Influence of martensite formation and grain size on room temperature low cycle fatigue behaviour of AISI 304LN austenitic stainless steel

Abstract

The effects of strain induced martensite formation and grain size on the room temperature low cycle fatigue behaviour of AISI 304LN austenitic stainless steel were considered. Two grain sizes, namely, 60 and 350 μm, were developed via suitable solution annealing treatments. Microstructural changes before and after low cycle fatigue testing were identified. The martensitic transformation was studied using aferritescope, X-ray diffractometry, and optical microscopy. The mechanical response was correlated with the microstructural changes. Secondary hardening as well as a crossover in the strain–life plots for the two grain sizes resulted from martensite formation. Dislocation configurations depended on the strains imposed.

MST/1902     

Influence of alloying elements on hot corrosion of superalloys and coatings: necessity of smart coatings for gas turbine engines

Abstract

Modern gas turbine engines require high performance materials and coatings to ensure high efficiency. The selection of high performance materials and coatings depends on the nature and concentration of alloying elements. The composition of materials and coatings, in particular, plays a major role in enhancing the life of gas turbine engines by exhibiting good resistance to oxidation and hot corrosion, which are major problems in gas turbine engines. The performances of several superalloys containing different alloying elements and MCrAlY type coatings containing a variety of major and minor alloying elements are described in detail. The effect of major and trace elements on the life of superalloys and coatings in the presence of pure Na₂SO₄, NaCl and vanadium containing environments is detailed. The relevant reaction mechanisms leading to the failure of superalloys and coatings are discussed. The major factors involved when selecting alloying elements for the preparation of superalloys to manufacture components intended for use under hot corrosion conditions and the selection of appropriate coatings are suggested. Finally, the necessity of innovation of 'smart coatings' to combat both oxidation and hot corrosion is discussed.     

Effect of temperature and strain rate on tensile flow and work hardening behaviour of a Ti modified austenitic stainless steel

Abstract

The tensile flow stress data for a 15Cr - 15Ni - 2.2Mo - Ti modified austenitic stainless steel in the temperature range 300 - 1023 K and in the strain rate range 6.3 × 10^-5- 1.3 × 10^-2 s^-1 was analysed in terms of the Ludwigson and Voce equations. It was found that the Ludwigson equation described the flow behaviour adequately up to the test temperature of 923 K, whereas the Voce equation could be employed over the full temperature range. The peaks/ plateaus observed in the variation of these parameters as a function of temperature and strain rate in the intermediate temperature range have been identified as one of the manifestations of dynamic strain aging (DSA). Also the variation of these parameters with temperature and strain rate could clearly bring out the different domains of DSA observed in this alloy. The work hardening analysis of the flow stress data revealed that, in the DSA regime, the onset of stage III hardening is athermal.     

Deformation twinning in AISI 316L austenitic stainless steel: role of strain and strain path

Abstract

AISI 316L austenitic stainless steel was deformed at different strain and strain paths. The twin boundaries in the deformed microstructure had two possible origins: decay of original annealing twins and generation of deformation twins. Assuming that rotations of grains, specifically grains on both sides of a twin boundary, are responsible for the twin decay, a simple model was proposed to bring out the domain of relative twin generation. A biaxial strain path, in general, was associated with strong twin generation – an association or dependency linked to the texture estimated values of Taylor factor. Formation of strain induced martensite was also observed to be strain and strain path dependent and was more in biaxial strain path.     

Effect of boron on hot ductility oflow carbon low alloyed steel

Abstract

The influence of boron on the hot ductility of C-Mn-Al-Cr steel has been investigated. At <980°C M(CB)₃ precipitated out and about half of the boron content was in solution in austenite at >900°C. It was found that solute boron atoms segregate to austenite grain boundaries and occupy the vacancies induced by deformation. This prevents the formation and propagation of microcracks at boundaries and results in improved hot ductility and a reduced dynamic recrystallisation temperature.     

Influence of hot rolling and heat treatment on structure and properties of HSLA steel explosively clad with austenitic stainless steel

Abstract

The present work aims at studying structure–property correlations in an explosively clad HSLA steel with austenitic stainless steel of AISI 304L grade. The clad plate was subjected to hot rolling followed by a quenching and tempering treatment to achieve better mechanical properties in the base plate. Optical microscopy studies revealed that the interface between the two steels was wavy in the as clad plate and the waviness decreased substantially due to hot rolling. Subsequent heat treatment has not shown any significant effect either. The base plate had tempered martensite/bainite structure in as clad or heat treated conditions and ferrite-pearlite-bainite structure in hot rolled condition. The grains were finer and elongated near the interface. The stainless steel exhibited equiaxed grain structure in as clad, hot rolled or heat treated plates. Tensile properties and charpy impact energy of the base plate were lowered due to hot rolling and then increased substantially due to heat treatment. The microhardness was observed to be a maximum at the bond interface for all three conditions studied. The shear bond strength was the highest in the as clad condition and decreased for the rolled as well as heat treated conditions. Scanning electron microscopy fractography on shear bond specimens revealed the presence of predominantly equiaxed dimples with few regions of rubbed fracture. Quantitative electron probe microanalysis across the bond interface indicated linear change in concentrations of nickel, chromium and manganese between the levels appropriate to the clad layer and base metal.     

