触变成型工艺对AZ91D镁合金摩擦磨损行为的影响

以触变成型AZ91D镁合金为对象,研究了坯料保温温度、加热时间和模具预热温度对其摩擦磨损行为的影响。结果表明:触变成型工艺能显著提高材料的耐磨性,其最佳成型工艺参数为:坯料保温温度585℃、加热时间60min、模具预热温度300℃。在较低摩擦载荷下,AZ91D镁合金表面易形成Mg O、Al2O3氧化薄膜,其在连续接触的切应力往复作用下易脱落又生成新的氧化薄膜而产生氧化磨损。随着摩擦载荷的增加,磨屑由片状剥层向棉絮团状转变,且粘着力增加,合金逐渐发生轻微剥层磨损、轻微粘着磨损和严重粘着磨损。     

石墨-AZ91镁基复合材料及其摩擦磨损性能的研究

研究了不同石墨颗粒含量对AZ91镁合金基复合材料摩擦磨损性能的影响。结果表明：在所研究的范围内，复合材料的摩擦磨损特性明显优于基体合金；随着石墨颗粒含量从5％增加到20％，镁合金基复合材料的耐磨性得到明显的改善，磨损质量损失与摩擦系数都降低到较低水平。在不同磨损阶段，对应着不同磨损机制。随着磨损过程的进行，在磨损试样表面逐渐形成一层连续黑色润滑膜，这层润滑膜有效隔离两摩擦副的直接接触，有效地延迟了镁合金基复合材料由轻微磨损向严重磨损的转变过程。     

增强颗粒对镁基复合材料磨损性能的影响(英文)

研究增强颗粒Mg2Si对镁基复合材料摩擦磨损性能的影响,讨论Si加入量、载荷和滑动速度对Mg2Si/AM60镁基复合材料磨损性能的影响。结果表明,向镁合金中加入合金元素Si,可原位生成增强颗粒Mg2Si,增强颗粒Mg2Si可明显提高AM60镁合金的磨损性能。随着载荷和滑动速度的增加,AM60镁合金和Mg2Si/AM60镁基复合材料的磨损量都增大。AM60镁合金的磨损机制为粘着磨损。随着载荷的增大,Mg2Si/AM60镁基复合材料的磨损由磨粒磨损向粘着磨损转变。     

纳米SiCp增强AZ91D复合材料的摩擦磨损性能

采用机械搅拌与高能超声处理法制备了纳米SiCp增强AZ91D镁基复合材料(n-SiCp/AZ91D),研究了n-SiCp含量及温度对材料摩擦磨损性能的影响.结果表明,AZ91D镁合金中加入n-SiCp能够改善材料的耐磨损性能,并随着n-SiCp添加量的增加,耐磨损性逐渐增加.基体和复合材料在室温至300 ℃范围内,经历了从轻微摩擦磨损到严重磨损的转变.复合材料从轻微摩擦磨损到严重磨损的转变温度比基体提高了50℃,另外,复合材料还表现出较好的耐高温磨损性能.     

温度和时间对触变成型AZ91D镁合金摩擦磨损行为的影响

以AZ91D镁合金为对象,研究了触变成型坯料保温温度、加热时间和模具预热温度对摩擦磨损性能的影响,通过磨痕面、磨屑的SEM和EDS分析,优化了成型工艺参数并探讨了磨损机理。结果表明:触变成型工艺能显著提高合金的耐磨性,相对理想的成型工艺参数为保温温度585℃、加热时间60 min、预热温度300℃。较低载荷下,AZ91D镁合金主要发生氧化磨损,摩擦表面易形成MgO、Al_2O_3氧化薄膜,其在连续接触的切应力往复作用下极易脱落而生成新的氧化膜,磨屑呈细小颗粒。随着试验载荷的增加,磨痕面可观察到唇边撕裂和不同程度的塑性变形迹象,合金发生轻微剥层磨损、轻微粘着磨损到严重粘着磨损的转换,磨屑由片状剥层向棉絮团状转变,堆积在磨道两侧且粘着力明显增加。     

