杯芳烃-SAW传感器检测有机磷响应特性研究

研究了以25-(硫代烷基烷氧基)-对叔丁基杯[4]芳烃自组装分子作为声表面波(SAW)化学传感器敏感膜材料的SAW双通道延迟线传感器对DMMP检测的敏感特性.实验结果表明杯芳烃-SAW传感器对DMMP有高的灵敏度、好的响应特性和重复性.     

SAW传感器对神经性毒剂及模拟剂的检测进展

基于压电效应和化学特异选择性的有机敏感材料的声表面波(SAW)传感器,因其具有体积小、响应时间快、选择性好、可集成度高等优点而成为对气体实时、在线检测的重要手段之一。介绍了SAW传感器在神经性毒剂及其模拟剂检测中的应用,重点从SAW传感器测试电路、敏感膜材料、成膜方法及信号处理等方面介绍此领域的研究现状,并对发展趋势进行了展望。     

间苯二酚杯[4]芳烃硫醚衍生物SAW分子印迹膜的合成

设计合成了用于检测有机磷类化合物的声表面波(SAW)间苯二酚杯[4]芳烃硫醚衍生物分子印迹敏感膜材料,对产物的化学结构进行了FTIR、TOF-MS和1H、13C NMR等多种手段的表征,对表征结果给予了合理的理论解释,证明了产物即为所设计的目标物,并以自组装分子印迹方法制备的SAW-MIP、SAW-Non-MIP传感器对DMMP进行了检测,证实了分子印迹的效果.     

SAW化学战剂传感器的研究进展

简要叙述了声表面波(SAW)化学战剂传感器的传感原理和研究进展.详细阐述了高Q低插损SAW振荡电路的设计、敏感膜材料和成膜技术的研究进展,指出了SAW化学战剂传感器发展的趋势.     

双端谐振型SAW气体传感器的优化设计

针对FPOL敏感膜ST切石英基底双端谐振型SAW传感器的频率响应特性和敏感机理进行了理论分析.采用P矩阵级联方法与微扰理论,系统地讨论了影响传感器频率响应特性与探测灵敏度的因素.研究结果表明:在优化设计传感器器件结构的基础上,还需合理选择敏感区宽度、敏感膜材料特性及厚度,以提高探测灵敏度、降低插入损耗.给出了优化后的器件结构和敏感膜参数,可对双端谐振型SAW传感器的设计号性能分析提供重要参考.     

基于超支化聚合物的声表面波化学毒剂传感器

基于声表面波（SAW）技术的化学毒剂传感器在检测下限、响应速度以及减小温度、湿度交叉敏感等方面还需进一步提高。提出了在SAW双端口谐振器上涂敷超支化聚合物的方法提高传感器的检测下限和灵敏度。通过建立Van Dyke模型,分析了敏感膜对SAW化学毒剂传感器Q值、插入损耗以及电路阻抗匹配的影响。利用谐振器代替延迟线,确保了器件具有插入损耗、高Q值的特点。实验证实,在谐振器的中心栅结构上涂覆聚合物可以减小粘弹性聚合物对谐振器插损、Q值以及输入输出阻抗的影响。对设计的化学毒剂传感器进行了沙林毒剂检测实验,采用315MHz的SAW谐振器结合超支化聚合物膜,检测沙林气体浓度为5．0mg／m^3。实验表明：这种传感器的灵敏度可达到600Hz／mg／m^3,响应时间为50s,恢复时间约为60s。     

SAW聚环氧氯丙烷传感器检测芥子气的研究

研究了以聚环氧氯丙烷为敏感膜的SAW双通道延迟线传感器对芥子气检测的实用性.实验结果表明气体浓度和膜厚之间存在一定的函数关系,并初步讨论了聚环氧氯丙烷敏感膜和芥子气之间的相互作用过程.     

