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在自行设计的恒速型毛细管动态流变装置上,对聚合物熔体进行动态挤出实验。实时采集毛细管的挤出胀大值,借助已建立的振动力场下聚合物熔体弹性行为的表征公式,计算振动力场下聚合物熔体在毛细管壁处的第一法向应力差。通过对比分析有无振动场下以及不同振动强度下聚合物熔体的流变性能,找到聚合物熔体弹性行为对振动力场的响应规律。 相似文献
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振动力场下聚合物熔体流变行为的响应与分析——I.毛细管压力降和熔体表观粘度 总被引:1,自引:0,他引:1
在自行设计的恒速型毛细管动态流变装置上,对聚合物熔体进行动态挤出实验。借助已建立的振动力场下聚合物熔体流变行为的表征公式,分别计算振动力场下聚合物熔体在毛细管壁处的剪切应力、剪切速率和表观粘度。与稳态挤出时相比,引入振动力场后,发现毛细管压力降、表观粘度均显著降低,且随着振动频率和振幅的改变呈非线性变化趋势,作者对此进行了深入分析。 相似文献
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聚合物熔体粘弹行为对振动力场响应规律的研究进展 总被引:9,自引:2,他引:7
综述了国内外对聚合物熔体粘弹行为的研究,针对前人研究的不足,并为进一步解释聚合电磁动态成型机理,提出了黛助毛细管动态流变仪,从理论和实践角度探索聚物熔体粘弹行为对振动力场响应规律的新思路。 相似文献
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聚合物动态挤出流变行为研究 总被引:30,自引:5,他引:25
本文论述聚合物材料毛细管动态流变行为的测量原理,介绍了自行研制成功的用于合物熔体挤出的毛细管动态流变仪。在该仪器上对LDPE进行了实验研究,发现熔体的粘度与振动源的频率、振幅呈非线性关系。在振动必场作用下LDPE熔体的粘度减小,随振动频率的变化有一最小值。这对矣合物动态塑化挤出工艺过程控制具有十分重要意义。 相似文献
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在本文(Ⅰ)报所建立的振动力场作用下聚合物分子运动物理模型和解析模型的基础上,推导出了振动诱导作用下聚合物熔体动态表观黏度与振动频率的关系表达式。通过实例计算和动态流变仪实验验证,证明了该模型的正确性和有效性,并且得出结论:振动力场作用下,聚合物熔体的表观黏度与振动频率密切相关,表观黏度随振动频率增加而减小;当振幅大于聚合物分子链长度时(一般都会大于分子链长度),再增加振幅对表观黏度的影响不大。证明了(Ⅰ)报中物理模型以及数学推导的正确性,为聚合物成型加工工艺制定及成型设备研制提供了理论依据。 相似文献
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A pulse pressure was superimposed on the melt flow in extrusion, called vibration extrusion. A die (L/D = 17.5) was attached to this device to study the rheological properties of an amorphous polymer (ABS) and semicrystalline polymer (PP, HDPE), prepared in the vibration field, and the conventional extrusion were studied for comparison. Results show that the melt vibration technique is an effective processing tool for improving the polymer melt flow behavior for both crystalline and amorphous polymers. The enhanced melt rheological property is also explained in terms of shear thinning criteria. Increasing with vibration frequency, extruded at constant vibration pressure amplitude, the viscosity decreases sharply, and so does when increasing vibration pressure amplitude at a constant vibrational frequency. The effect of vibrational field on melt rheological behavior depends greatly on the melt temperature, and the great decrease in viscosity is obtained at low temperature. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5292–5296, 2006 相似文献
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Yue Jun Liu 《Polymer-Plastics Technology and Engineering》2013,52(8-9):1645-1656
The apparent viscosity of a polymer melt within a capillary was analyzed based on experimental measuring when a sine vibration of small amplitude was superimposed in a parallel manner on the extruding direction of polymer melt. The theoretical model for apparent viscosity of polymer melt under an superimposed vibration was set up independent of any existing constitutive equations. Meanwhile, the calculating steps for previously apparent viscosity were established by making use of novel rheological measurement equipment that was designed by the author. Through collecting and analyzing the instantaneous data of a polymer melt dynamic extruding through a capillary under definite frequency and amplitude of vibration, the apparent viscosity of a polymer melt within a capillary was then calculated. 相似文献
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In this article, under shearing vibration and pressure vibration, the rheological behavior of HDPE, ABS, and PS melts and the mechanical properties of molded parts are studied. The experimental results show that, under the vibration condition, the apparent viscosity of the polymer melt decreases with an increasing of the vibration frequency and amplitude applied. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1587–1592, 2002 相似文献
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The isothermal sagging resistance of different grades of conventional and a high melt strength (HMS) PP has been correlated with the rheological characteristics of the polymers, such as dynamic shear properties, melt strength, and zero shear viscosity. A thermoforming grade of acrylonitrile‐butadiene‐styrene (ABS) was used as a reference material. At 190°C, ABS had the highest viscosity and elastic modulus in the frequency range measured, showing that this polymer is highly elastic. HMS PP had a greater shear thinning behavior than conventional PP because of its broader molecular weight distribution. The tan δ of the polymers showed that conventional PP had a higher tendency to flow than HMS PP and ABS when heated above 172°C. This was confirmed with sagging experiments performed in an air circulating oven, where the rate of sagging decreased as the melt strength and the zero shear viscosity of the polymer increased. 相似文献