Influence of ethanol-diesel blended fuels on diesel exhaust emissions and mutagenic and genotoxic activities of particulate extracts

This study was aimed at evaluating the influence of ethanol addition on diesel exhaust emissions and the toxicity of particulate extracts. The experiments were conducted on a heavy-duty diesel engine and five fuels were used, namely: E0 (base diesel fuel), E5 (5%), E10 (10%), E15 (15%) and E20 (20%), respectively. The regulated emissions (THC, CO, NOx, PM) and polycyclic aromatic hydrocarbon (PAH) emissions were measured, and Ames test and Comet assay, respectively, were used to investigate the mutagenicity and genotoxicity of particulate extracts. From the point of exhaust emissions, the introduction of ethanol to diesel fuel could result in higher brake specific THC (BSTHC) and CO (BSCO) emissions and lower smoke emissions, while the effects on the brake specific NOx (BSNOx) and particulate matters (BSPM) were not obvious. The PAH emissions showed an increasing trend with a growth of ethanol content in the ethanol-diesel blends. As to the biotoxicity, E20 always had the highest brake specific revertants (BSR) in both TA98 and TA100 with or without metabolizing enzymes (S9), while the lowest BSR were found in E5 except that of TA98-S9. DNA damage data showed a lower genotoxic potency of E10 and E15 as a whole.     

Study on the effect of exhaust gas-based fuel preheating device on ethanol–diesel blends operation in a compression ignition engine

Rapid depletion of fossil fuels and stringent emission regulations compel the scientific community to search for alternative energy sources for the internal combustion engines. Among many alternative biofuels, ethanol is getting worldwide attention for compression ignition engine either in the form of partial substitute or complete replacement for diesel fuel. Ethanol fuel has certain undesirable properties like poor flammability limit which results in cold starting issues and higher hydrocarbon emission which restricts their use in compression ignition engine. This issue can be easily overcome by preheating of ethanol fuel before it gets admitted inside the engine cylinder. In the present study, a standard preheating device is designed and fabricated in accordance with engine specifications and simulations were carried out under various operating conditions to evaluate its performance. Furthermore, experimental investigations were carried out in a compression ignition engine fueled with ethanol blends of 20 and 30% with diesel by volume and the fuel blends were preheated using burned exhaust gases. In addition, a comparative study has been carried out for preheated and non-preheated blends of E20 (20% of ethanol and 80% of diesel) and E30 with baseline diesel. The experimental results show that the preheated E20 (20% of ethanol and 80% of diesel) blend has higher brake thermal efficiency of 36.28% with a significant reduction in brake specific fuel consumption when compared with all the other blends. Moreover, the preheated E20 blend reduces the carbon monoxide, unburned hydrocarbon and smoke emissions by 49, 48 and 10%, respectively. However, the NOx emission is increased by 6% as compared to the non-preheating effect. It is also noted that the preheating of ethanol blends produced better combustion results with a significant reduction in the ignition delay period. Hence, it can be concluded that the ethanol fuel can be effectively used in a diesel engine by means of preheating using exhaust gases and could be a viable option for diesel engine applications.     

Test run evaluation of a blend of fuel-grade ethanol and regular commercial gasoline: its effect on engine efficiency and exhaust gas composition

The purpose of this study is to evaluate the performance of a nationally manufactured vehicle on a test run with a blend of fuel-grade ethanol and commercial regular gasoline. The results showed that, when 10% ethanol was added to the gasoline, general engine performance was 5–10% higher, which was due to the increase in octane number of the mixture. Nevertheless, according to the lower heat value of the mixture, fuel consumption was approximately 5% higher than the regular gasoline. Carbon monoxide (CO) and hydrocarbon (HC) emissions were dramatically lower because, when ethanol (an oxygenate) was added to the fuel, it had an influence on combustion reaction improvement. On the other hand, nitrogen oxides (NOx) emissions increased due to the higher temperature in the combustion chamber.     

A comparison of the emissions of gasoline–ethanol fuel and compressed natural gas fuel used in vehicles with spark ignition engine in Rio de Janeiro: Brazil

Clean Technologies and Environmental Policy - A comparison of the emissions of gasoline–ethanol fuel and compressed natural gas (CNG) fuel used in vehicles with spark ignition engine was...     

