不同工质对太阳能有机朗肯循环系统性能的影响

循环工质的特性是影响有机朗肯循环系统性能的重要因素之一,在不同的蒸发温度条件下,选取R600、R600a、R245fa、R236fa、R236ea、R601、R601a、RC318及R227ea共9种有机工质,基于热力学第一定律和第二定律对其热力循环特性进行了计算分析,并对各有机工质的蒸发压力、热效率、功比和不可逆损失等进行了比较.结果表明：R245fa作为太阳能低温热发电朗肯循环系统的循环工质具有较高的热效率和效率,并且产生的系统总不可逆损失较小,是一种较理想的有机工质;其次,R236fa和R236ea作为系统循环工质也具有较为良好的性能.     

地热驱动非共沸工质有机闪蒸循环的热性能分析

非共沸工质具有变温相变特性,可有效改善有机闪蒸循环系统与冷源温度匹配差的问题,进而提高系统的循环性能.文章构建了有机闪蒸循环系统模型,其中,循环工质为R245fa/R601a混合物,热源温度为150℃.文章以净输出功率作为目标函数对有机闪蒸循环系统进行优化,研究了R245fa/R601a混合物的组分变化对有机闪蒸循环系...     

基于遗传算法的有机朗肯循环系统参数优化

在有机朗肯循环系统中,汽轮机进口压力与进口温度是影响系统性能的重要因素.遗传算法在参数优化方面,具有显著的优点,广泛的应用于优化领域,是目前影响较广泛、应用较多、比较成熟的优化算法.本文采用遗传算法,对以R600,R600a,R245fa,R236fa,R236ea,R601,R601a,RC318,R227ea作为循环工质的有机朗肯循环系统进行参数优化,得出在特定的进口压力和进口温度的条件下,系统具有最小的总不可逆损失.     

回收低温余热的有机朗肯循环性能分析及优化

选取R113、R114、R141b、R123、R245fa、R245ca、R600、R600a作为回收120~200℃低温余热的有机朗肯循环工质,从净功量、热效率、不可逆损失等方面对有机朗肯循环系统性能进行分析和优化,得出系统最佳运行工况。     

用于高温热泵蒸汽系统的几种工质的循环性能

建立了高温热泵蒸汽系统的热力学模型。在蒸发温度为60℃,冷凝温度为120~140℃的工况下,进行经过初步筛选的4种高温热泵纯工质(R123,R141b,R245ca,R245fa)和传统高温热泵工质(R114)的循环性能对比研究。结果表明:R245fa的综合循环性能良好,单位容积制热量最高,其性能系数(COP)比R114平均高13.65%,压缩比与R114最接近;在符合干压缩要求的前提下,排气温度较低,而且环境友好,可作为高温热泵蒸汽系统的工质。     

应用热力学分析方法与AHP_熵值法对ORC的工质比较及优化

选取4种有机工质R245fa、R123、R600和R141b做为循环工质,采用火用分析方法在烟气入口温度为150℃、出口温度为75℃的条件下,在蒸发温度为80-140℃范围内对4种有机工质的亚临界有机朗肯循环进行分析,发现系统各设备的火用效率、系统总的火用效率、热效率、净输出功随蒸发温度的升高而升高,火用损失随蒸发温度的升高而降低。当蒸发温度达到140℃时,系统各设备的火用效率、系统总的火用效率、热效率、净输出功均达到最大值,而火用损失达到最小值。因此,4种有机工质蒸发温度在80-140℃范围内的最佳蒸发温度都为140℃,且4种工质中R141b的有机朗肯循环系统各设备的火用效率、系统总的火用效率、热效率、净输出功最大,火用损失最少,所以R141b为该系统的最适合工质,R123、R600和R245fa依次次之。以系统总火用损失、热效率、火用效率和净输出功为评价指标,采用层次分析法(The Analytic Hierarchy Process,AHP),通过熵值法确定权重因子,得到R600和R245fa的综合评价指标ξ,发现R600比R245fa更优。     

低温余热有机朗肯循环发电系统工质选择

对有机朗肯循环系统工质的优化选择已逐渐从单一优化目标向多目标发展,但所选的优化目标及优化方法普遍存在主观性较强的问题.针对上述问题,从环保性、安全性等方面对工质进行初选,得到了R123、R245fa、R245ca和R601等9种工质,然后采用主成分分析法对工质的热效率、循环净功和不可逆损失等7个热力性能指标进行了分析计算,得到了两个较为客观的综合评价指标,并在不同蒸发温度下对工质的综合热力性能进行了分析.结果表明:R601做功能力较强,综合效率较高,是该循环系统较为理想的工质.     

