Modeling hydrogen production in a catalytic-inert packed bed reactor by rich combustion of heavy fuel oil

This work presents simulation results for the production of hydrogen by the rich combustion of heavy fuel oil in a dual zone packed bed reactor. The first zone provides catalytic-thermal cracking of the fuel and is followed by a second zone for partial oxidation reforming of the cracked products. The kinetic model for the heavy fuel oil reactions in the catalytic zone uses decalin as a model compound. The partial oxidation reforming zone uses model compounds for the product groups formed from decalin cracking, and uncracked decalin. The hybrid reactor model is compared to results from a model of an inert (non-catalytic) porous media reactor. The work considers equivalence ratios from 1 to 2, filtration velocities between 15.0 and 65.5 cm/s, heat loss from 10 to 108% and particle diameter between 3 and 7 mm, and evaluates their effect on conversion. The simulations with the hybrid reactor model, in slightly rich conditions (equivalence ratio = 1.3) and constant filtration velocity of 19.3 cm/s deliver maximum hydrogen production for an optimal length of the intermediate zone. Considering this optimization: the total energy conversion efficiencies improve with the increase of the equivalence ratio due to the presence of hydrocarbon species generated by the cracking process. It is observed that the hybrid reactor model makes a better use of vaporized fuel, compared to a model for an inert packed bed reactor, when the deposits of carbonaceous material in the latter exceed 7.4%.     

Experimental investigation of the performance of a liquid fuel-fired porous burner operating on kerosene-vegetable cooking oil (VCO) blends for micro-cogeneration of thermoelectric power

Studies related to porous burner for thermoelectric (TE) power generation have mainly focused toward achieving a specific range of power output for various applications. However, detailed analyses on the performance and emission aspects of the porous burner are lacking. In addition, physical integration between the burner and TE modules has added further complexity in this research area. Thus, this work aims to comprehend the effects of fuel–air equivalence ratio on the performance and emission characteristics of a liquid fuel-fired porous burner for micro-cogeneration of TE power. A catalytically inert Al₂O₃ porous medium was incorporated into a liquid fuel-fired porous burner operating on four mixtures of kerosene-vegetable cooking oil (VCO) blends: 100 kerosene, 90/10 KVCO, 75/25 KVCO, and 50/50 KVCO. Ten bismuth-telluride TE cells were arranged in a ten-sided polygon that, together with finned dissipators, formed a TE module electrically connected in series but thermally connected in parallel. The performance aspects at various fuel–air equivalence ratios were thoroughly evaluated with the corresponding temperature profiles, voltage, current, power output, and electrical efficiency. Results indicated that the surface temperature of the porous media was generally higher than the developed and exit flame temperature of the burner. Varying the fuel-air equivalence ratio significantly affected the electrical efficiency, with a maximum and minimum value of 1.94% and 1.10%, respectively. The power output steadily increased in the lean region, but stabilized as the fuel–air equivalence ratio slowly increased beyond the stoichiometric ratio. The CO emission was relatively lower at the lean region; however, significant amount was recorded in the rich combustion region. Moreover, NOx fluctuated between 1 ppm and 4 ppm over the entire range of fuel–air equivalence ratio.     

Study of a TE (thermoelectric) generator incorporated in a multifunction wood stove

Replacing traditional open fire stoves, characterized by low efficiency, with improved ones is an important challenge for developing countries. Adding TE (thermoelectric) generators can provide electricity that permits not only the use of an electric fan increasing the ratio air to fuel to achieve a complete combustion in the stoves but also the satisfaction of basic needs: light, phones and other electronic devices. A review of existing TE generators for stoves is presented. To test the TE modules, an experimental device has been carried out in our laboratory where a gas heater simulates the stove. The generator set-up is described including the switching electric regulator that stabilizes the fluctuating voltage from the modules and stores the energy in a battery. The performance of the generator mostly depends on the heat transfer through the modules and especially on the thermal contact resistances. First experiments show the influence of the pressure on these resistances. Then a study of temperatures and electrical power measurements is compared to a theoretical analysis using TE and heat transfer equations. The very reasonable value of the obtained contact resistances shows that the mechanical design of the generator is almost optimized. The TE generator has produced up to 9.5 W.     

