共查询到20条相似文献,搜索用时 464 毫秒
1.
在相转移催化剂四丁基碘化铵的作用下.溴代乙酰基葡萄糖与取代苯甲酸反应合成了6个取代苯甲酸葡萄糖酯.所合成的糖酯的结构经IR、^1HNMR、元素分析确证。通过对糖酯化合物的^1HNMR图谱中糖环C1位质子的化学位移及偶合常数.并结合红外图谱中糖环C1H的弯曲振动吸收,确证糖酯化合物均为β型异构体。 相似文献
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介绍了C9石油树脂的原料组成及C9石油树脂合成机理。对C9石油树脂的合成工艺进行了介绍,阐述了合成工艺的选择原则并对几种C9石油树脂的合成工艺进行了比较分析。重点介绍了C9石油树脂合成工艺的发展状况,指出了C9石油树脂加氢技术研发要解决的关键技术及发展方向。 相似文献
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介绍了C306型甲醇合成催化剂在大庆油田甲醇厂的实际应用情况。阐述了C306型催化剂的特点,总结了C306型催化剂在生产操作及管理中的使用经验。 相似文献
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Toraj Mohammadi Hojjatollah Maghsoodloorad 《International Journal of Applied Ceramic Technology》2013,10(2):365-375
In this article, effects of synthesis parameters (synthesis temperature, synthesis time, and number of layers) on W‐type zeolite membranes synthesized over flat SUS supports for O2/SF6 gas separation were experimentally investigated. Experiments were carried out at these levels of synthesis temperature: 165°C, 185°C, and 200°C; synthesis time: 6, 12, and 18 h and number of layers: 1 and 2. Permeation measurements, XRD and SEM analysis were used for characterization of the synthesized membranes. The results showed that increasing synthesis temperature from 165°C up to 185°C increases separation factor of O2/SF6, however, further increasing decreases the separation performance. The same trend was observed for synthesis time for the single layer synthesized zeolite W membrane, although for the double layer synthesized zeolite W membrane, separation factor increased with increasing synthesis time. Repetition of layering has a net positive effect on separation factor of O2/SF6, and negative effect on permeation flux through the membranes. This behavior was attributed to the dual effect of synthesis temperature and synthesis time on selectivity. More zeolite crystals are deposited and larger crystals are formed at higher synthesis temperatures and longer synthesis times. Well W‐type zeolite membrane was synthesized at 185°C for 18 h with two repeating layers with a high separation factor of 20.1. 相似文献
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丙烯酸高级酯的微波合成与结构表征 总被引:1,自引:0,他引:1
以丙烯酸、十二醇、十四醇、十六醇、十八醇为原料,采用微波辅助合成技术分别制备了丙烯酸十二酯、丙烯酸十四酯、丙烯酸十六酯和丙烯酸十八酯。考察了微波功率、辐射时间和原料配比等反应条件对不同长链酯酯化产率的影响,并对它们的物理性质、元素组成和分子结构进行了测定与表征。结果表明,微波辅助合成技术能高效、快速地合成丙烯酸高级酯,但各高级酯的最佳微波酯化条件明显不相同,随着高级酯碳链的增长,微波功率、辐射时间和酸醇摩尔比增大,在优化的微波合成条件下,反应速率可提高20倍以上,酯产率≥96%,且所得产物的物理性质、分子结构与传统方法加热制备的产物无明显差异。 相似文献
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Silicalite nanocrystals were synthesized in a pressurized capillary microreactor at 150 °C within 11 min with synthesis solutions aged at 80 or 100 °C for 1–6 h. The effects of aging of the synthesis solution and the reaction pressure were examined. The resulting products were characterized by XRD, DLS, TEM, FT‐IR and TG‐DSC. Aging of the synthesis solution played an important role in shortening the crystallization time of the silicalites. The synthesis pressure should be higher than the saturation vapor pressure of water at 150 °C (~0.5 MPa) and silicalite nanocrystals with crystallinities of 70 % and 100 % could be produced from the synthesis solution aged at 100 °C for 2 h with residence times of 11 min at 0.7 MPa and 1 MPa, respectively. The mean particle sizes of these two samples were 102.2 nm and 166.4 nm, respectively. Thus, the crystallization time of the silicalite nanocrystals is shown to be significantly reduced in the capillary microreactor compared to a traditional batch system. 相似文献
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Saudan LA 《Accounts of chemical research》2007,40(12):1309-1319
Homogeneous catalytic hydrogenation has played an important role in the development of modern organic synthesis. Indeed, the discovery of highly regio- and stereoselective catalysts for C=C and C=O bonds reductions has allowed the efficient synthesis of optically active compounds. As the fragrance industry has turned to synthetic ingredients to fulfill the need for novel, cost-effective, and environment-friendly products, the use of catalytic processes are more and more in demand. In this Account, we thus highlight the application of catalytic hydrogenation in the synthesis of fragrance ingredients. 相似文献
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一碳化工产品及其发展方向 总被引:11,自引:4,他引:11
一碳化工是替代石油合成路线制备基本有机化工原料、燃料和其他重要化学品的最重要的最有发展前景的途径.本文综合讨论了以含一个碳原子化合物为原料合成化学品和新材料的国内外研究与开发的进展,包括已工业化的技术.同时也对一碳化工产品发展方向和与一碳化合物相关的能源技术产品、环境保护技术产品及低品位一碳化合物资源化技术作了较全面的分析. 相似文献
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Two products derived from rat renal tissue have been shown to affect in vitro hepatic cholesterol synthesis. A premevalonate
inhibitor of hepatic cholesterol synthesis is associated with the membranes of the renal endoplasmic reticulum. It is stable
at −75 C and at 4 C but is heat labile. A pre-mevalonate stimulator of in vitro hepatic cholesterol synthesis is located within
renal lysosomes and can be prepared in a nonsedimentable form by extraction with hypotonic buffer. While it is stable at −75
C, it loses activity at 4 C. Both of these products appear to have a molecular weight in excess of 150,000 as determined by
gel filtration.
Deceased. 相似文献
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C—N键的构建反应对于药物开发,天然产物合成,以及含氮化合物的代谢等都具有重要意义。本文结合作者的研究,主要介绍基于2-溴芳基烷基酮的C—N键构建反应及其在药物合成中的应用。 相似文献
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Biyun Fang Chuanfeng Zhang Miaodi Yang Jiahui Li Chunyan Li Jun Ni Jianxin Lin Bingyu Lin Lilong Jiang 《American Institute of Chemical Engineers》2023,69(10):e18163
Development of the cost-effective catalysts with excellent catalytic performance is highly demanded for ammonia synthesis, and the strong adsorption of ammonia greatly hinders the design of cost-effective and high-performance ammonia synthesis catalysts. Herein, we report that the addition of a small amount of Co species (0.1 wt%) into Mo2C catalyst, which can provide electrons to Mo2C, not only leads to improvement of the adsorption and migration of hydrogen, but also facilitates the adsorption and desorption of ammonia. Consequently, Mo2C catalyst with 0.1 wt%Co offers a 40% higher ammonia synthesis activity and a lower negative reaction order with respect to NH3 in comparison to Mo2C. This work stresses the importance of the minor components in improving the ammonia synthesis activity by accelerating the migration of reactants over the catalyst surface and the escape of products from the catalyst. 相似文献