共查询到19条相似文献,搜索用时 125 毫秒
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综述了玻纤增强热塑性复合材料界面结晶的形成机理及其研究进展,从结晶动力学的角度深入阐述了不同晶型(α晶和β晶)横晶的形成条件和结构特点,全面归纳了横晶形成的各种影响因素及研究者的不同观点,详细讨论了横晶对玻纤增强热塑性复合材料力学性能的影响,展望了热塑性复合材料界面结晶行为的研究动态。 相似文献
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研究了碳纤维(CF)表面阴离于接技尼龙6(PA6)对CF/PA 6复合材料界面形态的影响,考察了纤维表面、结晶温度对CF/PA 6复合材料界面形成横晶的影响.结果表明在低于初始结晶温度至接近熔点范围内,PA6在未接枝与接枝CF表面均可以形成横晶,结晶温度低形成的横晶不致密、不完整,纤维诱发横晶的能力小,结晶温度高形成的横晶完整而致密,纤维诱发横晶的能力大.在相对较低的结晶温度下,接枝CF比未接枝CF具有较高的诱发横晶能力,同时诱发的横晶致密度高及完整性好. 相似文献
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通过剪切诱导熔体结晶方法,制备了具有α球晶、α横晶和β横晶的等规聚丙烯(iPP)/玻璃纤维(GF)单纤维复合材料。利用单纤维断裂试验方法,测试了iPP/GF单纤维复合材料的界面剪切强度(IFSS),探讨了界面晶型对IFSS的影响。结果表明,界面为α球晶、α横晶和β横晶试样的IFSS依次增大。这说明界面结晶晶型对IFSS有显著的影响。 相似文献
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Cengiz Kaya Aldo R. Boccaccini Krishan K. Chawla 《Journal of the American Ceramic Society》2000,83(8):1885-1888
The present paper introduces a novel processing technique that involves in situ electrophoretic deposition (EPD), followed by pressureless sintering, to produce dense, defect-minimized, carbon-fiber-reinforced borosilicate-glass-matrix composites with a nickel interface. The process relies on the deposition of submicrometer-sized, colloidal charged particles onto unidirectionally aligned nickel-coated carbon fibers. The preparation and characterization of a kinetically stable nanosized borosilicate sol suitable for EPD are described. The most-important EPD processing parameters in the formation of dense, fully infiltrated, green-body compacts are described, and issues that concern the infiltration of very tight carbon fiber preforms are discussed and effectively solved. Using the crack-path-propagation test, the metallic nickel interface is determined to be very effective to improve the composite mechanical performance, in terms of the nonbrittle fracture behavior. Catastrophic crack growth is prevented by such mechanisms as constrained plastic deformation of the interface and fiber debonding and pullout. The proposed processing technique has great potential to fabricate defect-minimized and damage-tolerant fiber-reinforced brittle-matrix composites with a ductile interface. Overall, this new approach offers a cost-effective and short-time processing route for the fabrication of continuous-fiber-reinforced ceramic-matrix composites. 相似文献
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Markys G. Cain Rebecca L. Cain Michael H. Lewis John Gent 《Journal of the American Ceramic Society》1997,80(7):1873-1876
A novel in situ reaction between a ceria-doped zirconia interphase coating on Saphikon fibers and an outer alumina coating has resulted in the formation of oriented hexaaluminate platelets which can act as a low fracture energy interface barrier for crack deflection in oxide-oxide ceramic-matrix composites (CMCs). The reaction proceeds only in reducing environments where the reduction of the cerium and zirconium ions to their 3+ valent state causes a destabilization phenomenon consistent with previously reported findings. The diffusion of the cerium from the zirconia into solid solution with the alumina can stabilize the layered hexaaluminate structure. Preferred orientational growth of the hexaaluminate parallel to the coating interface was observed which is the required orientation for enhanced debonding at the fiber/matrix interface in long-fiber-reinforced CMCs. 相似文献
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M. Xanthos 《Polymer Engineering and Science》1988,28(21):1392-1400
The rapid growth in the use of multiphase polymer systems (blends and composites) is undoubtedly related to the availability of methods of controlling the physical and chemical interactions at the interface. Compounds acting as interfacial agents are commonly known as “compatibilizers” in blends, or “coupling agents” in composites; their function is to promote adhesion and enhance overall properties. This paper is a review of recent advances in the use of these compounds in immiscible polymer blends and thermoplastic composites. Polymeric compatibilizers are classified according to their method of addition (in situformation vs. separate addition) and reactivity. Reactive low molecular weight compounds are also listed and their various coupling mechanisms are discussed. It is demonstrated that common routes to enhanced adhesion exist for some types of blends and composites. For example, reactive graft copolymers and certain crosslinklng agents are equally effective as adhesion promoters in blends and composites containing a polyolefin phase. 相似文献
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Jianbao Hu Shaoming Dong Bin Wu Xiangyu Zhang Haijun Zhou Zhen Wang Yanmei Kan 《International Journal of Applied Ceramic Technology》2014,11(2):207-217
Cf/SiC composites were fabricated using fiber coatings including CNTs and matrix infiltration using the polymer impregnation and pyrolysis process. Interface between fiber and CNTs (CF/CNTs) was tailored to optimize mechanical properties of hybrid composites. The tailored interphases, such as Pyrocarbon (PyC) and PyC/SiC, protect fibers from degradation during the growth of CNTs successfully. Hybrid composites with well‐tailored CF/CNTs interface displayed significantly increased mechanical strength (352 ± 21 MPa) compared with that (34 ± 3 MPa) of composites reinforced with CNTs, which grown on carbon fibers directly. The interfacial bonding strength of hybrid composites was improved and optimized by tailoring the CF/CNTs interface. Interfacial failure modes were studied, and a firm interface bonding at the joint where CNTs grown was observed. 相似文献
