Phase separated thermotropic layers based on UV cured acrylate resins - Effect of material formulation on overheating protection properties and application in a solar collector

This paper focuses on the effect of material composition on the overheating protection properties of thermotropic systems with fixed domains for solar thermal collectors. Numerous functional layers were prepared by a variation of base resin (polyester-, epoxy- or urethane-acrylate) and of thermotropic additives (non-polar and polar waxes) as well as by additive concentration (5 and 7 wt%). A detailed investigation of optical properties, switching temperature and switching process was performed applying UV/Vis/NIR spectroscopy. Thermal transitions of both the thermotropic layers and the additives used were determined by Differential Scanning Calorimetry (DSC). The capability of the produced thermotropic layers to reduce stagnation temperatures in an all-polymeric flat plate collector was evaluated by theoretical modeling. The thermotropic layers showed a hemispheric solar transmittance between 76% and 87% in clear state. Above the switching threshold this transmittance changed by 1-16% to values between 62% and 85%. The layers exhibited switching temperatures between 33 and 80 °C. The transition is fully completed within a temperature frame of 10-25 °C. Resin types with higher glass transition temperatures were detected to benefit the reduction of the hemispheric solar transmittance above the switching threshold. This reduction was also found to increase with increasing molecular weight of the non-polar additive types. The comparison of the switching performance with the thermal transitions of the additives revealed a good correlation. Theoretical modeling showed that by the use of selected thermotropic layers in the glazing the maximum absorber temperatures can be limited to temperatures below 130 °C.     

Thermotropic layers for flat-plate collectors—A review of various concepts for overheating protection with polymeric materials

Within this paper a comprehensive review of the developments of thermotropic hydrogels, thermotropic polymer blends and thermotropic systems with fixed domains for overheating protection purposes is given. In addition, performance properties for thermotropic layers to prevent overheating in solar collectors are defined. The different thermotropic material classes are discussed as to their ability to meet these requirements. The review shows that thermotropic layers developed so far need to be adapted as to switching temperature and long-term stability for applicability in solar thermal collectors.     

Detailed comparison of the performance of flat-plate and vacuum tube solar collectors for domestic hot water heating

The performance of a DHW system fitted with flat-plate and vacuum collectors has been analysed. Simulations were carried out on the basis of equal aperture or gross areas of basis using TMY data for hour-by-hour dynamic simulation generated for 1036 sites located in different regions of the world. The performance indicators of solar fractions and number of days were determined for specific water mean temperatures in the storage tank of 37 °C, 45 °C and 55 °C. It has been shown that vacuum tube collectors provide slightly better DHW performance indicators than typical flat-plate collectors having the same aperture area. However, since the space that needs to be provided and directly or indirectly paid for is what matters to the user of solar heating systems, the analysis was also carried out on equal gross area basis; on this basis, the advantages of using vacuum collectors are not obvious.     

配合集热器的盐梯度太阳池热性能实验与分析

构建表面积为1.50 m×1.50 m的小型实验用盐梯度太阳池,并与平板太阳能集热器配合使用,分别对普通太阳池和集热增强型太阳池进行了储热、放热实验。实验研究与理论分析表明:单独盐梯度太阳池的放热量为3.5×103k J,热效率为13.6%;集热增强型太阳池放热量可以达到4.8×103k J,且热效率增至28.1%。另外后者下对流层温度最高可提升10℃以上,从而证明太阳能集热器可以有效提高太阳池热效率,增加下对流层储热量。此外,考虑了放热过程换热器对太阳池下对流层的扰动,对比实验前后的溶液浓度,可以看出实验后太阳池盐度曲线合理,非对流层呈良好梯度分布,太阳池稳定性并未遭到破坏。     

Potential for large-scale solar collector system to offset carbon-based heating in the Ontario greenhouse sector

In the Ontario greenhouse sector the misalignment of available solar radiation during the summer months and large heating demand during the winter months makes solar thermal collector systems an unviable option without some form of seasonal energy storage. Information obtained from Ontario greenhouse operators has shown that over 20% of annual natural gas usage occurs during the summer months for greenhouse pre-heating prior to sunrise. A transient model of the greenhouse microclimate and indoor conditioning systems is carried out using TRNSYS software and validated with actual natural gas usage data. A large-scale solar thermal collector system is then incorporated and found to reduce the annual heating energy demand by approximately 35%. The inclusion of the collector system correlates to a reduction of about 120 tonnes of CO₂ equivalent emissions per acre of greenhouse per year. System payback period is discussed considering the benefits of a future Ontario carbon tax.     

Study of three‐dimensional natural convection and entropy generation in an inclined solar collector equipped with partitions

Three‐dimensional natural convection in an inclined solar collector equipped with partitions has been investigated numerically. The presence of partitions improves the performances of the collector by increasing the heat transfer near the absorber. A parametric study was done for various partitions length and Rayleigh numbers, while Prandtl number and inclination angle were fixed at 0.71 and 45°, respectively. Results are reported in terms of isosurfaces of temperature, isotherms, particles trajectories, velocity vector projection, average Nusselt number along the absorber plate and entropies generation contours.     

