雾状钠火钠滴燃烧比率的模拟及应用

将雾状钠火中钠滴的燃烧分成预燃阶段和燃烧阶段,利用雾状钠火程序计算得到钠滴燃烧比率和时间的关系曲线,分别用幂函数、指数函数和线性函数对曲线进行拟合,拟合效果较好。拟合函数中包含钠滴下落时间和钠滴最大燃烧比率等参数,这些参数可通过钠滴下落燃烧试验或雾状钠火程序计算得到。通过推导得到了雾状钠火燃烧和单个钠滴燃烧的关系,钠滴燃烧比率的拟合函数被用来模拟雾状钠火燃烧的过程,包括用于计算已燃烧的钠质量、空气中未燃烧的钠质量、进入钠池的钠质量和雾状钠火的燃烧速率。当雾状钠火燃烧过程中钠泄漏流量恒定不变时,空气中未燃烧的钠质量和钠泄漏流量呈正比,雾状钠火的燃烧速率和钠泄漏流量呈正比。雾状钠火的燃烧速率和钠火造成的事故工艺间内的温度与压力变化直接相关。雾状钠火的燃烧速率被用来求解钠气溶胶的生成速率、钠燃烧火焰层和空气之间的传热、钠燃烧火焰层和墙壁之间的传热。总之,使用简单的函数模拟钠滴的燃烧比率曲线,将雾状钠火燃烧当成事故工艺间的热源和钠气溶胶源作为输入,便可模拟雾状钠火的整个燃烧过程,计算得到工艺间温度、压力和钠气溶胶浓度的变化。钠滴的燃烧比率曲线、雾状钠火的燃烧速率曲线还可与试验数据进行对比验证后作为雾状钠火模拟的输入,这种模拟方法可用于钠火事故安全分析中雾状钠火的模拟。     

A Steam-Plasma Igniter for Aluminum Powder Combustion

High-temperature ignition is essential for the ignition and combustion of energetic metal fuels,including aluminum and magnesium particles which are protected by their highmelting-temperature oxides.A plasma torch characterized by an ultrahigh-temperature plasma plume fulfills such high-temperature ignition conditions.A new steam plasma igniter is designed and successfully validated by aluminum power ignition and combustion tests.The steam plasma rapidly stabilizes in both plasma and steam jet modes.Parametric investigation of the steam plasma jet is conducted in terms of arc strength.A high-speed camera and an oscilloscope method visualize the discharge characteristics,and optical emission spectroscopy measures the thermochemical properties of the plasma jet.The diatomic molecule OH fitting method,the Boltzmann plot method,and short exposure capturing with an intensified charge coupled device record the axial distributions of the rotational gas temperature,excitation temperature,and OH radical distribution,respectively.The excitation temperature at the nozzle tip is near 5500 K,and the gas temperature is 5400 K.     

Sodium/water combustion and the chemistry of wastage at sodium/water leak sites

The ignition and combustion of sodium in water vapour are demonstrated experimentally, and the composition and temperature of the flame region are discussed in terms of thermodynamic and kinetic factors. Steels have been shown to suffer rapid wastage in these flame regions. Corrosion tests to simulate the chemical environment of the flame showed that a greater rate of attack on 2.25C-1 Mo steel occurred with sodium hydroxide in a water vapour atmosphere than with sodium hydroxide alone. Extrapolation of these corrosion rates to the steel temperature in the flame leads to the conclusion that these corrosion processes are the origin of the flame wastage. The tube wastage found during water injection tests in fast reactor heat exchangers is discussed in terms of rapid corrosion by sodium hydroxide and water vapour within the flame region generated at the boundary of the water jet.     

Application study on plasma ignition in aeroengine strut-cavity-injector integrated afterburner

To increase the thrust-weight ratio in next-generation military aeroengines,a new integrated afterburner was designed in this study.The integrated structure of a combined strut-cavity-injector was applied to the afterburner.To improve ignition characteristics in the afterbumer,a new method using a plasma jet igniter was developed and optimized for application in the integrated afterburner.The effects of traditional spark igniters and plasma jet igniters on ignition processes and ignition characteristics of afterburners were studied and compared with the proposed design.The experimental results show that the strut-cavity-injector combination can achieve stable combustion,and plasma ignition can improve ignition characteristics.Compared with conventional spark ignition,plasma ignition reduced the ignition delay time by 67 ms.Additionally,the ignition delay time was reduced by increasing the inlet velocity and reducing the excess air coefficient.This investigation provides an effective and feasible method to apply plasma ignition in aeroengine afterburners and has potential engineering applications.     

