Statistical study of the grid zone behavior in a shallow gas—solid fluidized bed using a mini-capacitance probe

The behavior of the grid zone in a shallow-air-sand fluidized bed was studied by means of a mini-capacitance probe coupled with the on-line correlation technique. Experiments were carried out in a bed with a diameter of 203 mm. The bed had a height of 50 mm and was operated at different air flow rates. A perforated “plexiglas” plate with a hole diameter of 1.59 mm and a thickness of 9.53 mm was used as the distributor. The technique has been found to be effective in determining locally or microscopically the jet penetration depth and the dead zone height. The phenomenon of jetting in a shallow gas—solid fluidized bed is described semi-quantitatively.     

大型射流流化床的流型转变与射流深度

在高 8m、直径 0 .5m的大型射流流化床中 ,通过摄像分析法 ,研究了射流、喷流两种流型的转变 .结果表明在低静床高、大射流气速下易出现喷流 ;喷流出现时 ,功率谱主频射流气速曲线上出现一转折点 .转折点射流气速与摄像法得出的流型转变射流气速相同 .提出了射流、喷流流型转变关系式 .同时发现射流深度随射流气速变大而增大 ,结合二维射流床射流深度的研究结果 ,得出了射流深度的预测式     

内循环微型流化床流动特性

针对开发适用于化学气相沉积反应动力学研究的微型流化床反应分析仪的应用需求,研究了外径为30 mm的内循环微型流化床中气固流动特性,具体考察了中心射流管伸入高度、内导流管直径和颗粒装载量对实现固体物料内循环的最小操作气速和导流管与环隙区间窜气的影响。结果表明,随着射流管伸入高度的增大,实现颗粒内循环流动的最小操作气速变大;存在最优的导流管直径（20 mm）,使得实现颗粒环流的最小操作气速较小;增大颗粒装载量有利于降低颗粒内循环的最小操作气速。通过检测示踪气体在环隙区内的质谱信号,发现在所考察的参数范围内,反应器底部不存在导流管区向环隙区的窜气;在反应器上部,由于颗粒对气体的夹带,环隙区上部总能检测到示踪气体,且窜气特性随操作气速的增大而增强。研究结果可为设计适用于化学气相沉积反应的内循环微型流化床反应器提供参考。     

MULTI-SCALE MASS TRANSFER MODEL FOR GAS-SOLID TWO-PHASE FLOW

This article is devoted to analyzing the mass transfer in heterogeneous gas-solid flow by means of structure and process decomposition. A multi-scale mass transfer model was developed on the basis of the hydrodynamics calculated from the so-called EMMS model. This resulted in the predictions of the steady-state two-dimensional concentration distributions of sublimated substance as well as total mass transfer coefficient for circular concurrent gas-solid contactors. The predictions were validated by experimentally measured (via an on-line HP GC-MS system) axial concentration distributions of sublimated naphthalene in air in a circulating fluidized bed riser 3.0 m in height and 72 mm in diameter. The experiment also obtained mass transfer coefficients comparable to theoretical predictions under conditions with various gas velocities, solid circulation rates, particle sizes, and active material fractions in the particles. Both the theoretical and experimental results demonstrated that the heterogeneous flow structure prevailing in the concurrent gas-solid flow greatly influenced the flow's mass transfer.     

大型双射流流化床的流体动力学特性

在Ф0 .5m× 8m大型双射流流化床中 ,通过摄像、放像逐帧分析法和sthVCD软件分析录像转换的VCD ,得到了不同管间距下双射流典型的运动图像 .同时研究了两射流独立存在区、过渡区和射流合并区 3种流型的相互转变 ,得出了流型转变的关系式 .不同射流管间距下相同射流气速的射流深度相比 ,管间距减小则射流深度减小 ;在较小的管间距和相对高的射流气速下 ,两射流在射流深度之内始终合并 ,表现为射流合并高度 .得出了射流深度、射流合并高度的定量关系式 .分数维关联维数表明大型双射流流化床是一个确定性混沌系统 ,考查了管间距、静床高度对关联维数的影响     