GB 17930-2016与GB 18351-2015标准异同及影响

GB 17930-2016包含国Ⅳ(已废止)、国V和Ⅵ的车用汽油技术要求和试验方法,GB18351-2015包含国Ⅳ(已废止)、国V的车用乙醇汽油(E10)技术要求和试验方法;2个标准(现行有效的技术要求)均按研究法辛烷值分为89号、92号、95号和98号4个牌号,都强调企业有条件生产和销售98号汽油时应符合对应规定的技术要求;GB17930-2016中的国Ⅵ10%馏出温度、苯、芳烃、烯烃等项目质量指标高于GB18351-2015中国V对应项目的质量指标.车用乙醇汽油(E10)燃烧比普通汽油更完全,可降低尾气中的污染物排放.     

Emission reduction on ethanol–gasoline blend using cerium oxide nanoparticles as fuel additive

In this study, the effect of ethanol–gasoline blend with cerium oxide nanoparticles as additive on a Tata Nano twin–cylinder SI engine was investigated. In this work, the combustion, performance and emission tests were conducted. The experiment fuels were prepared using 99.9% pure ethanol and gasoline with cerium oxide nanoparticles. The volumetric percentages of ethanol–gasoline blends with cerium oxide nanoparticles additive are in the ratio of E30, E40 and E50. These represent the ratios of ethanol amount in the total blend and the rest of gasoline. Additionally, 100?mg, 150?mg and 200?mg cerium oxide nanoparticles additive are mixed to E30, E40 and E50, respectively. The venture of this investigation was to reformulate the fuel to utilize the cerium oxide nanoparticles with ethanol and gasoline blend to develop the fuel’s performance and to decrease the pollution from the engine. The experimental results expose an increase in brake thermal efficiency for the nanoparticles blends. In the emission test CO, CO₂, HC and NOx are noticeably reduced, and O₂ increased for all the blends. In combustion analyses, the cylinder pressure is higher for nanoparticles blends, when compared to that of the sole fuel.     

微乳化乙醇柴油热物性计算与分析

车用清洁型微乳化油是内燃机的理想代用燃料之一．微乳化油热物性参数难以计算,从而影响在内燃机上对它的定量计算研究．以微乳化乙醇柴油为例,用经验公式计算其蒸发焓、生成焓、液体比热容、导热率和微乳化油蒸气的扩散系数,分析了温度和压力以及不同溶醇量对热物性参数的影响规律,为微乳化油热物性参数的计算提供一种工程方法．结果表明：随着温度的增加,微乳化乙醇柴油蒸发焓、导热率降低,定压比热容和微乳化油蒸气扩散系数增加;随着压力增加,微乳化油蒸气扩散系数降低;随着混合燃料中乙醇含量的增加,定压比热容和混合气扩散系数均增大,蒸发焓减小;乙醇含量对混合燃料导热率的影响与燃料温度有关,在一定温度下乙醇含量效应发生逆转;微乳化乙醇柴油中乙醇含量增加有利于燃料蒸发．     

Compatibility study of high density polyethylene with bioethanol–gasoline blends

In order to evaluate the compatibility of high density polyethylene (HDPE) in E5 (5% v/v bioethanol, 95% v/v gasoline) and E10 (10% v/v bioethanol, 90% v/v gasoline), immersion tests have been performed in fuel blends at 45 °C during 2000 h. Different mechanical and physical–chemical properties of HDPE have been assessed before and after the execution of these tests.     

The performance analysis and design optimization of fuel temperature control for the injection combustion engine

The purpose of the paper is to analyze the performance and design optimization of fuel temperature control in the injection combustion engine. There is a fuel temperature control device designed between the injection and fuel pump to cool down or warm up the fuel. Thermoelectric module (TEC) chips are applied in the device to absorb or dissipate heat from the fuel. There are several results relating exhaust emission and engine output performance to fuel temperature in this paper to display the optimization of fuel temperature for the injection engine. The experimental results indicate that increasing fuel temperature will result in an increase in CO, HC, and in a decrease in NO_x. Increasing the fuel temperature may affect the fuel consumption and engine output for a gasoline engine at different A/F (air to fuel) ratios. With enhanced understanding and analyses, the effects of fuel temperature on engine performance, fuel consumption and emissions can be taken into account in engine design and evaluation.     