太阳能驱动的有机朗肯-喷气增焓（带二次吸气的增效）蒸汽压缩制冷系统性能分析

为有效利用太阳能,以有机朗肯−喷气增焓（带二次吸气的增效）蒸汽压缩式制冷系统为研究对象,建立了系统的热力学模型,分别选取R236fa、R245fa、RC318和R141b作为系统工质,研究了发生温度、凝结温度、冷凝温度、蒸发温度、膨胀机等熵膨胀效率及压缩机等熵压缩效率对系统性能的影响,并以系统性能最佳为目标对工质进行了优选。计算结果表明：对整个系统而言,R141b是最合适的工质,凝结温度和冷凝温度对系统性能有重要影响。以R141b为例,当发生温度在85℃、凝结温度为40℃、冷凝温度为40℃、蒸发温度为 −15℃时,系统COP_s达到0.2528,采用喷气增焓技术对于环境温度很低、太阳能资源丰富的北方地区具有很大的优势。     

利用中低温余热的回热有机朗肯循环性能分析

通过选取R227ea、R600和R141b 3种典型有机干流体作为工质,在热源流体进口温度设定为典型工业锅炉排烟温度423.15 K,冷却水进口温度和环境温度分别设定为283.15 K和293.15 K的条件下,分析蒸发温度、过热度和给水加热器出口处工质温度对回热有机朗肯循环性能的影响,比较回热有机朗肯循环与基本有机朗肯循环的性能。结果表明:随着蒸发温度的增大,循环总不可逆损失减小,循环热效率和第二定律效率增大,而循环输出净功率则先增大后减小;随着过热度的增大,循环总不可逆损失和循环输出净功率均减小,而循环热效率和第二定律效率的变化趋势则因工质而有所不同;随着给水加热器出口处工质温度的增大,循环总不可逆损失和循环输出净功率不断降低,而循环热效率和第二定律效率则先增后减;在相同工况下,回热有机朗肯循环的循环热效率和第二定律效率高于基本有机朗肯循环,但对于循环输出净功率和循环总不可逆损失,结果则相反。     

基于MOSSA算法的混合工质双压ORC系统多目标优化

以R141b/R245fa混合工质为研究对象,利用Matlab软件建立混合工质双压有机朗肯循环(ORC)系统数学模型,分析混合工质组分、高压蒸发温度、低压蒸发温度对系统热力、经济、环境性能的影响。采用多目标麻雀搜索(MOSSA)算法对系统热力、经济、环境性能进行多目标优化,并对3种性能的函数关系进行拟合。结果表明:系统热效率与R141b质量分数呈负相关,随高压蒸发温度呈先增大后减小趋势,存在最佳高压蒸发温度使系统热效率达到最大,与低压循环蒸发温度呈正相关;混合工质双压ORC热经济环境三目标优化的Pareto最优解(η_orc,LEC,ECE)为(0.134 3,0.701 9元/kWh,11.605 kgCO₂eq/kWh),综合性能最优时的运行参数为R245fa质量分数为0.1,高压循环蒸发温度为387.65 K,低压循环蒸发温度为357.83 K,窄点温差为5.02 K,提高系统热力性能和环境性能必然会降低其经济性能。     

