高剂量铂和钇离子注入Al2O3单晶的表面改性

研究了〈０００１〉和〈１２↑－１０〉晶向α－Ａｌ２Ｏ３单晶在高剂量的Ｙ、Ｐｔ离子注入后产生的损伤,注入层的性能变化和退火行为。实验结果表明,在室温,１７１ｋｅＶ、１×１０＾１７／ｃｍ＾２Ｙ离子注入的〈１２↑－１０〉α－Ａｌ２Ｏ３单晶的表面层约有１３９ｎｍ厚被无定形化。而１５８ｋｅＶ、９×１０＾１７／ｃｍ＾２Ｐｔ离子注入的〈０００１〉α－Ａｌ２Ｏ３单晶的表面层不产生无定形,且实际离子注入进衬底的剂量     

高能离子注入对聚酰亚胺薄膜硬度的影响

报道了聚酰亚胺薄膜在高能（６５０ｋｅＶ－２ＭｅＶ）Ｂ＾＋、Ｃ＾＋和Ｃｕ＾＋离子注入后硬度的变化。对注入样品进行了显微硬度测量和ＸＰＳ及ＲＢＳ分析，观察了硬度与离子种类、能量及注入剂量的依赖关系。结果表明，离子注入之后薄膜样品的显微硬度值明显提高，注入离子在样品中的电子能量损失对聚合物材料改性起着关键作用。ＸＰＳ和ＲＢＳ分析显示，离子注入之后聚酰亚胺薄膜中Ｃ的含量增加，形成了以苯环结构为主的新的交联     

离子注入α—Al2O3陶瓷材料的表面改性研究

研究了α－Ａｌ２Ｏ３单晶注入Ｎ＾＋后的力学性能变化。结果表明，注入剂量为１×１０＾１７Ｎ＾＋／ｃｍ＾２时，Ａｌ２Ｏ３的显微硬度提高了９２％，注入剂量为３×１０＾１７Ｎ＾＋／ｃｍ＾２时，在Ａｌ２Ｏ３表面形成晶层，导致表面软化，显微硬度只是其５０％左右。离子注入在样品表面产生了高达－１１５０ＭＰａ的压应力，材料的断裂韧性的改善与此有关，实验亦发现Ｎ＾＋离子注入后Ａｌ２Ｏ３的断裂韧性提高了９５％左右。     

大剂量P^＋离子注入单晶硅的研究

采用４８０ｋｅＶ Ｐ＾＋离子注入单晶硅，注入剂量为１×１０＾１６ｃｍ＾－２。采用ＲＢＳ、ＴＥＭ技术测试样品，发现样品经６００℃退火后，距样品表面约２４０ｎｍ处有一条低密度缺陷带。研究表明，这一现象与Ｐ＾＋的剂量及退火温度有关。     

In^＋离子注入蓝宝石（α—Al2O3单晶）的表面改性研究

研究了〈０００１〉和〈１＾－２１０〉晶向蓝宝石（α－Ａｌ２Ｏ３单昌）在注入３６０ｋｅＶ、１×１０＾１６ｃｍ＾－２或１００ｋｅＶ、６×１０＾１６ｃｍ＾－１的Ｉｎ＾＋后产生的损伤、注入层的性能变化和退火行为。实验结果表明，退火过程中损伤的恢复和Ｉｎ的分布与退火气氛有关：在１００ｋｅＶ、６×１０＾１６ｃｍ＾－２的Ｉｎ＾＋注入时，注入层电阻率降低了１０个量级，大小为６．８×１０＾３Ω·ｃｍ，表面损伤层的显     

高能离子注入对聚酚亚胺薄膜硬度的影响

报道了聚酚亚胺薄膜在高能（６５０ｋｅＶ－２ＭｅＶ）Ｂ＋、Ｃ＋和Ｃｕ＋离子注入后硬度的变化。对注入样品进行了显微硬度测量和ＸＰＳ及ＲＢＳ分析，观察了硬度与离子种类、能量及注入剂量的依赖关系。结果表明，离子注入之后薄膜样品的显微硬度值明显提高，注入离子在样品中的电子能量损失对聚合物材料改性起着关键作用。ＸＰＳ和ＲＢＳ分析显示，离子注入之后聚酰亚胺薄膜中Ｃ的含量增加，形成了以苯环结构为主的新的交联网状结构。     

