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1.
The ordering of bainite is studied and compared with that of martensite in a Cu-20Zn-6Al(wt—%) alloy by X-ray analysis. Experilnental results show that in contrast with the diffraction pattern for 9R or 18R martensite, in which the (115) diffraction peak is distinguishable from the (■ 0 5), and the (1 2 10) from the (2 0 10), the (1 1 5) and (■ 0 5) or the (1 2 10) and (■0 10) diffraction peaks in the bainites formed from high temperature B2 or low temperature L2 parent phase overlap, and these phenomena do not change after prolonged aging or slow-cooling. The bainite structure is quite different from that of the martensite, i. e., the inheritance of the ordering of the parent phase would not occur, during bainite formation.  相似文献   

2.
INTRODUCTIONThestabilizationofmartensitereferstothephenomenonthatthereversetransformationstartandfinishtemperatures(AsandAf)i...  相似文献   

3.
DEFORMATIONBEHAVIOUROFCu-Zn-AlALLOYSANDITSEFFECTONTRANSFORMATIONHYSTERESISWangMingpu;XuGenyin;YinZhiming(DepartmentofMaterial...  相似文献   

4.
Cu-25Al-3Mn合金马氏体结构及其内部缺陷   总被引:4,自引:0,他引:4  
利用金相观察、X射线衍射、透射电镜分析等方法研究 Cu-25Al-3Mn(原子分数,%)合金马氏体结构. 确认该合金淬火态为有序M2H型马氏体,其基面原子分布为:Al原子占据顶角;Cu原子占据面心;原子占据b边中点,其点阵常数 a=0.4459 nm,b=05279 nm,c=0.4241 nm,β=8864°合金马氏体内发现有由变体群形成的一种三角形组态及其它复杂组态.  相似文献   

5.
    
The correlation between the shape memory effect(SME)and the ordering degree inmartensite formed through various heat-treatment processes,e.g.ice water quenching,step-quenching and aging etc.,has been studied in a Cu-26Zn-4Al alloy.The martensite or-dering degree is estimated by △d,the spacing difference of some pairs of diffracting planeswith indices satisfying a relation of(h_1~2-h_2~2)/3=(k_2~2-k_1~2)/n(n=1 for 9R martensite,n=4for 18R martensite).M 18R martensite is obtained from step-quenching,in which the valueof △d increases with the holding duration of step-quenching,and the shape recoveryrate η increases synchronouslly.9R martensite is obtained from direct water-quenching,thevalue of △d is quite large and SME is also good at just quenching state.But both △dand η decrease continuously with aging time at room temperature.This stabilization phe-nomenon of martensite is explained by the observation of TEM lattice fringe image,and itmay be attributed to the clustering of quenched-in supersaturated vacancies at(001)_M close-packed plane in martensite and decreasing the ordering degree.A reduction in△d and η occuring in the specimens on step-quenching or aging at higher temperature,which may be related to the precipitation of the α-phase and the enrichment of solute atoms,decreases the ordering degree.  相似文献   

6.
制备了Cu-27Zn-4.6Al(质量百分数)形状记忆合金,采用不同的工艺参数进行热处理.通过显微组织观察、XRD物相分析、形状回复率测试等对不同热处理后的样品进行了分析研究.结果显示,在850℃固溶淬火后出现板条较细小、界面平直清晰的典型马氏体组织;随着固溶温度的升高,合金的晶粒逐渐变大,形状回复率先增大后减小,850℃时达到最大.  相似文献   

7.
通过TEM及SEM分析研究了Cu-25.9wt%zn-4wt%Al合金在200~100℃范围内等温过程中析出相的形态及内部结构的变化。初生α_1片(贝氏体)有生长台阶,内部无层错。在其生长的第二阶段出现层错,界面处有生长台阶。第三阶段界面弯曲,层错逐渐消失,代之以位错网。片状α_1逐步转变为块状平衡α相。实验证明,α_1片的相变特征与各种切变长大机制不符,属扩散控制的台阶长大机制。  相似文献   