Investigation of Deposit Formation Mechanisms for Engine In-cylinder Combustion and Exhaust Systems Using Quantitative Analysis and Sustainability Study

The formation of SI engine combustion deposits is a complex phenomenon which depends on various factors of fuel, oil, additives, and engine. The goal of this study is to examine the effects of operating conditions, gasoline, lubricating oil, and additives on deposit formation. Both an experimental investigation and theoretical analysis are conducted on a single cylinder engine. As a result, the impact of deposits on engine performance and exhaust emissions (HC, NO _x ) has been indicated. Using samples from a cylinder head and exhaust pipe as well as switching gases via the dual-gas method (N₂, O₂), the deposit formation mechanism is thoroughly investigated via the thermogravity analysis approach, where the roles of organic, inorganic, and volatile components of fuel, additives, and oil on deposit formation are identified from thermogravity curves. Sustainable feedback control design is then proposed for potential emission control and performance optimization     

汽油清净剂的研究进展

清净剂是现代清洁汽油重要组成部分，文中基于大量研究文献，报道了国外基于聚异丁烯、聚氧烯烃醚、聚内酯与胺合成的大分子清净剂的研究进展。     

The operation of a turbulence chamber diesel engine with LPG fumigation for exhaust emissions control

An experimental study is conducted to evaluate the use of liquefied petroleum gas (LPG) as a secondary fuel for a Ricardo E-6, naturally aspirated, four-stroke diesel engine having a turbulence combustion chamber (indirect injection). The gaseous LPG is introduced together with the aspirated air (fumigation) at various proportions with respect to the diesel fuel which constitutes the main part. The influence of fuel feed ratios (LPG/diesel), in a vast range of loads, on fuel consumption, pressure diagrams, exhaust smokiness and exhaust gas emissions (nitrogen oxides, hydrocarbons and carbon monoxide) is investigated, the baseline being the single diesel fuel operation. The study for this type of engine, which has not being reported in the literature, shows a promise of the present method and reveals that above 60 per cent of maximum load the whole effect is beneficial concerning specific fuel consumption and smoke reduction. The examination of gaseous pollutant levels shows an involved relation with respect to load and fuel proportions. The best results (coupled to acceptable cylinder pressure levels) is obtained at a diesel fuel substitution value of 75% of maximum load, with an LPG mass fraction in the range 10 to 15%.     

Effect of oxy-hydrogen blending with gasoline on vehicle performance parameters and optimization using response surface methodology

ABSTRACT

Rapid decline in fossil fuel reservoirs has attracted researchers to use a variety of fuel blends in Spark ignition (SI) and Compression ignition (CI) engines demonstrating similar performance and lower emissions. Oxy-hydrogen gas obtained through electrolysis has been successfully tested for this use. This paper presents a two wheeler chassis dynamometer based study of a two wheeler loaded with newly developed single cylinder variable compression ratio (VCR) engine utilizing different blends of gasoline and oxy-hydrogen gas. Variation in fuel average performance (FAP), wheel power (WP) and acceleration performance (AP) due to oxy-hydrogen blending with gasoline is studied and compared with neat gasoline at five different gears. Further multi objective optimization of FAP and WP is carried out using response surface methodology (RSM). Regression models are postulated for predicting FAP and WP at different levels of compression ratio (CR) and oxy-hydrogen gasoline blends. Interaction between CR and oxy-hydrogen-gasoline blending is also studied and discussed. Modification carried out on an engine improves vehicle performance parameters and oxy-hydrogen gasoline blending further enhances the improvements. Maximum FAP and WP in top gear is obtained at highest CR of 11.57:1 and a oxy-hydrogen gasoline blend with 112.558 ml/min flow rate of oxy-hydrogen gas.     