Ash-forming elements in four Scandinavian wood species. Part 1: Summer harvest

Woody biomass in Finland and Sweden comprises mainly four wood species: spruce, pine, birch and aspen. To study the ash, which may cause problems for the combustion device, one tree of each species were cut down and prepared for comparisons with fuel samples. Well-defined samples of wood, bark and foliage were analyzed on 11 ash-forming elements: Si, Al, Fe, Ca, Mg, Mn, Na, K, P, S and Cl. The ash content in the wood tissues (0.2–0.7%) was low compared to the ash content in the bark tissues (1.9–6.4%) and the foliage (2.4–7.7%). The woods’ content of ash-forming elements was consequently low; the highest contents were of Ca (410–1340 ppm) and K (200–1310), followed by Mg (70–290), Mn (15–240) and P (0–350). Present in the wood was also Si (50–190), S (50–200) and Cl (30–110). The bark tissues showed much higher element contents; Ca (4800–19,100 ppm) and K (1600–6400) were the dominating elements, followed by Mg (210–2400), P (210–1200), Mn (110–1100) and S (310–750), but the Cl contents (40–330) were only moderately higher in the bark than in the wood. The young foliage (shoots and deciduous leaves) had the highest K (7100–25,000 ppm), P (1600–5300) and S (1100–2600) contents of all tissues, while the shoots of spruce had the highest Cl contents (820–1360) and its needles the highest Si content (5000–11,300). This paper presented a new approach in fuel characterization: the method excludes the presence of impurities, and focus on different categories of plant tissues. This made it possible to discuss the contents of ash element in a wide spectrum of fuel-types, which are of large importance for the energy production in Finland and Sweden.     

NEXT GENERATION ENGINEERED MATERIALS FOR ULTRA SUPERCRITICAL STEAM TURBINES

正1 ABSTRACT To reduce the effect of global warming on our climate,the levels of CO2emissions should be reduced.One way to do this is to increase the efficiency of electricity production from fossil fuels.This will in turn reduce the amount of CO2emissions for a given power output.Using US practice for efficiency calculations,then a move from a typical US plant running at 37%efficiency to a 760℃/38.5 MPa(1 400/5 580 psi)plant running at 48%efficiency would reduce CO2emissions by 170kg/MW.hr or 25%.     

Aerodynamic performance effects of leading-edge geometry in gas-turbine blades

The purpose of this paper is to illustrate the advantages of the direct surface-curvature distribution blade-design method, originally proposed by Korakianitis, for the leading-edge design of turbine blades, and by extension for other types of airfoil shapes. The leading edge shape is critical in the blade design process, and it is quite difficult to completely control with inverse, semi-inverse or other direct-design methods. The blade-design method is briefly reviewed, and then the effort is concentrated on smoothly blending the leading edge shape (circle or ellipse, etc.) with the main part of the blade surface, in a manner that avoids leading-edge flow-disturbance and flow-separation regions. Specifically in the leading edge region we return to the second-order (parabolic) construction line coupled with a revised smoothing equation between the leading-edge shape and the main part of the blade. The Hodson–Dominy blade has been used as an example to show the ability of this blade-design method to remove leading-edge separation bubbles in gas turbine blades and other airfoil shapes that have very sharp changes in curvature near the leading edge. An additional gas turbine blade example has been used to illustrate the ability of this method to design leading edge shapes that avoid leading-edge separation bubbles at off-design conditions. This gas turbine blade example has inlet flow angle 0°, outlet flow angle −64.3°, and tangential lift coefficient 1.045, in a region of parameters where the leading edge shape is critical for the overall blade performance. Computed results at incidences of −10°,   −5°,   +5°,   +10° are used to illustrate the complete removal of leading edge flow-disturbance regions, thus minimizing the possibility of leading-edge separation bubbles, while concurrently minimizing the stagnation pressure drop from inlet to outlet. These results using two difficult example cases of leading edge geometries illustrate the superiority and utility of this blade-design method when compared with other direct or inverse blade-design methods.     

Hydrogen production by steam-gasification of carbonaceous materials using concentrated solar energy – V. Reactor modeling,optimization, and scale-up

A chemical reactor for the steam-gasification of carbonaceous particles (e.g. coal, coke) is considered for using concentrated solar radiation as the energy source of high-temperature process heat. A two-phase reactor model that couples radiative, convective, and conductive heat transfer to the chemical kinetics is applied to optimize the reactor geometrical configuration and operational parameters (feedstock's initial particle size, feeding rates, and solar power input) for maximum reaction extent and solar-to-chemical energy conversion efficiency of a 5 kW prototype reactor and its scale-up to 300 kW. For the 300 kW reactor, complete reaction extent is predicted for an initial feedstock particle size up to 35 μm at residence times of less than 10 s and peak temperatures of 1818 K, yielding high-quality syngas with a calorific content that has been solar-upgraded by 19% over that of the petcoke gasified.     