Mg97Zn1Y2合金的摩擦磨损性能研究

研究了铸态Mg97Zn1Y2合金的室温、高温力学性能和干摩擦条件下摩擦磨损行为,并与AZ91合金进行了对比.结果表明:室温下AZ91合金的屈服强度要高于Mg97Zn1Y2合金,但高温下Mg97Zn1Y2合金较AZ91合金表现出更好的热强性,当温度超过150 ℃时,AZ91合金的屈服强度急剧下降,Mg97Zn1Y2合金则下降较少.Mg97Zn1Y2合金由轻微磨损向严重磨损的转变点明显滞后于AZ91合金,相同载荷范围内Mg97Zn1Y2合金磨损表面的温升要低于AZ91合金,其原因是Mg97Zn1Y2合金中的金属间化合物Mg12YZn较AZ91合金中的Mg17Al12相具有更佳的热稳定性.     

Ce对AZ91D镁合金干摩擦磨损性能的影响

研究了不同稀土Ce含量对AZ91D镁合金显微组织和干摩擦磨损性能的影响.通过x射线衍射(XRD)及扫描电镜(SEM)观察与分析表明,AZ91D镁合金中添加稀土Ce后,生成了杆状的稀土化合物Al4Ce.干摩擦磨损结果表明,在高载荷作用下,稀土的加入量并不能提高AZ91D镁合金的摩擦磨损性能.     

4种铸造镁合金在SBF溶液中的腐蚀行为研究

比较了ZK60、AM60、AZ31和AZ91D等4种铸造镁合金在SBF模拟体液中浸泡72 h的腐蚀性能。利用SEM观察了镁合金腐蚀后的显微形貌,根据失重法计算了镁合金的腐蚀速率,采用极化曲线和电化学阻抗方法进一步评价了镁合金的耐蚀性。研究表明,AZ91D合金腐蚀速率最低,并且呈均匀腐蚀。AZ31合金耐蚀性最差,且点蚀严重,AM60和ZK60合金的耐蚀性相近。     

稀土Ce含量对AZ91D镁合金组织和性能的影响

研究了稀土Ce对AZ91D镁合金的显微组织、力学性能、腐蚀性能和磨损性能的影响。结果表明,向AZ91D镁合金中加入稀土Ce,出现了杆状化合物Al4Ce相,并提高了合金的室温力学性能。当稀土加入量为0.7%时,合金的抗拉强度和伸长率由117.4 MPa和4.0%提高至138.87 MPa和6.5%。进一步提高稀土含量,杆状化合物Al4Ce变得粗大,合金力学性能下降。AZ91D镁合金中加入稀土Ce可提高其耐蚀性,加入0.7%Ce的AZ91D镁合金的耐蚀性能提高了87%,当稀土Ce含量进一步提高时,AZ91D镁合金中的耐蚀性又变差。向AZ91D镁合金中加入稀土Ce,其耐磨性能也得到提高,当稀土Ce含量为1.0%时,合金耐磨性能最优,但只是略高于稀土Ce含量为0.7%时合金的耐磨性。综合本研究结果,稀土Ce的最佳加入量为0.7%。     

Effects of Lanthanum and Cerium Mixed Rare Earth Metal on Abrasion and Corrosion Resistance of AM60 Magnesium Alloy

模板通过析氢集气法、增重法、电化学测试和摩擦磨损性能测试等方法,研究了添加铈镧混合稀土对AM60镁合金耐蚀、耐磨性能的影响。结果表明,在0.35%Na Cl溶液中加入铈镧混合稀土后的AM60镁合金析氢腐蚀电流密度下降、腐蚀电位升高,极化电流密度降低,极化电阻增大、容抗减小,改善了腐蚀电化学性能。其原因归结于混合稀土加入后,细化了镁合金的α相和Mg17Al12相,合金形成的Al2Ce和Al11La3新相抑制了阴极去极化的历程、合金表面形成的Ce O2、La2O3复合阳极氧化膜阻滞了合金的溶解,提高了耐蚀性。加入铈镧混合稀土后,AM60镁合金的摩擦系数较AM60合金明显降低,比磨损率减小,改善了合金的摩擦磨损性能,在0.35%Na Cl溶液中低载荷、滑动速度和短距离滑动时AM60镁合金的主要磨损形式为氧化磨损。     

Effects of rare earths on friction and wear characteristics of magnesium alloy AZ91D

The influence of various rare-earth contents on the friction and characteristics of magnesium alloy AZ91D was studied.The results show that the wear r5esistance properties of rare-earth magnesium alloys are better than those of the matrix alloy under the testing conditions.Magnesium alloys undergo transition from mild wear to severe wear.The addition of rare earths refines the structure of alloys,improves the comprehensive behaviors of the magnesium alloys,increases the stability of oxidation films on worn surfaces,enhances the loading ability of rareearth magnesium alloys,and delays the transition from mild wear to severe wear effectively.     