Reaction sintering and joining nickel aluminide to AISI 316 stainless steel by self-propagating high temperature synthesis

Abstract

Self-propagating high temperature synthesis (SHS) is a process whereby reactants are ignited to spontaneously transform to products in an exothermic reaction. The aim of this study is to propose a method to join nickel aluminide with AISI 316 stainless steel by SHS and to study the combustion synthesis of nickel aluminide. From the heat of combustion synthesis junctions were formed between annular AISI 316 stainless steel and a powder metallurgy compact of Ni and Al blends. The Al mole ratio for testing the joining grade in the initial powder mixture varied from 25 at.-% to 40 at.-%. In order to check the sufficiency of the SHS reaction, the test temperature was compared with the thermodynamic calculation values. The metallographic analysis indicated that NiAl and Ni₃Al were formed in the joint layer.     

Effect of strain rate on quasistatic tensile flow behaviour of solution annealed 304 austenitic stainless steel at room temperature

Room temperature tensile test results of solution annealed 304 stainless steel at strain rates ranging between 5 × 10⁻⁴ and 1 × 10⁻¹ s⁻¹ reveal that with increase in strain rate yield strength increases and tensile strength decreases, both maintaining power–law relationships with strain rate. The decrease in tensile strength with increasing strain rate is attributed to the lesser amount of deformation-induced martensite formation and greater role of thermal softening over work hardening at higher strain rates. Tensile deformation of the steel is found to occur in three stages. The deformation transition strains are found to depend on strain rate in such a manner that Stage-I deformation (planar slip) is favoured at lower strain rate. A continuously decreasing linear function of strain rate sensitivity with true strain has been observed. Reasonably good estimation for the stress exponent relating dislocation velocity and stress has been made. The linear plot of reciprocal of strain rate sensitivity with true strain suggests that after some critical amount of deformation the increased dislocation density in austenite due to the formation of some critical amount of deformation-induced martensite plays important role in carrying out the imposed strain rate.     

Effect of nitrogen on tensile flow behaviour of type 316 LN austenitic stainless steel

Abstract

The influence of nitrogen content on the tensile flow behaviour of type 316 LN austenitic stainless steel has been studied. Nitrogen content in the steel has been varied in the range 0·07 to 0·22 wt-%. Tensile tests were carried out over the temperature range of 300–1123 K at a nominal strain rate of 3×10^?3 s^?1. The tensile flow behaviour of the steels has been analysed based on the constitutive equation proposed by Voce. The Voce’s parameters of initial stress (σ_i) and saturation stress (σ_s) were found to increase linearly with increase in nitrogen content at all the test temperatures. Tensile properties of the steels were predicted from Voce constitutive equation parameters.     

Prediction of ferrite grain size and tensile properties of a low carbon steel

Abstract

A relationship between ferrite grain size, cooling rate from austenitising temperature, austenitising time, and austenitising temperature is developed to predict the ferrite grain size of a low carbon steel. The coefficients of that relationship are determined experimentally. A Hall - Petch relationship is used to predict the yield stress and fracture stress from the predicted ferrite grain size. Considering the experimental results, maximum errors of 12.5% and 6.5% were found in the prediction of ferrite grain size and strengths, respectively.     

Effect of pre-strain on grain size distributions in 316H austenitic stainless steel

An experimental study addressing the effect of tensile deformation on recrystallized grain size has been undertaken to explore the conditions leading to abnormal grain growth in Type 316H austenitic stainless steel. Following a solution heat treatment, a Type 316H stainless steel has been subjected to various tensile deformations up to a maximum of approximately 50% strain and then heated at a temperature of 1150 °C for 0.5 h followed by furnace cooling. A fraction of abnormally large grains is observed following a prior strain of approximately 20%. The results are presented, in terms of standard statistical analysis, and also graphically. The graphical presentation provides a clear, visual appreciation of uni- and bi-modal distributions, which may be of general help in other analyses of this nature.     