Heat pipes thermoelectric solar collectors for energy applications

This study investigates the load characteristics of heat pipe thermoelectric solar collector (HPTSC) in practice. Heat pipe thermoelectric solar collector converts the heat generated by the Sun directly into electrical energy and produces hot water as well. The maximum power in HPTSC is obtained when the internal resistance of the thermoelectric module is equal to the load resistance. It has been observed to be possible to produce both hot water and electricity by improving available solar collectors or producing new generation HPTSC. While it is possible to generate an electrical power of 160 W from a HPTSC of one square meter using the thermoelectric method, the power produced with an average photovoltaic panel with the same area is only 132 W. Accordingly, HPTSC is a superior alternative not only to available solar collectors, but also to available PV panels. HPTSC, involving three different technologies, is environmentally friendly and certainly a product that allows for more efficient use of solar energy.     

Development of a thermoelectric battery-charger with microcontroller-based maximum power point tracking technique

This article describes a battery charger, which is powered by thermoelectric (TE) power modules. This system uses TE devices that directly convert heat energy to electricity to charge a battery. The characteristics of the TE module were tested at different temperatures. A SEPIC dc–dc converter was applied and controlled by a microcontroller with the maximum power point tracking (MPPT) feature. The proposed system has a maximum charging power of 7.99 W: that is better than direct charging by approximately 15%. The objectives are to study the principle of TE power generation and to design and develop a TE battery charger that uses waste heat or another heat source as the direct input power.     

Experimental study of combustion performances and emissions of a spark ignition cogeneration engine operating in lean conditions using different fuels

This work presents an experimental study describing a six-cylinder spark ignition engine running with a lean equivalence ratio, high compression ratio, ignition delay and used in a cogeneration system (heat and electricity production). Three types of fuels; natural gas, pure methane and methane/hydrogen blend (85% CH₄ and 15% H₂ by volume), were used for comparison purposes. Each fuel has been investigated at 1500 rpm and for various engine loads fixed by electrical power output conditions. CO, CO₂, HC, and NOx emissions values, and exhaust gas temperature were measured. The effect of fuel composition on engine characteristics has been studied. The results show, that the hydrogen addition increased HC emissions (around 18%), as well as performance, whilst it reduced NO_x (around 31%), exhaust gas temperature, CO and CO₂.     

Distributed swirl combustion for gas turbine application

Colorless distributed combustion (CDC) has been shown to provide significant improvement in gas turbine combustor performance. Colorless distributed combustion with swirl is investigated here to develop ultra-low emissions of NO and CO, and significantly improved pattern factor. Experimental investigations have been performed using a cylindrical geometry combustor with swirling air injection and axial hot gas exit stream from the combustor. Air was injected tangentially to impart swirl to the flow inside the combustor. The results obtained from the combustor have demonstrated very low levels of NO (∼3 PPM) and CO (∼70 PPM) emissions at an equivalence ratio of 0.7 and a high heat release intensity of 36 MW/m³-atm under non-premixed combustion. To further simulate gas turbine operating conditions, inlet air to the combustor was preheated to 600 K temperature and the combustor operated at 2 atm pressure. Results showed very low levels of CO (∼10 PPM) but the NO increased somewhat to ∼10 PPM at an equivalence ratio of 0.5 and heat release intensity of 22.5 MW/m³-atm under non-premixed combustion conditions. For premixed combustion, the combustor demonstrated low levels of both NO (5 PPM) and CO (8 PPM) at an equivalence ratio of 0.6 and a heat release intensity of 27 MW/m³-atm. Results are reported at different equivalence ratios on the emission of NO and CO, lean stability limit and OH^* chemiluminescence. These results suggest that further performance improvement can be achieved with improved fuel mixture preparation prior to the ignition of fuel at higher operational pressures using swirling combustor design for our quest to develop ultra low emission high intensity combustor for gas turbine application.     