Particle size distribution of polycyclic aromatic hydrocarbons in motorcycle exhaust emissions

The size distribution of polycyclic aromatic hydrocarbons (PAHs) in emission of a two-stroke carburetor motorcycle was studied. The exhaust gas from the test motorcycle was passed to a dilution tunnel and collected using a 10 cascade micro-orifice uniform deposit impactor (MOUDI) of 0.056-10 microm aerodynamic diameter fitted with aluminum substrates. All MOUDI substrates were analyzed for particulate mass and for PAHs by GC/MS. Most of the 21 analyzed PAHs have two significant modes that peak at <0.1 and 0.18-0.32 microm. For some PAHs, a third peak appears around 1.8 microm. MOUDI impactor samples show that 88.9% particulate and 89.6% PAH mass distributed smaller than 2.5 microm. Mass median diameters of PAHs are about 0.2 microm. Total benzo[a]pyrene toxic equivalency emission factor was 440+/-13.8 ng/km for the test motorcycle. An average of 90.3% of carcinogenicity is observed in particulate smaller than 1.0 microm. The results suggest that submicron particulates predominate in the exhaust from motorcycle and exhibit high carcinogenic potency for these particulate.     

天然气发动机电控喷射系统研制

天然气发动机具有低排放、使用经济性好等特点,在汽车上得到了广泛的应用,对天然气发动机电控喷射系统的研制也越来越受到重视。为将YF465Q汽油发动机改装成天然气单燃料发动机,对其电控喷射系统进行了深入研究。通过AMESim/Simulink建模仿真、硬件电路设计、软件编制,完成了电控喷射系统研制。硬件在环仿真试验结果显示,所设计的电控喷射系统能够满足应用的要求。     

Comprehensive two-dimensional gas chromatography and chemometrics for the high-speed quantitative analysis of aromatic isomers in a jet fuel using the standard addition method and an objective retention time alignment algorithm

A high-speed quantitative analysis of aromatic isomers in a jet fuel sample is performed using comprehensive two-dimensional gas chromatography (GC x GC) and chemometrics. A GC x GC separation time of 2.8 min is achieved for three aromatic isomers in jet fuel, which is 5 times faster than a reference method in which a singlecolumn separation resolves two of the three isomers of interest. The high-speed GC x GC separation is more than 10 times faster than a recent GC x GC separation that fully resolves the three components of interest in gasoline. The high-speed GC x GC analysis of jet fuel is accomplished through short GC columns, high gas velocities, and partial chromatographic peak resolution followed by chemometric resolution of overlapped peaks. The standard addition method and an objective retention time alignment algorithm are used to correct for retention time variations prior to the chemometric data analysis. The standard addition method corrects for chemical matrix effects that cause analytes in complex samples to have peak shapes, widths, and retention times that differ considerably from those of calibration standards in pure solvents. The retention time alignment algorithm corrects for the relatively small retention time variations caused by fluctuating instrumental parameters such as flow rate and temperature. The use of data point interpolation in the retention time alignment algorithm results in a more accurate retention time correction then previously achieved. The generalized rank annihilation method (GRAM) is the chemometric technique used to resolve the overlapped GC x GC peaks. The correction of retention time variations allows for successful GRAM signal deconvolution. Using the retention time alignment algorithm, GRAM quantification accuracy and precision are improved by a factor of 4. The methodology used in this paper should be applicable to other comprehensive separation methods, such as two-dimensional liquid chromatography, liquid chromatography coupled with capillary electrophoresis, and liquid chromatography coupled with gas chromatography.     

Experimental investigation of doped mwcnts on biodiesel for enhancement of the performance and exhaust emissions in a diesel engine

This article deals with an experimental work that aims to examine the effects of MWCNTs dispersed into diesel fuels. Nano diesel fuels were prepared by dispersing multi-walled carbon nanotubes into base liquid. The MWCNT nanomaterial was mixed in the fuel blend along with a surfactant by means of an ultrasonicator, to attain stable dispersion. Physicochemical properties of nano-additive based diesel were measured and compared with pure diesel fuel. Physicochemical properties of nano-additive based diesel were measured and compared with pure diesel fuel. An experimental investigation was performed at a constant speed of 1500 revolution per minutes at different engine load conditions. The engine performance and exhaust emissions of a diesel engine burning MWCNTs were compared with pure diesel fuel. MWCNTs to diesel oil is effectively enhancing the performance and decreasing exhaust emissions in a diesel engine. The properties of N80?+?JB20 with MWCNT fuel blend are changed owing to the mixing of biodiesel and the combination of the MWCNT nanomaterials.     

