基于容量比较法的卧式罐容量表计算方法研究

在卧式罐容量计量容量比较法原理的基础上,讨论了由有限的卧式罐离散(V-H)点计算出全高度量程范围内任意点的容积值的4种计算方法。并以30m³卧式罐为对象进行了试验研究。试验结果表明:Lagrange插值方法、分段线性插值方法、三次多项式拟合方法和三次样条插值方法在中间液位区间的计算结果较为一致;三次样条插值方法计算结果与试验值偏差最小,最大偏差值23.0L,而且稳定性较好;Lagrange插值方法、分段线性插值方法和三次多项式拟合方法在低液位高度或高液位高度的偏差比中间液位区间的计算偏差大;但是在低液位高度和高液位高度区间,由于多节点时边沿振荡原因,Lagrange插值方法的计算偏差大于三次样条插值方法。     

立式金属计量罐罐底变形原因及引起计量差量的分析与解决

<正>立式金属罐产生计量差量的原因很多,其中立式金属罐在工程项目设计和建设施工中产生罐底变形是计量差量的主要原因之一。本文就立式金属罐因地基基础及罐体建造过程中焊接方法、工艺过程的选择而造成罐底变形的问题加以分析并提出解决办法。     

立式金属罐罐底变形容量修正方法研究

通过建立立式金属罐的罐底有限元模型,提出罐底标高修正法和附件修正法,减少立式金属罐装油后罐底变形对容量计量的影响,提高贸易计量交接的准确性。对容量为5 000 m3的立式金属罐,分别采用容量比较法与几何测量法进行测量试验分析;通过采用罐底标高修正和附件修正两种方法对几何测量法的测量结果进行修正,并与容量比较法的结果进行比较,验证两种修正方法的可靠性。     

Improvements in the capacity of computer-generated holographic storage using the Lee method with sparse multivalued reconstructions

The use of sparse multivalued data encodings for the purpose of increasing the capacity of parallel-access optical memories based on Fourier-transform computer-generated holography is discussed. Results based on the Lee method indicate that a sparse encoding of nonbinary data words can be used to increase the storage-area utilization efficiency from 35% to > 70%. It is also found that for signal-to-noise ratios greater than 200, five-level data encoding can be used to achieve bit error rates less than 10(-12) reliably with 60% area efficiency.     

Influence of the synthesis method on electrical storage capacity of graphene-related materials

ABSTRACT

The electrochemical properties and their relationship with the physico-chemical properties of graphene-based materials have been studied. Graphite was used as the raw material and it was oxidised and then reduced by two alternative approaches, namely thermal and multi-step reduction using ascorbic acid. It was demonstrated that the physico-chemical characteristics of the material are directly related to the synthesis method and greatly influence the major capacitance of the material. It was observed that the materials with lower levels of functional oxygen groups and with a more ordered structure, i.e. similar to graphene powder, are the ideal candidates for use in electrochemical applications as these materials have better capacitance and specific capacitances.     

Influence of Sn and Mo on corrosion behavior of ferrite-pearlite steel in the simulated bottom plate environment of cargo oil tank

This work investigated the influence of Sn and Mo on corrosion behavior of ferrite-pearlite steel in the simulated bottom plate environment of cargo oil tank. The results indicate that the corrosion rate of three ferrite-pearlite steels increased with extending the immersion time due to the continuous accumulation of the residual Fe_3C. However, the addition of Sn or the combined addition of Sn and Mo could reduce the corrosion rate of Sn containing steel and Sn-Mo containing steel to 37.5% and 20% of that of carbon steel, respectively. Moreover, the cathodic reaction of Sn containing steel and Sn-Mo containing steel was always controlled by the charge transfer step during the whole immersion test, while that of carbon steel was gradually transformed into the diffusion-controlled process. These results were mainly related with the deposition of metallic Sn and Mo on the steel surface. The metallic Sn and Mo with uniform distribution restrained the galvanic effect through suppressing both the anodic dissolution of ferrite and cathodic hydrogen evolution reaction on the residual Fe_3C.     

基于附加质量法的大型固定顶储液罐基底隔震分析

鉴于目前储液罐基底隔震研究多采用一维简化的Haroun-Housner模型,基于附加质量法,考虑液体对流质量和脉冲质量,建立储液罐三维简化的附加质量模型。通过分析比较相同地震激励下不同高径比储液罐罐的Haroun-Housner模型、附加质量模型和流固耦合模型的动力响应,验证了附加质量模型的合理性。针对某大型固定顶储液罐,基于此简化模型,基底引入FPS隔震支座,系统地研究了基底隔震储液罐在不同场地条件下的非线性地震动力响应。分析结果表明:FPS隔震支座对储液罐地震响应有很好的控制作用,有效地降低了液体脉冲分量的运动,避免了罐壁发生屈曲破坏,但放大了液体对流分量的运动。     

Improving hydrogen storage capacity of MOF by functionalization of the organic linker with lithium atoms

A combination of quantum and classical calculations have been performed in order to investigate hydrogen storage in metal-organic frameworks (MOFs) modified by lithium alkoxide groups. Ab initio calculations showed that the interaction energies between the hydrogen molecules and this functional group are up to three times larger compared with unmodified MOF. This trend was verified by grand canonical Monte Carlo (GCMC) simulations in various thermodynamic conditions. The gravimetric capacity of the Li-modified MOFs reached the value of 10 wt % at 77 K and 100 bar, while our results are very promising at room temperature, too, with 4.5 wt %.