Air-hydrogen deflagration tests at the University of Pisa

In severe accidents, large amounts of hydrogen may be released in the safety containment of a nuclear plant and the gas mixture may become explosive. The University of Pisa and ENEA have undertaken an experimental program to study the physics of flame propagation in a containment model under accident conditions. Up to now 41 deflagration tests have been performed at the HYDRO-SC facility at ambient pressure and temperature. Concentrations, water spray conditions, ignition source and gas turbulence levels were varied. The vessel volume was 0.5 m³, the ignition sources were an electrical spark discharge and an electrically heated surface (glow-plug), the hydrogen molar fractions were in the range 4–16%, the turbulence was generated by fan or spray and two different spray nozzles were utilized. The experimental data indicate that the peak pressures nearly fit the adiabatic isochoric values at the highest hydrogen concentrations and gas turbulences. Weak pressure waves were observed for H₂ molar fractions greater than 10%. A careful examination of the pressure and temperature transients gave information on the flame path and on the heat transfer process during and after combustion. Scale effects on the peak pressures were not observed by comparison of the HYDRO-SC results with data obtained in other laboratories. The glow plug igniter has proved to be a reliable tool for use in deliberate ignition schemes for hydrogen control in nuclear plants.     

Effect of shock wave formation on propellant ignition in capillary discharge

In order to study the effect of shock wave formation on propellant ignition in capillary discharge, the shock wave formation process was analyzed using experimental and theoretical methods; the plasma jet temperature was measured, and closed bomb and 30 mm gun experiments were carried out. The results show that the first shock wave has a smaller value and larger range of influence, while the second shock wave has a larger value and smaller range of influence. A plasma jet can generate a shock wave at the nozzle according to the calculated plasma pressure and velocity, which is well confirmed by experiments and calculations. The plasma jet temperature is high during the formation of a shock wave and then decreases sharply. Plasma ignition can increase the burning rate of a propellant by about 30% by increasing the burning surface area of the propellant. Compared to conventional ignition, the average maximum chamber pressure and average muzzle velocity of plasma ignition are increased by 9.1 MPa and 29.3 m·s−1(∼3%), respectively, in a 30 mm gun. Plasma ignition has strong ignition ability and short ignition delay time due to the generation of a shock wave. By increasing the burning rate of the propellant, the muzzle velocity can be greatly improved when the maximum chamber pressure increases a little. The characteristics of the shock wave can be applied in the application of the capillary discharge plasma. For example, it can be applied in fusion, launching and combustion.     

Combustion of stratified hydrogen-air mixtures in the 10.7 m combustion test facility cylinder

This paper presents preliminary results from hydrogen concentration gradient combustion experiments in a 10.7 m³ cylinder. These gradients, also referred to as stratified mixtures, were formed from dry mixtures of hydrogen and air at atmospheric temperature. Combustion pressures, burn fractions and flame speeds in concentration gradients were compared with combustion of well-mixed gases containing equivalent amounts of hydrogen. The studied variables included the quantity of hydrogen in the vessel, the steepness of the concentration gradient, the igniter location, and the initial concentration of hydrogen at the bottom of the vessel.Gradients of hydrogen and air with average concentrations of hydrogen below the downward propagation limit produced significantly greater combustion pressures when ignited at the top of the vessel than well-mixed gases with the same quantity of hydrogen. This was the result of considerably higher burn fractions in the gradients than in the well-mixed gas tests. Above the downward propagation limit, gradients of hydrogen ignited at the top of the vessel produced nearly the same combustion pressures as under well-mixed conditions; both gradients and well-mixed gases had high burn fractions. Much higher flame speeds were observed in the gradients than the well-mixed gases.Gradients and well-mixed gases containing up to 14% hydrogen ignited at the bottom of the vessel produced nearly the same combustion pressures. Above 14%, hydrogen, gradients produced lower combustion pressures than well-mixed gases having the same quantity of hydrogen. This can be attributed to lower burn fractions of fuel from the gradients compared with well-mixed gases with similar quantities of hydrogen. When ignited at the bottom of the vessel, 90%, of a gradient's gases remained unburned until several seconds after ignition. The remaining gases were then consumed at a very fast rate.     

