磨细粉煤灰与分选细粉煤灰的性能对比研究

本文研究了比表面积相近的由分选粗灰粉磨而成的磨细粉煤灰与分选细粉煤灰的颗粒形貌及水泥胶砂性能.研究结果表明,磨细粉煤灰圆珠状颗粒较少,且表面较为粗糙,在相同水胶比的条件下,其水泥胶砂流动度较小;在相同水泥胶砂流动度的条件下,磨细粉煤灰配制的水泥胶砂28d及早期强度较低,但随着龄期的增长,其差距逐步缩小,至60d时,掺磨细粉煤灰的水泥胶砂强度可超过掺分选细粉煤灰的水泥胶砂强度.     

磨细粉煤灰对水泥基复合胶凝材料流变性能及硬化性能的影响

本文主要研究磨细粉煤灰对水泥基复合胶凝材料的流变性能及硬化性能的影响.研究结果表明:磨细粉煤灰较小的颗粒能够弥补水泥粉体颗粒中8μm以下较小颗粒的缺乏,使磨细粉煤灰-水泥复合胶凝颗粒形成良好的级配,在掺量适宜的情况下对复合水泥浆体的流动度会略有改善,但掺量过大,会显著降低复合水泥浆体的流动度;与Ⅰ级粉煤灰相比,磨细粉煤灰的颗粒粒径更小,火山灰活性更大,火山灰活性对强度的贡献在3d时开始显现,且随着龄期增长越来越大,能显著提高硬化浆体中后期抗压强度;与抗压强度相比,磨细粉煤灰更利于提高抗折强度,且掺量越大,中后期抗折强度越高.     

用粉煤灰配制调粒水泥的研究

对粉煤灰等工业废渣进行深加工处理,进而配制调粒水泥,结果表明,在普通水泥或超细水泥中单掺60%原状粉煤灰或超细粉煤灰制备调粒水泥是不可行的,其胶砂流动度差, 3d和28d强度低。正交实验结果表明,在40%比表面积为765m2/kg的超细水泥中掺加10%比表面积为392m2/kg的磨细矿渣、 30%比表面积为789m2/kg的磨细粉煤灰以及20%比表面积为350m2/kg的市售石灰石粉可制得525#复合调粒水泥,与原水泥相比,在胶砂流动度大致相同的条件下,其需水量可降低约3个百分点, W/C为0.44时,胶砂流动度高达159mm。用所得调粒水泥配制高性能砼,拌合物坍落度与扩展高达260mm和660mm, 1h、 2h坍落度损失仅为5mm和15mm,而扩展度损失也仅有60mm和50mm, 28d强度达到71.5MPa, 180d强度则高达91.0MPa。     

用粉煤灰配制调料水泥的研究

对粉煤灰等工业废渣进行深加工处理 ,进而配制调粒水泥 ,结果表明 ,在普通水泥或超细水泥中单掺6 0 %原状粉煤灰或超细粉煤灰制备调粒水泥是不可行的 ,其胶砂流动度差 ,3d和 2 8d强度低。正交实验结果表明 ,在40 %比表面积为 76 5m2 /kg的超细水泥中掺加 10 %比表面积为 392m2 /kg的磨细矿渣、30 %比表面积为 789m2 /kg的磨细粉煤灰以及 2 0 %比表面积为 35 0m2 /kg的市售石灰石粉可制得 5 2 5 #复合调粒水泥 ,与原水泥相比 ,在胶砂流动度大致相同的条件下 ,其需水量可降低约 3个百分点 ,W /C为 0 .44时 ,胶砂流动度高达 15 9mm。用所得调粒水泥配制高性能砼 ,拌合物坍落度与扩展高达 2 6 0mm和 6 6 0mm ,1h、2h坍落度损失仅为 5mm和 15mm ,而扩展度损失也仅有 6 0mm和 5 0mm ,2 8d强度达到 71.5MPa ,180d强度则高达 91.0MPa     

聚羧酸高效减水剂对分选和磨细粉煤灰作用差异研究

为揭示聚羧酸高效减水剂对分选和磨细粉煤灰的作用效果差异,采用净浆流动度法和吸光度法,研究了聚羧酸高效减水剂对两种粉煤灰浆体流动度的影响差异,以及在其表面吸附特征的差异.结果表明,在水灰比为0.4时,磨细粉煤灰浆体没有流动性,而分选粉煤灰净浆流动度为98 mm;但掺入聚羧酸高效减水剂后,磨细粉煤灰浆体的流动性明显高于分选粉煤灰;聚羧酸高效减水剂在两种粉煤灰颗粒表面的吸附均符合Langmuir等温吸附方程,且磨细粉煤灰颗粒表面的吸附量远大于分选粉煤灰.     

