Tribo-layer and its role in dry sliding wear of Ti–6Al–4V alloy

Dry sliding wear tests were performed for Ti–6Al–4V alloy under a load of 50–250 N at 25–500 °C on a pin-on-disk elevated temperature tester. Worn surfaces and subsurfaces were thoroughly investigated for the morphology, composition and structure of tribo-layers. Ti–6Al–4V alloy could not be considered to possess poor wear resistance at all times, and presented a substantially higher wear resistance at 400–500 °C than at 25–200 °C. The tribo-layer, a mechanical mixing layer, was noticed to exist on worn surfaces under various conditions. High wear rate at 25–200 °C was ascribed to no protective tribo-layer containing no or trace tribo-oxides. As more oxides appeared in the tribo-layers, they presented an obviously protective role due to their high hardness, thus giving a reasonable explanation for high wear resistance of Ti–6Al–4V alloy at 400–500 °C.     

Influence of graphite content on the dry sliding and oil impregnated sliding wear behavior of Al 2024–graphite composites produced by in situ powder metallurgy method

The influence of graphite content on the dry sliding and oil impregnated sliding wear characteristics of sintered aluminum 2024 alloy–graphite (Al/Gr) composite materials has been assessed using a pin-on-disc wear test. The composites with 5–20 wt.% flake graphite particles were processed by in situ powder metallurgy technique. For comparison, compacts of the base alloy were made under the same consolidation processing applied for Al/Gr composites. The hardness of the sintered materials was measured using Brinell hardness tester and their bending strength was measured by three-point bending tests. Scanning electron microscopy (SEM) was used to analyze the debris, wear surfaces and fracture surfaces of samples. It was found that an increase in graphite content reduced the coefficient of friction for both dry and oil impregnated sliding, but this effect was more pronounced in dry sliding. Hardness and fracture toughness of composites decreased with increasing graphite content. In dry sliding, a marked transition from mild to severe wear was identified for the base alloy and composites. The transition load increased with graphite content due to the increased amount of released graphite detected on the wear surfaces. The wear rates for both dry and oil impregnated sliding were dependent upon graphite content in the alloy. In both cases, Al/Gr composites containing 5 wt.% graphite exhibited superior wear properties over the base alloy, whereas at higher graphite addition levels a complete reversal in the wear behavior was observed. The wear rate of the oil impregnated Al/Gr composites containing 10 wt.% or more graphite particles were higher than that of the base alloy. These observations were rationalized in terms of the graphite content in the Al/Gr composites which resulted in the variations of the mechanical properties together with formation and retention of the solid lubricating film on the dry and/or oil impregnated sliding surfaces.     

Multi-response optimisation of sintering parameters of Al–Si alloy/fly ash composite using Taguchi method and grey relational analysis

In this paper, an attempt has been made to optimise the sintering process parameters of Al–Si (12%) alloy/fly ash composite using grey relational analysis. Al–Si alloy/fly ash composite was produced using powder metallurgy technique. Al–Si alloy powder was homogenously mixed with various weight percentages of fly ash (5–15 wt.%) and compacted at a pressure ranging from 307 to 512 MPa. The green compacts were sintered at temperatures between 575 and 625°C. Experiments have been performed under different conditions of temperature, fly ash content, and compacting pressure. Taguchi’s L₉ orthogonal array was used to investigate the sintering process parameters. Optimal levels of parameters were identified using grey relational analysis, and significant parameter was determined by analysis of variance. Experimental results indicate that multi-response characteristics such as density and hardness can be improved effectively through grey relational analysis.     

A comparison of the reciprocating sliding wear behaviour of steel based metal matrix composites processed from self-propagating high-temperature synthesised Fe–TiC and Fe–TiB2 masteralloys

Steel matrix particulate composites were processed by direct addition of various powders to molten medium carbon steel. Fe–TiC and Fe–TiB₂ powders were produced using a self-propagating high-temperature synthesis (SHS) reaction and consisted of a dispersion of fine TiC (5–10 μm) and TiB₂ particles (2–5 μm), respectively in an iron binder.Addition of the Fe–TiC powder to the steel resulted in the formation of a metal matrix composite containing a homogeneous dispersion of TiC particles. However, addition of the Fe–TiB₂ powder resulted in the formation of a parasitic Fe₂B phase and TiC within the steel microstructure. In response to this an SHS masteralloy composed of Fe–(50% TiB₂+50%Ti) was manufactured which, when added to steel, prevented the formation of Fe₂B and resulted in a composite containing a mixture of TiB₂ and TiC particles.Dry reciprocating sliding wear behaviour of the three composite materials and their unreinforced counterpart was investigated at room temperature against a white cast iron counterface. Relative wear behaviour of the materials varied as a function of load. In all cases, the composite manufactured by addition of Fe–TiB₂ (yielding Fe₂B and TiC phases in the steel) exhibited wear rates greater than three times that of the unreinforced alloy. However, improvements in wear resistance over the base steel of up to two and a half times were observed with the other composites where the desired TiC and/or TiB₂ phases were retained in the steel. Scanning electron microscopy has been used to interpret wear behaviour in relation to both the as-cast microstructures of the composites and the wear scar microstructures observed.     