The ignition and burning behaviour of sodium metal in air

A review has been made of the ignition and combustion of sodium, both in terms of the fundamental chemistry and also with reference to its use as the heat transfer fluid of a fast breeder reactor. In the discussions of both the combustion chemistry and the scientific mechanisms of possible fire extinguishants comparisons are made with the burning of hydrocarbon fluids. A large part of the review is devoted to the considerable amount of quantitative data produced by various agencies in the world in their pursuit of commercial fast reactor technology. Both practical and theoretical studies have been carried out, some on a large scale, mainly in the field of spray fires and pool fires. Vapour combustion is briefly discussed as is the subject of passive and active fire extinction and possible corrosion damage to structures. Some suggestions are made as to which areas are adequately understood and which areas need significant further work in the context of sodium cooled fast reactors.     

Thermal Fragmentation of a Molten Metal Jet Dropped into a Sodium Pool at Interface Temperatures below Its Freezing Point

In order to verify the thermal fragmentation of a molten jet dropped into a sodium pool at instantaneous contact interface temperatures below its freezing point, a basic experiment was carried out using molten copper and sodium. Twenty grams of copper was melted in a crucible with an electrical heater and was dropped through a 6 mm nozzle into a sodium pool of 553 K, in the form of a jet column. Thermal fragmentation originating inside the molten copper jet with a solid crust was clearly observed in all runs. It is verified that a small quantity of sodium, which is locally entrapped inside the molten jet due to the organized motion between the molten jet and sodium, is vaporized by the sensible heat and the latent heat of molten copper, and the high internal pressure causes the molten jet with a solid crust to fragment. It is also found that the fragmentation caused in the molten copper-sodium interaction was severer than that in the molten uranium alloy jet-sodium interaction, which was reported by Gabor et al, under the same superheating condition and lower ambient Weber number condition of molten copper.     

Effect of Spatial Variation of Flux on Diffusion Coefficient of a Cylindrical Cell

In order to improve the performance of the sodium vapor trap, the sodium trapping efficiency has been analyzed using a simplified model of the mesh-packed region, supplemented by considering the effect of mist formation in the trap. The results led to the following conclusions:

(1) When mist containing sodium vapor is supplied to the trap, the sodium trapping efficiency is greatly lowered because of condensation of vapor to inist.

(2) Even if the sodium vapor contains no mist initially, it forms when nuclei for condensation exist which are larger than a critical value. This mist formation causes a decreased sodium trapping efficiency.

(3) The sodium trapping efficiency can be maximized by decreasing the gas temperature along the mesh in a manner inversely proportional to the trap length.     

Experimental investigation on plasma jet deflection with magnetic fluid control based on PIV measurement

This paper is devoted to experimentally investigating the influence of magnetic field intensity and gas temperature on the plasma jet deflection controlled by magneto hydrodynamics. The catalytic ionization seed CS_2CO_3 is injected into combustion gas by artificial forced ionization to obtain plasma fluid on a high-temperature magnetic fluid experimental platform. The plasma jet was deflected under the effect of an external magnetic field, forming a thrust-vector effect.Magnesium oxide was selected as a tracer particle, and a two-dimensional image of the jet flow field was collected using the particle image velocimetry(PIV) measurement method. Through image processing and velocity vector analysis of the flow field, the value of the jet deflection angle was obtained quantitatively to evaluate the thrust-vector effect. The variation of the jet deflection angle with the magnetic field intensity and gas temperature was studied under different experimental conditions. Experimental results show that the jet deflection angle increased gradually with a rise in gas temperature and then increased substantially when the gas temperature exceeded 2300 K. The jet deflection angle also increased with an increase in magnetic induction intensity. Experiments demonstrate it is feasible to use PIV test technology to study the thrust vector under magnetic control conditions.     

Natural Convection Sodium Boiling Experiments in 37-Pin Bundle Geometry

Decay heat removal capability under boiling condition was studied using an LMFBR fuel subassembly mockup loop. The sodium flow was driven by natural convection through the loop in which was installed a 37-pin bundle heated electrically over a length of 45 cm.

The heat flux furnished by the pins was increased stepwise, upon which the two-phase flow regime changed from bubble to slug flow and then to annular or annular mist flow. Dryout occurred even in slug flow regime, but only momentarily, and permanent dryout was not observed before establichment of annular flow. A suitable criterion for permanent dryout is considered to be 0.5 average exit sodium vapor quality. The results indicated that upon occurrence of sodium boiling, the coolability of fuel subassembly would be maintained by natural convection after reactor shutdown.     

