等离子喷涂Al_2O_3-TiO_2/MoS_2陶瓷减摩耐磨涂层的结构与性能研究

采用等离子喷涂技术在钛合金表面制备Al2O3-TiO2陶瓷涂层,并用MoS2均匀填充涂层表面空隙,在TE66微磨粒磨损试验机上对涂层的摩擦学性能进行系统研究,利用扫描电镜、光学显微镜对涂层的表面形貌、元素构成、膜层厚度和磨斑形貌进行分析,并采用显微维氏硬度计和划痕试验机对涂层的显微硬度和结合强度进行测试。结果表明:涂层与基体之间的结合强度良好,显微硬度高达HV1 457,磨损失重量仅为未涂层样品的1.29%,摩擦因数大幅度降低,存在轻微的疲劳磨损特征。     

高速重载下三种固体润滑膜耐磨性的实验研究

用销盘摩擦实验机研究三种固体润滑涂层；喷涂NF-1、粘结PEF及粘结Teflon-S涂层在高速（5.6m/s）、重载（初始接触应力400MPa)干摩擦条件下的摩擦磨损性能。结果表明：这三种涂都具有接近30min的使用寿命，具有较低的摩擦系数和磨损率，提高了抗咬合能力，基点NF-1和Teflon的摩擦系数从0.08分别增加到0.14和0.15。PEF涂层摩擦系数从0.1降低到0.08。     

石墨烯/MoS2复合涂层多环境下的摩擦学性能

以MoS2作为润滑剂,以石墨烯(GE)作为润滑添加剂,采用喷涂法在GCr15钢样片表面制备不同含量的GE/MoS2复合涂层.利用HSR-2M型高速往复式摩擦磨损试验机测试涂层在干摩擦及海水环境中的摩擦磨损性能,并分析了磨痕形貌及磨损机制.结果表明:添加适量石墨烯可明显改善MoS2涂层的摩擦磨损性能,且海水环境中涂层的摩...     

磷酸酯偶联剂改性衬垫对自润滑关节轴承性能的影响

利用 Instron5944型电子万能材料试验机和自制的关节轴承摩擦磨损试验机,研究磷酸酯偶联剂接枝改性处理衬垫对自润滑关节轴承黏接性能和摩擦磨损性能的影响。结果表明：磷酸酯偶联剂接枝改性处理衬垫可以有效提高轴承衬垫的黏接性能;自润滑关节轴承的摩擦磨损性能与摆动频率呈现明显的相关性,摩擦因数和磨损量均随摆动频率的增大而减小,而摩擦温度随之升高;衬垫经改性处理的轴承摩擦因数、磨损量以及摩擦温升均明显降低,表明衬垫经改性处理后改善了自润滑关节轴承的摩擦学性能。     

热喷涂MoS2/PA(聚酰胺)复合涂层的摩擦学性能及磨损机理研究

利用热喷涂技术在45钢上制备了MoS2／PA(聚酰胺)复合涂层，考察了不同填料含量复合涂层的摩擦磨损性能，采用SEM分析涂层及对偶磨损表面形貌，并探讨了填料对复合涂层摩擦磨损性能的影响机制。结果表明：填料含量大于39／6时，虽然摩擦因数较小，但磨损率很大，且大于纯PA涂层的磨损率；当填料含量小于3％时，涂层摩擦学性能有所提高。     

PTFE/芳纶纤维编织衬垫自润滑关节轴承的黏接性能及摩擦学性能

对PTFE/Kevlar纤维混合编织衬垫分别进行超声波处理、稀土CeO2处理后,制备了自润滑关节轴承,利用Instron5944型电子万能材料试验机和自制的高频摆动摩擦磨损试验机对关节轴承进行了剥离强度测试和摩擦磨损性能试验,考察了前处理工艺对关节轴承的黏接性能和摩擦学性能的影响,并采用扫描电镜(SEM)观察分析了衬垫表面的微观形貌变化,以探究轴承的摩擦学性能与衬垫形成PTFE转移膜的成膜性能之间的关系。结果表明,衬垫经改性前处理后,不仅提高了衬垫与基体的黏接性能,而且提高了轴承的摩擦学性能;轴承的摩擦学性能与其在摩擦磨损过程中形成PTFE转移膜的成膜性能之间存在一定的对应关系,即PTFE转移膜的形成越快,耐磨性、均匀连续性越好,在摩擦磨损过程中表现出较优的摩擦诱导成膜性能,其摩擦学性能也越优。     

硫化物固体润滑剂的研究现状

综述固体润滑材料中应用最为广泛的硫化物固体润滑剂的研究现状;介绍硫化亚铁、二硫化钼、硫化钨以及二硫化锌固体润滑剂的制备工艺的发展及其相应的润滑薄膜的摩擦学性能;指出进一步弄清渗流层硫化亚铁的减磨机制以及改善二硫化钼的抗潮性以及与基体的结合强度是未来的研究方向.     

