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1.
Effects of rare earth on inclusions and corrosion resistance of 10PCuRE weathering steel 总被引:1,自引:0,他引:1
YUE 《中国稀土学报(英文版)》2010,28(6):952-956
The types,morphologies and distributions of nonmetallic inclusions in Cu-P weathering steels with and without rare earth were analyzed through a quantitative image analyzer,scanning electron microscopy(SEM)and energy dispersive spectroscopy(EDS)attached to SEM.Solid-soluble content of rare earth in the steels was analyzed by non-aqua electroanalysis and ICP.The results showed that rare earth modified the types and the morphologies of inclusions in the weathering steels.The small spherical rare earth oxysulfides and rare earth sulphides replaced the elongated MnS inclusions in the RE weathering steels.The rare earth inclusions dispersedly distributed and most inclusions were smaller than 2 μm in size.The optimum content of RE was 0.0065%-0.016% for 10PCuRE weathering steels containing about0.002% oxygen and 0.004% sulfur.Solid-soluble content of rare earth in steels was(14-20)x 10-6,which can act as a micro-alloying element.The corrosion resistance of 10PCuRE weathering steels and Q235 were studied by dry-wet cyclic immersion test.Their corrosion rates were obtained respectively.The polarization curves and pitting corrosion behaviors of weathering steels with and without rare earth were measured by electrochemical methods.The corrosion resistance of Cu-P weathering steels was improved by adding an appropriate amount of rare earth.Less and fewer rare earth inclusions largely decreased pitting susceptibility and rate of pit propagation.The pitting potential and the resistance against pitting corrosion of the RE weathering steel were significantly improved due to the modification of rare earth to inclusions. 相似文献
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Lanthanide NIR luminescence for telecommunications, bioanalyses and solar energy conversion 总被引:4,自引:0,他引:4
Present-day advanced technologies heavily rely on the exciting magnetic and spectroscopic properties of lanthanide ions. In particular, their ability to generate well-characterized and intense near-infrared (NIR) luminescence is exploited in any modern fiber-optic telecommunication network. In this feature article, we first summarize the whereabouts underlying the design of highly luminescent NIR molecular edifices and materials. We then focus on describing the main trends in three applications related to this spectral range: telecommunications, biosciences, and solar energy conversion. In telecommunications, efforts concentrate presently on getting easily processable polymer-based waveguide amplifiers. Upconversion nanophosphors emitting in the visible after NIR excitation are now ubiquitous in many bioanalyses while their application to bio-imaging is still in its early stages; however, highly sensitive NIR-NIR systems start to be at hand for both in vitro and in vivo imaging, as well as dual probes combining magnetic resonance and optical imaging. Finally, both silicon-based and dye-sensitized solar cells benefit from the downconversion and upconversion capabilities of lanthanide ions to harvest UV and NIR solar light and to boost the overall quantum efficiency of these next-generation devices. 相似文献
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XIONG 《中国稀土学报(英文版)》2010,(6)
Batch adsorption experiments were conducted for the adsorption of Eu(Ⅲ) ions from aqueous solution by D113 resin. The results indicated that D113 resin could adsorb Eu(Ⅲ) ion effectively from aqueous solution. The adsorption was strongly dependent on pH of the medium with enhanced adsorption as the pH turned from 3.50 to 7.00 and the optimal adsorption condition was in HAc-NaAc medium with pH value of 6.50. The maximum uptake capacity of Eu(Ⅲ) ions was 290.9 mg/g D113 at 298 K, at an initial pH value of 6.50. The overall adsorption process was best described by Lagergren-first-order kinetics. When Freundlich and Langmuir isotherms were tested, the latter had a better fit with the experimental data. The thermodynamic parameters such as free energy (G) which were all negative, indicated that the adsorption of Eu(Ⅲ) ions onto D113 resin was spontaneous and the positive value of enthalpy (H) showed that the adsorption was endothermic in nature. Thomas model was applied to experimental column data to determine the characteristic parameters of column useful for process design. Furthermore, Eu(Ⅲ) could be eluted by using 3.0 mol/L HCl solution and the D113 resin could be regenerated and reused. 相似文献
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XIA 《中国稀土学报(英文版)》2010,28(6):874-877
Green-emitting Sr2LiSiO4F:Eu2+ and blue-emitting Sr2MgSi2O7:Eu2+ phosphors were synthesized by the conventional high temperature solid-state route,respectively.Their structures and photoluminescenee properties were comparatively investigated.It was found that the mixture phases of Sr2MgSi2O7 and SrF2 were obtained when a part of Sr2+ in Sr2LiSiO4F was replaced by some amount of Mg2+ in order to design the possible SrMgLiSiO4F:Eu2+ phosphor.Based on the photoluminescence analysis,Sr2LiSiO4F:Eu2+ phosphor exhibited a green broad emission band of main peak at 513 nm under the excitation of 365 nm,while the Sr2MgSi2O7:Eu2+ and SrMgLiSiO4F:Eu2+ phosphor showed blue emission centered at 467 nm.The temperature dependent photoluminescence properties and room temperature decay time for the three kinds of phosphors were also discussed in this paper. 相似文献
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HUANG 《中国稀土学报(英文版)》2010,28(6):940-943