Combination of a vacuum solar collector system and an internal combustion engine in a local heat network

Different measures to reduce the space heating consumption can contribute to a more rational use of energy. Such measures are for example the use of solar collectors and the application of the principle of cogeneration by block-type thermal power stations (BTP) with internal combustion engines. This contribution presents some part of the results of an investigation in which the dimensioning of an internal combustion engine under the special conditions of the combination with a solar-heating system was analyzed. Concerning the course of the yearly duration curve which is an important criterion in dimensioning a BTP it can be found out that the shape of the course looks like a step. This is suitable for the block-type thermal power station if the thermal power of the combustion engine modules is chosen in a way that they fit in these steps.     

Energy consumption minimization in an innovative hybrid power production station by employing PV and evacuated tube collector solar thermal systems

Combination of a grid connected photovoltaic (PV) plant with a compressed air energy storage system (CAES) and a city gate station (CGS) has been proposed and investigated recently, leading to satisfactory performance results. The only deficiency of this system is the huge amount of fuel required to provide its heating demand. In this work, feasibility of employing evacuated tube solar thermal systems to supply the heating demand of the hybrid power plant is studied. After presenting detailed mathematical modeling, the solar heating units and other components of the power plant are properly sized. The results of simulations demonstrate that a total of 7000 evacuated tube collectors are required in the system, leading to elimination of the air heater from the CAES system completely and 17.2% fuel saving at the CGS. The total annual solar heat of 17.5 GWh is supplied for the system, 214 GWh power could directly be sold to the grid, 9.7 GWh power slumps is recovered and 53.5 GWh power is produced at nights. In the end, internal rate of return (IRR) method is used to compare economically the proposed system with similar systems proposed previously, outperforming all of the other candidates with an IRR of 11.1%.     

Photoluminescence characteristics of CdS layers deposited in a chemical bath and their correlation to CdS/CdTe solar cell performance

In this work, we study CdS films processed by chemical bath deposition (CBD) using different thiourea concentrations in the bath solution with post-thermal treatments using CdCl₂. We study the effects of the thiourea concentration on the photovoltaic performance of the CdS/CdTe solar cells, by the analysis of the I–V curve, for S/Cd ratios in the CBD solution from 3 to 8. In this range of S/Cd ratios the CdS/CdTe solar cells show variations of the open circuit voltage (V_oc), the short circuit current (J_sc) and the fill factor (FF). Other experimental data such as the optical transmittance and photoluminescence were obtained in order to correlate to the I–V characteristics of the solar cells. The best performance of CdS–CdTe solar cells made with CdS films obtained with a S/Cd ratio of 6 is explained in terms of the sulfur vacancies to sulfur interstitials ratio in the CBD–CdS layers.     

Novel superhydrophobic microporous layers for enhanced performance and efficient water management in PEM fuel cells

Microporous layers (MPLs) obtained from inks containing three fluorinated polymers (perfluoroalcoxy, fluorinated ethylene propylene and a fluorinated polyurethane based on perfluoropolyether blocks) replacing conventional PTFE were prepared. Inks composition and rheological behaviour were fixed in order to apply the blade coating technique for MPL deposition. Superhydrophobic layers were obtained since contact angles higher than 150° were measured. The samples, tested in a single fuel cell at lab scale, at 60 °C and different relative humidity (RH 80/100 and 80/60, hydrogen/air) evidenced that new polymers are able to improve electrical performances reaching maximum power density values higher than those showed by conventional MPLs based fuel cells. Electrochemical impedance spectroscopy (EIS) was also carried out on the running cell using a Frequency Response Analyzer to assess the different dissipation phenomena and related losses.     

Anchorage of N3 dye-linked polyacrylic acid to TiO2/electrolyte interface for improvement in the performance of a dye-sensitized solar cell

A synthetic route was developed to link N3 dye to polyacrylic acid (PAA) using ethylenediamine (en) as the linker. The resulting complex, PAA–en–N3, was then coated onto a TiO₂ film. The modified TiO₂ film electrode (hereafter PAA–en–N3/TiO₂), when used as the photoanode in a dye-sensitized solar cell (DSSC), exhibited enhanced solar energy conversion efficiency compared with that of the usual DSSC with the N3/TiO₂ film electrode. The increase in efficiency was attributed to the increased open-circuit voltage (V_oc) and short-circuit photocurrent (J_sc). The increase in V_oc was attributed to the formation of a hydrophobic PAA–en–N3 layer on the TiO₂/electrolyte interface, while the increase in J_sc was attributed to the additional dye acquired by the TiO₂ film from the PAA–en–N3 complex.     

On the displacement in origin for turbulent boundary layers subjected to sudden changes in wall temperature and roughness

The present work studies the behavior of flows that develop over surfaces that present a sudden change in surface temperature and roughness. A particular interest of this study is to investigate any existing relationship between the error in origin for both the velocity and the temperature profiles, so that any analogy between the logarithmic laws for the velocity and the temperature profiles can be assessed. Three different types of surfaces are considered and the flow is made to pass from a cold smooth surface to a hot rough surface. Measurements are presented for the mean velocity and temperature profiles.     

