共查询到19条相似文献,搜索用时 93 毫秒
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异丙醇钇[Y(OC3H7)3]合成的研究 总被引:4,自引:0,他引:4
本文采用I2及HgCl2为催化剂,用金属钇和异丙醇直接反应合成了异丙醇钇,产率可达83%以上, 而反应时间只需5个小时左右,超过已有文献的报道。 相似文献
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锦州石化历时3年时间自主开发10万t级异丙醇工艺包,终于在2007年11月,确定了异丙醇合成工艺条件,一举解决了长期以来异丙醇生产高能耗的问题,实现装置节能49%,异丙醇单程产率提高10%,物耗下降5%,大大提高了异丙醇产品的盈利能力。[编者按] 相似文献
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Synthesis of Yttrium Aluminum Garnet by the Glycothermal Method 总被引:9,自引:0,他引:9
Masashi Inoue Hiroyuki Otsu Hiroshi Kominami Tomoyuki Inui 《Journal of the American Ceramic Society》1991,74(6):1452-1454
The reaction of a stoichiometric mixture of aluminum isopropoxide and yttrium acetate in 1,4-butanediol at 300°C yielded crystalline yttrium aluminum garnet having an approximate particle size of 30 nm. No other phases were detected. The use of ethylene glycol in place of 1,4-butanediol afforded an amorphous product. 相似文献
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Frank Lauterwasser Paul G. Hayes Warren E. Piers Laurel L. Schafer Stefan Brse 《Advanced Synthesis \u0026amp; Catalysis》2011,353(8):1384-1390
The intramolecular hydroamination of aminoalkynes and unactivated aminoalkenes catalyzed by yttrium N,O‐ and N,N‐complexes has been investigated. The N,N‐yttrium complexes are highly active, catalyzing the conversion of a wide range of terminal aminoalkenes at room temperature, and internal aminoalkenes at elevated temperature, to yield pyrrolidine and piperidine products in high yields. A high diastereoselectivity of up to 23:1 is observed at 0 °C with 1‐methyl‐4‐pentenylamine as substrate. 相似文献
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以Y2O3、Y(C2H3O2)3和Bi2O3为原料,采用高温固相反应合成铋酸钇(YBiO3)。借助热重-差热、X射线衍射、SEM等分析手段,探讨了不同原料、煅烧温度、保温时间、预烧等因素对铋酸钇合成的影响。结果表明:高温固相反应能够合成高纯度的铋酸钇;与Y(C2H3O2)3相比,Y2O3是合成YBiO3的较佳原料,其合成YBiO3的最低温度是766℃左右,YBiO3的开始分解温度是917℃左右;合成YBiO3的较佳工艺为两磨两烧,在800℃预烧90min,其较佳工艺参数为煅烧温度为900℃,保温时间120min。 相似文献
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We have conducted classical molecular dynamics simulations of three compositions of yttrium-containing phosphate glasses, to study the atomic structure around yttrium, and understand how yttrium incorporation will affect the glass dissolution rate. The Y-O bond length is about 2.2 Å and the coordination number is 6.3. To avoid effects due to different network connectivities, our compositions were chosen to keep the Qn distribution and network connectivity roughly constant, which was confirmed through direct calculation. For these compositions, the structure of the phosphate network is comprised of finite-length chains of PO4 tetrahedra bound to the network modifiers. We showed that yttrium bonds to 4.2-4.3 of these chains, compared to 3.8 for calcium, and 3.1-3.2 for sodium. This implies that yttrium will bond more parts of the glass to the same place, and therefore, that yttrium incorporation will strengthen phosphate glass against dissolution, making it potentially suitable for radiotherapy applications where a durable glass is required. 相似文献
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综述了氧化钇纳米粉体的应用及研究现状,着重介绍了共沉淀法、喷雾热解法、溶胶一凝胶法以及近几年开发的高分子网络凝胶法等7种制备氧化钇粉体的方法。 相似文献
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Optical and Scintillation Properties of Ce3+‐Doped LuAG and YAG Transparent Ceramics: A Comparative Study
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Jiang Li Sunil Sahi Michael Groza Yubai Pan Arnold Burger Rasool Kenarangui Wei Chen 《Journal of the American Ceramic Society》2017,100(1):150-156
Cerium‐doped lutetium aluminum garnet (LuAG:Ce) and yttrium aluminum garnet (YAG:Ce) transparent ceramics of same dimension were fabricated and their optical and scintillation properties were studied. LuAG:Ce transparent ceramic showed higher light yield under UV and X‐ray excitation with respect to YAG:Ce transparent ceramic. YAG:Ce transparent ceramic showed higher light yield under gamma excitation and better energy resolution, which could be due to the considerable amount of slower emission (38.5%) in LuAG:Ce as well as lower optical transparency with respect to YAG:Ce ceramic. 相似文献
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微乳液法制备纳米球形YAG:Ce3+荧光粉及其发光性能 总被引:2,自引:1,他引:1
采用反相微乳液法,以水/曲拉通X-100/正己醇/(环己烷 正己烷)为微乳体系,铝(Al)、钇(Y)和(Ce)的硝酸盐和氯化物作为起始反应物,氨水作为沉淀剂,成功制备了纳米球形铈掺杂钇铝石榴石(cerium doped yttrium aluminum garnet,YAG:Ce3 )荧光粉.实验表明:单相YAG可以在800℃合成,比周相反应法合成温度(1 500℃)大幅度降低.用失重-差热分析仪、Fourier变换红外光谱仪、X射线衍射仪、透射电镜、荧光分光光度计等对粉体特性进行了表征.结果表明:粉体颗粒粒径约为50nm,粒度分布均匀,球形度好,分散性好,粉体的激发光谱为双峰结构,主激发波长为469nm,发射波长为532nm,适用于白光发光二极管. 相似文献