Experimental and numerical study of fluid dynamic parameters in a jetting fluidized bed of a binary mixture

The solid circulation pattern, the voidage profile, and the jet penetration height have been investigated experimentally and computationally in a cold-flow model of jetting fluidized beds (JFBs) of a binary mixture in this paper. This rectangular two-dimensional bed is 0.30 m wide and 2.05 m high with a central jet and a conical distributor, which roughly stands for the ash-agglomerating fluidized-bed coal gasifier. A video camera and coloured particle tracer method were employed to explore the fluid dynamics in the bed. In terms of the average physical properties of binary mixtures, a hydrodynamic model describing the gas-solid flow characteristics in a jetting bed is resolved by using a modified Semi-Implicit Method for Pressure-Linked Equation (SIMPLE) algorithm. This paper focuses on three features of the fluid dynamics—solid circulation pattern, voidage profile, and jet penetration height. The solid circulation pattern is composed of three regions: the jetting region, the bubble street, and the annular region. Above the central nozzle the time-averaged isoporosity contours are almost elliptic, while near the walls of the bed, the voidage in high solid concentration region is approximately equal to that at the minimum fluidization state. The jet penetration height increases with increasing jet gas velocity and with decreasing average particle diameter. The increase in weight percentage of the lighter component in the binary system reveals that reduction of average density causes the enlargement of jet penetration height. The simulated results show good agreement with the experimental data.     

Euler multiphase-CFD simulation on a bubble-driven gas–liquid–solid fluidized bed

An integrated flow model was developed to simulate the fluidization hydrodynamics in a new bubble-driven gas–liquid–solid fluidized bed using the computational fluid dynamic (CFD) method. The results showed that axial solids holdup is affected by grid size, bubble diameter, and the interphase drag models used in the simulation. Good agreements with experimental data could be obtained by adopting the following parameters: 5 mm grid, 1.2 mm bubble diameter, the Tomiyama gas–liquid model, the Schiller–Naumann liquid–solid model, and the Gidaspow gas–solid model. At full fluidization state, an internal circulation of particles flowing upward near the wall and downward in the centre is observed, which is in the opposite direction compared with the traditional core-annular flow structure in a gas–solid fluidized bed. The simulated results are very sensitive to bubble diameters. Using smaller bubble diameters would lead to excessive liquid bed expansions and more solid accumulated at the bottom due to a bigger gas–liquid drag force, while bigger bubble diameters would result in a higher solid bed height caused by a smaller gas–solid drag force. Considering the actual bubble distribution, population balance model (PBM) is employed to characterize the coalescence and break up of bubbles. The calculated bubble diameters grow up from 2–4 mm at the bottom to 5–10 mm at the upper section of the bed, which are comparable to those observed in experiments. The simulation results could provide valuable information for the design and optimization of this new type of fluidized system.     

网格尺度、时间步长和颗粒堆积率对射流床CFD模拟的影响

采用欧拉-欧拉双流体模型,在CFX4.4软件上增加用户自定义子程序模拟了高2.0 m、宽0.3 m的二维射流床内空气和玻璃珠体系的流体动力学特性. 考察了网格尺度、最大颗粒堆积率和时间步长对射流的形成及发展过程、射流穿透深度及射流频率的影响,并与实验数据进行了对比. 结果表明,对于本研究的气固体系,当床层下部纵向网格数为100、时间步长0.0005 s时,不仅可以满足网格尺度和时间步长的无关性要求,而且模拟的射流穿透深度和射流频率与实验测量值的误差分别为5.7%和3.8%. 最大颗粒堆积率在本研究范围对模拟结果的影响可以忽略.     