磨细粉煤灰与起细粉煤灰的性能对比试验研究

比较了在同等细度下,用普通球磨机粉磨的磨细粉煤灰与电收尘气流分选工艺收集的超细粉煤灰的物理、化学性质,以及力学性能。试验结果表明,磨细粉煤灰的性能优于超细粉煤灰,进而确定了激发剂的最佳掺量。     

掺纳米SiO2/稻壳灰/粉煤灰水泥基材料性能的试验研究

通过对不同掺量稻壳灰(RHA)/粉煤灰(FA)和纳米SiO2 (NS)水泥基试样比表面积、需水量、凝结时间和水泥胶砂强度的测试,讨论了RHA/FA和NS掺量对水泥比表面积、需水量、凝结时间和胶砂强度的影响.结果表明,掺加RHA/FA会增大水泥比表面积,引起需水量的增大,延长水泥初、终凝时间,适量掺加NS会降低水泥比表面积,缩短水泥初、终凝时间,当RHA/FA掺量为20％时加入2％ NS,RHA/FA和NS对水泥浆的需水量及凝结时间影响不大;RHA/FA取代水泥后,水泥胶砂3d和28 d强度均有所下降,加入NS后,各龄期强度均得到提高,尤其是3d强度提高幅度较大.可以通过掺加NS来弥补RHA/FA的掺入所引起的早期强度降低,达到相同强度可以适当提高RHA/FA的掺量.     

一种磨细粉煤灰的新型检测方法

发现一种数值图像分析法检测磨细粉煤灰,并对掺加磨细粉煤灰的砂浆的流动性能进行研究。研究结果表明:细度、比表面积与破碎率之间不存在显著的线性关系。破碎率与水泥净浆和砂浆的流动性能存在良好线性关系。相同配比时,随着破碎率增加,浆体的流动度逐渐增大;相同流动度砂浆,随着破碎率增加,浆体的需水量比逐渐降低。     

粉煤灰粉磨方式对其电耗及性能的影响研究

本文对比了两种粉磨设备（立磨和球磨）以及球磨中不同研磨介质在粉磨粉煤灰时,其电耗及性能的差别。通过试验得出：粉煤灰磨细到相同比表面积时,立磨主机电耗约为球磨主机电耗的70%~75%,且随着比表面积的增加,立磨与球磨主机电耗的差值变小。磨细粉煤灰的活性均有提高,且活性随着比表面积的增加而增加,球磨机系统活性增长明显,而立磨活性的增长则相对较小。当磨细粉煤灰比表面积为6000cm2/g时,立磨粉煤灰的活性最大。球磨机采用不同研磨介质生产的粉煤灰,其活性相差不多。粉磨设备及研磨介质类型对粉煤灰的需水量比无影响。     

磨细循环流化床飞灰对水泥性能的影响

本文用球磨机将循环流化床飞灰磨细,通过测试细度、安定性、需水量比、砂浆流动度、活性指数、胶砂强度等指标,分析粉磨前后飞灰的物理性能变化和对水泥性能的影响。结果表明：随着磨细时间的增加,可有效降低掺入飞灰后水泥的需水量,使流动度提升;粉磨可明显提高飞灰活性,使飞灰自硬性与干缩性能也有所改善;粉磨30 min和50 min的飞灰掺入水泥后均未发现安定性问题;10%飞灰掺量可以使水泥胶砂强度提升,继续增加飞灰掺量则会降低水泥胶砂强度。将循环流化床飞灰磨细可有效改善原状飞灰需水量大、活性低的问题,可作为辅助胶凝材料用于水泥或混凝土中。     

公路粉煤灰水泥的研制（一）

文中研究了熟料掺量、复合激发剂、石膏掺量、水泥颗粒粒度对公路粉煤灰水泥的影响.获得了公路粉煤灰水泥的最佳配料方案和工艺参数.与粉煤灰硅酸盐水泥性能相比,公路粉煤灰水泥早期强度略低于粉煤灰硅酸盐水泥,凝结时间较长,但其7d～28d水化龄期内的强度增长率较高,28d强度已赶上或超过粉煤灰硅酸盐水泥,胶砂流动度好.     

