HCS degradation of 5 nm oxide high-voltage PLDMOS

Hot carrier (HC) injection, inducing drain and gate leakage current increase in 5 nm oxide p-channel LDMOS transistors, is investigated. Devices with two different drain implants are studied. At low gate voltage (V_GS) and high drain voltage (V_DS), reduction of the ON-resistance (R_ON) is observed. At stress times at which R_ON almost reaches its constant level, an increase of the drain leakage in OFF state (V_DS = −60 V, V_GS = 0 V) is observed. Longer stress time leads to increased gate leakage and in some cases oxide breakdown. In contrast to what was reported for devices with 25 nm gate oxide thickness, the threshold voltage of 5 nm gate oxide PLDMOS transistors does not drift. The experimental data can be fully explained by hot carrier injection and the oxide damage can be explained by two different and competing degradation mechanisms. By combining experimental data and TCAD simulations we are further capable to locate the hot spot of maximum oxide damage in the accumulation (Acc) region of the PLDMOS.     

Performance analysis of nanoscale GeSn MOSFETs for mixed-mode circuit applications

Using extensive numerical analysis we investigate the impact of Sn ranging 0–6% in compressively strained GeSn on insulator (GeSnOI) MOSFETs for mixed-mode circuit performance at channel lengths (L_g) ranging 100–20 nm with channel thickness values of 10 and 5 nm. Our results reveal that 10 nm thick Ge_0.94Sn_0.06 channel MOSFETs produce improvement of peak transconductance g_m, peak gain Av, peak cut-off frequency f_T and maximum frequency of oscillations f_max by 80.5%, 18.8%, 83.5% and 81.7%, respectively compared with equivalent GeOI device at L_g =20 nm. Furthermore, such devices exhibit 78.8% increase in ON-current I_ON while yield 44.5% reduction in delay as compared to Ge control devices enabling them attractive for logic applications. Thinning of the channel thickness from 10 to 5 nm increases peak Av, peak transconductance efficiency and reduces output conductance and OFF-current I_OFF while degrading other parameters in all GeSnOI and control Ge devices.     

Impact of source-to-drain tunnelling on the scalability of arbitrary oriented alternative channel material nMOSFETs

In this work, the scalability of alternative channel material double gate nano nMOSFETs has been investigated by the mean of semi-analytical models of I_on/I_off currents, accounting for quantum capacitance degradation, short channel effects, band-to-band and source-to-drain tunnelling in arbitrary substrate and channel direction.Contrary to most of the previous study neglecting source-to-drain tunnelling, it has been found that for devices with physical gate length below 13 nm (as required in the 22 and 16 nm nodes), this mechanism significantly penalises the I_on/I_off trade off of small effective masses channel materials like Ge or GaAs, much more than in the case of Si and biaxially strained Si (s-Si). In addition, only strained Si-MOSFETs has been found to meet the performance expectation of the International Technology Roadmap of Semiconductor for the 22 nm and 16 nm technological nodes.     

Impact of the gate stack on the electrical performances of 3D multi-channel MOSFET (MCFET) on SOI

In this study, we integrate and compare the electrical performances of metal/high-K embedded gates in 3D multi-channel CMOSFETs (MCFETs) on SOI. The electrical characteristics of embedded gates obtained by filling cavities with TiN/HfO₂, TiN/SiO₂ or N⁺ poly-Si/SiO₂ are compared to a planar reference. In particular, we investigate electron and hole mobility behaviours (300 K down to 20 K) in embedded and planar structures, the gate leakage current and the negative bias temperature instability (NBTI). Despite a lower mobility, TiN/HfO₂ gate stack demonstrates the best I_ON/I_OFF compromise and exhibits NBTI life time higher than 10 years up to 1.3 V.     

Growth temperature dependence of epitaxial Gd2O3 films on Si(1 1 1)

This article reports on the epitaxy of crystalline high κ oxide Gd₂O₃ layers on Si(1 1 1) for CMOS gate application. Epitaxial Gd₂O₃ thin films have been grown by Molecular Beam Epitaxy (MBE) on Si(1 1 1) substrates between 650 and 750 °C. The structural and electrical properties were investigated depending on the growth temperature. The C–V measurements reveal that equivalent oxide thickness (EOT) equals 0.7 nm for the sample deposited at the optimal temperature of 700 °C with a relatively low leakage current of 3.6 × 10^?2 A/cm² at |V_g ? V_FB| = 1 V.     