声表面波气体传感器聚合物敏感膜材料的选择

聚合物敏感膜材料是声表面波（SAW）气体传感器应用最为广泛的膜材料。该文就聚合物敏感膜材料的吸附原理、物理性质以及线性溶解能关系（LESR）予以论述。给出了筛选和设计特种性能聚合物膜的方法．旨在为声表面波气体传感器选择或设计合适的聚合物敏感膜材料提供依据。     

一种谐振器型单端SAW湿度传感器测试系统

声表面波(SAW)传感器已经广泛应用在各个领域.本文介绍了一种基于改进皮尔斯振荡器,中心频率为433.92MHz的谐振器型单端SAW(SAWR)湿度传感器的测试系统,经测试该办法可有效抑制同频点传统SAW振荡器所产生的87MHz附近的谐波,并能有效提高输出信号的功率.本文采用有机复合材料酞菁铜(CuPc)掺杂聚乙烯吡咯烷酮(PVP)作为SAW传感器敏感膜进行了湿度测试,并讨论了膜层厚度对传感器特性的影响.     

一种采用穴番-A敏感膜的新型声表面波瓦斯传感器的研究

本文利用笼形超分子材料穴番-A对甲烷分子的特异性包合作用,提出了一种能够在室温下工作的采用穴番-A敏感膜的新型声表面波瓦斯传感器。设计研制了中心频率为300 MHz的低损耗、高Q值SAW谐振器,并以所研制的谐振器构成双通道差分振荡器。分别以点涂法和旋涂法在传感通道SAW谐振器表面进行了敏感膜的镀膜。通过实验观察对比了采用两种镀膜方式的SAW瓦斯传感器在常温下对5%甲烷气体的响应。实验结果显示点涂镀膜的传感器响应约为1 kHz,远大于旋涂镀膜方式。AFM表面形貌表征显示了敏感膜表面粗糙度是造成这一差异的主要原因。实验还研究了传感器对不同浓度甲烷气体的响应,结果表明传感器响应随气体浓度降低而减小,两者存在良好的线性关系,测试灵敏度为205 Hz/%,检测下限约为0.2%。     

Optical parameters of calix[4]arene films and their response to volatile organic vapors

The Langmuir-Blodgett (LB) technique was employed to produce thin LB films using an amphiphilic calix-4-resorcinarene onto different substrates such as quartz, gold coated glass and quartz crystals. The characteristics of the calix LB films are assessed by UV-visible, quartz crystal microbalance (QCM) and surface plasmon resonance (SPR) measurements. UV-vis and QCM measurements indicated that this material deposited very well onto the solid substrates with a transfer ratio of >0.95. Using SPR data, the thickness and refractive index of this LB film are determined to be 1.14 nm/deposited layer and 1.6 respectively. The sensing application of calixarene LB films towards volatile organic vapors such as chloroform, benzene, toluene and ethanol vapors is studied by the SPR technique. The response of this LB film to saturated chloroform vapor is much larger than for the other vapors. The response is fast and fully recoverable. It can be proposed that this sensing material deposited onto gold coated glass substrates has a good sensitivity and selectivity for chloroform vapor. This material may also find potential applications in the development of room temperature organic vapor sensing devices.     

Design considerations for plasmonic-excitation based optical detection of liquid and gas media in infrared

Surface plasmon resonance (SPR) sensor schemes based on silicon (Si) and chalcogenide glass are evaluated and compared for chemical as well as gas detection in a wide range of infrared (IR) wavelengths. The plasmonic characteristics in IR are critically dependent on the dispersive behavior of the coupling substrate material. The performance of sensor has been evaluated in terms of its intrinsic sensitivity (IS) that includes the FWHM and angular shift of SPR curve for a given change in refractive index of sensing medium. Both these materials are potential candidates for opening up new routes for detection in near- and mid-IR due to their strong dispersion capabilities as compared to normal silica-based glass. The IS of chalcogenide glass-based SPR sensor is found to be larger than Si-based one for a broad wavelength range of 700–2500 nm indicating that chalcogenide glass-based probe provides more sensitive as well as accurate sensing procedure than Si-based probe. Further, for both glasses, the single probe can be used for both aqueous as well as gaseous sensing. Furthermore, for both glasses, it is found that the values of IS are much larger for gaseous sensing in comparison to liquid sensing.     

