共查询到20条相似文献,搜索用时 218 毫秒
1.
采用模压成型制备了一系列聚氯乙烯(PVC)/氯化聚氯乙烯(CPVC)配比不同、无机刚性粒子含量不同的木塑复合材料。通过力学性能测试、热变形温度测试、扫描电子显微镜观察等手段对上述木塑复合材料的耐热性及力学性能进行了研究。结果表明,CPVC和无机刚性粒子均显著改善了PVC木塑复合材料的耐热性和力学性能。与PVC木塑复合材料相比,当PVC/CPVC配比为50/50,白云母或凹凸棒土的用量为3份时,改性木塑复合材料的热变形温度分别提高了14.3℃和19.7℃,且力学性能较好。凹凸棒土对木塑复合材料的耐热增强改性效果优于白云母。 相似文献
2.
《现代塑料加工应用》2017,(4)
通过亚临界乙醇辅助反应挤出法,以纳米有机膨润土和超细重质碳酸钙作为填料制备木塑复合材料,考察了亚临界乙醇对木塑复合材料力学性能的影响,并用傅里叶红外光谱和扫描电子显微对木塑复合材料进行了分析。结果表明,亚临界乙醇能改善木粉与聚丙烯(PP)之间的界面结合,在亚临界乙醇作用下,超细重质碳酸钙能更好地发挥增强增韧效果,当添加1份超细重质碳酸钙时,有亚临界乙醇制备的木塑复合材料的冲击强度比无亚临界乙醇的提高了34%。 相似文献
3.
针对废旧地膜资源化利用过程中出现的高成本和低性能问题,本文提出了废旧地膜免清洗和剑麻纤维边角料增强的废旧地膜资源化利用技术。采用挤出造粒和注塑成型工艺,制备了剑麻边角料填充含红土废旧聚乙烯复合材料,分析了红土和剑麻纤维边角料对废旧地膜的填充作用。结果表明,红土颗粒使废旧地膜注塑试样的拉伸模量、硬度和耐热温度分别提高了34.4%、41.3%、和33.1%。红土颗粒难以和塑料基体形成良好的界面粘结,导致含红土废旧地膜注塑试样的拉伸强度、弯曲性能和冲击强度轻微降低,表明红土颗粒不能对废旧地膜进行增韧增强,但可以提高模量和耐热温度。剑麻纤维边角料对含红土废旧地膜具有明显的增强增韧作用,随着剑麻纤维添加量的增加,剑麻纤维填充的含红土废旧地膜复合材料的力学性能增加。剑麻纤维填充量超过一定值后,会在复合材料中引入气孔,同时会降低剑麻纤维的分散程度,出现剑麻聚集体,导致复合材料的力学性能降低。 相似文献
4.
5.
以植物纤维、聚氯乙烯(PVC)为原材料制备植物纤维/PVC木塑复合材料,研究了植物纤维种类与含量及偶联剂含量对复合材料洛氏硬度、冲击强度、弯曲强度以及拉伸强度等力学性能的影响。结果表明,20%含量稻壳粉填充PVC木塑复合材料的硬度最大,40%含量稻壳粉填充PVC木塑复合材料硬度最小,复合材料的硬度几乎不随花生壳粉含量的变化而变化,20%含量稻壳粉填充PVC木塑复合材料的拉伸强度和弯曲强度都最大。植物纤维/PVC木塑复合材料的吸水性能随着稻壳粉和花生壳粉等植物纤维含量的增加而增强,50%含量稻壳粉/PVC木塑复合材料的吸水率最大。添加偶联剂的稻壳粉填充PVC木塑复合材料的力学性能有所提高,吸水性降低,在一定程度上提高材料的耐磨性能,降低损耗。 相似文献
6.
以植物纤维、聚氯乙烯(PVC)为原材料制备植物纤维/PVC木塑复合材料,研究了植物纤维种类与含量及偶联剂含量对复合材料洛氏硬度、冲击强度、弯曲强度以及拉伸强度等力学性能的影响。结果表明,20%含量稻壳粉填充PVC木塑复合材料的硬度最大,40%含量稻壳粉填充PVC木塑复合材料硬度最小,复合材料的硬度几乎不随花生壳粉含量的变化而变化,20%含量稻壳粉填充PVC木塑复合材料的拉伸强度和弯曲强度都最大。植物纤维/PVC木塑复合材料的吸水性能随着稻壳粉和花生壳粉等植物纤维含量的增加而增强,50%含量稻壳粉/PVC木塑复合材料的吸水率最大。添加偶联剂的稻壳粉填充PVC木塑复合材料的力学性能有所提高,吸水性降低,在一定程度上提高材料的耐磨性能,降低损耗。 相似文献
7.
《工程塑料应用》2020,(2)
以稻壳、竹粉、杨木粉作为聚乳酸(PLA)的增强材料,添加硅烷偶联剂进行界面处理,采用模压成型的方法制备PLA木塑复合材料,研究了纤维的种类与含量以及偶联剂对PLA木塑复合材料力学性能和吸水性能的影响,并采用体式显微镜对其形貌和结构进行了表征。结果表明,杨木粉对PLA复合材料的增强效果最好;杨木粉、稻壳、竹粉质量分数为30%时,PLA木塑复合材料的拉伸强度最大,分别为16.26,11.27,14.17 MPa,杨木粉质量分数为30%时PLA木塑复合材料的冲击强度最大,为4.44 kJ/m~2,随着复合材料中木粉含量的增加,其吸水率呈上升趋势;添加硅烷偶联剂改性使PLA/竹粉复合材料的拉伸强度最大提高了119.74%,冲击强度最大提高了86.52%,改性后的木塑复合材料各组分较为均匀、空洞和缺陷较少。 相似文献
8.
