水辅成型技术在自行车前叉上的应用

基于纯水液压水辅助注射成型设备,将水辅成型技术与传统注塑行业结合起来,以自行车前叉为模具,成型自行车前叉制件.主要从制件水穿透长度,中空率及残余壁厚等方面对试验结果进行分析,结果表明,在适当注塑工艺参数条件下.水辅成型技术能应用于自行车前叉的成型.     

超声振动场对玻纤增强型PBT薄壁塑件成型性能的影响

以一般注塑条件下发生严重短射的薄壁制件为成型目标,利用自主研发的超声辅助薄壁注塑成型装置,研究了超声振动场对玻纤(含量30%)增强型聚对苯二甲酸丁二醇酯(PBT)充填性能及成型制件性能的影响。结果表明:超声辅助薄壁注塑成型技术能够改善成型制件的充填质量,超声振动场能够影响制件芯层玻纤取向。另外,由该技术得到的成型制件的熔点比传统注塑成型制件有所升高。     

成果转让

气体辅助注塑成型技术项目简介气体辅助注塑成型是通过把高压气体引入到制件的厚壁部位 ,在注塑件内部产生中空截面 ,完全充填过程、实现气体保压、消除制品缩痕的一项新颖的塑料成型技术。传统注塑工艺不能将厚壁和薄壁结合在一起成型 ,而且制件残余应力大 ,易翘曲变形 ,表面时有缩痕。新发展的气辅技术通过把厚壁的内部掏空 ,成功地生产出厚壁、偏壁制品 ,而且制品外观表面性质优异 ,内应力低。轻质高强。现已开发成功气辅产品结构和模具设计包括浇注系统、进气方式和气道分布设计技术 ,气辅注塑工艺设计技术 ,气辅注塑过程计算机仿真技术…     

薄壁注塑对注射机和模具的要求

对生产小而轻的制件的需求已经使薄壁注塑成为注塑机最需增加的性能。“薄壁”通常由壁厚小于1mm的轻便电子制件所定义的。对大的汽车制件来说，“薄”可以是2mm。总之，薄壁制品要求改变加工工艺：更高的压力和速度，更短的冷却时间，改变制件顶出和浇口排列。加工工艺的改变进而促进了模具、机器和制件设计的发展。下面就薄壁注塑对于注射机和模具的要求作一介绍，希望能对关注薄壁注塑的读者有所帮助。     

薄壁注塑对注射机和模具的新要求

对生产小而轻的制件的需求已经使薄壁注塑成为注塑机最需增加的性能。“薄壁”通常是由壁厚少于1mm的轻便电子制件所定义的。对大的汽车制件来说，“薄壁”可以是2mm。总之，薄壁制品要求改变加工工艺：更高的压力和速度、更短的冷却时间、改变制件顶出和浇口排列。以下是薄壁注塑对注射机和模具的要求。     

薄壁注塑对注射机和模具的新要求

对生产小而轻的制件的需求已经使薄壁注塑成为注塑机最需增加的性能。“薄壁”通常是由壁厚少于1mm的轻便电子制件所定义的。对大的汽车制件来说，“薄壁”可以是2mm。总之，薄壁制品要求改变加工工艺：更高的压力和速度、更短的冷却时间、改变制件顶出和浇口排列。以下是薄壁注塑对注射机和模具的要求。     

薄壁产品对注塑设备的新要求

现今，薄壁产品的注塑生产显得越来越重要，以至对其注塑设备提出新要求，成为注塑机最需增加的性能。薄壁通常是指壁厚小于1mm的轻便电子制件。对大的汽车制件来说，薄壁壁厚可以是2mm。据专家介绍，薄壁制品要求注塑设备具有更高的压力和速度、更短的冷却时间、改变制件顶出和浇口排列。     

薄壁注射对注射机和模具的要求

对生产小而轻的制件的需求已经使薄壁注塑成为注塑机最需增加的性能。“薄壁”通常由壁厚小于1mm的轻便电子制件所定义的。对大的汽车制件来说，“薄”可以是2mm。总之，薄壁制品要求改变加工工艺：更高的压力和速度，更短的冷却时间，改变制件顶出和浇口排列。加工工艺的改变进而促进了模具、机器和制件设计的发展。下面对薄壁注塑对注射机和模具的要求作一介绍，希望对读者有所帮助。     

溴化1-乙烯基-3-烷基咪唑离子液体的电化学性能

合成了溴化1-乙烯基-3-烷基咪唑([VAIM]Br)离子液体,采用FTIR、¹H NMR、TG及DSC进行了表征,并系统研究了[VAIM]Br的电化学性能。结果表明:在298.15～323.15 K内,[VAIM]Br的电导率(σ)与温度符合Arrhenius方程,电导活化能随[VAIM]⁺上烷基链的增长而降低。分别以水、甲醇和乙醇为溶剂的[VAIM]Br溶液的电导率均随浓度的增大而显著增大,且σ(水)>σ(甲醇)>σ(乙醇)。通过电导法确定了[VAIM]Br在水、甲醇、乙醇中的临界胶束浓度,分别约为6.8×10^-6、1.5×10^-5、2.0×10^-5 mol·L^-1,表面活性优异。[VAIM]Br的电化学窗口在1.6～2.5 V,其电化学稳定性随[VAIM]⁺上烷基链的增长而逐渐降低。     