Numerical simulation of single and multiple gas jets in bubbling fluidized beds

The behavior of single and multiple horizontal gas jet injections into a rectangular bubbling fluidized bed are studied with three-dimensional numerical simulations. The jet penetrations as well as the interactions between the jet and the surrounding gas, solids, bubbles, and other jets are investigated. As far as the average jet penetration length is concerned, limited influence of each jet on the others is observed in multiple jet injections until the jets start to overlap. The effect of the secondary gas injection on the flow hydrodynamics in the bed is examined for multiple jet injections with different jetting velocities and arrangements. It is found that the secondary gas injection mainly affects the hydrodynamics of the upper section above the injection level, while its effect is nearly negligible below the injection. Above the injection level, more particles are brought upward and the circulation of solids is promoted. Furthermore, the tendency of slugging inside the bed is observed at high secondary injection flow rates.     

湍动流化床过渡段固含率分布特征的实验及数值模拟

在湍动流化床中,过渡段对于包括甲醇制烯烃在内的气固催化快反应有着重要的作用。采用PV6D反射型光纤探针对内径95 mm的湍动流化床内过渡段的固含率分布和脉动参数进行了测量,分别考察了表观气速和静床高的影响,并采用修正的基于颗粒动力学的三段曳力双流体模型进行模拟。实验表明,湍动流化床过渡段中固含率的轴向分布呈现S型和指数型两种类型,固含率轴向与径向分布都在过渡段内出现最大梯度,表明过渡段中固体浓度分布比稀相段和密相段更不均匀。表观气速和静床高的变化将导致S型和指数型分布的相互转变,并且对过渡段底部与壁面附近的固体高浓度区影响最为显著。局部固含率脉动概率密度分布表明,在静床高较小时,随着气速的增大,床层下部气含率最大值位置将从中心区移动至环隙区,呈现气含率的双峰型分布。本文提出的修正三段曳力模型考虑了颗粒团聚的影响,对过渡段中分布板影响区之外的固含率分布均能较好地模拟。     

EFFECT OF PARTICLE SIZE DISTRIBUTION ON LOCAL VOIDAGE IN A BENCH-SCALE CONICAL FLUIDIZED BED DRYER

The effect of particle size distribution (PSD) on local voidage has been investigated in a conical fluidized bed containing dried placebo pharmaceutical granule. For each of the five PSDs examined, the static bed height was varied between 0.12 and 0.17 m and the superficial gas velocity was varied between 0.05 and 0.75 m/s. The local voidage was measured using a twin-plane electrical capacitance tomography (ECT) system. A wide PSD containing 12 wt% solids with a diameter of 2 mm or larger resulted in two different types of gas flow: an annular gas flow up to a gas velocity of 0.50 m/s and a centrally concentrated gas flow above 0.50 m/s. The mixtures containing less coarse material exhibited a centrally concentrated gas flow surrounded by a dense phase at the walls of the bed over the entire range of gas velocities and bed heights examined. Consideration of previous work by other researchers suggests that the behavior of the wide PSD mixture is due to segregation at the lower velocities. The local voidage was sensitive to small changes in static bed height. For the wide PSD mixture at a fixed gas velocity, the gas tended to spread more uniformly over the bed cross-section as static bed height increased. The opposite was true of the other mixtures, i.e., the gas flow became more centralized with increasing bed height.     

Hydrodynamic studies on three-phase fluidized bed using CFD analysis

Three-phase fluidization refers to fluidization of solid particles by co-current, upward flow of gas and liquid-phases for the purpose of bringing three-phases in contact in a single operation. Due to complications in understanding hydrodynamics of three-phase fluidized bed, CFD analysis is used to predict the hydrodynamics of it. In this study, liquid-phase is water which flows continuously, where as the gas phase is air which is distributed discretely throughout the bed. Ceramic particle of 1 mm diameter, density of 2650 kg/m³ is used as a solid phase. Excellent mixing, heat and mass transfer rates are the unique features of three-phase fluidized bed. The selection of distributor plays an important role in the quality of fluidization [1]. CFD model is created as the realistic representation of actual fluidized bed. The liquid and solid flow is represented by the mixture model. The air is injected from the bottom of the fluidized by means of discrete phase method (DPM). Simulation results are obtained by using porous jump and porous zone model to represent the distributor. It is found that porous zone model is best applicable in the industries, since stability of operating conditions is achieved even with non-uniform air, water flowrates and with different bed heights(100 mm, 200 mm, 300 mm, 400 mm and 500 mm).Simulated Pressure drop values of the fluidized bed have good agreement with the experimental findings. As the gas flowrate increases, the pressure drop in the column is decreases, provided the initial bed height, diameter of the column, and liquid flowrate are constant. This is due to decrease in density of the fluid medium in the bed by means of more gas hold up. The approach of the simulated values to the experimental values can be reduced with better understanding the nature of the fluidized bed.     