Influence of Ultrasonic Modified Liners on the Adhesive and Tribological Performances of Self-Lubricating Radial Spherical Plain Bearings

For self-lubricating spherical plain bearings, poor interface bonding strength between the polytetrafluoroethylene (PTFE)/aramid fabric hybrid woven liners and the outer rings can influence the full play of tribological performance of the self-lubricating liner. To solve this problem, the liners were modified by ultrasonic treatment. The adhesive performances of the modified and unmodified liners and the tribological performance of the self-lubricating radial spherical plain bearings with two kinds of liners were tested and compared. Results show that ultrasonic modification can improve the bonding performance of the liners significantly; compared to unmodified liners, the modified liners can decrease the friction coefficient, wear loss, and friction temperature of the bearings, which shows that ultrasonic modification can improve the tribological performance of self-lubricating spherical plain bearings. Bearings with modified liners only produced slight adhesive wear, but bearings with unmodified liners produced moderate adhesive wear and slight abrasive wear during test procedures.     

粘结固体润滑涂层在油润滑条件下的摩擦学性能

为了探讨粘结MoS2基固体润滑涂层在油润滑条件下的抗磨减摩性能,采用MHK-500型摩擦磨损试验机对粘结MoS2基固体润滑涂层在4种常用油(液体石蜡、RP-3煤油、4050滑油和CD-40柴油)润滑下的摩擦磨损性能进行了研究,考察了速度和载荷对润滑涂层在4种不同的常用油润滑下的摩擦磨损性能。结果表明,在低载荷(320N)试验条件下,4种常用油润滑下涂层的耐磨性比干摩擦下得到显著的提高,摩擦因数从0.12降低到0.08左右;但在高载荷(1100N)下,油润滑对涂层的摩擦磨损性能没有明显的改善。只有在合适的载荷下,固/油复合润滑技术可明显改善摩擦副的润滑性能。     

Tribological Properties of Lubricating Films on the Al-Si Alloy Surface via Laser Surface Texturing

Dimpled textures were prepared by using a pulse solid laser on the surface of Al-Si alloy. The combination of laser surface texturing (LST) and MoS₂ solid lubricant as well as their tribological properties were investigated in this article. The obtained friction and wear data were critically analyzed to investigate how the parameters of texture influence the tribological performance of Al-Si alloy. Furthermore, morphological investigations of the transfer layers on the worn surfaces were performed and the wear mechanisms are discussed. The results show that the combination of LST and solid lubricant improves the tribological characteristics of Al-Si alloy. The friction coefficient of Al-Si alloy: steel friction pairs can be reduced to 0.15 under dry friction. The lubrication mechanism is attributed to a synergetic effect of providing solid lubricant and traps wear debris in the dimples. It was found that the optimum density of structure was 37% for excellent tribological properties.     

Sliding wear behavior of Fe-Al and Fe-Al/WC coatings prepared by high velocity arc spraying

A comparative study was carried out to investigate the microstructure and tribological behavior of Fe-Al and Fe-Al/WC iron aluminide based coatings against Si₃N₄ under dry sliding at room temperature using a pin-on-disc tribotester. The coatings were prepared by high velocity arc spraying (HVAS) and cored wires. The effect of normal load on friction coefficient and wear rate of the coatings was studied. The microstructure and the worn surfaces of the coatings were analysed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersion spectroscope (EDS). The results showed that, the main phases in both coatings were iron aluminide (Fe₃Al and FeAl) and α. WC/W₂C particles were embedded in the matrix of the composite coating. With adding WC hard particles, the Fe-Al/WC composite coating exhibited higher wear-resistance than Fe-Al coating. But the friction coefficient of both coatings showed little difference. As the load increased, the friction coefficient decreases slightly due to a rise of friction contact temperature and larger areas of oxide film formation on the worn surface, which act as a solid lubricant. Increasing load causes the maximum shear stress occurring at the deeper position below the surface, thereby aggravating the wear. The coating surface is subjected to alternately tensile stress and compression stress during sliding, and the predominant wear mechanism of the coatings appears to be delamination.     