脱硝粉煤灰铵含量对水泥胶砂性能影响研究

研究了脱硝粉煤灰的铵含量对水泥胶砂物理性能的影响规律,提出脱硝粉煤灰残留铵的安全含量阈值。结果表明:随着粉煤灰中铵含量的逐渐升高,水泥标准稠度用水量、需水量比和含气量呈现逐渐升高的趋势,而胶砂强度、活性指数和流动度逐渐降低,且凝结时间显著延长。粉煤灰铵含量对水泥安定性、水化热、假凝和干缩性能的影响并不明显。在一般工程情况下,建议脱硝粉煤灰的铵含量应不大于200 mg/kg。     

粉煤灰、矿渣掺量对胶砂强度的影响

对不同粉煤灰、矿渣掺量的胶砂抗压、抗折强度进行了研究.结果表明,水泥胶砂中随粉煤灰取代水泥量增加,胶砂3d、28d抗压和抗折强度不断减小.水泥胶砂中随矿渣取代水泥量增加,胶砂3d抗压和抗折强度不断减小;当矿渣取代量小于55％时,胶砂28d的抗压和抗折强度均稍有提高,当矿渣取代量大于60％时,胶砂28d的抗压和抗折强度均...     

Packing effect and pozzolanic reaction of fly ash in mortar

This research is to study the effect of particle size of fly ash on packing effect and pozzolanic reaction of mortar when 20% of fly ash is used to replace Portland cement type I. Both effects can be determined by using fly ash and insoluble material which have almost the same particle size to replace Portland cement type I. Normally, the compressive strength of fly ash mortar is contributed from hydration reaction, packing effect, and pozzolanic reaction. For mortar mixed with insoluble material, the compressive strength is due to hydration reaction and packing effect. Thus, compressive strength due to pozzolanic reaction can be determined from the difference in compressive strength between fly ash mortar and insoluble material mortar. The results show that the strength activity index of fly ash mortar depends on the median particle size of fly ash and curing ages of mortar samples. At early ages, the strength activity index of fly ash mortar due to packing effect is higher than that due to pozzolanic reaction. At the ages of 3 to 90 days, the difference in strength activity index due to packing effect of fly ashes with median particle size of 2.7 and 160 μm is almost constant about 22% of the strength of standard mortar (STD). The differences in strength activity index due to pozzolanic reaction of fly ashes with median particle size of 2.7 and 160 μm are 3%, 20%, and 27%, respectively, at the ages of 3, 28, and 90 days.     

粉煤灰渣替代细骨料对砂浆混凝土强度及抗冻性影响

通过筛分和破碎两种方式分别获得粒径区间为0.6~1.18 mm、0.3~0.6 mm的粉煤灰渣,并用其等体积替代对应粒径区间的细骨料,分析粉煤灰渣对砂浆工作性和强度的影响,探究粉煤灰渣的最优替代粒径区间。结合扫描电镜(SEM)、能谱分析(EDS)等方法分析了粉煤灰渣替代细骨料后砂浆试件的强度变化机理。基于砂浆最优替代粒径区间结果,验证了砂浆混凝土试件的强度和抗冻性。研究结果表明:分别以筛分方式和破碎方式得到的0.3~0.6 mm粒径区间粉煤灰渣替代对应区间细骨料后,其砂浆试件强度均与基准组(未替代)基本一致;而以筛分方式得到的0.3~0.6 mm粒径区间粉煤灰渣替代对应区间细骨料后,其混凝土试件强度和抗冻性与基准组基本一致。在水泥提供的氢氧化钙环境下粉煤灰渣表面生成水化硅酸钙,从而增加了水泥和粉煤灰渣界面胶结强度,强化水泥与粉煤灰渣界面区域,凹凸不平的粉煤灰渣表面与水泥浆咬合嵌锁,保证了试件的强度。     