Simulation and experimental studies on fluidization properties in a pressurized jetting fluidized bed

The influence of pressure on the bubble size and average bed voidage has been investigated experimentally and computationally in a circular three-dimensional cold-flow model of pressurized jetting fluidized bed of 0.2 m i.d. and 0.6 m in height with a central jet and a conical distributor, which roughly stands for the ash-agglomerating fluidized bed coal gasifier. The pressurized average bed voidage and bubble size in the jetting fluidized bed were investigated by using electrical capacitance tomography (ECT) technique. The time-averaged cross-sectional solids concentration distribution in the fluidized bed was recorded. The influence of pressure on the size of bubble and the average bed voidage in a pressurized fluidized bed was studied. Both experimental and theoretical results clearly indicate that there is, at the lower pressure, a small initial increase in bubble size decided by voidage and then a decrease with a further increase in pressure, which proves the conclusion of Cai et.al. [P. Cai, M. Schiavetti, G. De Michele, G.C. Grazzini, M. Miccio, Quantitative estimation of bubble size in PFBC, Powder Technology 80 (1994) 99-109]. At higher pressure, bubbles become smaller and smaller because of splitting. The average bed voidage increases gradually with the pressure at the same gas velocity. However, there is a disagreement between the experimental results and simulation results in the average bed voidage at the higher gas velocity, especially at the higher pressure. It suggests that the increase in density of gas with pressure may result in the drag increase and the drag model needs to be improved and revised at higher pressure.     

Batch Drying Kinetics in a Two-Zone Bubbling Fluidized Bed

This article deals with investigation and modeling of batch drying process of solids in fluidized bed apparatus. There has been used model of fluidized bed drying, which consists two zones: emulsion zone and bubbling zone with taking into consideration the presence of solid particles in the bubbles. The results of theoretical expectations that arise from simulation calculations have been verified with experimental data obtained with the use of fluidized bed dryer 0.225 m in diameter. A drying process of silica gel, sand, and ammonium sulfate has been tested. To verify the model, the concept of a generalized drying curve has also been employed.     

Influence of ash agglomerating fluidized bed reactor scale‐up on coal gasification characteristics

To study the influence of fluidized‐bed reactor scale‐up on coal gasification characteristics, a model of the ash agglomerating fluidized‐bed reactor has been developed using an equivalent reactor network method. With the reactor network model, the scale‐up effects of a gasifier were studied in terms of the characteristics of the chemical reactions in the jet zone, the annulus dense‐phase zone and the freeboard zone. Results showed that the changes occurred in the inequality proportion of the volume of the jet zone during the reactor scale‐up. Taking into consideration the utilization of a portion of the backflow gas, the expansion of the jet zone volume and the coal particle residence time, the temperature of the jet zone was increased from 1592 to 1662 K. Also, both the annulus dense‐phase zone temperature and the freeboard zone temperature decreased, causing subsequent decrease in the carbon conversion efficiency. © 2014 American Institute of Chemical Engineers AIChE J, 60: 1821–1829, 2014     

Numerical modeling of a jetting fluidized bed gasifier and the comparison with the experimental data

A model for a jetting fluidized bed gasifier is developed, treating the grid, bubble and freeboard zones in series. Reactions including char combustion, steam gasification, CO₂ gasification and water–gas shift reaction are taken into account. The effects on model predictions of assumptions regarding the primary products of char combustion and char reactivity factor are analyzed by comparing the predictions with experimental data from a bench-scale jetting fluidized bed gasifier using different kinds of chars. Contributions of various reactions and different zones and phases to carbon conversion are analyzed.     