Contents in Volume 23,2014

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汽轮机数字电液调节系统挂闸异常的技术完善

分析了200MW汽轮机数字电液调节系统在运行中存在的挂闸异常问题,采取了相应的技术处理措施,且运行实践效果良好。     

新型高压共轨ECU升压模块的数字化开发与优化

为了提高喷油器电磁阀的响应速率,提出了一种基于CPLD(复杂可编程逻辑器件)应用于高压共轨ECU的数字升压模块。鉴于该升压电路结构参数多,其升压电压的恢复响应要求高等特征,基于Pspice建立了升压电路的仿真模型,研究了不同电路参数下升压模块的输出特性,全面优化了该升压模块的性能。结果显示,该升压模块的最大转换效率可以达90%以上。在柴油发动机上对ECU的试验表明,升压电压最大波动不超过10%,其恢复时间仅为1.3ms,功率管最大温升仅为41℃,满足整机运行范围内ECU的需求。     

Trace metal chemistry and silicification of microorganisms in geothermal sinter, Taupo Volcanic Zone, New Zealand

As part of a pilot study investigating the role of microorganisms in the immobilisation of As, Sb, B, Tl and Hg, the inorganic geochemistry of seven different active sinter deposits and their contact fluids were characterised. A comprehensive series of sequential extractions for a suite of trace elements was carried out on siliceous sinter and a mixed silica-carbonate sinter. The extractions showed whether metals were loosely exchangeable or bound to carbonate, oxide, organic or crystalline fractions. Hyperthermophilic microbial communities associated with sinters deposited from high temperature (92–94°C) fluids at a variety of geothermal sources were investigated using SEM. The rapidity and style of silicification of the hyperthermophiles can be correlated with the dissolved silica content of the fluid. Although high concentrations of Hg and Tl were found associated with the organic fraction of the sinters, there was no evidence to suggest that any of the heavy metals were associated preferentially with the hyperthermophiles at the high temperature (92–94°C) ends of the terrestrial thermal spring ecosystems studied.     

Assessment methods of material ageing using Sdobyrev''s creep rupture model

The physical aspects of the activation energy, in higher and high temperatures, of the metal creep process were examined. The research results of creep-rupture in a uniaxial stress state and the criterion of creep-rupture in biaxial stress states, at two temperatures, are then presented. For these studies creep-rupture, taking case iron as an example the energy and pseudoenergy activation was determined. For complex stress states the criterion of creep-rupture was taken to be Sdobyrev's, i.e. σ_red = σ₁ β + (1 − β)σ_i, where: σ₁-maximal principal stress, σ_i-stress intensity, β-material constant (at variable temperature β = β(T)). The methods of assessment of the material ageing grade are given in percentages of ageing of new material in the following mechanical properties: 1) creep strength in uniaxial stress state, 2) activation energy in uniaxial stress state, 3) criterion creep strength in complex stress states, 4) activation pseudoenergy in complex stress states. The methods 1) and 3) are the relatively simplest because they result from experimental investigations only at nominal temperature of the structure work, however, for methods 2) and 4) it is necessary to perform the experimental investigations at least at two temperatures.     

Production of hydrogen from sewage biosolids in a continuously fed bioreactor: Effect of hydraulic retention time and sparging

Hydrogen was produced from primary sewage biosolids via mesophilic anaerobic fermentation in a continuously fed bioreactor. Prior to fermentation the sewage biosolids were heated to 70 °C for 1 h to inactivate methanogens and during fermentation a cellulose degrading enzyme was added to improve substrate availability. Hydraulic retention times (HRT) of 18, 24, 36 and 48 h were evaluated for the duration of hydrogen production. Without sparging a hydraulic retention time of 24 h resulted in the longest period of hydrogen production (3 days), during which a hydrogen yield of 21.9 L H₂ kg⁻¹ VS added to the bioreactor was achieved. Methods of preventing the decline of hydrogen production during continuous fermentation were evaluated. Of the techniques evaluated using nitrogen gas to sparge the bioreactor contents proved to be more effective than flushing just the headspace of the bioreactor. Sparging at 0.06 L L min⁻¹ successfully prevented a decline in hydrogen production and resulted in a yield of 27.0  L H₂ kg⁻¹ VS added, over a period of greater than 12 days or 12 HRT. The use of sparging also delayed the build up of acetic acid in the bioreactor, suggesting that it serves to inhibit homoacetogenesis and thus maintain hydrogen production.