Correlative study of microstructure and performance for porous transport layers in polymer electrolyte membrane water electrolysers by X-ray computed tomography and electrochemical characterization

The porous transport layer (PTL) in polymer electrolyte membrane water electrolysers (PEMWEs) has the multiple roles of delivering water to the electro-catalyst, removal of product gas, and acts as a conduit for electronic and thermal transport. They are, thus, a critical component for optimized performance, especially at high current density operation. This study examines the relationship between the microstructure and corresponding electrochemical performance of commonly used titanium sinter PTLs. Four PTLs, with mean pore diameter (MPD) ranging from 16 μm to 90 μm, were characterized ex-situ using scanning electron microscopy and X-ray computed micro-tomography to determine key structural properties. The performance of these PTLs was studied operando using polarization and electrochemical impedance spectroscopy. Results showed that an increase in mean pore size of the PTLs correlates to an increase in the spread and multimodality of the pore size distribution and a reduction in homogeneity of porosity distribution. Electrochemical measurements reveal a strong correlation of mean pore size of the PTLs with performance. Smaller pore PTLs showed lower Ohmic resistance but higher mass transport resistance at high current density of 3.0 A cm⁻². A non-monotonic trend of mass transport resistance was observed for different PTLs, which suggests an optimal pore size beyond which the advantageous influence of macroporosity for mass transport is diminished. The results indicate that maximizing contact points between the PTL and the catalyst layer is the overriding factor in determining the overall performance. These results guide PTL design and fabrication of PEMWEs.     

An extremely facile route to Co2P encased in N,P-codoped carbon layers: Highly efficient bifunctional electrocatalysts for ORR and OER

Exploring low-cost, efficacious and stable bifunctional electrocatalysts for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is crucial yet highly challenging to the wide perspective practicability for rechargeable metal?air batteries together with fuel cells and electrochemical water splitting. Herein, we have successfully prepared a novel nanohybrid consisting of Co₂P nanocores encased in N,P-codoped carbon layers (denoted as Co₂P@NPC) through an extremely facile and effective pyrolysis route utilizing easily available raw materials. The as-prepared Co₂P@NPC exhibits excellent bifunctional electrocatalytic performances for both ORR and OER in alkaline solution. For ORR, Co₂P@NPC shows comparable activity to the commercial 20 wt% Pt/C in terms of the half-wave potential and limited current density under the identical linear sweep voltammetry measurement conditions. Moreover, the ORR durability and methanol tolerance of Co₂P@NPC are much better than those of 20 wt% Pt/C. As regards OER, Co₂P@NPC affords lower activity but better stability than the fresh RuO₂. The high electrocatalytic performances originate from the strong interaction between Co₂P nanocores and N,P-codoped carbon layers, the high BET surface area and the conductive network formed by the crosslinking of carbon coatings.     

Characterization of transport properties in gas diffusion layers for proton exchange membrane fuel cells: 1. Wettability (internal contact angle to water and surface energy of GDL fibers)

This is the first in a series of papers in which we present state-of-the-art methods demonstrated at Case for the estimation of transport properties in gas diffusion layers (GDLs) for proton exchange membrane fuel cells (PEMFCs). Most of the methods used today for measuring wettability properties of GDLs are related to the external contact angle to water. The external contact angle however does not describe adequately capillary forces acting on the water inside the GDL pores. We show as well that the direct method of estimation of the internal contact angle using goniometry on micrographs is impractical. We propose and describe in this paper a method for estimating the internal contact angle to water and the surface energy of hydrophobic and hydrophilic gas diffusion media. The method was applied to GDLs having different contents of hydrophobic agent and carbon types. The method can be applied separately to different components of the GDL including macro-porous substrates and micro-porous layers. The uncertainty estimates using this method are usually within 3% of the measured value.     

A new Gd-promoted nickel catalyst for methane conversion to syngas and as an anode functional layer in a solid oxide fuel cell

The effect of lanthanide promoters on a Ni-Al₂O₃ catalyst for methane partial oxidation, steam reforming and CO₂ reforming at 600-850 °C is systematically investigated. The promoters include La₂O₃, CeO₂, Pr₂O₃, Sm₂O₃ and Gd₂O₃. GdNi-Al₂O₃ shows comparable catalytic activity to LaNi-Al₂O₃ and PrNi-Al₂O₃ but higher activity than CeNi-Al₂O₃ and SmNi-Al₂O₃ for all three reactions. The O₂-TPO results show that GdNi-Al₂O₃ possesses the best coke resistance among those tested. It also displays good stability at 850 °C for 300 h. Raman spectroscopy indicates that the addition of lanthanide promoters can reduce the degree of graphitization of the carbon deposited on Ni-Al₂O₃. The GdNi-Al₂O₃ is further applied as an anode functional layer in solid-oxide fuel cells operating on methane. The cell yields peak power densities of 1068, 996 and 986 mW cm⁻² at 850 °C, respectively, for operating on methane-O₂, methane-H₂O and methane-CO₂ gas mixtures, which is comparable to operating on hydrogen fuel. GdNi-Al₂O₃ is promising as a highly coking-resistant catalyst layer for solid-oxide fuel cells.