Analysis of hydrogen flame acceleration in APR1400 containment by coupling hydrogen distribution and combustion analysis codes

This study was conducted as part of the construction of an integrated system to mechanistically evaluate flame acceleration characteristics in a containment of a nuclear power plant during a severe accident. In the integrated analysis system, multi-dimensional hydrogen distribution and combustion analysis codes are used to consider three-dimensional effects of the hydrogen behaviors. GASFLOW is used for the analysis of a hydrogen distribution in the containment. For the analysis of a hydrogen combustion in the containment, an open-source CFD (computational fluid dynamics) code OpenFOAM is chosen. Data of the hydrogen and steam distributions obtained from a GASFLOW analysis are transferred to the OpenFOAM combustion solver by a conversion and interpolation process between the solvers. The combustion solver imports the transferred data and initializes the containment atmosphere as an initial condition of a hydrogen combustion analysis. The turbulent combustion model used in this study was validated by evaluating the F22 test of the FLAME experiment. The coupled analysis method was applied for the analysis of a hydrogen combustion during a station blackout accident in an APR1400. In addition, the characteristics of the flame acceleration depending on a hydrogen release location are comparatively evaluated.     

The Feasibility of Applying AC Driven Low-Temperature Plasma for Multi-Cycle Detonation Initiation

Ignition is a key system in pulse detonation engines(PDE). As advanced ignition methods, nanosecond pulse discharge low-temperature plasma ignition is used in some combustion systems, and continuous alternating current(AC) driven low-temperature plasma using dielectric barrier discharge(DBD) is used for the combustion assistant. However, continuous AC driven plasmas cannot be used for ignition in pulse detonation engines. In this paper, experimental and numerical studies of pneumatic valve PDE using an AC driven low-temperature plasma igniter were described. The pneumatic valve was jointly designed with the low-temperature plasma igniter,and the numerical simulation of the cold-state flow field in the pneumatic valve showed that a complex flow in the discharge area, along with low speed, was beneficial for successful ignition. In the experiments ethylene was used as the fuel and air as oxidizing agent, ignition by an AC driven low-temperature plasma achieved multi-cycle intermittent detonation combustion on a PDE, the working frequency of the PDE reached 15 Hz and the peak pressure of the detonation wave was approximately 2.0 MPa. The experimental verifications of the feasibility in PDE ignition expanded the application field of AC driven low-temperature plasma.     

Development of the evaluation methodology for the material relocation behavior in the core disruptive accident of sodium-cooled fast reactors

The in-vessel retention (IVR) of core disruptive accident (CDA) is of prime importance in enhancing safety characteristics of sodium-cooled fast reactors (SFRs). In the CDA of SFRs, molten core material relocates to the lower plenum of reactor vessel and may impose significant thermal load on the structures, resulting in the melt-through of the reactor vessel. In order to enable the assessment of this relocation process and prove that IVR of core material is the most probable consequence of the CDA in SFRs, a research program to develop the evaluation methodology for the material relocation behavior in the CDA of SFRs has been conducted. This program consists of three developmental studies, namely the development of the analysis method of molten material discharge from the core region, the development of evaluation methodology of molten material penetration into sodium pool, and the development of the simulation tool of debris bed behavior. The analysis method of molten material discharge was developed based on the computer code SIMMER-III since this code is designed to simulate the multi-phase, multi-component fluid dynamics with phase changes involved in the discharge process. Several experiments simulating the molten material discharge through duct using simulant materials were utilized as the basis of validation study of the physical models in this code. It was shown that SIMMER-III with improved physical models could simulate the molten material discharge behavior, including the momentum exchange with duct wall and thermal interaction with coolant. In order to develop an evaluation methodology of molten material penetration into sodium pool, a series of experiments simulating jet penetration behavior into sodium pool in SFR thermal condition were performed. These experiments revealed that the molten jet was fragmented in significantly shorter penetration length than the prediction by existing correlation for light water reactor conditions, due to the direct contact and thermal interaction of molten materials with coolant. The fragmented core materials form a sediment debris bed in the lower plenum. It is necessary to remove decay heat safely from this debris bed to achieve IVR. A simulation code to analyze the behavior of debris bed with decay heat was developed based on SIMMER-III code by implementing physical models, which simulate the interaction among solid particles in the bed. The code was validated by several experiments on the fluidization of particle bed by two-phase flow. These evaluation methodologies will serve as a basis for advanced safety assessment technology of SFRs in the future.     