Effect of EGR on the exhaust gas temperature and exhaust opacity in compression ignition engines

In diesel engines, NOx formation is a highly temperature-dependent phenomenon and takes place when the temperature in the combustion chamber exceeds 2000 K. Therefore, in order to reduce NOx emissions in the exhaust, it is necessary to keep peak combustion temperatures under control. One simple way of reducing the NOx emission of a diesel engine is by late injection of fuel into the combustion chamber. This technique is effective but increases fuel consumption by 10–15%, which necessitates the use of more effective NOx reduction techniques like exhaust gas recirculation (EGR). Re-circulating part of the exhaust gas helps in reducing NOx, but appreciable paniculate emissions are observed at high loads, hence there is a trade-off between NOx and smoke emission. To get maximum benefit from this trade-off, a paniculate trap may be used to reduce the amount of unburnt particulates in EGR, which in turn reduce the paniculate emission also. An experimental investigation was conducted to observe the effect of exhaust gas re-circulation on the exhaust gas temperatures and exhaust opacity. The experimental setup for the proposed experiments was developed on a two-cylinder, direct injection, air-cooled, compression ignition engine. A matrix of experiments was conducted for observing the effect of different quantities of EGR on exhaust gas temperatures and opacity     

Toxicity assessment of volatile organic compounds and polycyclic aromatic hydrocarbons in motorcycle exhaust

This study investigates the toxicity of various pollutant species from motorcycle exhaust via dose-response analysis and margin of safety using Escherichia coli DH5 alpha. The toxicity evaluation of the major components of motorcycle exhaust volatile organic compounds (VOCs), collected with impinger, and polycyclic aromatic hydrocarbons (PAHs), collected with filter and XAD-2, is essential to determine emission standards for motorcycles. The toxicity of benzene (B), toluene (T), ethyl benzene (E) and xylene (X) was selected for comparison as standard VOCs emitted from motorcycles. In addition, three types of reformulated gasoline (high oxygenate and high benzene content (No. 1), low oxygen and high benzene (No. 2), and low oxygen and low benzene (No. 3) were prepared to reveal combined toxicity of individual compositions. Motorcycle exhaust is significantly more toxic than BTEX due to the highly toxic VOCs generated from incomplete combustion. Overall toxicity evaluation showed that the toxicity, indicated as EC50, was approximately as follows: PAHs>two-stroke engines>four-stroke engines>BTEX.     

Real-time, on-line characterization of diesel generator air toxic emissions by resonance-enhanced multiphoton ionization time-of-flight mass spectrometry

The laser-based resonance-enhanced multiphoton ionization time-of-flight mass spectrometry (REMPI-TOFMS) technique has been applied to the exhaust gas stream of a diesel generator to measure, in real time, concentration levels of aromatic air toxics. Volatile organic compounds, as well as several polycyclic aromatic hydrocarbons were detected in the concentration range of 10-200 ppb in the steady-state diesel generator exhaust. The results were verified and compared with conventional extractive sampling and analytical techniques using gas chromatography/mass spectrometry (GC/MS). The high isomer selectivity of the REMPI-TOFMS instrument provided data for individual xylene isomers that are otherwise (partially) coeluting in standard GC/MS analyses. Good agreement was observed between results for volatile and semivolatile organic compounds obtained with REMPI-TOFMS and conventional extractive sampling. Transient events, such as cold start-ups of the diesel generator, resulted in sharp (less than 15 s) peak emissions that were, for benzene, up to a factor of 90 higher than the predominately constant concentrations observed during steady-state operation; warm restarts resulted in lower peak concentrations by a factor of 2.5. These fast transient emissions are only detectable using a real-time approach (1-s resolution) as demonstrated here using REMPI-TOFMS.