Friction and wear behaviour of plasma sprayed WC–12Co coating sliding against Si3N4 under lubrication of ionic liquids

Abstract

The friction and wear behaviour of a WC–12Co coating prepared by plasma spraying sliding against a Si₃N₄ ceramic ball, under the lubrication of liquid paraffin and ionic liquids 1-methyl-3-butylimidazolium hexafluorophosphate and 1-methyl-3-hexylimidazolium hexafluorophosphate at room temperature, was investigated using an SRV tester. The morphology and elemental distribution of the worn coating surfaces were characterised by means of scanning electron microscopy (SEM) equipped with an energy dispersive X-ray analyser (EDXA) attachment, and the chemical state of typical elements in the boundary lubricating film on the worn coating surface was analysed by means of X-ray photoelectron spectroscopy (XPS). The SEM/EDXA analysis shows that phosphorus is uniformly distributed on the worn coating surface lubricated by ionic liquids. The XPS results also indicate that the boundary lubricating film is mainly composed of CoF₂ and PF_x and the tribochemical reaction products contribute to reducing the friction and wear of the plasma sprayed WC–12Co coating.     

Effects of cold working and heat treatment on microstructure and wear behaviour of Cu–Be alloy C17200

The effects of cold work process between aging and solution heat treatment on the microstructure, hardness and the tribologic behaviour of a copper–beryllium (Cu–Be) alloy C17200 were investigated. The wear behaviour of the alloys was studied using ‘pin on disc’ method under dry conditions. The results show that the formation of fine grained structure and γ phase particles enhances the mechanical properties of the alloy; nonetheless, they do not reduce the wear rate. This is attributed to the capability of the softer specimens to maintain oxygen rich compounds during the dry sliding test.     

On the role of sliding load and heat input conditions in friction stir processing on tribology of aluminium alloy–alumina surface composites

ABSTRACT

Aluminium (AA5083)-alumina surface composites are prepared by friction stir processing in two conditions of heat input. The low heat (LH) input conditions is achieved at a rotational speed of 710?rpm and a traverse speed of 100?mm/min, and high heat (HH) input conditions are achieved at a rotational speed of 1400?rpm and a traverse speed of 40?mm/min. The tribological characteristics of aluminium alloy, friction stir processed (FSPed) alloy and FSPed surface composites against steel ball are studied at 5, 10 and 20?N load. While no significant influence is found on frictional behaviour, wear resistance of FSPed composites is superior to FSPed alloys. FSPed composites fabricated at HH input conditions exhibited improved wear resistance as compared to LH input condition. Adhesion and delamination are dominant wear mechanisms at 20?N. Debris particles are reduced in size and hydroxidated in sliding of surface composites.     

The friction and sliding wear of unlubricated 316 stainless steel in air at room temperature in the load range 0.5–90 N

The reciprocating self-wear of 316 stainless steel in air and at room temperature has been investigated in the load range 0.5–90 N. Above approximately 40 N the debris was metallic, indicating a severe wear mode. The wear volume was a linear function of the sliding distance and the specific wear rate was independent of load.Below the 40 N load, after an initial severe stage, a transition occurred with a decrease in wear rate by up to an order of magnitude. The specific wear rate in both wear stages decreased with decreasing load, showing no indication of saturating at low loads. The load dependence of the wear volume V per unit sliding distance was of the form V = kLⁿ where n ≈ 1.8 for both pre- and post-transition stages.The transition and the decreasing specific wear rates with decreasing load are thought to be associated with an increasing proportion of asperity interactions' being elastic rather than involving plastic deformation. It is proposed that wear occurs by a multistage mechanism of metal transfer to form prows, prow oxidation in the post-transition stage and prow breakdown. The transition is associated with a change in the rate-limiting step. This is believed to be the metal transfer step in the pre-transitional stage and the prow breakdown step in the post-transitional stage. Only a tentative correlation could be made between the onset of a wear transition and changes either in the friction behaviour or in the appearance of oxide in the wear debris. The friction data suggest that wear in the post-transition stage is a cyclic process of prow breakdown, prow re-formation by further metallic transfer, prow embrittlement by oxidation leading once again to breakdown and the formation of oxide-containing wear debris.     

Dry sliding wear behaviour of Ti–6Al–4V pin against SS316L disc in vacuum condition at high temperature

ABSTRACT

Ti–6Al–4V alloy exhibit a unique combination of mechanical, physical, and chemical properties; that pronounced its desirability for implementation in the fields of aerospace, automobile, and chemical industries. The mechanisms, namely, strain rate response/adiabatic shear band (ASB) – effect of plastic deformation, tribo-chemical reaction and formation of the mechanically mixed layer (MML), can control wear behaviour of the alloy. Hence, the present work investigates the influence of these mechanisms in governing the tribological characteristics of the Ti6Al4V alloy aganist SS316L steel. The experiments were executed on a pin-on-disc tribometer under vacuum (2?×?10^?5?Torr), by varying the temperature (25, 100, 200, 300 and 400°C) at constant sliding speed (0.01?ms^?1) and load (137.3?N) conditions. Compression test was carried out at distinct strain rate (0.001 and 10 s^?1) and temperature (25, 100 and 400°C) values, to investigate the occurrence of ASB. The scanning electron microscopy and energy dispersive X-ray spectroscopy analyses were used to evaluate the formation of appendage layers (oxides and MML) and the composition of wear debris, respectively. The wear rate of the Ti–6Al–4V alloy decreased with increment in temperature (room condition to 400°C) inside vacuum environ, governed by ASB and the presence of oxide layers.     