双金属轴承材料表面黏结润滑涂层摩擦学性能研究

在HDM-10型端面摩擦磨损试验机上进行油润滑及规律变载条件下的摩擦磨损试验,考察了石墨﹑MoS2及其复合黏结润滑涂层的摩擦磨损性能.结果表明:固体润滑涂层显示了较好的减摩耐磨性能,摩擦副正常阶段的摩擦系数在0.09以下,摩擦温升小,涂层的承载载荷都超过了2 800 N,最高达到4 800N;石墨与MoS2有较好的协同效应,当石墨、MoS2与胶黏剂的比例为3∶ 2∶ 10时,涂层的摩擦学性能最佳.     

钢背衬碳纤维织物/环氧复合材料干摩擦特性研究

研究了钢背衬碳纤维织物/环氧复合材料在环-环端面干摩擦状态下的摩擦学特性,考察了MoS2与石墨粉及其配比、衬层厚度、法向载荷对衬层干摩擦性能的影响,用扫描电子显微镜对衬层的磨损表面及对偶件45^#钢环表面进行了观察与分析。结果表明：厚度为1.5mm的试环衬层在摩擦过程中主要表现出粘结磨损特性,而含20%（质量分数）MoS2粉的0.6mm衬层表现出疲劳磨损与磨粒磨损特性。摩擦因数-时间特性曲线表明MoS2粉在降低衬层摩擦因数的同时能够抑制环氧树脂向对偶钢环表面的粘结;石墨对衬层的减摩效果优于MoS2粉,但摩擦温升引起树脂向偶件表面转移增多使得减摩效果大大降低;质量分数为33%的MoS2与石墨粉衬层表现出最佳的摩擦学性能,衬层摩擦因数具有随载荷先减小后上升的趋势。     

Tribological Properties of Phosphor Bronze and Nanocrystalline Nickel Coatings Under PAO + MoDTC and Ionic Liquid Lubricated Condition

The friction and wear properties of phosphor bronze and nanocrystalline nickel coatings were evaluated using a reciprocating ball-on-plates UMT-2MT sliding tester lubricated with ionic liquid and poly-alpha-olefin containing molybdenum dialkyl dithiocarbamate, respectively. The morphologies of the worn surfaces for the phosphor bronze and nanocrystalline nickel coatings were observed using a scanning electron microscope. The chemical states of several typical elements on the worn surfaces were examined by means of X-ray photoelectron spectroscopy. Results show that the phosphor bronze and nanocrystalline nickel coatings exhibited quite different tribological behaviors under different lubricants. Phosphor bronze plate shows higher friction coefficient (0.14) and wear rate (3.2 × 10⁻⁵ mm³/Nm) than nanocrystalline nickel coatings (average friction coefficient is 0.097, wear rate is 1.75 × 10⁻⁶ mm³/Nm) under poly-alpha-olefin containing molybdenum dialkyl dithiocarbamate lubricated conditions. The excellent tribological performance of nanocrystalline nickel coatings under above lubricant can be attributed to the formation of MoS₂ and MoO₃ on the sliding surface. a quite a number of C, O and F products on worn surface of phosphor bronze than NC nickel coatings can improve anti-wear properties while using ionic liquid as lubricant.     

Sb2S3和MoS2的协同作用对摩擦材料摩擦性能的影响

采用MPX-2000型磨损试验机和定速摩擦实验机分别测试不同载荷及不同温度下固体润滑剂Sb2 S3和MOS2对摩擦材料摩擦性能的影响,探讨2种固体润滑剂的协同作用;采用扫描电镜分析摩擦材料磨损后摩擦表面的微观形貌.结果表明,固体润滑剂Sb2 S3和MoS2具有良好的协同效应,可大大改善摩擦材料的摩擦性能,这是因为MOS2和Sb2 S3分别在制动过程中的低温段和高温段起到良好的润滑作用.当Sb2S3的体积分数为6%,MoS2的体积分数为3%时,摩擦材料的摩擦性能最佳.     