利用超细粉煤灰及钢渣配制用于道路的复合硅酸盐水泥的试验研究

通过大量试验在水泥熟料中复合掺入超细粉煤灰及磨细钢渣粉,配制了用于公路路面水泥混凝土工程的复合硅酸盐水泥,重点改善道路水泥的抗折强度、耐磨性能以及收缩抗裂性能。结果表明,随着超细粉煤灰及磨细钢渣粉的掺入,所配制的水泥胶砂强度及耐磨性均满足425号道路硅酸盐水泥要求,与基准水泥相比,规定龄期的收缩变形均显著降低,圆环法抗裂试验结果也表明水泥抗裂性能得到大幅度增强。     

Influence of fly ash fineness on strength, drying shrinkage and sulfate resistance of blended cement mortar

In this paper, the influence of fineness of fly ash on water demand and some of the properties of hardened mortar are examined. In addition to the original fly ash (OFA), five different fineness values of fly ash were obtained by sieving and by using an air separator. Two sieves, Nos. 200 and 325, were used to obtain two lots of graded fine fly ash. For the classification using air separator, the OFA was separated into fine, medium and coarse portions. The fly ash dosage of 40% by weight of binder was used throughout the experiment. From the tests, it was found that the compressive strength of mortar depended on the fineness of fly ash. The strength of mortar containing fine fly ash was better than that of OFA mortar at all ages with the very fine fly ash giving the highest strength. The use of all fly ashes resulted in significant improvement in drying shrinkage with the coarse fly ash showing the least improvement owing primarily to the high water to binder ratio (W/B) of the mix. Significant improvement of resistance to sulfate expansion was obtained for all fineness values except for the coarse fly ash where greater expansion was observed. The resistance to sulfuric acid attack was also improved with the incorporation of all fly ashes. In this case the coarse fly ash gave the best performance with the lowest rate of the weight loss owing probably to the better bonding of the coarse fly ash particles to the cement matrix and less hydration products. It is suggested that the fine fly ash is more reactive and its use resulted in a denser cement matrix and better mechanical properties of mortar.     

Influence of fly ash and its mean particle size on certain engineering properties of cement composite mortars

An experimental investigation on the effects of incorporating large volumes of fly ash on the early engineering properties and long-term strength of masonry mortars is reported. The effect of fly ash and its mean particle size (PD) on the variation of workability and strength has been studied. It was found that fly ash and its mean particle size play a very significant role on the strength of masonry mortars. It has been observed that the early-term strength, except the mortars incorporating coarse fly ash (CFA), was slightly influenced by the replacement with fly ash. The long-term strength (both the bond strength and the compressive strength) will significantly increase, especially for the bond strength of mortars incorporating coarse fly ash. It was also found that the bond strength significantly increased as the mean particle size of fly ash decreases after 28 days curing. However, the 7-day strength was little influenced by fly ash particle size. The fluidity of composite mortar enhanced due to replace cement and lime with fly ash, and the mean PD of fly ash significantly influenced the workability.     

粉煤灰粒度分布对水泥性能的影响

主要研究了不同粉磨时间的粉煤灰密度、比表面积、粒度分布等颗粒特性的变化规律,以及研究了将不同粉磨时间的粉煤灰按30％比例掺人硅酸盐水泥中的水泥性能变化情况.结果表明：随着粉磨时间的增加,粉煤灰颗粒的密度、比表面积和粒度分布都呈有规律的变化;其中粉磨60 min时的粉煤灰水泥性能达到最佳.     

熟料细度对粉煤灰水泥浆体强度和自收缩的影响

通过实验室球磨机制备出比表面积分别为280m2/kg、370m2/kg和670m2/kg的3种水泥熟料,与不同掺量的粉煤灰配制成不同颗粒级配的粉煤灰水泥,并测试了粉煤灰水泥浆体的抗压强度、自收缩、孔隙率和显微结构。结果表明：提高熟料细度能在很大程度上降低粉煤灰水泥浆体的孔隙率并提高复合水泥浆体早期抗压强度;粉煤灰的掺入降低了水泥体系的自收缩,提高了粉煤灰水泥浆体的体积稳定性;粉煤灰水泥浆体背散射图像表明,提高熟料细度可显著减少粉煤灰水泥浆体中未水化的水泥颗粒含量,并在一定程度上减少未水化粉煤灰颗粒含量。