工艺参数对气体辅助注射成型结果的影响

以轿车保险杠为例，利用正交设计法和模塑流动软件定量分析了气体辅助注射成型的四个主要工艺参数对成型结果的影响。结果表明，制件的最终质量是各参数综合作用的结果，其中，熔体／气体延迟时间对成型结果的影响最大，气体注塑压力次之，预注射量最小。     

Process‐induced phase and crystal morphologies in water‐assisted injection molded polypropylene/polymeric β‐nucleating agent blend parts

By adding a polymeric β‐nucleating agent (acrylonitrile–styrene copolymer, SAN), in situ microfibril reinforced isotactic polypropylene (iPP)/SAN blend parts with high contents of β‐form crystals and transcrystals were molded via water‐assisted injection molding (WAIM). Thanks to the unique stress and temperature fields occurring during the WAIM, SAN microfibers formed across the whole residual wall of iPP/SAN blend parts with relatively large thickness. Numerical simulations on high‐pressure water penetration and cooling stages of the WAIM were carried out to reveal the stress and temperature fields. Comprehensive analysis of both experimental and simulated results showed that not only the shear flow field but also elongational flow field occurring during the WAIM was responsible for the formation of SAN microfibers and unique crystal morphology distribution in the WAIM iPP/SAN blend part. Moreover, during the WAIM, the high cooling rate also played an important role in the formation of both phase and crystal morphologies. The preferential formation of transcrystals in the inner layer of WAIM iPP/SAN blend part could be ascribed to the strong elongation, rather than the strong shear. It was believed that the quantification of stress and temperature fields of the WAIM via numerical simulation could provide a guidence for molding high‐performance products. POLYM. ENG. SCI., 55:1698–1705, 2015. © 2014 Society of Plastics Engineers     

水辅注射成型聚丙烯制品的取向结晶

应用小角X射线散射研究了水辅注射成型(WAIM)等规聚丙烯制品中串晶(shish-kebab)结构的形成、分布以及片晶取向行为.结果表明:根据取向度不同,WAIM制品沿壁厚方向可明显分为表层、芯层和水道层.表层和水道层均有shish-kebab结构生成,且在表层生成的数量比水道层多,而芯层则没有这种结构.这种shish...     

溢流法水辅注塑中注水参数对水穿透的影响分析

借助外挂有自主研发的注水系统及模具的注塑系统,采用单因素法实验分析了注水压力、注水温度和注水延迟时间等注水参数对水穿透及产品品质的影响规律及机理。研究发现,注水压力越大,试样残余壁厚越薄,内壁面也更加的光亮;低注水压力下,水的穿透容易出现界面不稳定现象,注水压力越高,水的穿透居中性越好;注水温度对试样残余壁厚的影响不明显;注水延迟时间增加,试样残余壁厚增加,且能有效削弱低注水压力下水穿透的界面不稳定现象。     

Numerical simulation on residual wall thickness of tubes with dimensional transitions and curved sections in water‐assisted injection molding

Residual wall thickness is an important indicator which aims at measuring the quality of water‐assisted injection molding (WAIM) parts. The changes of residual wall thickness around dimensional transitions and curved sections are particularly significant. Free interface of the water/melt two‐phase was tracked by volume of fluid (VOF) method. Computational fluid dynamics (CFD) method was used to simulate the residual wall thickness, and the results corresponded with that of experiments. The results showed that the penetration of water at the long straight sections was steady, and the distribution of the residual wall thickness was uniform. However, there was melt accumulation phenomenon at the dimensional transitions, and the distribution of the residual wall thickness wasn't uniform. Adding fillet at the dimensional transitions could improve the uniformity of the residual wall thickness distribution, and effectively reduce water fingering. Additionally, at the curved sections, the residual wall thickness of the outer wall was always greater than that of the inner wall, and the fluctuations of the residual wall thickness difference were small. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

成型工艺对短玻璃纤维增强聚丙烯注塑管件的壁厚分布及玻璃纤维取向的影响

以气体辅助注射成型（GAIM）、水辅助注射成型（WAIM）、气体驱动弹头辅助注射成型（G-PAIM）及水驱动弹头辅助注射成型（W-PAIM）制备了一系列短玻璃纤维增强聚丙烯弯形管件,对比了各成型工艺对其管件壁厚及玻璃纤维取向分布的影响。结果表明,以管件总体壁厚大小排序为GAIM>WAIM>W-PAIM>G-PAIM,其中G?PAIM与W-PAIM管件壁厚差异较小;4种成型工艺的管件壁厚方差均较小,各壁厚均匀性较好;WAIM管件的玻璃纤维取向度总体上高于GAIM;且弹头的引入使得管件沿流动方向的玻璃纤维取向度更高。     

