FeS/铜基复合材料摩擦磨损性能研究

通过粉末冶金方法制备含Fe S的铜基复合材料,采用M-200型摩擦磨损试验机,分别在干摩擦和浸油干摩擦条件下对其摩擦磨损性能进行检测。结果表明:Fe S/铜基复合材料在2种工况条件下均具有一定的减摩效果,并且随着Fe S含量的增多,摩擦副摩擦因数越来越小;在浸油干摩擦条件下,当Fe S含量较高时,润滑油与Fe S转移膜共同作用形成液-固润滑膜,边界润滑效果较好。     

纳米ZrO2改性热塑性聚酰亚胺复合材料的摩擦磨损性能

采用热模压工艺制备了纳米ZrO2改性热塑性聚酰亚胺(PI)纳米复合材料,考察了复合材料的力学性能、在干摩擦和油润滑条件下的摩擦磨损性能,并利用扫描电子显微镜观察了冲击断面和磨损表面形貌.结果表明:纳米ZrO2在低含量下对PI复合材料的力学性能影响不大,随着其含量的增大,材料的弯曲性能下降,刚性增大.在干摩擦条件下,较低的纳米颗粒含量有助于转移膜的形成,从而降低材料的摩擦因数及磨损率.纳米ZrO2体积分数为1%时,材料的摩擦磨损性能较纯PI分别下降了50%和15%;在油润滑条件下,润滑油的流动性有助于纳米颗粒分布到整个摩擦界面,PI复合材料的摩擦因数及磨损率有明显降低,此时磨损机制以疲劳磨损为主.     

聚氨酯和聚四氟乙烯的摩擦磨损性能试验研究

为提高现代密封行业中广泛应用的新型聚氨酯(PU)和聚四氟乙烯(PTFE)的密封性能,对其润湿性和摩擦磨损性能进行对比实验,并分析不同摩擦状态下的磨损性能,讨论接触压力和转速的影响。研究表明,聚氨酯的润湿性比聚四氟乙烯好;聚氨酯的耐磨性明显高于聚四氟乙烯,在干摩擦、滴油润滑和浸油润滑的试验条件下,聚氨酯都无明显磨损。干摩擦条件下,聚四氟乙烯的磨损主要受摩擦环转速的影响;滴油润滑条件下,摩擦环转速和接触压力对聚四氟乙烯的磨损都有一定影响;浸油润滑条件下,聚四氟乙烯的磨损主要受接触压力的影响。     

铁基材料表面粘结润滑涂层摩擦学性能研究

为改善铁基粉末冶金材料的摩擦磨损性能,在其表面制备了复合粘结润滑涂层,分别在干摩擦和油润滑条件下进行摩擦磨损试验与分析,结果表明:石墨、二硫化钼两者有协同作用,复合粘结润滑涂层具有良好的润滑减摩性能,油润滑条件下,涂层以石墨含量较多者为佳,干摩擦条件下,涂层以MoS2含量较多者为佳,采用硅烷偶联剂处理后,进一步提高了复合涂层的减摩耐磨性能和承载能力.     

添加聚四氟乙烯微粉后聚醚醚酮复合材料的摩擦学性能

采用常温机械共混+高温模压方法制备了添加不同含量聚四氟乙烯(PTFE)微粉聚醚醚酮复合材料,研究了其力学性能、摩擦磨损性能及磨损形貌,并探讨了其摩擦磨损机理。结果表明:随PTFE微粉含量的增加,复合材料的洛氏硬度和压缩强度均降低,干摩擦条件下的摩擦因数减小,体积磨损量先降后升,当PTFE微粉质量分数5%时,体积磨损量最低;在油润滑和水润滑条件下复合材料的摩擦因数和体积磨损量均小于干摩擦条件下的,且随PTFE微粉含量的增加,油润滑条件下的体积磨损量下降,而水润滑条件下的增大;在干摩擦条件下复合材料的磨损机制以磨粒磨损为主,并伴有疲劳磨损,在油润滑条件下复合材料表面存在少量片状PTFE磨屑和碳纤维富集,在水润滑条件下复合材料表面被PTFE微片层覆盖,局部存在微裂纹和孔洞。     