为了提高废纸的利用率,保护森林资源,开发绿色无污染的木塑复合材料,使用废弃纸箱和聚对苯二甲酸乙二酯–1,4–环己二甲酯(PETG)作为原料,利用烷基烯酮二聚体(AKD)对其进行改性制备木塑复合材料。选取碱处理浓度、时间、温度和AKD添加量四个方面进行实验,探究对PETG木塑复合材料力学性能、吸水性能和热稳定性的影响,并且结合红外和微观形貌表征,确定了对废纸纤维进行改性的木塑复合材料的最佳工艺为:NaOH溶液浓度15%,碱处理温度60℃,碱处理时间60 min,AKD最佳添加量为废纸粉质量的2%。 相似文献
9.
10.
11.
Natural fiber reinforced composites is an emerging area in polymer science. These natural fibers are low cost fibers with low density and high specific properties. These are biodegradable and nonabrasive. The natural fiber composites offer specific properties comparable to those of conventional fiber composites. However, in development of these composites, the incompatibility of the fibers and poor resistance to moisture often reduce the potential of natural fibers, and these draw backs become critical issue. Wood‐plastic composites (WPC) are a relatively new class of materials and one of the fastest growing sectors in the wood composites industry. Composites of wood in a thermoplastic matrix (wood–plastic composites) are considered a low maintenance solution to using wood in outdoor applications. WPCs are normally made from a mixture of wood fiber, thermoplastic, and small amounts of process and property modifiers through an extrusion process. In this study, Wood–plastic composites (WPC) are produce by adding a maleic anhydride modified low density polyethylene coupling agent to improve interfacial adhesion between the wood fiber and the plastic. Mixing is done with twin screw extruder. Subsequently, tensile strength, the modulus of elasticity, % elongation, hardness, Izod impact strength, melt flow index (MFI), and heat deflection temperature (HDT) are determined. Thermal transition temperatures and microstructure are determined with DSC and SEM, respectively. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
12.
《Polymer Composites》2017,38(10):2140-2145
Waste fiber reinforced polymer (FRP) combined with corn straw fiber was recycled and incorporated in wood plastic composite (WPC). The synergistic enhancement effect of glass fiber and corn straw fiber was investigated. The results show that there was a good physical interlocking structure among glass fiber of waste FRP, corn straw fiber and poly(vinyl chloride) (PVC) in WPC, which led to the enhancement of mechanical properties of WPC. With 30 phr (parts per hundreds of resin) waste FRP, the tensile strength and flexural strength of WPC were improved to 24 and 66 MPa, increased by 31% and 23% with respect to starting WPC. This study reveals that waste FRP and corn straw fiber can be good alternative for wood fiber in the production of WPC. POLYM. COMPOS., 38:2140–2145, 2017. © 2015 Society of Plastics Engineers 相似文献
13.
Foaming of wood fiber/plastic composites (WPC) with a fine‐celled structure can offer benefits such as improved ductility and impact strength, lowered material cost, and lowered weight, which can enhance their utility in many applications. Although a great deal of attention is now being focused on these composites in the scientific literature, there are still numerous aspects of WPC processing that need elucidation. In this context, this article investigates the effects of wood fiber (WF) size on fine‐celled extrusion foaming of WPC in terms of cell size, cell size distribution, and foam density. The effects of WF size and coupling agent content on the viscosity of WPC are also investigated. The experimental results revealed that the small‐sized WF provides a better cell morphology, a smaller cell size, and a better cell uniformity in WPC foams. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
14.
Fiber fillings of wood plastic composites (WPC) are almost exclusively limited to standard plastics such as polyethylene and polypropylene. At the Kunststofftechnik Paderborn of the University of Paderborn the wood fiber filling of engineering plastics is being promoted. WPC with different fiber types and fiber contents based on two thermoplastic polyurethanes (TPU) were compounded and subsequently characterized. We found that the physicochemical properties of the materials differ from standard plastic-based WPC. Wood filling with increasing fiber content did not immediately correlate with an increase in density. A decrease in density and swelling of the compound was detected with reaching a critical fiber content. Our compounds showed an increased water absorption at high-fiber contents over time, which can be described logarithmically. The observed viscosity curves obey the Ostwald and de Waele power law, but an increased viscosity at increased fiber content was not apparent for both TPU matrices. 相似文献
15.
16.
17.
18.
Gangjian Guo 《应用聚合物科学杂志》2020,137(26):48829
Foamed wood fiber/plastic composites (WPC) with a fine-cell structure offer many benefits compared with the unfoamed WPC, such as the reduced material cost and density, the improved toughness, and the enhanced processability. However, it is extremely challenging to achieve the desired density reduction and obtain a fine-cell structure simultaneously. One of the obstacles is that the volatiles released from the wood fiber (WF) during processing should be suppressed to ensure a fine-cell structure. Linear low-density polyethylene (LLDPE) has a relatively low melting temperature, and it can reduce the processing temperature and suppress volatiles when used as a polymer matrix for foamed WPC. This paper systematically investigates the foamability of LLDPE/WF composites in a continuous foam extrusion, with both a chemical blowing agent and a physical blowing agent (PBA). It turns out that the PBA-based foaming led to a smaller cell size and a narrower cell size distribution. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48829. 相似文献
19.
20.
木纤维增强热塑性复合材料的界面研究现状 总被引:1,自引:0,他引:1
综述了目前国内外关于木纤维增强热塑性复合材料界面的研究进展,介绍了常用的几种改善木塑复合材料界面相容性的方法,并分析了各自的优缺点。 相似文献