Operational frequency degradation induced trapping in scaled GaN HEMTs

Cut-off frequency increase from 12.1 GHz to 26.4 GHz, 52.1 GHz and 91.4 GHz is observed when the 1 μm gate length GaN HEMT is laterally scaled down to L_G = 0.5 μm, L_G = 0.25 μm and L_G = 0.125 μm, respectively. The study is based on accurately calibrated transfer characteristics (I_D-V_GS) of the 1 μm gate length device using Silvaco TCAD. If the scaling is also performed horizontally, proportionally to the lateral (full scaling), the maximum drain current is reduced by 38.2% when the gate-to-channel separation scales from 33 nm to 8.25 nm. Degradation of the RF performance of a GaN HEMT due to the electric field induced acceptor traps experienced under a high electrical stress is found to be about 8% for 1 μm gate length device. The degradation of scaled HEMTs reduces to 3.5% and 7.3% for the 0.25 μm and 0.125 gate length devices, respectively. The traps at energy level of E_T = E_V + 0.9 eV (carbon) with concentrations of N_IT = 5 × 10¹⁶cm^− 3, N_IT = 5 × 10¹⁷cm^− 3 and N_IT = 5 × 10¹⁸cm^− 3 are located in the drain access region where highest electrical field is expected. The effect of traps on the cut-off frequency is reduced for devices with shorter gate lengths down to 0.125 μm.     

Characterization of n-type Ge layers on Si (100) substrates grown by rapid thermal chemical vapor deposition

Phosphorus-doped n-type Ge layers were grown on p-type Si (100) wafers (8 in. in diameter, resistivity 5–15 Ω cm) using rapid thermal chemical vapor deposition (RTCVD). The surface morphology was very smooth, with a root mean square (RMS) surface roughness of 0.29 nm. The in-plane lattice constant calculated from high-resolution X-ray diffraction (HR-XRD) data was 0.5664 nm, corresponding to in-plane tensile strain of ～0.47%. The Raman Ge peak for each location indicates tensile strain from the Ge wafer. We estimated the in-plane strain as tensile strain of ～0.45%, in excellent agreement with the XRD analysis. Initial photocurrent spectrum experiments on the sample confirm valence band splitting of the direct gap induced by tensile strain. The temperature dependence of the direct bandgap energy E_Γ1 of Ge can be described by the empirical Varshni expression E_Γ1(T)=0.864–5.49×10^–4T ²/(T+296).     

Properties of high sensitivity ZnO surface acoustic wave sensors on SiO2/(1 0 0) Si substrates

The properties of ZnO/SiO₂/Si surface acoustic wave (SAW) Love mode sensors were examined and optimized to achieve high mass sensitivity. SAW devices A and B, were designed and fabricated to operate at resonant frequencies around 0.7 and 1.5 GHz. The ZnO films grown by pulsed laser deposition on SiO₂/Si demonstrated c-axis growth and the fabricated devices showed guided shear horizontal surface acoustic wave (or Love mode) propagation. Acoustic phase velocity in the ZnO layer was measured in both devices A and B and theoretical and experimental evaluation of the mass sensitivity showed that the maximum sensitivity is obtained for devices with ZnO guiding layer thicknesses of 340 nm and 160 nm for devices A and B, respectively. The performance of the SAW sensors was validated by measuring the mass of a well-characterized polystyrene–polyacrylic acid diblock copolymer film. For the optimized sensors, maximum mass sensitivity values were as high as 4.309 μm²/pg for device A operating at 0.7477 GHz, and 8.643 μm²/pg for device B operating at 1.5860 GHz. The sensors demonstrated large frequency shifts per applied mass (0.1–4 MHz), excellent linearity, and extended range in the femto-gram region. The large frequency shifts indicated that these sensors have the potential to measure mass two to three orders of magnitude lower in the atto-gram range.     

Comparative study of low-frequency noise in 0.18 μm and 0.35 μm gate-length nMOSFETs with gate area of 1.1 μm2

We analyzed the noise characteristics of 0.18 μm and 0.35 μm nMOSFETs with a gate area of 1.1 μm² in the frequency range of 1 Hz to 100 kHz. Both two- and four-finger devices were investigated and analyzed. The experimental results show that the noise of 0.35 μm gate-length nMOSFET possesses lower 1/f component than the 0.18 μm one, whereas the four-finger devices reveal less 1/f noise than those of with two-finger ones. Furthermore, we used time domain measurement of drain current and also the statistical analysis of wafer level on the random telegraph signals (RTS) tests, and the results showed that RTS noise is higher in devices with a 0.35 μm gate-length, and devices with a smaller gate finger width produce more RTS noise than devices with a larger gate finger width.     