Biocompatibility studies of low temperature nitrided and collagen-I coated AISI 316L austenitic stainless steel

The biocompatibility of austenitic stainless steels can be improved by means of surface engineering techniques. In the present research it was investigated if low temperature nitrided AISI 316L austenitic stainless steel may be a suitable substrate for bioactive protein coating consisting of collagen-I. The biocompatibility of surface modified alloy was studied using as experimental model endothelial cells (human umbilical vein endothelial cells) in culture. Low temperature nitriding produces modified surface layers consisting mainly of S phase, the supersaturated interstitial solid solution of nitrogen in the austenite lattice, which allows to enhance surface microhardness and corrosion resistance in PBS solution. The nitriding treatment seems to promote the coating with collagen-I, without chemical coupling agents, in respect of the untreated alloy. For biocompatibility studies, proliferation, lactate dehydrogenase levels and secretion of two metalloproteinases (MMP-2 and MMP-9) were determined. Experimental results suggest that the collagen protection may be favourable for endothelial cell proliferation and for the control of MMP-2 release.     

Effect of additions of Ti,B and Ce on microstructural stability,creep strength and creep damage in austenitic stainless steel

Abstract

Optical and transmission electron microscopy (TEM) and X-ray diffraction (XRD) analysis of bulk extracted precipitate residues were carried out on long term (more than 80 000 h) creep tested (at 1023 K) type 304 austenitic stainless steels with different levels of Ti content to assess the microstructural stability and creep strength. B and Ce were added to the steels to suppress the creep cavitation. Finer Ti(C,N) particles with higher density and narrower size distribution were observed in steels with a higher Ti content, resulting in an increase in the creep rupture strength. However, higher Ti content increased the intergranular precipitation of the σ phase on longer creep exposure, resulting in the increase in creep cavitation and in the decrease in creep rupture strength. The study indicated an optimum level of Ti and {C + (6/7)N} content with the Ti/{C + (6/7)N} ratio close to the stoichiometric value of the Ti(C,N) precipitate particles that should also be close to their solubility limit at the solution heat treatment temperature.     

Comparative evaluation of strain controlled low cycle fatigue behaviour of solution annealed and prior cold worked 316L(N) stainless steel

The effect of 20% prior cold work on low cycle fatigue (LCF) behaviour of type 316L(N) stainless steel (SS) was studied at 873 K by conducting total axial strain controlled tests in air with strain amplitudes in the range ±0.25% to ±1.0%. The cyclic deformation behaviour of 20% prior cold worked (PCW) material was compared with the LCF response of solution annealed (SA) alloy tested under similar conditions. The cyclic stress response (CSR) of 316L(N) SS in the PCW condition was characterized by a short period of hardening followed by prolonged softening prior to failure, whereas SA material exhibited a significant hardening regime followed by stress saturation. Interrupted tests on PCW material were carried out at different stages of CSR in order to determine the underlying mechanisms as reflected in substructural changes. The fatigue life in the solution annealed condition was similar to that of the PCW material at higher strain amplitudes of testing (≥±0.5%) while at lower strain amplitudes, the PCW material exhibited longer life.     

Effects of temperature on the low cycle fatigue behaviour of nitrogen alloyed type 316L stainless steel

Strain-controlled low cycle fatigue tests have been conducted in air between 298–873 K to ascertain the influence of temperature on LCF behaviour of nitrogen-alloyed type 316L stainless steel. A strain amplitude of ± 0.60% and a symmetrical triangular waveform at a constant strain rate of 3 × 10⁻³ s⁻¹ were employed for all tests. Crack initiation and propagation modes were evaluated, and the deformation and damage mechanisms which influence the cyclic stress response and fatigue life identified. The cyclic stress response at all temperatures was characterized by an initial hardening to the maximum stress, followed by gradual softening prior to attaining saturation. Temperature dependence of fatigue life showed a maximum in the intermediate temperature range. The drastic reduction in fatigue life at elevated temperatures has been ascribed primarily to the combined influence of dynamic strain ageing effects and oxidation-enhanced crack initiation, while the lower life at room temperature is attributed to detrimental effects associated with deformation-induced martensite.     

Assessment of low cycle fatigue improvement of machined AISI 316 stainless steel by brush hammering

The effects of wire brush hammering on low cycle fatigue behaviour of AISI 316 austenitic stainless steel has been investigated on turned samples through an experimental study combining strain controlled fatigue tests, scanning electron microscope examination and X‐ray diffraction analysis. An increase in fatigue life by 266% was reported at an imposed strain amplitude of Δε_t/2 = 0.2%. This improvement is limited to Δε_t/2 ≤ 0.5%. It is found that wire brush hammering produces a surface texture that favours, under cyclic loading, nucleation of randomly dispersed short cracks of the order of 50 µm in length stabilized by a compressive residual stress field. In contrast, turned surface showed much longer unstable cracks of the order of 200 µm in length nucleated in the machining groves and propagated under the effect of a tensile residual stress field. It has also been established that wire brush hammering can be used as intermittent treatment to improve the residual fatigue life of components subjected to cyclic loading. The treatment is very efficient if it is performed at a fraction of service lifetime n_i/N_r lower than 0.5.     