Optimization of thrust force, torque, and tool wear in drilling of coir fiber-reinforced composites using Nelder–Mead and genetic algorithm methods

Machining of composite materials is an important and current topic in modern researches on manufacturing processes. Determination of optimal cutting parameters is one of the most important elements in the machinability study of composites. Optimization has significant practical importance particularly for operating the machineries. In order to increase the accuracy of drill holes, the tool must be in good condition always as much as possible. To achieve good condition of tool, the optimization of machining parameters like drill bit diameter, spindle speed, and feed rate are mandatory. The objective of this paper is to study the effect of these process parameters on thrust force, torque, and tool wear in drilling of coir fiber-reinforced composites. The optimal settings of the parameters were determined through experiments planned, conducted, and analyzed using the Box–Behnken design, Nelder–Mead, and genetic algorithm methods. This paper also aimed to increase the cutting condition of tool, i.e., minimization of tool wear by applying the optimized input parameters using Nelder–Mead and genetic algorithm techniques.     

Sliding friction and wear of Cu–graphite against 2024, AZ91D and Ti6Al4V at different speeds

Cu–graphite composite fabricated by powder metallurgy art is no longer novel material. However, it might be a versatile self-lubricating material sliding against different metals and alloys. In this connection, understanding towards its tribological behavior and wear mechanism is very important. Sliding tribological behaviors of Cu–graphite composite against different counterparts, specified as 2024 aluminium alloy, AZ91D magnesium alloy, and Ti6Al4V titanium alloy, were investigated over varied sliding speeds at room temperature in air. The friction and wear tests were conducted on a pin-on-disk tribo-meter. Tribological performance of Cu–graphite composite strongly depended on its counterpart materials. Cu–graphite composite could provide friction reduction in sliding against 2024 and Ti6Al4V. Cu–graphite composite was a good self-lubricating material in sliding against AZ91D at low speeds but not at 0.25 and 0.50 m/s. Wear mechanism of Cu–Gr composite was related to the transfer, counter-transfer, mechanical mixing and tribo-oxidation at tribo-interface. Sliding speed had influences on tribo-interface and thereby wear mechanism. Finally, the effects of naturally occurred oxide film and sliding speed were discussed.     

A comparison between conventional speed grinding and super-high speed grinding of (TiCp + TiBw) / Ti–6Al–4V composites using vitrified CBN wheel

Comparative grinding experiments of (TiC_p?+?TiB_w)?/?Ti–6Al–4V composites were conducted using vitrified CBN wheel at the conventional wheel speed of 20 m/s and the super-high wheel speed of 120 m/s, respectively. The grinding behavior, i.e., grinding force and force ratio, grinding temperature, specific grinding energy, and ground surface morphology were analyzed. The results obtained indicate that the normal and tangential grinding forces at the super-high wheel speed are smaller than that at the conventional wheel speed. However, the force ratio, the specific grinding energy, and the grinding temperature show a contradictory trend compared to the grinding force between the conventional speed grinding and the super-high speed grinding. The main defects of the ground surface of (TiC_p?+?TiB_w)?/?Ti–6Al–4V composites are voids, micro-cracks, fracture or crushed, pulled-out, and smearing.     

Experimental investigation and optimization of EDM process parameters for machining of aluminum boron carbide (Al–B4C) composite

This study investigates the effect of electric discharge machining (EDM) process parameters [current, pulse-on time (T_on), pulse-off time (T_off) and electrode material] on material removal rate (MRR), electrode wear rate (EWR) and surface roughness (SR) during machining of aluminum boron carbide (Al–B₄C) composite. This article also summarizes a brief literature review related to aluminum metal matrix composites (Al-MMCs) based on different process and response parameters, work and tool material along with their sizes, dielectric fluid and different optimization techniques used. The MMC used in the present work is stir casted using 5% (wt) B₄C particles of 50 micron size in Al 6061 metal matrix. Taguchi technique is used for the design of experiments (L₉-orthogonal array), while the experimental results are analyzed using analysis of variance (ANOVA). Response table for average value of MRR, EWR and SR shows that current is the most significant factor for MRR and SR, while electrode material is most important for EWR. ANOVA also confirms similar results. It is also observed that the optimum level of process parameters for maximum MRR is A₃B₁C₃D₃, for minimum EWR is A₁B₂C₃D₁, and for SR is A₁B₃C₃D₃.