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P.C. Thomas E. Tomlal Jose Gejo George Sabu Thomas Kuruvilla Joseph 《Polymer Composites》2012,33(12):2236-2244
The diffusion and transport behavior of nitrile rubber nanocomposites was studied with respect to different types of filler and also different types of solvents. The nitrile rubber nanocomposites showed considerable variations in the molecular transport owing to the tortuosity of path, decreased segmental mobility, and difference in particle geometry. As the matrix under consideration is polar, the behavior of the filled systems in aniline was also studied with a view to understand the polar–polar interaction between the filled matrix and the solvent. The oil repellency as a result of filler addition in the matrix was investigated by studying oil uptake of the nanocomposites. In all these investigations, it has been observed that the filler geometry played an important role in controlling the molecular transport through the polymer matrix. The layered silicate‐filled system showed better solvent resistance and hence minimum solvent uptake in polar and nonpolar solvents and better oil repellency followed by titanium dioxide and calcium phosphate filled systems. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers 相似文献
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白炭黑-硅烷填充剂体系的化学性质及其对橡胶的补强性能 总被引:1,自引:0,他引:1
目前,降低燃油消耗,提高轿车轮胎的行驶性能及湿路面抓着力是个热门话题。文中详细论述了硅烷偶联剂TESPT及TESPD和沉淀法白炭黑-硅烷填料体系在SSBR/BR(70/30)胶料中的使用,白炭黑.硅烷-橡胶结合的化学反应机理以及对橡胶补强性能的提高。 相似文献
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Organically modified and unmodified montmorillonite clays (Cloisite NA, Cloisite 30B and Cloisite 15A), sepiolite (Pangel B20) and nanosilica (Aerosil 300) were incorporated into hydrogenated nitrile rubber (HNBR) matrix by solution process in order to study the effect of these nanofillers on thermal, mechanical and dynamic mechanical properties of HNBR. It was found that on addition of only 4 phr of nanofiller to neat HNBR, the temperature at which maximum degradation took place (Tmax) increased by 4 to 16°C, while the modulus at 100% elongation and the tensile strength were enhanced by almost 40–60% and 100–300% respectively, depending upon nature of the nanofiller. It was further observed that Tmax was the highest in the case of nanosilica‐based nanocomposite with 4 phr of filler loading. The increment of storage modulus was highest for sepiolite‐HNBR and Cloisite 30B‐HNBR nanocomposites at 25°C, while the modulus at 100% elongation was found maximum for sepiolite‐HNBR nanocomposite at the same loading. A similar trend was observed in the case of another grade of HNBR having similar ACN content, but different diene level. The results were explained by x‐ray diffraction, transmission electron microscopy, and atomic force microscopy studies. The above results were further explained with the help of thermodynamics. Effect of different filler loadings (2, 4, 6, 8, and 16 phr) on the properties of HNBR nanocomposites was further investigated. Both thermal as well as mechanical properties were found to be highest at 8 phr of filler loading. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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Reinforcement effect of nanocellulose on thermal stability of nitrile butadiene rubber (NBR) composites 下载免费PDF全文
Erfan Suryani Abdul Rashid Nurhidayatullaili Binti Muhd Julkapli Wageeh Abdul Hadi Yehya 《应用聚合物科学杂志》2018,135(32)
Poor physical and chemical attraction between nitrile butadiene rubber (NBR) matrix and filler resulted in low thermal properties. Therefore, nanocrystalline cellulose (NCC) as a reinforcement agent was used to increase the heat resistance and thermal stability of NBR composites. The addition of 2 phr NCC increased thermal stability and activation energy of NBR up to 75%. Meanwhile, the storage modulus of composites increased by 12 GPa at the similar loading of NCC. Good interfacial bonds of electrostatic interactions, formation of hydrogen bonds, crystallinity and nanosized of NCC are the main factors contribute to the final properties of NBR/NCC composites. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46594. 相似文献
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先采用离子液体(1-丁基-3-甲基咪唑六氟磷酸盐BMIM.PF6,IL)处理炭黑,而后进行微波处理得到改性炭黑(m-CB),将m-CB用于增强丁腈橡胶(NBR)。研究了m-CB的结构、混炼胶的硫化特性和补强效果。结果表明,IL可吸附到炭黑表面,而且部分IL强烈吸附于炭黑表面,微波处理之后,IL会发生部分分解;m-CB使混炼胶的硫化延迟;NBR/m-CB硫化胶的断裂伸长率、拉伸和撕裂强度相对于未改性炭黑均有较大提高,而模量和硬度略有下降。通过对硫化胶的交联密度、动态力学分析(DMA)、形态学等研究,探讨了改性炭黑补强橡胶机理。 相似文献
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Characterization of polypropylene/polystyrene boehmite alumina nanocomposites: Impact of filler surface modification on the mechanical,thermal, and rheological properties 下载免费PDF全文