Interface studies of ALD-grown metal oxide insulators on Ge and III–V semiconductors (Invited Paper)

Atomic layer deposited (ALD) HfO₂/GeO_xN_y/Ge(1 0 0) and Al₂O₃/In_0.53Ga_0.47As(1 0 0) ? 4 × 2 gate stacks were analyzed both by MOS capacitor electrical characterization and by advanced physical characterization to correlate the presence of electrically-active defects with chemical bonding across the insulator/channel interface. By controlled in situ plasma nitridation of Ge and post-ALD annealing, the capacitance-derived equivalent oxide thickness was reduced to 1.3 nm for 5 nm HfO₂ layers, and mid-gap density of interface states, D_it = 3 × 10¹¹ cm^?2 eV^?1, was obtained. In contrast to the Ge case, where an engineered interface layer greatly improves electrical characteristics, we show that ALD-Al₂O₃ deposited on the In_0.53Ga_0.47As (1 0 0) ? 4 × 2 surface after in situ thermal desorption in the ALD chamber of a protective As cap results in an atomically-abrupt and unpinned interface. By avoiding subcutaneous oxidation of the InGaAs channel during Al₂O₃ deposition, a relatively passive gate oxide/III–V interface is formed.     

Fabrication of NbN/AlN/NbN junctions with Al embedding circuits on Si membrane for 1.5 THz SIS mixers

A process has been developed to fabricate NbN tunnel junctions and 1.5 THz SIS mixers with Al electrodes and Al/SiO₂/Al microstrip tuning circuits on thin Si membranes patterned on silicon on insulator wafers (SIMOX). High Josephson current density (J_c up to 2×10⁴ A/cm²) NbN/AlN/NbN and NbN/MgO/NbN SIS junctions have been fabricated with a reasonably good V_m quality factor and energy gap values close to 5 meV at 4.2 K on (100) oriented 3 inches SIMOX wafers covered by a thin (∼8 nm) MgO buffer layer. The sputtering conditions critically influence the dielectric quality of both AlN and MgO tunnel barriers as well as the surface losses of NbN electrodes. 0.6-μm Si/SiO₂ membranes are obtained after processing of a whole wafer and etching the individual chips in EDP. Such a technology is applied to the development of a waveguide/membrane SIS mixer for use around 1.5 THz.     

High fluence 1.8 MeV proton irradiation effects on n-type MOS capacitors

MOS capacitors with 7 nm SiO₂ dielectrics and n-doped Si substrate were irradiated by 1.8 MeV protons with fluences ranging from 10¹² to 5 × 10¹³ cm^?2 which correspond to the typical LHC fluence range. No significant increase in gate oxide leakage current was detected. A decrease of the capacitance was observed in the accumulation regime. This effect is explained by an increase of the substrate resistivity caused by displacement damage.     

Microwave performance of field-plate 0.13-μm MOS transistors with varying field-plate extension

Si-based field-plate 0.13 μm gate length metal-oxide-semiconductor field effect transistor (Si MOSFET) with field-plate (FP) lengths of 0.1 μm, 0.2 μm, and 0.3 μm have been fabricated and investigated. The field-plate metals were connected to gate electrode in this study to improve device gate resistance (R_g) resulting in the better microwave performance. By increasing the length of field-plate metal extension (L_FPE), the off-state drain-to-source surface leakage current can be suppressed. Besides, low surface traps in FP NMOS also leads to a higher drain-to-source current (I_ds) especially at high current regime compared to standard device. The power added efficiency (PAE) was 56.3% for L_FPE of 0.3 μm device, and these values where 54.7% and 53.8% for L_FPE of 0.2 μm and 0.1 μm devices, respectively. Wider field-plate metal extension exhibits highly potential for low noise amplifier and high efficiency power amplifier applications.     

Non-functionalized soluble diketopyrrolopyrrole: Simplest p-channel core for organic field-effect transistors

We report the synthesis, characterization and behavior in field-effect transistors of non-functionalized soluble diketopyrrolopyrrole (DPP) core with only a solubilizing alkyl chain (i.e. –C₁₆H₃₃ or –C₁₈H₃₇) as the simplest p-channel semiconductor. The characteristics were evaluated by UV–vis and fluorescence spectroscopy, X-ray diffraction, cyclic voltammetry (CV), thermal analysis, atomic force microscopy (AFM) and density functional theory (DFT) calculation. For top-contact field-effect transistors, two types of active layers were prepared either by a solution process (as a 1D-microwire) or thermal vacuum deposition (as a thin-film) on a cross-linked poly(4-vinylphenol) gate dielectric. All the devices showed typical p-channel behavior with dominant hole transports. The device made with 1D-microwiress of DPP-R18 showed field-effect mobility in the saturation region of 1.42 × 10^?2 cm²/V s with I_ON/I_OFF of 1.82 × 10³. These findings suggest that the non-functionalized soluble DPP core itself without any further functionalization could also be used as a p-channel semiconductor for low-cost organic electronic devices.     

Performance assessment of (1 1 0) p-FET high-κ/MG: is it mobility or series resistance limited?