工艺参数对聚丙烯/聚酰胺6共混材料WAIM管件性能及微观形态的影响

基于自行搭建的水辅助注射成型(WAIM)实验平台对聚丙烯/聚酰胺6（PP/PA6）共混材料进行WAIM实验,探究工艺参数对PP/PA6共混材料的WAIM管件的残余壁厚、表观质量及力学性能的影响,并进行了微观形态观测。结果表明,随着熔体温度、模具温度和注水压力的增加,塑件残余壁厚逐渐减小;随着注水延迟时间的增加,塑件残余壁厚逐渐增大;随着模具温度、注水延迟时间的增加,管件拉伸强度逐步增大;随着熔体温度、注水压力的增大,管件拉伸强度逐步减小;工艺参数通过温度场的变化影响熔体的成核和晶体长大从而影响结晶度,结晶度越高,管件的拉伸强度越高。     

水辅助注塑聚丙烯制品的晶体结构研究

通过偏光显微镜(PLM)观察了水辅助注塑(WAIM)聚丙烯(PP)制品靠近注水喷嘴和远离注水喷嘴两个位置的晶体结构,发现WAIM制品沿壁厚方向都可以分为表层、中芯层和水道层,并且发现两个位置水道层和中芯层的晶体结构比较相似,表层晶体结构出现了较大的差异;靠近注水喷嘴位置表层晶体结构出现明显的取向现象,而在远离注水喷嘴位置没有出现。在晶体结构分析的基础上,初步探讨了水辅助注塑制品晶体结构的形成机理。结果表明:水的穿透对于熔体内部剪切的增加和取向结晶的形成有明显的促进作用。     

The hierarchical structure of water-assisted injection molded high density polyethylene: Small angle X-ray scattering study

High density polyethylene (HDPE) was molded by a new polymer processing method, that is, water-assisted injection molding (WAIM), and its hierarchical structure was studied by two-dimensional small angle X-ray scattering (SAXS). For comparison, the hierarchical structure of HDPE molded by conventional injection molding (CIM) was also characterized. The result shows that the WAIM part exhibits a distinct skin-core-water channel structure which is different from the skin-core structure for the CIM part. In the skin layer of both WAIM and CIM parts, the shish-kebab structure was formed due to the shear stress brought by melt filling, but the lamellar orientation parameter of CIM part is smaller than that of WAIM part. The spherulites with random lamellar orientation are dominant at the core of both parts owing to the low cooling rate and feeble shear stress therein. Interestingly, the shish structure and the lamellae with low level of orientation can be found at the water channel layer of WAIM part. They are attributed to the shear stress brought by water penetration. Moreover, the lamellar orientation parameter in water channel layer is smaller than that of skin layer. In addition, the long period of WAIM part first increases and then decreases with the elevating distance from the skin surface, while that of CIM part tends to increase monotonously. In a word, one can conclude that the rapid cooling rate and shear brought by the injected water have significant influence on the structural evolution for the WAIM part. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

水冷壁气化炉温度分布及影响因素分析

对气流床水冷壁气化炉炉壁的温度分布及影响因素进行了计算和分析。建立了气流床水冷壁气化炉的三维传热数学模型,运用有限元方法,计算出水冷壁的温度分布,炉壁导热主要通过渣钉完成;探讨了水冷管内工质传热系数、炉内温度、渣钉间距、鳍片厚度、鳍片宽度及熔渣厚度对渣钉、水冷管、鳍片端部和根部等关键部位的最高温度点温度的影响;为了验证热分析的正确性,在实验室的小型气化炉上进行试验,鳍端背火侧温度计算值与实验测量值吻合良好,误差在5%之内;其计算模型和分析结果可为水冷壁气化炉的设计提供相应依据。     

Prediction of process parameters of water-assisted injection molding based on inverse radial basis function neural network

Because of the introduction of new processing parameters in water-assisted injection molding (WAIM), processes control has become more difficult. First, design of experiment (DOE) was carried out by using optimized Latin hypercubes (Opt LHS). On the basis of this, computational fluid dynamics (CFD) method was used to simulate and calculate hollowed core ratios and wall thickness differences of cooling water pipe at different positions. Then inverse radial basis function (RBF) neural network model reflecting the fitting relationship between processing parameters and molding quality was established, and accuracy of the model was detected by cross validation. Finally, expected molding quality was applied to predict processing parameters, and the obtained molding quality under the predicted processing parameters was verified by computer aided engineering (CAE) simulation and experimental methods. The results showed that mean relative precisions of processing parameters such as melt temperature, delay time, short shot size, water pressure, and mold temperature for inverse RBF model were 98.6%, 93.6%, 98.5%, 93.9%, and 97.9%, respectively, which met the accuracy requirements. Furthermore, compared with expected values of hollowed core ratios and wall thickness differences, the average errors of CAE and experiment were 2.3% and 4.9%, respectively.