Vic-dioximes: A new class of sensitive materials for chemical gas sensing

Vic-dioximes, a class of organic chemical compounds, are proposed and characterized for the first time as sensitive materials for volatile organic compound sensing with sorption based chemical gas sensors. Their peculiar sensing properties described in this work originate in the oxime functional group which is a powerful H bond donor interacting strongly but reversibly with H bond acceptors. These specific interactions result in a high preferential enrichment of analyte molecules with H bonding acceptor capabilities in the sensitive material. Accordingly, sensitivity and selectivity for these compounds of vic-dioxime based sensors are high. The advantageous sensing properties are demonstrated in this work with quartz crystal microbalance sensors using 11 selected volatile organic compounds and a set of vic-dioximes varied in their substituents. Vic-dioximes with short alkylthiol substituents were found highly sensitive to such H bond acceptors as organic amines, alcohols, and esters with partition coefficients up to 26,000. At the same time they showed low affinity for aromatic compounds and chlorocarbons. Vic-dioximes are considered powerful sensing materials and interesting for practical use in chemical gas sensor arrays.     

基于聚合物碳黑混合物气敏微传感器的研究

通过四种不同的聚合物敏感材料以及混合的碳黑修饰在梳状微电极上,可以得到这种新型的化学气敏电阻型微传感器,将这四种不同聚合物的微传感器分别对丙酮、乙醇、甲醇、甲苯四种有机类气体进行了测试,比较其电阻的相对变化率,利用其响应的主元分析可以将四种气体区分开,并且在一定范围内,电阻的相对变化率可呈一定的线性分布.     

基于TiO2的气体传感器研究进展

气体传感器在石油化工、环境监测、航空航天等领域有着广泛的应用。由于具有独特的物理化学性质,TiO2被广泛用于气体传感器敏感材料的研究。综述了基于TiO2气体传感器的研究进展,并重点就H2,NH3,H2 S,CO和NO2五种常见的气体进行了阐述。从基于TiO2气体传感器的材料制备、传感性能、传感机理和存在的问题等方面进行了讨论,并指出了基于TiO2的气体传感器发展趋势。     

长余辉发光材料在传感方面的应用

随着传感器的广泛应用,开发新的敏感材料成为目前的研究热点。俗称为夜光粉的长余辉发光材料在传感器方面的应用优点与现状进行了阐述,介绍了不同种类的长余辉发光材料特性及其在传感器方面的应用和测量原理,并对其发展前景进行了展望。     

平面直热式气敏元件及其表面修饰

采用液相掺Sb的共沉淀方法制备低阻SnO2 纳米微粉 ,以其为敏感材料掺入Pt2wt%及Au5 .4at %的催化剂 ,在Si衬底上制作了平面直热式气敏元件。利用 2 %的Co(NO3 ) 3 溶液作为修饰液对元件进行表面修饰 ,可制得对NH3 具有较高灵敏度及选择性的敏感材料。     

基于金属有机框架化合物的气体传感器研究进展

金属有机框架化合物(MOFs)多孔材料具有形貌的多样性和组成的可调变性等特点,已经在气体吸附分离和气体传感领域得到广泛应用.综述了近年来基于MOFs材料的气体传感器的研究进展,从MOFs材料的合成制备、传感性能和存在的问题等方面进行了讨论,并指出了基于MOFs的气体传感器发展趋势.     

PdO纳米材料制备及室温甲醛气敏特性研究

采用水热合成的方法,以氯化钯(PdCl2)为原料,十二烷基三甲基溴化铵(CTAB)为分散剂,制备得到了四方结构的PdO材料,并利用X-射线衍射(XRD)、电子扫描显微镜(SEM)对得到的PdO颗粒进行了表征与分析.将制得的PdO材料制成传感器,在静态配气系统中测得了PdO材料对挥发性有机化合物(VOC)气体甲醛的敏感特性.结果表明,该PdO材料能够在室温(25℃)下对甲醛有很好的响应特性,对10×10-6甲醛响应达到3.90,测试浓度为0.1×10-6时,响应可达到1.84.