共查询到18条相似文献,搜索用时 93 毫秒
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以亚甲基蓝(MB)为研究对象,采用等体积浸渍法制备了不同相对含量的Mn-Ce双金属/活性炭,催化臭氧化处理MB废水,并对催化剂的孔结构和表面性质进行表征。研究表明,MB的氧化降解符合准一级动力学。与单独臭氧化和单金属催化臭氧化相比,Mn-Ce双金属之间的协同作用可以促进对MB的降解活性。在20℃、催化剂投加量为0.4 g/L、pH为6、MB初始质量浓度为200 mg/L的条件下,反应时间为33 min时MB去除率可达100%,COD去除率可达76.1%。催化剂循环使用5次后仍表现良好的催化活性。 相似文献
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污泥活性炭的制备及对亚甲基蓝吸附性能研究 总被引:1,自引:0,他引:1
以城市污水处理厂的剩余污泥为原料,磷酸为污泥活化剂,采用微波加热法制备了污泥活性炭,考察了吸附剂投加量、吸附时间和p H对吸附效果的影响,并对其吸附动力学特性进行了探讨。结果表明:p H为8,投药量m为0.26 g,吸附时间为59 min,吸附温度为35℃,吸附浓度为58 mg/L时,污泥活性炭对亚甲基蓝的吸附效果最佳。污泥活性炭对亚甲基蓝的吸附满足Langmuir等温吸附方程。 相似文献
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污泥活性炭的制备及其脱色性能 总被引:11,自引:0,他引:11
以污水污泥为原料,采用物理活化法制得污泥活性炭,并用该活性炭处理染料废水,研究了pH值、污泥活性炭的投加量、温度、吸附时间等因素对染料废水的脱色率和COD去除率的影响。结果表明:用污泥制备的活性炭,其碘值和亚甲基兰吸附值分别为254.36 mg/g和20.26 mg/g,而且BET比表面积值为25.1995 m2/g,总孔容积为0.0399 m3/g,具有较好的吸附性能;将污泥活性炭用来吸附氨基黑染料,并与商品活性炭处理氨基黑染料的效果进行对比,自制污泥活性炭的脱色效果达到了商品活性炭的水平;污泥活性炭对氨基黑染料的吸附过程符合Langmuir吸附等温线。 相似文献
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活性炭纤维对水中亚甲基蓝的吸附脱色研究 总被引:3,自引:2,他引:3
研究了活性炭纤维(ACF)对水中亚甲基蓝的吸附脱色试验,温度为15-20℃,滤速为4mL/min时,浓度为10mg/L的亚甲基蓝脱色率达98%以上。活性炭纤维经20次吸附与解吸实验,吸附脱色性能没有明显降低。与颗粒状活性炭(GAC)相比,活性炭纤维吸附脱色亚甲基蓝的速度快,在短时间内,就能达到吸附平衡。 相似文献
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以活性炭纤维为催化剂,采用微波诱导氧化工艺处理亚甲基蓝废水,考察了活性炭纤维用量、微波辐射时间、溶液浓度、pH值、盐含量、过氧化氢加入量等因素对处理效果的影响。结果表明,0.05 g活性炭纤维与400 mg/L 25 mL废水混合,在微波功率1 000 W,辐射时间120 s的条件下,亚甲基蓝的去除率达到98.2%,pH、盐和过氧化氢加入量对处理效果有不同的影响。微波诱导氧化、活性炭纤维吸附、单独微波辐射和沸水浴加热四种不同工艺的对比实验表明,微波诱导氧化工艺具有明显的优越性,不会对环境造成二次污染,机理是通过吸附和高温氧化协同作用。氧化动力学过程符合一级反应规律。活性炭纤维催化活性随着使用时间增加而减弱,连续使用29 min,催化能力几乎消失。 相似文献
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为实现城市污水短程硝化厌氧氨氧化生物脱氮,以去除有机物的实际污水为研究对象,考察了游离亚硝酸盐(FNA)处理污泥实现城市污水部分短程硝化的可行性。 结果表明,FNA处理活性污泥后,亚硝酸盐氧化菌(NOB)的亚硝酸盐氧化速率下降程度大于氨氧化菌(AOB)的氨氧化速率,且在0~0.75 mg HNO2-N·L-1范围内随着FNA浓度的增加抑制作用增强。接种实际污水厂活性污泥后,系统亚硝酸盐(NO2--N)积累率仅为1%,即为全程硝化。在控制污泥龄约为15 d的条件下,采用FNA处理污泥可使系统亚硝酸盐积累率增加至90%以上。水力停留时间调至2.5 h时,实现了部分短程硝化,且出水NO2--N/NH4+-N平均值为1.24,可满足厌氧氨氧化脱氮反应的要求。因此采用FNA处理污泥,结合水力停留时间和污泥龄控制可实现城市污水部分短程硝化。 相似文献
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zgür Akta Ferhan een 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2001,76(8):793-802
Leachate from a municipal landfill was combined with domestic wastewater and was treated in batch activated sludge systems. The effectiveness and applicability of the addition of Powdered Activated Carbon (PAC) to activated sludge reactors was investigated. Isotherm tests were carried out with PAC in order to estimate the extent of adsorption of organic matter onto PAC. Then, in activated sludge reactors COD (Chemical Oxygen Demand) removal and nitrification were studied both in the absence and presence of PAC for comparison purposes. In both cases, Oxygen Uptake Rates (OUR) were measured with respect to time in order to investigate substrate removal and change in microbial activity. Addition of PAC to activated sludge increased COD removal by removing mainly the non‐biodegradable fraction in leachate. The COD decreases in batch reactors were best expressed by a first‐order kinetic model that incorporated this non‐biodegradable leachate fraction. With added PAC, nitrification was also enhanced. But in all of the batch runs a significant accumulation of NO2 ‐N took place, indicating that the second step of nitrification was still inhibited. © 2001 Society of Chemical Industry 相似文献
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Development of microbubble aerator for waste water treatment using aerobic activated sludge 总被引:5,自引:0,他引:5
Koichi Terasaka Ai Hirabayashi Takanori Nishino Satoko Fujioka Daisuke Kobayashi 《Chemical engineering science》2011,(14):413
In large-scale waste water treatment plants, the aerobic biochemical reactor is the most important process, where the oxygen supply into the microorganisms often limits the overall waste water treatment rate. On the other hand, several kinds of microbubble distributors have been developed to enrich the oxygen dissolution in water. Therefore, the application of microbubbles for a waste water treatment system was investigated in this study.The oxygen absorption performance of typical microbubble generators was compared with typical bubble generators. To evaluate each bubble generator, the liquid-phase volumetric oxygen transfer coefficient, gas hold-up and power consumption per unit liquid volume were measured in a bubble column attached to each bubble generator. All the microbubble generators allowed the oxygen to dissolve faster than the typical aerators. The spiral liquid flow type microbubble generator had the highest oxygen transfer coefficient even at a low air flow rate although it used more energy than the typical distributors.To improve an industrial waste water treatment system, a novel aeration system utilizing a spiral liquid flow type microbubble generator was proposed in this study. The present system has some advantages such as compact size, portability and fast oxygen dissolution rate. To ensure the performance for organic waste water treatment, the effects of the aeration rate, dissolved oxygen concentration and device properties on the specific consumption rate of model organic waste were investigated. For the novel aeration system, the most suitable conditions to treat organic waste were found. 相似文献