Comparison of corrosion behaviors of AZ31, AZ91, AM60 and ZK60 magnesium alloys

The corrosion behaviours of four kinds of rolled magnesium alloys of AZ31, AZ91, AM60 and ZK60 were studied in 1 mol/L sodium chloride solution. The results of EIS and potentiodynamic polarization show that the corrosion resistance of the four materials is ranked as ZK60＞AM60＞AZ31＞AZ91. The corrosion processes of the four magnesium alloys were also analyzed by SEM and energy dispersive spectroscopy(EDS). The results show that the corrosion patterns of the four alloys are localized corrosion and the galvanic couples formed by the second phase particles and the matrix are the main source of the localized corrosion of magnesium alloys. The corrosion resistance of the different magnesium alloys has direct relationship with the concentration of alloying elements and microstructure of magnesium alloys. The ratio of the β phase in AZ91 is higher than that in AZ31 and the β phase can form micro-galvanic cell with the alloy matrix, as a result, the corrosion resistance of AZ31 will be higher than AZ91. The manganese element in AM60 magnesium alloy can form the second phase particle of AlMnFe, which can reduce the Fe content in magnesium alloy matrix, purifying the microstructure of alloy, as a result, the corrosion resistance of AM60 is improved. However, due to the more noble galvanic couples of AlMnFe and matrix, the microscopic corrosion morphology of AM60 is more localized. The zirconium element in ZK60 magnesium alloy can refine grain, form stable compounds with Fe and Si, and purify the composition of alloy, which results in the good corrosion resistance of ZK60 magnesium alloy.     

Evaluation of sliding wear behavior of graphite particle-containing magnesium alloy composites

1 Introduction More and more magnesium alloy products have been used in automobile and aerospace industries due to their low density, high specific strength and specific stiffness, good damping characteristic, excellent machineability and castability, etc…     

The corrosion performance of anodised magnesium alloys

The corrosion performance of anodised magnesium and its alloys, such as commercial purity magnesium (CP-Mg) and high-purity magnesium (HP-Mg) ingots, magnesium alloy ingots of MEZ, ZE41, AM60 and AZ91D and diecast AM60 (AM60-DC) and AZ91D (AZ91D-DC) plates, was evaluated by salt spray and salt immersion testing. The corrosion resistance was in the sequential order: AZ91D ≈ AM60 ≈ MEZ ? AZ91D-DC ? AM60-DC > HP-Mg > ZE41 > CP-Mg. It was concluded the corrosion resistance of an anodised magnesium alloy was determined by the corrosion performance of the substrate alloy due to the porous coating formed on the substrate alloy acting as a simple corrosion barrier.     

Wear and corrosion properties of laser cladded Cu47Ti34Zr11Ni8/SiC amorphous composite coatings on AZ91D magnesium alloy

To improve the wear and corrosion properties of AZ91D magnesium alloys, Cu-based amorphous composite coatings were fabricated on AZ91D magnesium alloy by laser cladding using mixed powders of Cu47Ti34Zr11Ni8 and SiC. The wear and corrosion behaviours of the coatings were investigated. The wear resistance of the coatings was evaluated under dry sliding wear condition at room temperature. The corrosion resistance of the coatings was tested in 3.5% （mass fraction） NaCl solution. The coatings exhibit excellent wear resistance due to the recombined action of amorphous phase and different intermetallic compounds. The main wear mechanisms of the coatings and the AZ91D sample are different. The former is abrasive wear and the latter is adhesive wear. The coatings compared with AZ91D magnesium alloy also exhibit good corrosion resistance because of the presence of the amorphous phase in the coatings.     