Effects of solution treatment temperature on grain growth and mechanical properties of high strength 18%Ni cobalt free maraging steel

Abstract

The effects of solution treatment (ST) temperature (1073–1473 K) on the prior austenite grain size, microstructure, and mechanical properties of a 2000 MPa grade 18%Ni Co free maraging steel have been investigated. The results show that prior austenite grain size normally increases with increase of ST temperature. Strength and ductility in the solution treated condition are independent of both ST temperature and prior austenite grain size due to constant martensite lath spacing and dislocation tangles. In the solution treated + aged condition, the relationship between yield strength and prior austenite grain size follows the Hall- Petch equation, and ductility improves until the ST temperature used is >1373 K. Accordingly, the fracture mode transforms from intergranular to transgranular at a critical prior austenite grain size of ~ 150 μ m, because of severe segregation of Ni₃(Mo,Ti) and reverted austenite at prior austenite grain boundaries and martensite lath boundaries. The variation of Charpy V notch impact energy with increase of ST temperature in both the solution treated and solution treated + aged conditions is similar to that of the tensile ductility. The fracture toughness K_IC, however, increases with increase of ST temperature. No thermal embrittlement resulted from the Ti(C,N,S) inclusion segregation at prior austenite grain boundaries and martensite lath boundaries in the high temperature solution treatment.     

The effect of thermal ageing on low cycle fatigue behaviour of 316 stainless steel welds

It is well known that welds are the weak links in any structure. Therefore, it is of out most importance to characterize the mechanical properties of welds. Moreover, the changes in the microstructure that occur in welds on exposure to high temperatures affect the mechanical properties and must be studied by ageing the welds at high temperature. In this paper the low cycle fatigue behaviour of thermally aged 316 stainless steel weld metal is presented. Weld pads with single V configuration were prepared by the shielded metal arc welding process using 316 electrodes. Thermal ageing was done for 10,000 h at 823 and 873 K. Total strain controlled low cycle fatigue tests were conducted at a constant strain rate of 3 × 10^?3 s^?1 with strain amplitudes in the range ±0.25% to ±0.6% at 823 and 873 K. Weld metal exhibited initial hardening followed by cyclic softening prior to failure. The aged samples exhibited higher stress response as compared to the unaged samples. At both the temperatures and all strain amplitudes fatigue life was inferior to that of unaged samples. The metallography of the aged and tested material was studied through optical, scanning and transmission electron microscopy. The effect of transformation of δ-ferrite to sigma phase and carbides in the weld metal on low cycle fatigue behaviour was evaluated.     

Effects of aging temperature and grain size on the formation of serrated grain boundaries in an AISI 316 stainless steel

The effects of aging temperature and grain size on the formation of serrated grain boundaries have been investigated in an AISI 316 stainless steel. Grain size increased slightly over aging temperature ranges of 650–870 °C, resulting in predominantly serrated grain boundaries. However, when the temperature exceeded 880 °C, the grain size significantly increased, and grain boundary serration was not observed. The initial grain size also had an influence on the occurrence of grain boundary serration. For specimen having a large initial grain size of about 200 μm, no serrated grain boundary formed after aging treatment at 760 °C. Serrated grain boundaries were observed when “normal” initial grain sizes 55 μm were employed. It was found that the frequency of low angle boundaries markedly increased as the initial grain size increased from 55 to 200 μm. From the results obtained, it is possible to describe that the grain boundary serration could be considered as a spontaneous reaction that aims to reduce the total free energy of the system, and form a new interface of lower free energy. We proposed that the competition between grain growth and grain boundary serration during aging treatment reduces the total free energy of the alloy system: at temperatures exceeding 880 °C, the dominant process is the grain growth, while grain boundary serration predominates over the range of 650–870 °C.     

Study on hot deformation behaviour of 316LN austenitic stainless steel based on hot processing map

Abstract

316LN is a type of austenitic stainless steel whose grain refinement only depends on hot deformation. The true stress–strain curves of 316LN were obtained by means of hot compression experiments conducted at a temperature range of 900–1200°C and at a strain rate range of 0·001–10 s^?1. The influence of deformation parameters on the microstructure of 316LN was analysed. Both the constitutive equation for 316LN and the model of grain size after dynamic recrystallisation were established, and the effect of different deformation conditions on the microstructure was analysed. The results show that the suitable working region is the one with a relatively higher deformation temperature and a lower strain rate, in which the dynamic recrystallisation is finely conducted. Moreover, the working region that should be avoided during hot deformation was indicated.