Low-friction wear-resistant coatings for high-temperature foil bearings

Compliant foil bearings offer many advantages over rolling element bearings in high-speed and high-temperature applications. However, implementation of foil bearings in these applications requires development of solid lubricant coatings that can survive the severe operating conditions encountered at high speeds and high temperatures. The objective of this paper is to present results on development of an advanced coating system for use with compliant foil bearings that permits higher operating speeds and temperatures. In order to evaluate the coating performance and to select the best coating combination for implementation, tests were conducted using a high-temperature, high-speed tribometer. In these tests, Inconel test substrates, representative of a portion of a foil bearing, were coated with several different Korolon^TM coatings. The counterface disks were coated with a dense chrome, plasma sprayed PS304, hard chrome and Korolon^TM 1350B. Each test was conducted for 500 start–stop cycles up to 810 °C foil pad temperature under 13.8 kPa normal loading.The test results confirmed the excellent tribological behavior of Korolon^TM coatings for high-speed, high-temperature foil bearing applications. While the tribological behavior of Korolon^TM coatings were determined to be a function of temperature, in most cases a minimum coefficient of friction less than 0.1 was observed during startup/shutdown periods. Based on the measured coefficient of friction and post-test visual inspection of the mating surfaces, the hard chrome coating proved unacceptable for high-temperature applications due to extensive surface cracking. The other disk coatings exhibited excellent tribological performance.Following these tests, a foil journal bearing was designed and a composite coating consisting of Korolon^TM 1350A with an overcoat of Korolon^TM 800 was applied to the bearing top foil; and a dense chrome coating was applied to the journal surface. The foil bearing and journal were installed in a 240-lb thrust turbojet engine and operated successfully to 54,000 rpm for over 70 start–stop cycles and 14 h.     

花状与球状MoS2对PAO15润滑油摩擦学性能的影响

为改善低黏度PAO15润滑油的摩擦学性能,通过水热法制备球形与花状MoS_2颗粒,采用X射线衍射仪(XRD)与扫描电子显微镜(SEM)对所制备的MoS_2颗粒进行表征。制备球形与花状MoS_2改性的PAO15油,利用四球摩擦试验机对比研究2种形貌MoS_2在不同用量条件下对PAO15油摩擦学性能的影响。采用光学显微镜、表面轮廓仪、扫描电子显微镜(SEM)与能谱仪(EDS)对磨痕表面进行表征。结果表明:制备的球形与花状MoS_2晶型均较好地符合MoS_2的晶型,掺杂至PAO15油中均能够提升其摩擦学性能,使其摩擦因数降低;随着MoS_2颗粒添加量的增加,PAO15油摩擦学性能有所提升,在质量分数为1.0%时达到最优;花状MoS_2具有更大的比表面积,其对PAO15油抗磨损性能的提升优于球形MoS_2,形成的转移膜能够更好地起到隔离摩擦表面的作用。     

钻井液用植物油润滑剂的制备及摩擦学性能研究

为了使钻井液用植物油润滑剂在高压和高温氧化后仍具有良好的抗磨减摩性能,将层状固体润滑剂石墨、蛇纹石加入植物油中,合成了几种含固体润滑剂的钻井液用植物油润滑剂;利用UMT-2球盘式摩擦试验机考察了各润滑剂的摩擦性能;在摇臂钻床上模拟钻探的摩擦工况,考察了合成的润滑剂的抗磨性能,利用扫描电子显微镜观察了钻头的磨损形貌。结果表明,在植物油中添加石墨、蛇纹石可以降低植物油的摩擦因数和摩擦副的磨损,同时可使植物油在高温氧化后仍能保持良好的减摩抗磨性能。     

Low temperature investigations on frictional behaviour and wear resistance of solid lubricant coatings

The tribological characteristics of polymer-based solid lubricant coatings under frictional stressing in vacuum at 293, 120 or 77 K were studied. Vacuum-friction apparatus with cryogenic pumps and low-temperature tribometer designed at SR&DB of ILTP&E was used for sliding tests. It was found that the coefficient of friction is somewhat higher at low than at room temperatures. The effect of temperature decrease on the wear life of solid lubricant coatings is ambiguous and determined by the direction of changes in physical and mechanical characteristics of a solid lubricant coating under cooling and by the rate of the process of a binder tribodestruction.     

激光微造型表面固体润滑性能研究

采用声光调Q二极管泵浦固体光源(DPSS)Nd:YAG激光器,在45#钢试样表面进行表面微造型加工。以聚酰亚胺(PI)和二硫化钼(MoS2)复合固体润滑材料作为固体润滑剂,通过两步加温固化黏结工艺成功制备微造型固体润滑试样。在MMW-1A型摩擦磨损试验机上进行光滑无润滑试样、光滑表面固体润滑试样和微造型固体润滑试样的摩擦性能对比试验,以及微造型固体润滑试样在不同转速和压力下的摩擦性能试验。结果表明,在经过激光加工的微凹坑中填充复合固体润滑材料的试样,在摩擦过程中微凹坑中填充的固体润滑材料能有效转移到在摩擦表面,补充消耗掉的润滑材料,因而表现出更好的摩擦学性能。