镁合金激光焊接气孔问题的实验研究

对变形镁合金AZ31B、AZ80A,砂铸镁合金AM60B、AZ91D及压铸镁合金AM50A激光焊接气孔倾向进行研究.研究表明:变形镁合金激光焊气孔倾向很小,在较宽的焊接工艺参数范围内均能得到无气孔的焊缝. 砂铸镁合金AM60B及AZ91D激光焊时气孔对气体保护条件非常敏感,在侧吹气体保护角度及流量选择不合适时气孔率非常高,在优化的气保护条件下可得到气孔率较低的焊缝.而压铸镁合金AM50激光焊缝中气孔问题非常突出,调整工艺参数无法解决气孔问题,焊接过程中的加热及添加填充材料可以在一定程度上减少气孔.     

Constitutive prediction and dependence of tensile properties of high-pressure die-cast AM60B and AZ91D magnesium alloy on microporosity

The effect of micro-voids on the tensile property of high-pressure die-cast AM60B and AZ91D magnesium alloy was investigated through systematic experimental approaches, with a constitutive prediction on the load carrying capacity and strain-related factors. The strain rate sensitivity was measured through the incremental strain rate change test, and the microporosity was measured from a comparison between the area of the micro-void and the cross-section area through the quantitative fractography on a fractured surface. The yield strengths of the AM60B and AZ91D alloys exhibit a linear dependence upon the variation of microporosity. In addition, the UTS and elongation of both alloys have a strong dependence upon the variation of microporosity, with an inverse parabolic relationship. The constitutive prediction exhibits is in good agreement with overall trend of the tensile properties of both alloys. From the constitutive prediction, it is confirmed that the differences in the UTS and elongation of both alloys arises from the divergence of the strain hardening ability, rather than from the strain rate sensitivity.     

Evaluation of corrosion resistance of magnesium alloys in radiator coolants

Abstract

Coolant corrosion is a major drawback for the use of magnesium alloys in engine and cooling system, but the coolant is not normally intended to prevent corrosion of magnesium alloys. This research assessed the corrosion performance of two magnesium alloys, AZ91D and AM50A, in two newly formulated radiator coolants using immersion test, potentiodynamic polarisation test, and corroded surface analysis. Two coolants were named as Irgacool Plus L and Irgacool Plus S. C7, C8-organic acids and polycarboxylic acid were the main inhibitor species in Irgacool Plus L while Irgacool Plus S was formulated with C7, C8-organic acids and sebacic acid inhibitors. Corrosion rates of magnesium alloys decreased twice in Irgacool Plus L compared with Irgacool Plus S. AZ91D alloy had better corrosion resistance than AM50A alloy in both radiator coolants. Both alloys suffered corrosion due to microgalvanic coupling between cathodic β-Mg₁₇Al₁₂ intermetallic and anodic α-Mg matrix, and the presence of Al₈Mn₅ and Al₁₁Mn₄ intermetallics in AM50A led to further microgalvanic corrosion. A continuous network of β-Mg₁₇Al₁₂ phase and higher Al content α-Mg matrix accounted for better corrosion resistance of AZ91D alloy.     

Analysis on flow stress of magnesium alloys during high temperature deformation

The flow stress of magnesium alloys during hot compression at different temperatures and strain rates was studied by experiments.Materials used were AZ91D alloys in as-cast,homogeneous treatment states,AZ31 and ZK60 alloys in as-cast state. The results show that the thermal simulation curves of different alloys differ from one another at the same deforming condition.The general curves of AZ31 and AZ91D alloys have the character of dynamic recrystallization.There are increase of true stress,drastic fallin...     

高能电子束处理对AZ91镁合金耐磨性影响

研究了AZ91镁合金电子束表面处理的耐磨性.结果表明,在不同处理条件下,AZ91镁合金表面分别形成了厚度为20～60μm的表面熔凝层;脉冲电流和脉冲次数对表面熔凝层厚度具有较大影响,而加速电压的影响不大.随着脉冲电流的增加, Mg_(17)Al_(12)相对应的衍射峰强度呈现上升趋势,并且在处理过的AZ91镁合金中可看到AlMg亚稳相的存在.显微硬度测试结果表明,处理层硬度比基体组织的硬度有所提高,最表层可达到基体组织的2倍.磨擦系数和表面磨损量均有不同程度下降,耐磨性明显提高主要是由于快速熔凝导致晶粒细化引起的.