In~+离子注入蓝宝石(α-A1_2O_3单晶)的表面改性研究

研究了＜０００１＜和＜１２１０＞晶向蓝宝石（α－Ａｌ２Ｏ３单晶）在注入３６０ｋｅＶ．１×１０￣１６ｃｍ￣－２或１００ｋｅＶ、６×１０￣１６ｃｍ￣－２的Ｉｎ￣＋后产生的损伤、注入层的性能变化和退火行为。实验结果表明，退火过程中损伤的恢复和Ｉｎ的分布与退火气氛有关：在１００ｋｅＶ、６×１０￣１６ｃｍ￣－２的Ｉｎ￣＋注入时，注入层电阻率降低了１０个量级，大小为６．８×１０￣３·ｃｍ，表面损伤层的显微硬度提高了９２％；在３６０ｋｅＶ，１×１０￣１６ｃｍ￣－２的Ｉｎ＋注入时，其表面损伤层的显微硬度提高了４５％，在空气中不同温度下退火后，其显微硬度的变化和损伤的变化具有相同的规律。     

离子注入C60薄膜的电导率变化

沉积在云母片上的纯Ｃ６０薄膜受２０ｋｅＶ的Ｌｉ＋和Ｎ＋２离子轰击，剂量在０．５×１０１６／ｃｍ２～５．０×１０１６／ｃｍ２之间改变，测量了离子注入后Ｃ６０薄膜方块电阻随温度的变化，进而推导出Ｃ６０薄膜电导率随温度和注入离子剂量的变化；分析了非原位测量中氧元素对电导率变化的影响以及能量较高的注入离子对Ｃ６０薄膜的辐照损伤效应。研究结果表明，Ｌｉ＋注入对Ｃ６０薄膜电导率的影响明显高于Ｎ＋２注入的影响，并给出了不同离子注入条件下Ｃ６０薄膜电导率随温度变化的函数关系式。     

离子注入对超高分子聚乙烯磨损性能的影响

用８０ｋｅＶ不同剂量的Ｃ３Ｈ＾＋８,Ｎ＾＋２对超高分子聚乙烯样品进行离子注入,通过反冲探测分析表明注入层Ｈ含量的变化,对样品表面在离子注入前后的磨损性能进行了测试。实验结果显示,离子注入以后样品表面氢含量减少,磨损性能增强。     

梯形聚合物BBL的磷离子注入

梯形聚合物ＢＢＬ－〔ｐｏｌｙ（ｂｅｎｚｉｍｉｄａｚｏｂｅｎｚｏｐｈｅｎａｔｈｒｏｌｉｎｅ）〕经能量为３０ｋｅＶ、剂量为４×１０＾１６／ｃｍ＾２的Ｐ＾＋注入掺杂后，可观察到其电导和谱特征的变化。对于用ＩＣ１进行掺杂的ＢＢＬ膜也进行了对照研究。     

Plasma-assisted Co/Zr-metal organic framework catalysis of CO_2 hydrogenation:influence of Co precursors

In this study, Co/Zr-metal organic framework(MOF) precursors were obtained by a roomtemperature liquid-phase precipitation method and the equivalent-volume impregnation method,respectively, using a Zr-MOF as the support, and Co/Zr-MOF-M and Co/Zr-MOF-N catalysts were prepared after calcination in a hydrogen–argon mixture gases(V_(Ar):V_(H_2)= 9: 1) at 350 °C for 2 h. The catalytic activities of the prepared samples for CO_2 methanation under atmosphericpressure cold plasma were studied. The results showed that Co/Zr-MOF-M had a good synergistic effect with cold plasma. At a discharge power of 13.0 W, V_(H_2):V_(CO_2)= 4: 1 and a gas flow rate of 30 ml·min~(-1), the CO_2 conversion was 58.9% and the CH_4 selectivity reached 94.7%,which was higher than for Co/Zr-MOF-N under plasma(CO_2 conversion 24.8%, CH_4 selectivity 9.8%). X-ray diffraction, scanning electron microscopy, transmission electron microscopy, N_2 adsorption and desorption(Brunauer–Emmett–Teller) and x-ray photoelectron spectroscopy analysis results showed that Co/Zr-MOF-M and Co/Zr-MOF-N retained a good Zr-MOF framework structure, and the Co oxide was uniformly dispersed on the surface of the Zr-MOF. Compared with Co/Zr-MOF-N, the Co/Zr-MOF-M catalyst has a larger specific surface area and higher Co~(2+)/Cototaland Co/Zr ratios. Additionally, the Co oxide in Co/ZrMOF-M is distributed on the surface of the Zr-MOF in the form of porous particles, which may be the main reason why the catalytic activity of Co/Zr-MOF-M is higher than that of Co/ZrMOF-N.     