8.
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The stability of thermoelastic martensite in a Cu-14.84 wt-%Zn-7.75 wt-%Al shape mem-ory alloy with M_s=106°C after direct quenching or stepped quenching has been investigatedby using TEM,X-ray diffroctometer and double electric bridge instrument.The martensiteaged for about 3 h at room temperature after either direct quenching or stepped quenching(150°C,2 rain)is the M18R structure.The martensite just directly quenched is not so stable,both its certain diffraction peaks and specific electric resistivity,change with aging at roomtemperature;whereas it is stable after stepped quenching(150°C.2 min),and its diffractionpeaks and specific electric resistivity change no more with aging at room temperature.Theabove mentioned results seem to be explained by the martensite reordering.  相似文献   

9.
MARTENSITE TRANSFORMATION OF A TiNiCu ALLOY   总被引:2,自引:0,他引:2  
MARTENSITETRANSFORMATIONOFATiNiCuALLOY¥Zhang,Yi;Jin,Jialing;Ji,Zhiqiang(ShanghaiIronandSteelResearchInstitute,Shanghai200940)...  相似文献   

10.
QUENCH IN STABILIZATION OF Cu-Zn-Al ALLOY   总被引:1,自引:0,他引:1  
QUENCHINSTABILIZATIONOFCuZnAlALLOY①PengKun,TanShusong,LiShutangDepartmentofMaterialsScienceandEnginering,CentralSouthUniver...  相似文献   

11.
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The stabilization of thermoelastic martensite in a rapidly solidified Cu-Zn-A1 alloy is be-lieved to be the process of disordering in atomic configuration during which the structure ofmartensite gradually transforms into N9R(b/a=1/3~(1/2))from M18R.This is dependentupon the intrinsic decomposition tendency of the martensite.  相似文献   

12.
鲁小叶 《金属学报》1990,26(3):35-39
用透射电镜,X射线衍射仪和电阻法研究了Cu-14.84wt-%Zn-7.75wt-%Al形状记忆合金在直接淬火和分级淬火后马氏体的稳定性。试验结果表明,直接淬火和分级淬火(150℃,2min)后于室温时效约3h的马氏体均为M18R结构,但刚直接淬火后马氏体并不稳定,其某些衍射峰位置和电阻率均随室温时效而变化;而分级淬火(150℃,2min)后马氏体是稳定的,其所有衍射峰位置和电阻率几乎不随室温时效而变化。上述结果可用“马氏体再有序化机制”解释。  相似文献   

13.
Cu-Zn-Al合金中马氏体的有序化对形状记忆效应的影响   总被引:7,自引:0,他引:7  
漆璇  江伯鸿  徐祖耀 《金属学报》1988,24(4):228-235
研究了Cu-Zn-Al合金分别经水淬、分级淬火和淬火加时效处理后,马氏体的有序化程度及其和形状记忆效应(SME)之间的关系.有序化程度用一些特定马氏体线对的面间距差值△d来表征,线对指数应满足下式:(h_1~2-h_2~2)/3=(k_2~2-k_1~2)/n(对9R马氏体n=1,对18R马氏体N=4).分级淬火得到M18R马氏体,其△d值随分级等温时间而增大,与形状恢复能力η的提高一致.水淬得到M9R马氏体,刚淬火状态有相当大的△d和良好的SME,但室温停留使△d和η均下降,TEM点阵条纹象证实这是淬火过饱和空位在(001)_M基面聚集、降低有序程度的结果.淬火后高温时效(180℃)或过高的分级温度都会使△d和η下降,这与α相析出以及可能发生的溶质原子偏聚有关,都会降低有序程度.  相似文献   