Syngas production by non-catalytic reforming of biogas with steam addition under filtration combustion mode

Biogas conversion to syngas (mainly H₂ and CO) is considered an upgrade method that yields a fuel with a higher energy density. Studies on syngas production were conducted on an inert porous media reactor under a filtration combustion mode of biogas with steam addition, as a non-catalytic method for biogas valorization. The reactor was operated under a constant filtration velocity of 34.4 cm/s, equivalence ratio of 2.0, and biogas concentration of 60 vol% Natural Gas/40 vol% CO₂, while the steam to carbon ratio (S/C) was varied between 0.0 and 2.0. Total volumetric flow remained constant at 7 L/min. Combustion wave temperature and propagation rate, product gas composition, reactants conversion as well as H₂ and CO selectivity were measured as a function of S/C ratio. Chromatographic parameters, method validation and measurement uncertainty were developed and optimized. It was observed that S/C ratio of 2.0 gave optimal results under studied conditions for biogas conversion, leading to maximum concentrations of 10.34 vol% H₂, 9.98 vol% CO and highest thermal efficiency of 64.2% associated with a modified EROI of 46.3%, which considered energy consumption for steam supply. Conclusions indicated that the increment of the steam co-fed with the reactants favored the non-catalytic conversion of biogas and thus resulted in an effective fuel upgrading.     

Hydrogen-fueled detonation ramjet model: Wind tunnel tests at approach air stream Mach number 5.7 and stagnation temperature 1500 K

The mode of continuous spinning detonation (CSD) combustion of hydrogen in the annular combustor of a model of a hydrogen-fueled detonation ramjet under conditions of approach air stream Mach number 5.7 and stagnation temperature 1500 K is registered experimentally in a short-duration (pulsed) wind tunnel at the overall air-to-hydrogen equivalence ratio (ER) ranging from 0.7 to 1.4. The maximum values of thrust and specific impulse of the ramjet model are attained at ER = 1.25 and are estimated as 1550 N and 3300 s, respectively. At 1.4 < ER < 1.6, the mode of longitudinally pulsating detonation (LPD) combustion is registered with somewhat lower values of thrust and specific impulse.     

Heat gain reduction by means of thermoelectric roof solar collector

This paper presents a numerical investigation on attic heat gain reduction by using thermoelectric modules integrated in a conventional roof solar collector (RSC). This system, called thermoelectric roof solar collector (TE-RSC), is composed of a transparent glass, air gap, a copper plate, thermoelectric modules (TE) and rectangular fin heat sink. Due to the incident solar radiation, a temperature difference is created between the hot and cold sides of TE modules that generates a direct current. This current is used to drive a ventilating fan for cooling the TE-RSC and enhancing attic ventilation that reduces ceiling heat gain. The system performance was simulated using TRNSYS program with new TE and DC fan components developed by our team and compared to a common house.Simulation results using real house configuration showed that a TE-RSC unit of 0.0525 m² surface area can generate about 9 W under 972 W/m² global solar radiation and 35 °C ambient temperature. The induced air change varied between 20 and 40 and the corresponding ceiling heat transfer rate reduction is about 3–5 W/m². The annual electrical energy saving was about 362 kWh. Finally, economical calculations indicated that the payback period of the TE-RSC is 4.36 years and the internal rate of return is 22.05%.     

Premixed hydrogen-air combustion system for fuel cell systems

The advance of efficient hydrogen-air combustion systems has increasingly become of interest in the framework of the development of fuel cell systems, especially for the automotive sector. Therefore, compact modulating systems are required, with the additional demand of low emissions, to be integrated in a fuel cell system. A modulating combustion system based on combustion within inert porous media and an integrated heat exchanger has been developed and investigated. The system is able to handle premixed combustion of lean H₂/air mixtures at a surface load range of 1075 kW/m²-2150 kW/m², and a global equivalence ratio of ?=0.5. The special hydrogen-air mixing concept eliminates the risk of flame flashback and enables operation with very low NO_x emissions.     

Numerical studies on flame inclination in porous media combustors

Inclinational instability developing during propagation of a filtration combustion wave in an inert porous medium is studied using two-dimensional numerical model. Stable and unstable combustion waves are generated by varying combustion parameters such as pressure, equivalence ratio, filtration velocity, effective conductivity of porous media, pellet diameter and combustor scale. The wave propagation velocity of inclinational flame is studied and compared with flat flame. The growth and reduction of inclinational instability are analyzed at different conditions. The numerical results show that a development of inclinational instability causes essential flow non-uniformity and can result in a separation of the flame front in the multiple flame zones. The limited conductive and radiant heat transfer in the solid phase, small pellet diameter of packed bed, high inlet velocity, large combustor scale and low equivalence ratio promote the instability growth. The inclinational instability is suppressed in a reciprocal combustor.     