界面粗糙度对Co/Cu/Co/NiO自旋阀磁电阻的影响

用磁控溅射方法制备了一系列含NiO反铁磁层的Co／Cu／Co自旋阀结构。电磁输运测量表明,对相同Co／Cu／Co结构的自旋阀,NiO在自旋阀的顶部(TSV)和在自旋阀的底部(BSV)表现了不同的磁电阻值和热稳定特性。X射线镜面反射和横向漫散射测量证明小的界面粗糙度是导致磁电阻增大的主要原因,而Co与NiO层间的耦合减弱将导致MR减小,两者共同的作用决定了含NiO的自旋阀的磁电阻。我们由此设计实验将BSV自旋阀的磁电阻值提高近1倍,即达到-12％,而对称自旋阀的磁电阻则提高到15％。     

60Co集装箱CT检测系统

首先说明反恐斗争对物性判别的要求和现有集装箱检测系统的不足,进而阐述了^60Co集装箱CT检测系统的原理、结构、性能和检测图像,并介绍它的应用领域和发展前景。     

60Co集装箱CT检测装置

文章介绍60Co集装箱CT检测装置结构及其性能.装置将辐射源装置和探测器固定在一环形支架上,该环形支架由轴承与支座连接,通过伺服电机驱动可以环绕被检客体旋转;被检客体采用辊子输送机平移通过环形支架内的检测通道.该装置可以对航空集装箱进行任意方向上透视检测,并可在可疑截面作CT图像.与目前的集装箱检测装置相比,提高了检测能力,且可根据图像灰度与材料密度相关特性对被检客体材料物性进行判别.     

双车车载移动式钴-60集装箱检测系统

介绍了双车车载式钴－60集装箱检测系统的研制及其性能指标。车载式钴－60集装箱检测系统将检测设备和监控系统分别集成在一台半挂车和一台IVECO汽车上,检测方式为被检客体和检测车都不动,由检测龙门架在车载轨道上往复运动完成扫描检测任务。系统主要技术指标为：ＳP为240mm铁,CI为0．5％(100mm铁屏后),IQI为2．5％(100mm铁屏后),一次检测最大吸收剂量小于5μGy,检测速度范围：6－18m／min,运输状态设计最大时速90km／h。     

Asymmetric intermixing in Co/Ti bilayer

Recently we have studied the ion mixing of mass-anisotropic bilayer and found strong asymmetry depending on the succession of the layers [P. Süle, M. Menyhárd, L. Kótis, J. Lábár, W.F. Egelhoff Jr., J. Appl. Phys. 101 (2007) 043502]. The finding was explained by the mass difference of the constituents. To check the validity of explanation we studied the interface broadening of Co/Ti and Ti/Co bilayers due to low-energy ion bombardment. We have applied Auger electron spectroscopy depth profiling and molecular dynamics simulation to determine the intermixing. Since the Co/Ti system is nearly mass isotropic the ballistic intermixing mechanism can be ruled out and no asymmetry is expected. In contrary to the expectation both methods showed asymmetry of intermixing at bombardment of 2 keV ion energy. The asymmetry vanishes progressively with decreasing ion energy. We suggest that atomic size-anisotropy could play some role in the enhancement of interdiffusion of Co in Ti.     

Tracer diffusion of Co into SUS-304

A piece of stainless steel 304 was thermal annealed either in a ⁶⁰Co solution at 280°C, or in a He atmosphere at 300 or 600°C after being smeared with a ⁶⁰Co solution. The depth profile of ⁶⁰Co in SUS was determined with these samples, together with those sampled from the water cleaning system in the Japan Power Demonstration Reactor and those exposed to a high-temperature water ( ˜ 280°C) circulating OWL-loop installed in the Japan Material Testing Reactor, in order to determine the apparent values of the volume and grain boundary diffusion constants. The results have been compared with those of the previous measurements on Ni, Cr, and Fe above 500°C. A consistency has been noticed between both results at 600°C, while the present values at 280 and 300°C are much larger than those expected from the extrapolation of the previous measurements. Although this inconsistency is ascribed to the contribution of the dislocation pipe diffusion at such a low temperature, an attempt has been made to apply the present values to estimate how deep ⁶⁰Co would penetrate SUS—one of the main constructing materials of the primary cooling system—in the life time of a power reactor.     

三门核电有限公司

<正>三门核电简介三门核电有限公司成立于2005年4月,由中国核能电力股份有限公司(中国核工业集团公司全资子公司)控股,全面负责电站的建造、调试、运营和管理。三门核电站地处中国东部沿海经济高速发展地区,位于浙江省台州市三门县境内,坐落在健跳镇猫头山半岛上。三门核电工程采用美国西屋公司开发的第三代核电技术AP1000,规划建设6台125万千瓦的核电机组,总装机容量750万千瓦,分三期建设,总投资超过1000亿人民币。一期工程于2009年4月19日正式开工,李克强同志出席仪式宣布开工并看望慰问建设者。一期工程投资约400亿,是浙江省有史以     

60Co production in BN-350 reactors

FéI. Atomic Energy Agency, Republic of Kazakhstan. MAéK. OKBM. Translated from Atomnaya énergiya, Vol. 77, No. 6, pp. 454–457, December, 1994.