of acid and sulfate. This study tries to improve the durability of brick aggregate concrete by the addition of rice husk ash, which has been termed brick-ash concrete in this paper. The permeability and sorptivity of stone-aggregate-concrete, brick-aggregate concrete, and brick-ash concrete samples with different percentages of rice husk ash and different water-to-binder ratios were investigated. The concrete samples were also exposed to 1.5 % hydrochloric acid and 5 % sodium sulfate along with periodic drying and wetting cycle and periodic observations in terms of compressive strength, weight loss, and ultrasonic pulse velocity test for 360 days. 5 % to 10 % rice husk ash can significantly improve the permeability and resistance to the harsh environment of brick aggregate concrete. Additionally, this study also presents the equations to predict the actual strength from ultrasonic pulse velocity values for the brick ash concrete specimen exposed to acid and sulfate environments.     

Synthesis and surface characteristics of nanosilica produced from alkali-extracted rice husk ash

Rice husk is a form of agricultural biomass that provides an abundant silicon source. This study used rice husk as a raw material to prepare nanosilica without adding an extra surfactant. This work investigated a dissolution-precipitation technique as a function of acid treatment, sodium silicate concentration, gelation pH, aging temperature, and aging time to establish optimum conditions for preparing silica nanoparticles. Experimental results showed that silica produced by hydrochloric acid possesses higher surface area than that of sulfuric, oxalic, and citric acids. Surface characteristics of the sample depend mainly upon gelation pH. The highest surface area and pore volume of silica samples were 634 m²/g and 0.811 cm³/g. Pore diameters were controllable from 3 to 9 nm by adjusting the solution pH value. Particles had a uniform size of 5-30 nm. The objective of this study was to develop a method of nanosilica preparation that enhances the economic benefits of re-using rice husk waste.