The influences of surface treatment and the concentration of boehmite alumina (BA) particles on polypropylene and polystyrene (PS) (80/20) blends produced via melt compounding were examined. The results show that p‐toluene sulfonic acid‐treated BA particles yielded the highest stiffness improvement (27.5%), followed by untreated particles (25.7%), and dodecylbenzene sulfonic acid‐treated BA particles (8.5%). Transmission electron microscopy revealed that p‐toluene sulfonic acid‐treated BA particle agglomerates were dispersed in the PS phase, whereas untreated particles formed agglomerations at the interfaces. Dodecylbenzene sulfonic acid‐treated particles were poorly dispersed in both matrices. Differential scanning calorimetry showed that both untreated and p‐toluene sulfonic acid‐treated BA particles acted as nucleating agents in the blend because of the shifting of crystallization peaks to higher temperatures by 12 and 8 °C, respectively. A significant increase in decomposition temperatures occurred upon 7 wt % loading of all types of BA particles into the blend. Heat deflection temperature measurements showed that all types of BA particles improved the thermal properties of the blend. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46376. 相似文献
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复配改性黏土/丁腈橡胶纳米复合材料的结构及性能 总被引:1,自引:0,他引:1
用不同阴离子表面活性剂十二烷基磺酸钠(SDS)和十二烷基苯磺酸钠(SDBS)与阳离子表面活性剂十六烷基三甲基溴化铵(CTAB)复配改性无机黏土,制备了有机改性黏土/丁腈橡胶(NBR)纳米复合材料,并表征了有机黏土与纳米复合材料,考察了不同表面活性剂及配比对纳米复合材料物理机械性能的影响。结果表明,CTAB/SDS复配改性黏土/NBR纳米复合材料的层间距比CTAB改性黏土/NBR纳米复合材料增加了1.15 nm,具有更多的插层结构,橡胶基体中黏土颗粒分布细致、均匀,且黏土片层间无聚集体存在;CTAB/SDS复配改性黏土/NBR纳米复合材料的物理机械性能优于CTAB/SDBS复配改性黏土/NBR纳米复合材料及CTAB改性黏土/NBR纳米复合材料,且当CTAB/SDS(质量比)为4∶2时,纳米复合材料的拉伸强度、撕裂强度及扯断伸长率出现最大值,其中,拉伸强度和撕裂强度较CTAB改性黏土/NBR纳米复合材料分别提高了62.7%和12.3%。 相似文献
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Preparation and mechanical properties of nitrile butadiene rubber/silicate nanocomposites 总被引:1,自引:0,他引:1
Elastomer nanocomposites consisting of nitrile butadiene rubber (NBR) latex and layered silicates are prepared by a modified latex shear blending process aided with ball milling. The mode of dispersion of layered silicates in NBR is partially exfoliated and intercalated when the concentration of layered silicates is below 7.5 wt%, as evidenced by transmission electron microscopy and X-ray diffraction results. The tensile and tear mechanical properties are much higher than that of neat NBR. Specifically, the tensile and tear mechanical properties of the NBR/layered silicates increase by 200 and 60%, respectively. The decomposition temperature of the nanocomposites increases slightly. 相似文献
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Anusuya Choudhury Anil K. Bhowmick Christopher Ong Matthias Soddemann 《Polymer Engineering and Science》2010,50(7):1389-1399
The present work derives a relationship between structure and properties of hydrogenated nitrile rubber (HNBR) in the presence as well as absence of nanofillers. Four different grades of HNBR were selected to examine the influence of polarity, unsaturation, and molecular weight on thermal, mechanical, and dynamic mechanical properties of the elastomers and particularly their nanocomposites. An increase in thermal stability, tensile strength, modulus at 100% elongation as well as storage modulus of the unfilled rubber was observed with increase in polarity (acrylonitrile content). Different nanofillers, such as montmorillonite, sepiolite, and nanosilica were used to improve the above properties of the unfilled rubber. Interestingly, a reverse trend of thermal properties was observed for the nanocomposites with acrylonitrile variation, although mechanical and dynamic mechanical properties exhibited similar trend to those of the unfilled rubber. These properties, however, gradually deteriorated as the level of unsaturation on the polymer backbone was increased. On addition of the nanofillers, it was found that the improvement in thermal and mechanical properties was higher for the elastomer having 5.5% diene content. The results were explained by X‐ray Diffraction, Atomic Force Microscopy, Energy Dispersive X‐ray mapping, and swelling studies. POLYM. ENG. SCI., 2010. © 2010 Society of Plastics Engineers 相似文献
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《Journal of Adhesion Science and Technology》2013,27(5):537-556
Silica filler improves the aluminum-aluminum bonding by a self-vulcanizable rubber blend based on chlorobutyl rubber and carboxylated nitrile rubber. The joint peel strength depends on the filler loading, the state of cure, the molding temperature, and the adhesive film thickness. The higher peel strength in the filled adhesive system is due to filler reinforcement resulting in tear path deviation and the formation of Si—O—Al linkage at the aluminum-adhesive interface. Maximum peel strength was obtained at 10 phr filler loading, when the molding temperature was 180°C and the molding pressure was 0.35 MPa. 相似文献