Er3+-substituted W-type barium ferrites Ba1-xErx(Zn0.3Co0.7)2Fe16O27(x=0.00,0.05,0.10,0.15,0.20)were synthesized by polymer adsorbent combustion method.Samples were characterized by X-ray diffraction analysis(XRD),X-ray fluorescence(XRF),scanning electron microscopy(SEM)and network analyzer to investigate the relationships among Er3+concentration,crystal structure,surface mcrphology and electromagnetic properties.All the XRD patterns showed pure phase of W-type barium ferrite when x≤0.15,while the impurity phase of ErFeO3 appeared when x=0.20.The pure W-type barium ferrite showed a hexagonal flake shape.In addition,the microwave electromagnetic properties of samples were analyzed in the frequency range of 2-18 GHz.It was indicated that the electromagnetic properties were significantly improved when Er3+doping content was 0.10.The reasons were also discussed using electromagnetic theory.The optimized ferrite exhibited excellent microwave absoption performance.The maximum of reflection loss(RL)reached about-27.4 dB and RL was below-10dB at the frequency range from 8.4 GHz to 18 GHz,when the thickness was 2.6 mm. 相似文献
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REN 《中国稀土学报(英文版)》2010,28(6):883-887
Nanosized terbium doped Lu2O3 phosphors were synthesized via a modified co-precipitation processing.The as-prepared Tb:Lu2O3 phosphors was consisted of well crystallized nanosized sphere particles with a diameter of about 30 nnx Local structure of Tb ions in Lu2O3 lattice was investigated by an analytical approach based on Fourier transformation of the extended X-ray absorption fine structure(EXAFS) data.X-ray near edge structure (XANES) spectra suggested that all Tb ions doped were tervalonce.EXAFS results indicated that Tb ions have entered the Lu2O3 cubic lattice by means of solid solution.The coordination number and first shell Tb-O distance dropped with the increasing of Tb concentration.Emission spectra of the phosphors was shown to be typical for Tb3+ with main components at 542,550 and 490 nm,derived from irradiative relaxation of 5D4 level.The emission intensity decreased severely with the increasing of Tb concentration from 1 mol.% to 15 tool.%,suggesting a significant concentration quenching above 1 mol.% Tb.The reduction of emission intensity was interpreted by higher distortion derived relaxation among the surface state resident Tb3+ ions. 相似文献
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Thermomechanical Controlled Processing (TMCP) including accelerated cooling after the final hot rolling pass is a well-established technology,widely applied in HSLA steel plate production.However,there are still certain limitations,especially for thicker plate.The rolling schedule includes a long holding period (HP) after the roughing stage to allow the temperature to fall sufficiently for optimised TMCP during finishing.Intermediate Forced Cooling (IFC) applied during the HP can increase productivity by decreasing the required hold time,can restrict austenite grain growth,and can also improve the subsequent strain penetration in thick plate with further metallurgical benefits.Multi-pass plane strain compression (PSC) tests have been performed on the thermomechanical compression (TMC) machine at Sheffield University including different severities of IFC.Clearly it is impossible to simulate all aspects of the temperature and strain gradients present in thick plates in laboratory specimens,and most of the tests were conducted at temperatures and strains calculated by Finite Element modelling as relevant to specific positions through the plate thickness.However,some aspects of the gradients were addressed with tests using cold platens.The results have indeed shown that IFC can shorten the HP and reduce austenite grain growth and its variation across thick plate. 相似文献
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Karl-Hermann TACKE 《钢铁研究学报(英文版)》2011,(Z2):211-219
This paper gives an overview of phenomena associated with particles and bubbles in continuously cast steel. During steel processing from deoxidation to solidification the inclusion population undergoes changes with opportunities of removal. Flotation is an important separation mechanism. Inclusion particles may accumulate in the solidifying strand, thus forming enriched bands, which depend on the type of casting machine. Bubbles are created during inert gas injection. They also change in size, can float out, but also form accumulation bands. The interaction of bubbles and particles is discussed. Internal structure that recently has been observed on the inner surface of bubbles will be reviewed. 相似文献
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肖玲君 《湖南冶金职业技术学院学报》2007,7(2):102-105
池莉的"人生三部曲"--<烦恼人生>、<不谈爱情>、<太阳出世>诉尽了普普通通的市民烦恼,小说中主人公被柴米油盐、吃喝拉撒、老婆孩子等琐事所烦着,从而构成他们的"烦恼人生".然而池莉通过自己的艺术创作,以积极的人生态度,又让读者体会到生活本身的快乐,"烦恼人生"中包含着"快乐人生". 相似文献
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介绍了在工程图形中用属性块标注表面粗糙度的方法.采用属性块不仅能避免大量重复性的工作,还能节省大量的存储空间,具有提高绘图速度、质量,便于修改,资源共享等应用价值. 相似文献
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In the following paper an experiment dedicated to the accident protection system of a Liquid Metal Target is presented.The test was carried out at the liquid metal test stand(LIMETS)at PSI in which the malfunctioning of a target during operation was simulated.It could be demonstrated that measurements and the proper(on-line)analysis of target vibrations and surrounding sound pressure fields allow the detection of a malfunctions like deformation or detaching of structural elements immeresed in the flow.Amplitudes of acceleration sensors and microphones signals as well as frequencies of the disturbances’signals are prospective parameters to be used in an automated accident protection system as indicators for a target malfunction. 相似文献
12.