Syngas production from wood pellet using filtration combustion of lean natural gas–air mixtures

A common method for the production of hydrogen and syngas is solid fuel gasification. This paper discusses the experimental results obtained from the combustion of lean natural gas–air mixtures in a porous medium composed of aleatory alumina spheres and wood pellets, called hybrid bed. Temperature, velocity, and chemical products (H₂, CO, CO₂, CH₄) of the combustion waves were recorded experimentally in an inert bed (baseline) and hybrid bed (with a volume wood fraction of 50%), for equivalence ratios (φ) from 0.3 to 1.0, and a constant filtration velocity of 15 cm/s. Upstream, downstream and standing combustion waves were observed for inert and hybrid bed. The maximum hydrogen conversion in hybrid filtration combustion is found to be ∼99% at φ = 0.3. Results demonstrate that wood gasification process occurs with high temperature (1188 K) and oxygen available, and the lean hybrid filtration process can be used to reform solid fuels into hydrogen and syngas.     

Study on combustion and emission characteristics of a n-butanol engine with hydrogen direct injection under lean burn conditions

The n-butanol fuel, as a renewable and clean biofuel, could ease the energy crisis and decrease the harmful emissions. As another clean and renewable energy, hydrogen properly offset the high HC emissions and the insufficient of dynamic property of pure n-butanol fuel in SI engines, because of the high diffusion coefficient, high adiabatic flame velocity and low heat value. Hydrogen direct injection not only avoids backfire and lower intake efficiency but also promotes to form in-cylinder stratified mixture, which is helpful to enhance combustion and reduce emissions. This experimental study focused on the combustion and emissions characteristics of a hydrogen direct injection stratified n-butanol engine. Three different hydrogen addition fractions (0%, 2.5%, 5%) were used under five different spark timing (10° ,15° ,20° ,25° ,30° CA BTDC). Engine speed and excess air ratio stabled at 1500 rpm and 1.2 respectively. The direct injection timing of the hydrogen was optimized to form a beter stratified mixture. The obtained results demonstrated that brake power and brake thermal efficiency are increased by addition hydrogen directly injected. The BSFC is decreased with the addition of hydrogen. The peak cylinder pressure and the instantaneous heat release rate raises with the increase of the hydrogen addition fraction. In addition, the HC and CO emissions drop while the NOx emissions sharply rise with the addition of hydrogen. As a whole, with hydrogen direct injection, the power and fuel economy performance of n-butanol engine are markedly improved, harmful emissions are partly decreased.     

Electric power generation by super-adiabatic combustion in thermoelectric porous element

A new system for converting combustion heat into electric power was proposed on the basis of reciprocating-flow super-adiabatic combustion in a catalytic and thermoelectric porous element. Self-sustaining combustion of an extremely low-calorific gas was successfully achieved in the element; because a reciprocating flow in the porous element recirculated energy, effectively regenerating combustion gas enthalpy into an enthalpy increase in the low-calorific gas. In the combustion system, a trapezoidal temperature distribution was established along the flow direction, resulting in a steep temperature gradient in the thermoelectric porous element. Numerical simulation showed that 94% of the combustion heat was transferred through the thermoelectric element by conduction. As a result, the total thermal efficiency, which was defined as the ratio of the electric power generated to the combustion heat, attained a value close to the conversion efficiency of the thermoelectric device itself.     

Unsteady fluid mechanics and heat transfer study in a double-tube air–combustor heat exchanger with porous medium

Fluid mechanics and heat transfer are studied in a double-tube heat exchanger that uses the combustion gases from natural gas in a porous medium located in a cylindrical tube to warm up air that flows through a cylindrical annular space. The mathematical model is constructed based on the equations of continuity, linear momentum, energy and chemical species. Unsteady fluid mechanics and heat transfer by forced gas convection in the porous media, with combustion in the inner tube, coupled to the forced convection of air in the annular cylindrical space are predicted by use of finite volumes method. Numerical simulations are made for four values of the annular air flow Reynolds number in the range 100 ? Re ? 2000, keeping constant the excess air ψ = 4.88, the porosity ε = 0.4, and the air–fuel mixture inlet speed Uo = 0.43 m/s. The results obtained allow the characterization of the velocity and temperature distributions in the inner tube and in the annular space, and at the same time to describe the displacement of the moving combustion zone and the annular porous media heat exchanger thermal efficiency. It is concluded that the temperature increase is directly related to the outer Reynolds number.     