Experimental study on drop formation in liquid-liquid fluidized bed

Drop formation in liquid-liquid fluidized bed was investigated experimentally. The normal water was injected via a fine-capillary spray nozzle into the co-flowing No. 25 transformer oil with jet directed upwards in a vertical fluidized bed. Experiments under a wide variety of conditions were conducted to investigate the instability dynamics of the jet, the size and size distribution of the drops. Details of drop formation, drop flow patterns and jet evolution were monitored in real-time by an ultra-high-speed digital CCD (charge couple device) camera. The Rosin-Rammler model was applied to characterize experimental drop size distributions. Final results demonstrate that drop formation in liquid-liquid system takes place on three absolutely different developing regimes: bubbling, laminar jetting and turbulent jetting, depending on the relative Reynolds number between the two phases. For different flow domains, dynamics of drop formation change significantly, involving mechanism of jet breakup, jet length pulsation, mean size and uniformity of the drops. The jet length fluctuates with time in variable and random amplitudes for a specified set of operated parameters. Good agreement is shown between the drop size and the Rosin-Rammler distribution function with the minimum correlation coefficient 0.9199. The mean drop diameter decreases all along with increasing jet flow rate. Especially after the relative Reynolds number exceeds a certain value about 3.5×10⁴, the jet disrupts intensely into multiple small drops with a diameter mainly ranging from 1.0 to and a more and more uniform size distribution. The turbulent jetting regime of drop formation is the most preferable to the dynamic ice slurry making system.     

Mass transfer in liquid-fluidized and spouted beds of ion exchange resin at low Reynolds number

Rates of mass transfer from the liquid phase to small ion exchange resin particles (0.78 mm in mean diameter) in fluidized and spouted beds were studied experimentally. Dilute aqueous solution of sodium hydroxide was fed into the beds of strong cation exchange resin and the exit concentration of the solution was determined by conductivity measurement. In spouted beds, the initial conversion and K_l increased with bed height, but decreased with fluid flowrate. The model, applying material balance of the reactant and axisymmetric flow of fluid in the annulus of a spouted bed, predictions of the initial conversion in spouted beds are satisfactory. In fluidized beds, the obtained mass transfer coefficients were correlated and compared with other works.     

Numerical simulation of horizontal jet penetration in a three-dimensional fluidized bed

The introduction of reactant gas as a jet into a fluidized bed chemical reactor is often encountered in various industrial applications. Understanding the hydrodynamics of the gas and solid flow resulting from the gas jet can have considerable significance in improving the reactor design and process optimization. In this work, a three-dimensional numerical simulation of a single horizontal gas jet into a cylindrical gas-solid fluidized bed of laboratory scale is conducted. A scaled drag model is proposed and implemented into the simulation of a fluidized bed of FCC particles. The gas and particles flow in the fluidized bed is investigated by analyzing the transient simulation results. The jet penetration lengths of different jet velocities have been obtained and compared with published experimental data as well as with predictions of empirical correlations. The predictions by several empirical correlations are discussed. A good agreement between the numerical simulation and experimental results has been achieved.     

射流流化床中锥形分布板对流动的影响

给出了具有锥形分布板的射流流化床中浓密气固两相流动的多相流体力学基本方程组. 采用二维正交曲线坐标并生成了数值网格,用改进的IPSA方法求解二维正交曲线坐标中的多相流基本方程组,并编制了大型通用程序,流场可视化使用Tecplot软件. 对于给定的模拟计算,计算结果与实验值吻合. 模拟计算中改变了锥形筛板的角度、射流管的直径、床层高度、分布板开孔率的分布、射流气速、床层表观气速等,通过模拟得到床内的流动图像,考察了射流高度及颗粒循环的影响.