Xiangjun Liu Jichun Yang Fang Zhang Xiaoyang Fu Hongwei Li Changqiao Yang 《中国稀土学报(英文版)》2021,39(4):477-486
To provide insights into deforming Ce-O-S-Al inclusions in steels and improving the mechanical properties,the evolution process of such harmful inclusions in clean steels was investigated by thermodynamic calculation,metallographic examination and first-principles calculation in this paper.For the tested IF steel,the thermodynamic analysis results are consistent with the calculated formation enthalpy.After Ce addition,the inclusions are transformed from Al2O3and TiN-Al2TiO5-Al2O3to Ce2O3,Ce2O2S,CeAlO3,TiN-Al2TiO5-Ce2O3and TiN-Al2TiO5-Ce2O2S composite inclusions,which can be confirmed by metallographic examination.The elastic constants were calculated,and the bulk modulus,Young's modulus,shear modulus and Poisson's ratio were evaluated by the Voigt-Reuss-Hill(VRH)approximation.All inclusions except Ce2O3show apparent brittleness.TiN,Al2O3,Al2TiO5and CeAlO3present much higher hardness than iron matrix,while the hardness of Ce2O3or Ce2O2S is close to that of iron matrix.The thermal expansion coefficients of Ce2O3and CeAlO3are close to that of iron matrix,whereas,Ce2O2S inclusion has largely different thermal expansion coefficient from iron matrix and may deteriorate the steel performance at higher temperatures.The relatively small differences between Ce inclusions and iron matrix in terms of hardness,toughness,brittleness,and thermal expansion coefficient can explain the improvement of the mechanical properties of the tested steel. 相似文献
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通过对某铅锌矿不同出矿点矿石及综合样(将各出矿点的矿样按一定比例配制而成)的试验研究,查明了各个出矿点矿石的选别特性,提出了综合样在现有现场流程下能够达到的选别指标,为更好地指导生产及评价生产指标提供了科学依据. 相似文献
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傅晶 《湖南冶金职业技术学院学报》2007,7(1):47-50
介绍了客户关系管理的概念,分析了金融业客户关系管理(CRM)存在的问题,指出了CRM实施过程中必须处理好人、流程、科技三项要素的关系,提出了金融业发展CRM应采取的措施. 相似文献
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TAN 《中国稀土学报(英文版)》2010,28(6):888-892
An investigation on the photophysical properties of the newly designed terbium imidazole-4,5-dicarboxylic acid complex encapsulated in the inert matrices(tetraethoxysilane,TEOS)was performed.The composite material was very stable and showed strong green emission in pure water.Interestingly,we discovered that the luminescence of hybrid material was selectively responsive to H2PO4-.1H-NMR and fluorescence spectra supported that the receptor had strong affinity to dihydrogen phosphate.Meanwhile,the luminescence was quenched by Fe3+ when adding different metal ions such as Fe3+,Pd2+,Cd2+,Co2+ and Mn2+ concomitantly.Moreover,thin film was successfully prepared by the same materials and it also exhibited selective recognition behavior to the above two ions. 相似文献
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4月11日,由美铝副总裁兼首席技术官Mohammad Zaidi先生率领的美铝公司代表团一行9人访问了郑州研究院。中铝公司副总裁刘祥民会见了Mohammad Zaidi先生一行,研发中心总经理李旺兴、中铝公司科技部主任张吉龙、郑州研究院党委书记、副院长顾松青、中铝广西分公司副总经理刘永刚、中铝山西分公司副总经理张占明、中国铝业公司科技部项目处处长孟杰等领导和研究院各研究所所长40余人参加了会见。 相似文献
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