Gasification of oil shale dust in a counterflow moving bed filtration combustion reactor

Experimental investigation of gasification of oil shale dust in a counterflow moving bed filtration combustion reactor was carried out. The process was implemented similar to filtration combustion of gases: pulverized solid fuel supplied simultaneously with oxidizer. For a controlled supply of fuel dust a new rotating dispenser was used. Characteristics of process depending on the equivalence ratio were obtained. The absence of a rise in pressure drop over time indicates the lack of fuel accumulation and ash inside the porous bed, all ash was carried out from the reactor with a gas stream. It is shown that an increase in the flow rate of a gaseous oxidizer leads to an increase in both temperature and the inert velocity. The inert velocity, the calorific value of gaseous products, and the efficiency of gasification increase almost linearly with the equivalence ratio. Proposed method allows producing combustible gaseous products without a noticeable concentration of pyrolysis tars and calorific value up to 4 MJ/m³, gasification efficiency was ~85%.     

Thermal‐hydraulic design features of a micronuclear reactor power source applied for multipurpose

Microheat pipe cooled reactor power source (HRP) designed for space or underwater vehicles meets the future demands, such as safer structure, longer operating time, and fewer mechanical moving parts. In this paper, potassium heat pipe cooled reactor power source system which generates 50 kWe electricity is proposed. The reactor core using uranium nitride fuel is cooled by 37 potassium high‐temperature heat pipes. The shields are designed as tungsten and water, and reactor reactivity is controlled by control drums. The thermoelectric generator (TEG) consists of thermoelectric conversion units and seawater cooler. The thermoelectric conversion units convert thermal energy to electric energy through the high‐performance thermoelectric material. A code applied for designing and analyzing the reactor power system is developed. It consists of multichannel reactor core model, heat pipe model using thermal resistance network, thermoelectric conversion, and thermal conductivity model. Then, the sensitivity analysis is performed on two key parameters including the length of the heat pipe condensation section and the cold junction temperature of the TE cell. Meanwhile, the steady‐state calculations are conducted. Results show that the maximum fuel temperature is 938 K located in the center of reactor core and the outlet temperature of coolant reaches 316 K. Both of them are within the limitation. It is concluded that the preliminary design of HPR design is reasonable and reliable. The designed residual heat removal system has sufficient safety margin to release the decay heat of the reactor. This research provides valuable analysis for the application of micronuclear power source.     

An integrated system of zinc oxide solar panels,fuel cells,and hydrogen storage for heating and cooling applications

Due to the production of hydrogen, using fuel cells for energy conversion and storing encounters safety problems. Combining high-temperature solid oxide fuel cells with photovoltaic solar panels or zinc oxide solar panels can be a good candidate to produce/convert and store the energy more efficiently for using at peak times. The current paper intends to analyze the efficiency of integration of zinc oxide solar panels and fuel cells to produce hydrogen directly. Therefore, the excess step of converting electricity to hydrogen and re-converting it to electricity, which is customarily used for the integration of the photovoltaic and solid oxide fuel cells, could be skipped. The new method paves the way for providing the required energy for heating/cooling through the floor heating and ceiling cooling systems as well as generating electricity. The article also demonstrates that it is possible to have heat during the day and night for an area of 1920 m² and 542 m². It is also possible to create coolness during the day and night for an area of 925 m² and 260 m².     

Nonlinear convection flow of dissipative Casson nanofluid through an inclined annular microchannel with a porous medium

The nonlinear convection study on the flow of a dissipative Casson nanofluid through a porous medium of an inclined micro-annular channel is presented. The cylindrical surfaces were conditioned to temperature increase and velocity slip effects. A uniform magnetic field strength was applied perpendicular to the cylinder surface. The heat source and Darcy number influence are explored in the examination of the blood rheological model (Casson) through the annular cylinder. Appropriate dimensionless variables are imposed on the dimensional equations encompassing Casson nanofluid rheology through an annular microchannel. The resulting systems of equations were solved and computed numerically via Chebyshev-based collocation approach. Thus, the solutions of flow distributions, volumetric flow rate, and other flow characteristics were obtained. The result shows that both nonlinear convection parameters decrease the nanoparticle volume fraction, whereas they increase the energy and momentum distributions. Moreover, the volumetric flow rate is upsurged significantly by a wider porous medium, annular gap, a higher Casson parameter, and nonlinear convection influence.