14.
Cu-Zn-Al合金热弹性马氏体稳定化机理的探讨SCIEI   总被引:9,自引:0,他引:9  
本文研究了快速凝固Cu-Zn-Al合金热弹性马氏体稳定化的机理,认为该合金马氏体稳定化实际上是一个原子组态由有序向无序、马氏体结构由M18R向b/a=1/3^(1/2)的N9R转变的过程,这一过程是由马氏体固有的分解趋势所决定的。  相似文献   

15.
用DSC研究了预变形对Ti51Ni49形状记忆合金薄膜的相变行为的影响,结果表明:预变形后薄膜的马氏体发生了稳定化现象,第一次逆相变温度T^1A随预应变量增加而升高,而在第二次相变循环中,马氏体稳定化现象消失,逆相变温度T^2A基本恢复到变形前的温度值,马氏体相变温度随预应变量增大而降低,但R相变受预变形影响不大,形状记忆效应研究表明,Ti51Ni49合金薄膜的可恢复应变随预应变量的增加而增大,其最大值4.5%在预应变量为6%时获得。  相似文献   

16.
1 Introduction Cu-Zn-Al alloys as well as Ni-Ti alloys are known to exhibit the shape memory effect, being associated with a thermoelastic martensite transformation and its reversion[1- 4]. Cu-Zn-Al alloys are less stable than the Ni-Ti alloys above room …  相似文献   

17.
采用化学失重法、电化学方法和原子吸收光谱法研究了紫铜、Cu-Zn-Al形状记忆合金和Cu-Zn-Al合金在模拟宫腔液中的腐蚀行为.结果表明, 模拟宫腔液中紫铜、Cu-Zn-Al形状记忆合金和Cu-Zn-Al合金的腐蚀历程受阴极氧去极化步骤控制.Cu-Zn-Al形状记忆合金和Cu-Zn-Al合金由于铝的表面离子化倾向比锌的大, 优先形成致密坚固的保护性氧化铝膜, 降低了腐蚀速率.在模拟宫腔液中发现Cu-Zn-Al形状记忆合金和Cu-Zn-Al合金发生脱铝腐蚀, Cl-参与腐蚀反应历程, 促进脱铝腐蚀的进行.白蛋白与氧的竞争吸附加速了阳极溶解, 使紫铜、Cu-Zn-Al形状记忆合金和Cu-Zn-Al合金的阳极活性电流密度随白蛋白浓度的上升而增加.  相似文献   

18.
形状记忆合金的剪切本构模型   总被引:1,自引:0,他引:1  
利用形状记忆因子的概念,建立了用于描述纯剪切状态下形状记忆合金(SMA)相变行为的形状记忆演化方程.在假设SMA为各向同性材料和利用三维细观力学本构方程的前提下,推导了纯剪切状态下SMA的力学本构方程.所建立的形状记忆演化方程和力学本构方程中的材料常数均可以通过宏观实验来测定,便于工程实际中的应用.数值计算结果表明,所建立的形状记忆演化方程能正确地描述纯剪切状态下SMA发生在奥氏体、孪晶马氏体和非孪晶马氏体间的相变行为,力学本构方程可再现形状记忆效应和超弹性的热力学过程.  相似文献   

19.
运用原子力显微镜(AFM)对形状记忆合金CuNiAl中裂纹扩展行为进行了观察。观察表明、拉伸时、裂纹尖端首先产生马氏体。纳米微裂纹择优沿马氏体相界面形核。但当外力较大,且裂纹扩展距离较长使裂尖应力集中足够大时,不但能诱发马氏体相变。也可出现滑移带。一旦出现滑移带,裂纹也可沿马氏体或滑移带交替扩展。  相似文献   

20.
TiNi合金连接技术的研究现状及发展趋势   总被引:4,自引:1,他引:3  
简述TiNi合金的性能及应用,着重论述了TiNi合金连接技术的研究现状,简要分析了TiNi合金现有连接方法的不足,并对TiNi合金连接技术需进一步开展的研究工作做了展望。  相似文献   

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