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The morphologies of the fracture surface under impact and flexural testing of Mg(OH)2/Polypropylene (PP) composites and their modified composites were investigated by scanning electron microscopy. Experimental results indicated that addition of functionalized polypropylene (FPP) and acrylic acid (AA) and the formation of in situ FPP changed the fracture morphologies of Mg(OH)2/PP composites. We believe that addition of these modifiers improved the interfacial interaction and enhanced the interface adhesion between the particle and the matrix in Mg(OH)2/PP composites. The degree of improvement was more significant in Mg(OH)2/PP composites modified by the formation of in situ FPP. At low Mg(OH)2 content, 2 phr AA exhibited a marked effect, but at high Mg(OH)2 content, 4 phr AA afforded good effect. Due to the improved interface adhesion by interface interactions the fracture mechanism transformed from interface debonded fracture into a matrix fracture. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2148–2159, 2003 相似文献
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Haitang Yang Zilong Lu Bixiong Bie Zeyu Fu Jianling Yue Xiaozhong Huang 《Ceramics International》2019,45(9):11395-11402
SiCf/PyC/SiC and SiCf/BN/SiC mini-composites comprising single tow SiC fibre-reinforced SiC with chemical vapor deposited PyC or BN interface layers are fabricated. The microstructure evolutions of the mini-composite samples as the oxidation temperature increases (oxidation at 1000, 1200, 1400, and 1600?°C in air for 2?h) are observed by scanning electron microscopy, energy dispersive spectrometry, and X-ray diffraction characterization methods. The damage evolution for each component of the as-fabricated SiCf/SiC composites (SiC fibre, PyC/BN interface, SiC matrix, and mesophase) is mapped as a three-dimensional (3D) image and quantified with X-ray computed tomography. The mechanical performance of the composites is investigated via tensile tests.The results reveal that tensile failure occurs after the delamination and fibre pull-out in the SiCf/PyC/SiC composites due to the volatilization of the PyC interface at high temperatures in the air environment. Meanwhile, the gaps between the fibres and matrix lead to rapid oxidation and crack propagation from the SiC matrix to SiC fibre, resulting in the failure of the SiCf/PyC/SiC composites as the oxidation temperature increases to 1600?°C. On the other hand, the oxidation products of B2O3 molten compounds (reacted from the BN interface) fill up the fracture, cracks, and voids in the SiC matrix, providing excellent strength retention at elevated oxidation temperatures. Moreover, under the protection of B2O3, the SiCf/BN/SiC mini-composites show a nearly intact microstructure of the SiC fibre, a low void growth rate from the matrix to fibre, and inhibition of new void formation and the SiO2 grain growth from room to high temperatures. This work provides guidance for predicting the service life of SiCf/PyC/SiC and SiCf/BN/SiC composite materials, and is fundamental for establishing multiscale damage models on a local scale. 相似文献
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A functionally graded hybridization approach has been used in the formation of polymer-ceramic composites of polymethylmethacrylate (PMMA) and hydroxyapatite (HAp). HAp was successfully reinforced by sedimentary HAp distributions on a PMMA matrix using a centrifuge to avoid stress convergence on the interface. The stress-strain curves of the functionally graded PMMA-HAp composite showed sufficient mechanical strength with reduced brittleness. Scanning electron micrographs also showed evidence of exposed HAp on the surface of the composites. 相似文献
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将改性石蜡(NR)作为非反应性助偶联剂,考察了其对高密度聚乙烯/碳酸钙(HDPE/CaCO_3)复合体系中微观相界面的作用及其对体系物理机械性能的影响。结果表明:由于新的第3相界面的形成,一方面改善了CaCO_3与基体树脂之间的界面粘结状态,另一方面增加了CaCO_3与基体树脂之间的力学作用层厚度,促进了CaCO_3对HDPE树脂的增韧作用,使冲击强度得到大幅度的提高。NR的改性作用与基体树脂的韧性、偶联剂种类及其用量水平等有关。体系的缺口冲击强度因NR的加入有明显提高,对韧性较差的基体有明显的增韧效果。对拉伸强度影响较小,对弯曲强度略下降。若基体树脂韧性较好,NR可使HDPE/CaCO_3复合体系保持较好的综合物理性能。 相似文献
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A water-soluble sulfonated poly (ether ether ketone) (SPEEK) sizing agent is prepared and applied to improve the interfacial adhesion of carbon fiber/poly (ether ether ketone) (CF/PEEK) composites. The surface morphology, surface roughness, surface chemistries, and surface free energy of SPEEK sized CF are obtained to understand the sizing effect. The results reveal the increased surface free energy and surface roughness of SPEEK sized CF. In addition, a chemical reaction between the CF surface and sizing layer is proved based on the results of XPS, IR, and 1H NMR. The interfacial structure of CF/PEEK composites is further ascertained by AFM and the appearance of gradient interface could be verified for SPEEK sized CF/PEEK composites. The formation of the gradient interface is due to the chemical reaction between the CF and sizing agent as well as the improved compatibility between the sized CF and matrix, which benefits the improvement of interfacial adhesion. 相似文献