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Organo‐montmorillonite/nitrile rubber (NBR) nanocomposites were prepared by a melt intercalation process. The characteristics of NBR nanocomposites were determined by an oscillating disk rheometer and transmission electron microscopy. The cure characteristics were investigated according to the change in clay content and clay types. This study confirmed that organo‐montmorillonite/NBR nanocomposites have various cure characteristics, namely minimum torque, maximum torque, scorch time and curing time, according to the change in clay content and clay types. In particular, as the chain length of the modifier used for the treatment of Na+‐MMT following vulcanization increases, scorch time and optimum curing time are reduced. This is because, as the chain length of the modifier increases, organo‐MMT is distributed more equally during the formation of the nanocomposites. As swelling increases, the chain length of the clay modifier expands and then constitutes a better barrier. Copyright © 2003 Society of Chemical Industry 相似文献
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Yingqing Zhan Xulin Yang Fanbin Meng Yajie Lei Jiachun Zhong Rui Zhao Xiaobo Liu 《Polymer International》2011,60(9):1342-1348
Poly(arylene ether nitrile) (PEN) nanocomposites containing various functionalized multi‐walled carbon nanotubes (MWCNTs) were prepared through a solution‐casting method. The as‐prepared PEN nanocomposites were investigated using parallel‐plate rheometry and thermogravimetric analysis, aimed at examining the effect of surface functionalization on the dispersion of MWCNTs from the viscoelastic and thermal properties. The linear viscoelasticy results indicated that 4‐aminophenoxyphthalonitrile‐grafted MWCNTs presented better dispersion in the PEN matrix than purified and carboxylic MWCNTs because the corresponding composite showed the lowest rheological percolation threshold, which was further confirmed from scanning electron microscopy, dissolution experiments and solution rheological experiments. The thermogravimetric analysis results revealed that the presence of 4‐aminophenoxyphthalonitrile‐grafted and carboxylic MWCNTs retarded the depolymerization compared with purified MWCNTs, showing a marked increase in the temperature corresponding to a loss of 5 wt% (increased by 14–22 °C) and maximum rate of decomposition (increased by 4–8 °C). Both the state of dispersion and the surface functionalization of MWCNTs are very important to the thermal stability of the PEN matrix. Copyright © 2011 Society of Chemical Industry 相似文献
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丁腈橡胶/聚氯乙烯/有机蒙脱土纳米复合材料的结构与性能 总被引:3,自引:0,他引:3
采用胶乳共沉法和直接共混法制备了丁腈橡胶/聚氯乙稀/有机蒙脱土(NBR/PVC/OMMT)纳米复合材料。通过X射线衍射(XRD)法和透射电子显微镜(TEM)法对NBR/PVC/OMMT纳米复合材料的结构进行了袁征,并研究了复合材料的力学性能、耐油性能和耐老化性能。结果表明,2种方法所获得的复合材料是插层型纳米复合材料;胶乳共沉法制备的纳米复合材料中OMMT的分散更为均匀,其力学性能、耐油性能和耐老化性能优于直接共混法制备的复合材料。 相似文献
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采用乳液法制备了天然橡胶/丁腈橡胶/蒙脱土纳米复合材料,考察了其微观形态,探讨了复合材料的硫化特性及静态和动态力学性能.结果表明,蒙脱土以纳米尺寸均匀分布于丁腈橡胶基质中,橡胶分子链并未插层进入蒙脱土片层;蒙脱土使复合材料的焦烧时间和正硫化时间增加,可明显提高复合材料的静态力学性能;复合材料具有与天然橡胶/丁腈橡胶共混... 相似文献
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We study the effect of in situ synthesized 10 nm silica nanoparticles on the glass transition and dynamics of natural rubber networks using differential scanning calorimetry, broadband dielectric relaxation spectroscopy and thermally stimulated depolarization currents. Even in the absence of specific polymer-filler interactions, polymer segments within a few nanometers of the filler particles exhibit relaxation times up to 2-3 orders of magnitude slower and reduced heat capacity increment at the glass transition compared to bulk natural rubber. These effects are only observed when the nanoparticles are uniformly distributed in the polymer matrix. 相似文献
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Variation of dynamic mechanical propeties like storage modulus (E′) and loss tangent (tan δ) with temperature show the presence of two transitions in the carboxylated nitrile rubber (XNBR) molded in the presence of zinc oxide (ZnO). The low-temperature transition is due to the glass–rubber transition (Tg) of XNBR, and the high-temperature transition is due to formation of ionic clusters. Incorporation of reinforcing silica filler makes the high temperature transition more prominent and high filler loading casues a shift of the transition temperature to the higer side. It is believed that the rubber–filler interaction in the cluster region causes striking changes in the variation of E′ and tan δ with a double-strain amplitude (DSA). © 1995 John Wiley & Sons, Inc. 相似文献