In this article the impact of Si-substrate orientation on mobility performance is studied for p-MOSFET’s with both HfSiON and SiON based dielectrics. Consistent with previous studies, the I_on at fixed I_off is 100% larger for Si(1 1 0) larger than for standard Si(1 0 0). A thorough analysis of the factors influencing I_on (EOT, mobility and R_series) for short channel devices (until L_met = 80 nm) indicates that a 200% increase of the mobility at high V_g is the source of this performance enhancement. The lower I_on increase (only 100%) compared to what is expected from the mobility is only explained by a larger impact of the R_series (70% of the total resistance) for short channel devices. As a result additional room for I_on improvement can be reached by device and R_series optimization.     

Low temperature fabrication of a ZnO nanoparticle thin-film transistor suitable for flexible electronics

A bottom-gate/top-drain/source contact ZnO nanoparticle thin-film transistor was fabricated using a low temperature annealing process (150 °C) suitable for flexible electronics. Additionally, a high-k resin filled with TiO₂ nanoparticles was used as gate dielectric. After fabrication, the transistors presented almost no hysteresis in the I–V curve, a threshold voltage (V_T) of 2.2 V, a field-effect mobility on the order of 0.1 cm²/V s and an I_ON/I_OFF ratio of about 10⁴. However, the transistor is sensitive to aging effects due to interactions with the ambient air, resulting in current level reduction caused by trapped oxygen at the nanoparticle surface, and an anti-clockwise hysteresis in the transfer curve. It was demonstrated, conjointly, the possible desorption of oxygen by voltage stress and UV light exposure.     

Harmonic distortion analysis of triple gate SOI nanowire MOSFETS down to 100 K

The linearity of triple gate nanowire transistors (NWs) implemented on a Silicon-On-Insulator (SOI) substrate is investigated in this work considering temperature (T) influence. The analysis is performed in long channel nanowire MOSFETs with different fin width (W_FIN), from quasi-planar structures (W_FIN = 10 μm) to narrow devices (9.5 nm), operating as single-transistor amplifiers from room temperature down to 100 K. The total, second and third order harmonic distortions (THD, HD2 and HD3, respectively) are extracted using the Integral Function Method (IFM). The analysis is divided in two parts. First, a fixed input signal is applied at the gate of the single-transistor amplifiers and, then, the output signal is fixed. Transport parameters such as effective mobility (μ_eff), mobility degradation coefficient (θ) and series resistance (R_S) have been extracted down to 100 K and correlated to the distortion to explain linearity peaks behavior with temperature and fin width. Narrow transistors have shown improved linearity mainly due to higher intrinsic voltage gain (A_V) considering the entire temperature range. Low temperature operation has shown to degrade the linearity characteristics of both wide and narrow NW MOSFETs.     

Determination of the laterally homogeneous barrier height of palladium Schottky barrier diodes on n-Ge (1 1 1)

We have studied the experimental linear relationship between barrier heights and ideality factors for palladium (Pd) on bulk-grown (1 1 1) Sb-doped n-type germanium (Ge) metal-semiconductor structures with a doping density of about 2.5×10¹⁵ cm^?3. The Pd Schottky contacts were fabricated by vacuum resistive evaporation. The electrical analysis of the contacts was investigated by means of current–voltage (I–V) and capacitance–voltage (C–V) measurements at a temperature of 296 K. The effective barrier heights from I–V characteristics varied from 0.492 to 0.550 eV, the ideality factor n varied from 1.140 to 1.950, and from reverse bias capacitance–voltage (C^?2–V) characteristics the barrier height varied from 0.427 to 0.509 eV. The lateral homogenous barrier height value of 0.558 eV for the contacts was obtained from the linear relationship between experimental barrier heights and ideality factors. Furthermore the experimental barrier height distribution obtained from I–V and (C^?2?V) characteristics were fitted by Gaussian distribution function, and their mean values were found to be 0.529 and 0.463 eV, respectively.     

Growth of a Ge layer on 8 in. Si (100) substrates by rapid thermal chemical vapor deposition

We have made the successful growth of Ge layer on 8 in. Si (100) substrates by rapid thermal chemical vapor deposition (RTCVD). In order to overcome the large lattice mismatch between Ge and Si, we used a two-step growth method. Our method shows the uniformity of the thickness and good quality Ge layer with a homogeneous distribution of tensile strain and a lower etch pit density (EPD) in order of 10⁵ cm⁻². The surface morphology is very smooth and the root mean square (RMS) of the surface roughness was 0.27 nm. The photocurrent spectra were dominated by the Ge layer related transition that corresponding to the transitions of the Si and Ge. The roll-off in photocurrent spectra beyond 1600 nm is expected due to the decreased absorption of Ge.