低碳低硅铝镇静钢的夹杂物控制工艺计算与分析

围绕低碳低硅铝镇静钢的可浇性问题,以大量的生产数据及现场实际生产状况为计算依据,对出钢终点[O]、夹杂物数量、精炼终渣渣量等进行了工艺计算分析。分析认为：在保证转炉出钢[C]小于0.05%的同时终点[O]控制在600×10-6～900×10-6较好,与之对应的精炼终渣渣量控制15 kg/t钢～18 kg/t钢为宜,渣中铝脱氧产物约合3.25 kg/t钢～3.88 kg/t钢;此时可将低碳低硅铝镇静钢的精炼终渣渣系控制在较佳的范围,渣中w（Al2O3）在18%～25%,碱度R（CaO/SiO2）在4.5～5.5,对脱除钢中夹杂物、控制钢水回硅、保证钢水可浇性意义重大。     

210 t RH精炼参数对IF钢洁净度的影响和工艺优化

基于IF钢（/%:≤0.0025C,≤0.005Si,0.01～0.12Mn,≤0.020P,≤0.010S,0.02～0.04Als,0.03～0.05Ti）冶炼过程工艺数据的统计,分析了Ar站钢水氧含量和RH脱碳期加铝量对钢中T[O]的影响,以及合金加入时机,顶渣改质处理和连铸保护浇铸对钢水洁净度的影响。研究结果表明,适当提高转炉终点氧含量和温度、延长加铝和钛铁之间的时间间隔、顶渣改质处理、连铸保护浇铸等方法可有效提高钢水洁净度。生产结果得出,通过RH进站钢水温度平均提高2.4℃,通过控制转炉下渣量,使顶渣厚度由≥80 mm降至60～75 mm,使RH脱碳过程加铝炉次由原36%降至3%,通过顶渣改质,使（FeO+MnO）由原22%降至17%,连浇炉数由8炉提高到10炉,连铸中间包T[O]由37.4×10^-6降低至21.6×10^-6,钢水洁净度得到了显著提高。     

LF处理过程中钢水增铝问题的研究

硅镇静钢及少量铝脱氧的钢在LF处理过程中会发生钢水中铝含量增加以及夹杂物组成改变的现象.通过理论计算和工业生产实践研究了不同的渣系、钢水成分、处理时间等对LF精炼过程增铝的影响,不同精炼渣系下钢中夹杂的组成,结果表明采用CaO-SiO2渣系LF处理过程几乎不发生增铝现象,而采用CaO-Al2O3渣系随着处理时间的延长以及钢种成分的区别,钢中铝有不同程度的增加,生产实践结果与理论计算趋势基本一致.采用CaO-Al2O3渣系精炼与CaO-SiO2渣系相比,钢中Al2O3夹杂数增加4倍,氧化物复合夹杂中w(Al2O3)提高113%,w(CaO)提高24.5%.在帘线钢72A以及HRB400、SS400钢的生产实践中加以应用,使得LF处理后72A的w(Al)小于0.000 5%,HRB400、SS400的小于0.003%,避免了有害夹杂物的形成,消除了在小方坯连铸过程中的水口堵塞现象.     

50 t EAF EBT-60 t LF工艺冶炼GCr15钢的氮含量控制

研究了西宁特钢50 t EAF EBT-60 t LF冶炼GCr15高碳铬轴承钢时电弧炉泡沫渣操作、钢包炉(LF)吹氩精炼和成分微调、浇铸等工艺因素对钢中氮含量的影响.研究结果表明,电弧炉良好的泡沫渣操作,钢水脱碳量ΔC大于0.6%可使钢中氮含量降到(10～20)×10-6.在LF精炼时50 t钢水加200 kg碳粉可使钢水氮含量增加19×10-6,加合金可使钢水中平均氮含量增加4.2×10-6,浇铸过程钢水氮含量增加12×10-6.因此在LF精炼时减小碳和合金加入量可减少钢中氮含量的增加.     