GCr15钢渗硫层的摩擦学性能研究

利用低温离子渗硫技术在GCr15钢球表面形成渗硫层以提高其摩擦学性能。采用四球摩擦试验机,考察渗硫和未渗硫试样在干摩擦及油润滑条件的摩擦学性能。结果表明：在干摩擦和油润滑条件下渗硫试样的摩擦因数均远低于未渗硫试样;在干摩擦条件下,渗硫试样的磨损率相比未渗硫试样大幅下降,这主要归因于渗硫层良好的减摩抗磨作用;在油润滑条件下,因油润滑和渗硫层的固体润滑相互协调作用,渗硫试样的摩擦和磨损性能明显优于未渗硫试样,其磨损表面的痕迹浅而轻,磨损机制为轻微的磨粒磨损。     

粘结固体润滑涂层在油润滑条件下的摩擦学性能

为了探讨粘结MoS2基固体润滑涂层在油润滑条件下的抗磨减摩性能,采用MHK-500型摩擦磨损试验机对粘结MoS2基固体润滑涂层在4种常用油(液体石蜡、RP-3煤油、4050滑油和CD-40柴油)润滑下的摩擦磨损性能进行了研究,考察了速度和载荷对润滑涂层在4种不同的常用油润滑下的摩擦磨损性能。结果表明,在低载荷(320N)试验条件下,4种常用油润滑下涂层的耐磨性比干摩擦下得到显著的提高,摩擦因数从0.12降低到0.08左右;但在高载荷(1100N)下,油润滑对涂层的摩擦磨损性能没有明显的改善。只有在合适的载荷下,固/油复合润滑技术可明显改善摩擦副的润滑性能。     

碳纤维增强聚酰亚胺在海水润滑下的摩擦学性能

利用MCF-10耐海水腐蚀摩擦磨损试验机考察不同含量碳纤维(CF)增强的聚酰亚胺(PI)聚合物在海水润滑条件下的摩擦磨损性能,并利用扫描电子显微镜(SEM)观察磨损表面形貌,分析材料磨损机制。结果显示,CF填料能够有效地提高PI在海水中的耐磨性,其耐磨性能随着CF添加量的增加先上升后下降,当CF体积分数为20%时,PI复合材料的抗磨性能最好,这是因为耐磨性好的CF承担了摩擦过程中的大部分载荷,抑制了PI的磨损;CF的加入增强了PI复合材料对对偶面的刮擦和犁耕作用,导致摩擦因数升高并出现较大幅度的振荡,不同CF添加量的PI复合材料的摩擦因数差不大;纯PI的磨损主要表现为黏着磨损和机械犁耕,CF增强PI的磨损主要是基体的磨粒磨损和填料的磨平和折断。     

稀土化合物改性复合材料在油润滑下的摩擦学性能

以竹纤维为增强相,通过稀土化合物改性制备一种树脂基复合材料;采用环块式摩擦磨损实验,研究稀土化合物改性复合材料在油润滑状态下载荷、转速对试样摩擦学性能的影响,以及稀土化合物改性对复合材料试样摩擦学性能的影响;比较干摩擦状态和油润滑状态下复合材料的摩擦学性能,观察和分析试样磨损表面形貌,探讨其磨损机制。实验结果表明:油润滑条件下,稀土化合物改性复合材料的摩擦因数和磨损率都随着载荷的增大而增加;较高载荷下摩擦因数随着转速的增大先增加后减小,而磨损率则呈现逐步增加的趋势;稀土化合物的改性使竹纤维和基体界面结合更为紧密,提高摩擦因数的同时降低了磨损率;在油润滑作用下,试样磨损由干摩擦时的磨粒磨损和疲劳磨损转变成为轻微的疲劳磨损;在油润滑状态下,复合材料处于边界润滑状态,故摩擦因数和磨损率均低于干摩擦。     

大比压油润滑条件下C/C复合材料的摩擦特性

研究C/C复合材料在油润滑下的摩擦磨损性能,测试C/C复合材料在大比压油润滑条件下的摩擦因数,并与干摩擦工况进行对比。结果表明:在载荷500~720 MPa、速度300~1 200 r/min工况下,油润滑条件下C/C复合材料的摩擦因数在0.1~0.17之间,而在干摩擦条件下摩擦因数在0.13~0.27之间,表明在油润滑条件下C/C复合材料表现出更优的摩擦特性;与油润滑相比,干摩擦条件下C/C复合材料表面的碳纤维显现出明显的磨损痕迹,表明C/C复合材料在油润滑条件下具有更好的耐磨性。     

Ag-G-MoS2复合材料在不同气氛下的摩擦磨损性能研究

采用粉末冶金方法制备银-二硫化钼-石墨复合材料,考察了不同成分的复合材料在大气与气氛中的摩擦磨损性能,分析讨论了成分改变对材料摩擦磨损性能的影响。实验表明:随着二硫化钼与石墨含量比的增大,复合材料在大气中的减摩性能逐渐减弱,耐磨性由于受到材料力学性能与摩擦机理的共同作用,变化不大,在N2气氛中的复合材料的减摩性增强,硬度增大,磨损率下降。对比结果表明,银-石墨(体积分数为20%)-二硫化钼(体积分数为10%)在不同气氛下的摩擦磨损性能较好且稳定。     

铜包石墨含量对铜锰铝复合材料摩擦磨损性能的影响

为改善铜锰铝合金的烧结性能,并提高其在干摩擦下的摩擦磨损性能,以铜包石墨作为自润滑相加入到铜锰铝合金中,采用等离子真空压力烧结方法制备铜锰铝/石墨复合材料,分析铜包石墨含量对复合材料的密度、硬度的影响,探讨不同复合材料在干摩擦和油润滑条件下的摩擦磨损性能.结果表明:相比真空和氢气还原气氛下的烧结方式,等离子体烧结铜锰铝...     

Corrosive wear characteristics of bronze friction resisting composites

Abstract

Three groups of bronze based composites with different amounts of slide additive (graphite) and friction additives (SiC and SiO₂) were prepared by powder metallurgy technique. The corrosive wear behaviours of the resulting composites in electrochemical aqueous solutions, namely, acidic rain, neutral rain and wastewater, were comparatively investigated. The corrosive wear mechanisms of the bronze composites were discussed based on examination of the worn surface morphologies of the composite block materials by means of scanning electron microscopy equipped with an energy dispersion spectrometry. The determination of corrosive wear rates was carried out by means of a combination of electrochemical and gravimetric techniques. Increasing both slide and friction additives improved the corrosion resistance of these bronze composites. Samples with 1·5% graphite, 3%SiO₂ and 3%SiC had the highest corrosive wear resistance in neutralised as well as in acid rain due to the high amount of antifriction and slide additives, in addition to low porosity.     

模拟矿井环境下的PEEK/SiO2/CF-MoS2复合材料摩擦行为研究*

为改善聚醚醚酮（PEEK）在矿井工况下的摩擦性能,选用纳米二氧化硅（SiO2）、二硫化钼（MoS2）和短切碳纤维（CF）为增强填料制备PEEK/SiO2/CF-MoS2复合材料,并探究PEEK/SiO2/CF-MoS2复合材料在不同工况条件下的滑动与滚动摩擦学性能;通过模拟滚轮罐耳在矿井环境下的运行方式,分析其磨损形貌和磨损机制。结果表明：PEEK/SiO2/CF-MoS2复合材料在不同载荷条件下均具有良好的减摩和耐磨特性;滑动摩擦在水介质工况下及滚动摩擦在干摩擦工况下,复合材料的摩擦因数和磨损率最低,其磨损机制均以磨粒磨损为主。与矿井常用的聚氨酯材料的对比,PEEK/SiO2/CF-MoS2复合材料的摩擦学性能更为优异。     

Study on Tribological Performance of NiAl Matrix Self-Lubricating Composites Containing Graphene at Different Loads

This study aimed to explore the possibility of improving the tribological performance of NiAl matrix composites by graphene addition. Friction and wear experiments of as-prepared specimens were conducted under different conditions using a pin-on-disk wear testing machine. NiAl matrix composites containing graphene showed satisfactory performance in friction coefficient and wear resistance compared to NiAl matrix composites without graphene. For the active effect of graphene, the friction coefficient and wear rate of NiAl matrix composites were maintained at relatively lower values. The beneficial antifriction and antiwear effects of graphene gradually failed when the applied load was above 8 N. Graphene in NiAl matrix composites played an active role in the formation of a friction layer, which was beneficial to the lower friction coefficient and wear rate. In light of this research, graphene plays an active role in reducing the friction coefficient and wear rate. Hence, graphene has great potential in applications as an effective solid lubricant to promote tribological behavior.     

Effect of the Graphite Content on the Tribological Behavior of Al/Gr and Al/30SiC/Gr Composites Processed by In Situ Powder Metallurgy (IPM) Method

The influence of graphite content on the dry sliding wear characteristics of Al6061/Gr composites along with Al6061/30SiC/Gr hybrid composites has been assessed using a pin-on-disc wear test. The composites with different volume fraction of graphite particles up to 13% were processed by in situ powder metallurgy (IPM) technique. The porosity and hardness of the resultant composites were also examined. It was found that an increase in the graphite content reduced the porosity, hardness, and friction coefficient of both types of composites. The hybrid composites were more porous and exhibited higher hardness and lower coefficient of friction at identical graphite contents. The increased graphite content in the range of 0–13 vol.% resulted in increased wear rate of Al/Gr composites. The Al/30SiC composite exhibited a lower wear rate as compared with the base alloy and graphite addition up to 9 vol.% improved the wear resistance of these hybrid composites. However, more graphite particles addition resulted in increased wear rate. SEM micrographs revealed that the wear mechanism was changed from mostly adhesive in the base alloy sample (Al/0Gr) to the prominently abrasive and delamination wear for Al/Gr and Al/SiC/Gr/composites.     

Influence of Polyfluo-Wax on the Friction and Wear Behavior of Polyimide/Epoxy Resin–Molybdenum Disulfide Bonded Solid Lubricant Coating

Polyimide/Epoxy resin–molybdenum disulfide bonded solid lubricant coatings (denoted as PI/EP-MoS₂) were prepared. The influence of polyfluo-wax (denoted as PFW) on the microhardness and friction and wear behavior of as-prepared PI/EP-MoS₂ lubricant coating was measured using a microhardness tester and a reciprocating ball-on-disc tribometer, respectively. The worn surfaces of the lubricant coatings were observed with a scanning electron microscope, and their wear rate was determined with a Micro XAM surface mapping microscope. Moreover, the transfer films formed on the counterpart steel ball surfaces were analyzed by X-ray photoelectron spectroscopy. Results indicate that the incorporation of a proper content of PFW filler is effective at improving the antifriction performance of the PI/EP-MoS₂ lubricant coating while maintaining better wear resistance. Moreover, the friction coefficient of the lubricant coating decreases with increasing content of PFW from 2 to 10%, and the one with a filler content over 6% PFW has a steady friction coefficient of 0.07. The improvement in the antifriction performance of the lubricant coating with the incorporation of the PFW filler is attributed to the excellent lubricity of homogeneously distributed PFW.     

高效重载螺旋传动技术的研究开发综述

综述了目前高效、重载螺旋副研究开发的三个发展方向:减摩耐磨合金螺母、聚合物自润滑整体螺母、钢背衬复合材料螺母这三种。铜基、锌基等减摩耐磨合金螺母可以有效提高螺旋传动的工作性能,但采用切削加工难以形成有效的润滑油道;尼龙和酚醛树脂等非金属聚合物自润滑整体螺母具有良好的减摩性能,但承载能力低。钢背衬碳纤维织物/树脂复合材料螺母兼具高的承载能力和良好的减摩耐磨性能,具有良好的发展和应用前景。     

Effect of the silicon content and thermomechanical treatment on the dry sliding wear behavior of spray-deposited Al–Si/SiCp composites

In this study, The wear behaviors of spray-deposited Al–Si/SiC composites, with Si contents between 9 and 20% and 15 vol.% SiC particles, were investigated by using a ring-on-ring test at room temperature under dry conditions. The microstructures, morphologies and phases of worn surfaces were analyzed by scanning electron microscope (SEM) and energy-dispersive X-ray microanalysis (EDAX), respectively. In addition, the wear mechanisms of the composites with different silicon content were discussed. It has been found that the wear rate decreases with the increase of hardness of composites due to silicon content increasing. The wear resistances of the composites are improved dramatically through thermomechanical treatment, compared to as-sprayed composite, due to increasing hardness and elimination of porosity. The wear mechanisms of composites vary with silicon content from abrasive to oxidative wear.     

Tribological behavior of thin-film copper-carbon composites formed by plasma-enhanced chemical vacuum deposition in mixtures of reaction gases Ar-CH<Subscript>4</Subscript> and Ar-C<Subscript>2</Subscript>H<Subscript>2</Subscript>

Results of tribotests of copper-carbon films formed by combining plasma-enhanced chemical vacuum deposition of carbon from a mixture of reaction gases and the physical sputtering of a copper target yield basic regularities of their tribological behavior. The wear resistance of the composites is governed by the type of plasma-forming gas that influences their surface morphology and structure state. The films deposited from a mixture of 50% acetylene and 100% methane possess the best wear resistance. The composites can be used in electrical engineering as interrupting (sliding) contacts, in instrument making, and in machine building as antifriction, wear-resistant, and high-strength protective layers with high adhesion characteristics.