Plasma-Assisted Chemistry in High-Speed Flow

Fundamental problems related to the high-speed combustion are analyzed. The result of plasma-chemical modeling is presented as a motivation of experimental activity. Numerical simulations of the effect of uniform non-equilibrium discharge on the premixed hydrogen and ethylene-air mixture in supersonic flow demonstrate an advantage of such a technique over a heating. Experimental results on multi-electrode non-uniform discharge maintenance behind wallstep and in cavity of supersonic flow are presented. The model test on hydrogen and ethylene ignition is demonstrated at direct fuel injection to low-temperature high-speed airflow.     

Behaviors of Impurities in Liquid Sodium, (II)

The behavior of hydrogen in liquid sodium containing relatively large amounts of oxygen were investigated with the aid of the hydrogen sensor of niobium membrane. The partial pressure of the hydrogen in liquid sodium at hot zone of a cold-trapped natural circulation sodium loop was measured as functions of temperatures of the cold trap and the hot zone of the loop. It was observed that at constant cold trap temperature the partial pressure of hydrogen in sodium increases with increasing the hot zone temperature. This study also showed that, keeping the temperature of hot zone constant, a logarithmic plot of hydrogen concentration calculated from the equilibrium hydrogen partial pressure vs. the reciprocal temperature of cold trap yields a straight line whose slope is nearly equal to that on the solubility of sodium hydroxide in sodium. Finally, it was observed that the permeation of hydrogen in sodium through a niobium membrane is a process controlled by diffusion. But the permeability for hydrogen in niobium is a few-hundredths smaller than that in literature, owing to the oxide film on the membrane surface.     

Development of unstructured mesh-based numerical method for sodium–water reaction phenomenon in steam generators of sodium-cooled fast reactors

When pressurized water or vapor leaks from a failed heat transfer tube in a steam generator of sodium-cooled fast reactors, a high-velocity and high-temperature jet with sodium–water chemical reaction may cause wastage on the adjacent tubes. For safety assessment of the steam generator, a computational fluid dynamics code called SERAPHIM calculating compressible multicomponent multiphase flow with sodium–water chemical reaction has been developed. The original SERAPHIM code is based on the finite difference method. In this study, unstructured mesh-based numerical method for the SERAPHIM code was developed to advance a numerical accuracy for the complex-shaped domain including multiple heat transfer tubes. Numerical analysis of an underexpanded jet experiment was performed as part of validation of the unstructured mesh-based SERAPHIM code. The calculated pressure profile showed good agreement with the experimental data. To investigate the effect of the introduction of the unstructured mesh and to confirm applicability of the numerical method for the actual situation, water vapor discharging into liquid sodium was analyzed. The calculated behavior of the reacting jet agreed with the previous experimental knowledge. It was demonstrated that the proposed numerical method could be applicable to evaluation of the sodium–water reaction phenomenon.     

Cold fusion—Engineering perspectives

Considerable heat was liberated from a palladium-deuterium (Pd-D) system and this was attributed to cold nuclear fusion of deuterium within the palladium lattice.¹ The primary source of heat in cold fusion was proposed to be the work-of-fracture of cracks in the Pd electrodes, and the mechanism for crack initiation and propagation was identified as deuterium or hydrogen embrittlement.² In this paper, comparable characteristics of cold fusion and embrittlement are established, relevant aspects of the extensive engineering database on hydrogen and deuterium embrittlement are reviewed, some areas of study and applications of the cold fusion process are identified, and parameters for controlling the ignition and heat release from metals are specified.This and related works have been fully sponsored by the author.     

Effect of turbulent natural convection on sodium pool combustion in the steam generator building of a fast breeder reactor

A computational model is proposed to simulate sodium pool combustion considering the effect of turbulent natural convection in a vented enclosure of the steam generator building (SGB) of a fast breeder reactor. The model is validated by comparing the simulated results with the experimental results available in literature for sodium pool combustion in a CSTF vessel. After validation, the effects of vents and the location of the pool on the burning rate of sodium and the associated heat transfer to the walls are studied in an enclosure comparable in size to one floor of the steam generator building. In the presence of ventilation, the burning rate of sodium increases, but the total heat transferred to the walls of the enclosure is reduced. It is also found that the burning rate of sodium pool and the heat transfer to the walls of the enclosures vary significantly with the location of sodium pool.