转炉-LF和铁水预处理-转炉-钢包吹氩对耐候钢冶金质量的影响

进行了60 t转炉(钢水温度1653℃)-LF精炼(渣碱度2.5～3.0、喂Al线、吹氩)和铁水预处理([S]≤0.010%)-60 t转炉(钢水温度1670℃,出钢过程加80～100 kg精炼渣)-钢包喂A1线、吹氩≥8 min两种工艺冶炼耐候钢SPA-H(%:≤0.12C、0.30～1.25Cr、0.25～0.55Cu)的试验。62炉生产结果表明,有LF精炼炉次吹氩前[O]37.7×10^-6,喂丝量25 kg,平均[S]0.014%,无LF精炼吹氩前[O]53.3×10^-6,喂丝量33.9 kg,平均[S]0.017%,两种工艺生产的耐候钢力学性能和夹杂物级别均达到要求,但无LF工艺有利于提高生产率,降低物料消耗。     

SPHC钢的冶炼实践

介绍了迁安轧一钢铁集团炼钢厂生产低碳低硅铝镇静钢SPHC的生产实践。通过优化生产工艺,控制转炉出钢过程中下渣量,保护浇铸,LF炉精炼等措施,使钢水成分得到精确控制,钢中夹杂物大量减少,钢水的可浇性提高,铸坯表面及内部质量均达到了标准要求,满足了用户需求。     

Theoretical calculation for aluminum pick-up of high carbon steel in LF refining process and study on tundish nozzle clogging

以热力学计算为基础,探讨了唐山钢铁集团有限责任公司硬线钢LF精炼过程中,钢水中Si、C与精炼渣中的A12O3反应导致钢水增铝的可能性;通过理论计算分析LF精炼工艺参数对钢水平衡含铝量的影响,确定了最佳的LF精炼工艺。并结合文献分析了唐钢硬线钢小方坯连铸中间包水口结瘤原因。通过理论计算得出：目前硬线钢LF精炼工艺,满足钢水可浇性的要求;高牌号硬线钢LF精炼工艺采用精炼渣碱度R≤1．0,精炼渣中的叫（Al2O3）≤5％,精炼温度t〈1600℃,同时严格控制原材料的含铝量,LF精炼过程中钢水平衡讪（A1s）〈3．5×10-6。     

薄板坯连铸SPHC钢硅质量分数控制

为了解决低碳低硅铝镇静钢精炼过程中的增硅问题,结合马鞍山钢铁股份有限公司CSP流程SPHC钢生产过程,分析了转炉下渣量、连铸热态铸余回渣量、钢中Als质量分数、精炼炉渣成分和精炼处理时间对钢水中硅质量分数增加的影响。严格控制转炉下渣量不超过3.0 kg/t、适当减少热态铸余回渣量和钢中Als质量分数、适当调整精炼渣系成分、提高炉渣碱度和合理缩短LF炉精炼处理时间,均可不同程度地减少精炼处理过程中钢水增硅,有利于将钢水中硅质量分数控制在较低水平,满足后续加工需求。     

超低硫钢冶炼工艺实践

中厚板卷厂采用铁水预处理→BOF→精炼(LF/RH)→CCM生产流程,通过铁水预处理脱硫扒渣,转炉出钢铝块深脱氧和复合精炼渣顶渣改质,LF精炼炉铝丝渣脱氧、石灰造渣以及喂铝线微调钢水中铝,结合LF炉冶炼过程全程合理的氩气底吹控制,充分发挥脱硫的冶金热力学和动力学条件,把扩散脱氧和沉淀脱氧进行有机结合,已能批量生产[S]≤10 ppm低硫钢,铸坯质量良好,钢板探伤合格率控制在99%以上,完全满足生产需要。     

改善钢水可浇性的生产实践

针对承钢LF炉因钢水可浇性差造成生产中断的问题,分析了水口堵塞物的化学成分、形成原因。通过采取加强转炉出钢操作、测量渣层厚度和定氧、优化精炼渣成分、控制铝钙比等措施,钢水的可浇性明显改善,钢中的夹杂物数量和形态得到有效控制。     

China's Major Non-ferrous Metals Imports & Exports

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Zinc Production by Province in 2014

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80% of Chinese Firms Purchasing Overseas Mines Ended up in the Red

<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic     

Copper Processing Profit Dropped Sharply,Copper Consumption Will Face Impact in the Second Half of the Year

正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field,     

Central Geological Prospecting Fund Newly Added 16.47 Million Tonnes of Bauxite in 2013

正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF     

Manufacturers of Copper Tube for Central Air Conditioner Use Face Mounting Pressure in the Final Quarter of the Year

正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure     

Xinjiang Ranks No.1 in Production of Primary Aluminum in China

正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year,     

Shenhuo Coal Industry and Electricity Power Completed800,000 t/a Aluminum Project in Xinjiang

正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform.     

Guangdong Metal Transaction Center has Become the Second Largest Precious Metal Transaction Platform Nationwide

正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness.     

Seven Rare Earth Projects Involving Close to 3 Billion Yuan Investment Landed In the HighTech Zone

正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully.