共查询到19条相似文献,搜索用时 62 毫秒
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铝支撑酸化蒙脱土的表征及催化性能 总被引:3,自引:0,他引:3
通过XRD、脱吸附分析、FTIR、骨架振动红外光谱等手段表征了铝支撑酸化蒙脱土。结果表明:经酸化后的蒙脱土再进行铝交联,具有较强的固体酸性,对柴油转化为汽油和联二苯丙烯烷基化反应都有较高的催化活性。本文也讨论了固体酸对催化活性的影响。 相似文献
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三聚阳离子表面活性剂改性蒙脱土的制备与表征 总被引:3,自引:0,他引:3
合成了一种含六氢三嗪的新型三聚季铵盐阳离子表面活性剂T16,以13C NMR和ESI-MS表征其结构,并作为有机插层剂应用于蒙脱土的改性。红外光谱(FTIR)、热重分析(TGA)表明,T16已插层到蒙脱土片层间。X射线粉末衍射(XRD)表明,T16改性后蒙脱土层间距从原来的1.486 nm增加到3.324 nm。沉降实验表明,改性后蒙脱土在苯乙烯和甲苯中形成凝胶体系,表现出很好的相容性和分散性,有利于聚合物或其单体进入蒙脱土层间形成纳米复合材料。 相似文献
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三元柱交联蒙脱土的合成及其催化性能的研究 总被引:1,自引:1,他引:0
采用共混法制备了一系列三元柱交联蒙脱土,并以偏三甲苯和甲醇的烷基化及均四甲苯的异构化作为探针反应考察其催化活性,找出金属离子的种类和预处理温度对偏三甲苯、偏四甲苯转化率及均四甲苯收率的影响。结果发现,少量二价离子的引入能提高三元柱交联蒙脱土的活性,但大量二价离子的引入反而会降低其活性。催化剂最适宜的预处理温度为500~550 ℃,同时以偏三甲苯-甲醇烷基化反应对催化剂的失活进行了考察。结果表明,催化剂经20多个脉冲后仍能保持较好的活性。 相似文献
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以临安钠基蒙脱土为原料,制备了铁交联和铁镧复合交联蒙脱土催化剂,利用物理吸附(BET)、扫描电镜(SEM)和X-射线衍射(XRD)对催化剂进行表征,并以铁镧复合交联蒙脱土(Fe/La-PILC)为催化剂,质量分数为30%的过氧化氢水溶液为氧化剂,考察反应时间、催化剂用量和过氧化氢用量对苯甲醇催化氧化制苯甲醛的影响.结果表明:铁镧复合交联蒙脱土形成了比较均一的中孔骨架结构;当苯甲醇与过氧化氢物质的量之比为1:2,Fe/La(200)-PILC(Fe与La物质的量之比为200)质量分数为4%,反应5 h时,苯甲醇转化率和苯甲醛选择性分别为62.1%和86.4%.研究铁镧交联蒙脱土催化剂的催化氧化机理,发现Fe/La-PILC催化氧化苯甲醇的活性氧来自于Fe/La-PILC所吸附的氧. 相似文献
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交联聚乙烯料加工设备的选型分析 总被引:2,自引:0,他引:2
通过多年从事硅烷交联聚乙烯料的实践和研究,就交联料生产的主要影响因素,即加工设备进行了剖析,对使用的几种机型的工作原理、运动方式、混炼效果、接枝反应时间、优缺点等问题进行了较深入的说明和比较,提出了自己的看法。 相似文献
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(Meth)acrylic cross‐linked polymer microparticles have been synthesized by dispersion polymerization in organic media. They were produced by radical copolymerization of mono(meth)acrylate monomers with a certain concentration of a diacrylate as cross‐linker, in a mixture of two organic solvents, heptane and propan‐2‐ol. The reactive surfactant (“surfmer”) was a low solubility parameter acrylate monomer, based on an aliphatic ester group (generally C18) or an isobornyl cycle, which gave auto‐dispersing character to the microparticles. By using glycidyl methacrylate in the monomer mixture, oxirane groups were introduced in the particles. The influence of the major synthesis parameters such as solvent composition, monomer composition and concentration, and initiator concentration has been investigated regarding the size and the molar mass of the cross‐linked polymer microparticles. The study was completed with the influence of the nature and the concentration of the surfmer, the concentration of cross‐linking agent and the composition of monomers feed. Stable cross‐linked microparticles ranging from z‐average radius of gyration, Rz = 20 nm to Rz > 60 nm were obtained by varying the synthesis conditions. The smallest microparticles were prepared with a blend of heptane and propan‐2‐ol in the 50/50 ratio by weight. Increasing the surfmer concentration or reducing the monomer concentration in the reaction mixture usually led to smaller microparticles. The longer the aliphatic chain of the surfmer, the smaller the microparticles. Minimum sizes were obtained for cross‐linking agent concentrations between 5 and 7.5 mol‐%, depending on monomers composition. For higher concentrations, macrogelation may occur during the synthesis. 相似文献
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DanielI. Perez Fred van Rantwijk RogerA. Sheldon 《Advanced Synthesis \u0026amp; Catalysis》2009,351(13):2133-2139
In this study we have optimized the conditions to precipitate and cross‐link the enzyme chloroperoxidase (EC 1.11.1.10) from Caldariomyces fumago (CPO) using 1,2‐dimethoxyethane as the precipitating agent. The coprecipitation of the enzyme with albumin and pentaethylenehexamine was needed for optimum results, presumably due to the low number of lysines available in CPO. The enzyme was immobilized with an activity recovery of 68%. The cross‐linked enzyme aggregate showed higher temperature and pH stability, and better hydrogen peroxide tolerance than the free enzyme. 相似文献
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以溶胶凝胶法合成镱改性的铬掺杂的介孔氧化铝催化剂Yb-Cr/Al2O3,通过X-射线衍射(XRD)、N2吸附-脱附等温线(BET)、程序升温还原(TPR)、透射电镜(TEM)等现代分析手段对制备的催化剂的结构进行表征。结果表明,稀土镱的引入使铬负载的介孔氧化铝表面更规整,结构更稳定。将催化剂用于以过氧化氢为氧化剂的苯氧化反应进行催化剂活性评价,Yb-Cr/Al2O3比Cr/Al2O3表现出了更高的苯转化率和苯酚选择性。 相似文献
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以脱脂棉为模板制备了多孔管状结构的Al2O3材料,用不同浓度的氢溴酸对多孔管状结构的Al2O3材料进行化学剪裁,制备了活性量可控,比表面积可调,不同形貌的负载型催化剂Al2O3-AlBr x。采用电场发射扫描电镜(SEM)和X射线衍射仪(XRD)对催化剂进行了表征。结果表明,该催化剂较好地复制了棉纤维的宏观和微观结构,呈现出明显的生物形貌特征。在光照条件下以空气为氧化剂的醇的选择性氧化反应中,发现催化剂Al2O3-AlBr x-3可以高选择性地将醇氧化为相应的醛、酮或酸,并对反应机理进行了探讨。该催化剂循环使用3次仍保持较高的催化活性。 相似文献
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利用电导实验技术,跟踪交联壳聚糖树脂吸附游离酸的行为,研究吸附体系的性质对吸附的影响。实验结果表明,表观吸附速率常数随外加盐离子强度和吸附质浓度的增大而降低,交联壳聚糖树脂吸附游离酸的行为遵循单分子层吸附机制。 相似文献
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Mechanical and Rheological Behavior of Hybrid Cross‐Linked Polyacrylamide/Cationic Micelle Hydrogels
《大分子材料与工程》2017,302(12)
In this work, a hybrid cross‐linked polyacrylamide (PAM)/cationic micelle hydrogel is fabricated by introducing the cationic micelles into the chemically cross‐linked PAM network. The cationic micelles act as the physical cross‐linking points through the strong electrostatic interaction with anionic initiator potassium persulfate. Thereafter, in situ free radical polymerization is initiated thermally from the cationic micelle surface to form the hybrid cross‐linked network. The synergistic effect between chemical and physical cross‐link endows the hydrogel with excellent mechanical and recoverable properties. The resulting hydrogel exhibits tensile stress of 481 kPa and fracture toughness of 1.65 MJ m−3. It is found that the chemical cross‐linking can inhibit the hysteresis of the hybrid hydrogel, exhibiting good elasticity in the tensile loading–unloading test. Moreover, dynamic rheological measurements show that the hybrid hydrogels possess fewer defects of network and exhibit excellent self‐recovery behavior. Thus, this investigation provides a different view for the design of new high elastic and tough hydrogels containing hybrid physical and chemical cross‐linking networks. 相似文献