Thermal and heat transfer characteristics in a latent heat storage system using lauric acid

The thermal and heat transfer characteristics of lauric acid during the melting and solidification processes were determined experimentally in a vertical double pipe energy storage system. In this study, three important subjects were addressed. The first one is temperature distributions and temporal temperature variations in the radial and axial distances in the phase change material (PCM) during phase change processes. The second one is the thermal characteristics of the lauric acid, which include total melting and total solidification times, the nature of heat transfer in melted and solidified PCM and the effect of Reynolds and Stefan numbers as inlet heat transfer fluid (HTF) conditions on the phase transition parameters. The final one is to calculate the heat transfer coefficient and the heat flow rate and also discuss the role of Reynolds and Stefan numbers on the heat transfer parameters. The experimental results proved that the PCM melts and solidifies congruently, and the melting and solidification front moved from the outer wall of the HTF pipe (HTFP) to the inner wall of the PCM container in radial distances as the melting front moved from the top to the bottom of the PCM container in axial distances. However, it was difficult to establish the solidification proceeding at the axial distances in the PCM. Though natural convection in the liquid phase played a dominant role during the melting process due to buoyancy effects, the solidification process was controlled by conduction heat transfer, and it was slowed by the conduction thermal resistance through the solidified layer. The results also indicated that the average heat transfer coefficient and the heat flow rate were affected by varying the Reynolds and Stefan numbers more during the melting process than during the solidification process due to the natural convection effect during the melting process.     

Thermal Energy Storage Performance of Fatty Acids as a Phase Change Material

Thermal energy storage performance of fatty acids and a eutectic mixture as phase change materials (PCMs) has been investigated experimentally. The selected PCMs for this study were palmitic acid, myristic acid, stearic acid, and a mixture of stearic and myristic acids in eutectic combination ratio of 65.7 wt% myristic acid and 34.3 wt% stearic acid. The PCMs have a melting temperature range of 50.0°C to 61.20°C and a latent heat range of 162.0 J/g to 204.5 J/g. The inlet temperature and the mass flow rate of heat transfer fluid (HTF) were selected as experimental parameters to test the thermal energy storage performance of the PCMs. The transition times, temperature range, propagation of the solid-liquid interface, as well as heat flow rate characteristics of the employed cylindrical tube storage system were studied at varied experimental parameters. The experimental results show that the melting front moves to inward in the radial directions as well as in the axial directions from the top toward to the bottom of the PCM tube. It was observed that the convection heat transfer in the liquid phase plays an important role in the melting process. The changes in the studied HTF parameters have more effect on the melting processes than the solidification processes of the PCMs. The average heat storage efficiency calculated from data for all the PCMs is 51.5%, meaning that 48.5% of the heat actually was lost somewhere.     

Thermal performance analysis of a flat slab phase change thermal storage unit with liquid-based heat transfer fluid for cooling applications

This paper presents the results of a thermal performance analysis of a phase change thermal storage unit. The unit consists of several parallel flat slabs of phase change material (PCM) with a liquid heat transfer fluid (HTF) flowing along the passages between the slabs. A validated numerical model developed previously to solve the phase change problem in flat slabs was used. An insight is gained into the melting process by examining the temperatures of the HTF nodes, wall nodes and PCM nodes and the heat transfer rates at four phases during melting. The duration of the melting process is defined based on the level of melting completion. The effects of several parameters on the HTF outlet temperature, heat transfer rate and melting time are evaluated through a parametric study to evaluate the effects of the HTF mass flow rate, HTF inlet temperature, gap between slabs, slab dimensions, PCM initial temperature and thermal conductivity of the container on the thermal performance. The results are used to design a phase change thermal storage unit for a refrigerated truck.     

Thermal performance simulations of a packed bed cool thermal energy storage system using n-tetradecane as phase change material

The objective of this paper is to study the thermal performance of latent cool thermal energy storage system using packed bed containing spherical capsules filled with phase change material during charging and discharging process. According to the energy balance of the phase change material (PCM) and heat transfer fluid (HTF), a mathematical model of packed bed is conducted. n-tetradecane is taken as PCM and aqueous ethylene glycol solution of 40% volumetric concentration is considered as HTF. The temperatures of the PCM and HTF, solid and melt fraction and cool stored and released rate with time are simulated. The effects of the inlet temperature and flow rate of HTF, porosity of packed bed and diameter of capsules on the melting time, solidification time, cool stored and released rate during charging and discharging process are also discussed.     

Performance enhancement of a solar dynamic LHTS module having both fins and multiple PCMs

Latent heat thermal storage units span a wide and varied range of applications in the domestic, industrial and space based activities. Numerical investigations on the performance enhancement of a solar dynamic latent heat thermal storage (LHTS) unit employing multiple phase change materials (PCM) and fins are made. The LHTS unit has been studied for the charging mode alone. Enthalpy based formulation of the energy equations governing the behaviour of the LHTS system has been made and compared with the response of a single PCM unit. The governing conjugate equations have been solved employing finite difference techniques. The results show an appreciable enhancement in the rate of melting of PCM and nearly uniform exit temperature of heat transfer fluid (HTF) in the multiple PCM LHTS unit.     

Thermal Energy Storage Behavior of a Paraffin during Melting and Solidification

Abstract

In this study, experiments are conducted to investigate charging and discharging characteristics of a paraffin as a phase change material (PCM). A vertical tube-in-shell geometry is designed to store the PCM. The thermophysical properties of the paraffin examined are determined through the differential scanning calorimeter (DSC) analysis. A series of experiments are carried out to investigate the effect of increasing the inlet temperature and the mass flow rate of the heat transfer fluid (HTF) both on the charging and discharging processes (i.e., melting and solidification) of the PCM.     

An experimental optimization study on a tube-in-shell latent heat storage

Thermal energy storage (TES) using phase change materials (PCMs) has recently received considerable attention in the literature, due to its high storage capacity and isothermal behaviour during the storage (melting or charging) and removal (discharging or solidification). In this study, a novel modification on a tube-in-shell-type storage geometry is suggested. In the proposed geometry, the outer surface of the shell is inclined and it is the objective of this study to determine the optimum range for the inclination angle of the shell surface. Paraffin with a melting temperature of 58.06°C, which is supplied by the Merck Company, is used as the PCM. The PCM is stored in the vertical annular space between an inner tube through which the heat transfer fluid (HTF), hot water, is flowing and a concentrically placed outer shell. At first, the thermophysical properties of this paraffin are determined through the differential scanning calorimeter (DSC) analysis. Temporal behaviour of the PCM undergoing a non-isothermal solid–liquid phase change during its melting or charging by the HTF are determined for different values of the inlet temperature and the mass flow rate of the HTF. The new geometry is shown to respond well with the melting characteristics of the PCM and to enhance heat transfer inside the PCM for a specific range of the shell inclination angle. Copyright © 2006 John Wiley & Sons, Ltd.     

Numerical and experimental investigation of heat transfer in a shell and tube thermal energy storage system

A numerical and experimental investigation of phase change process dominated by heat conduction in a thermal storage unit is presented in this paper. The thermal energy storage involves a shell and tube arrangement where paraffin wax as phase change material (PCM) is filled in the shell. Water as heat transfer fluid (HTF) is passed inside the tube for both charging and discharging cycles. According to the conservation of energy, a simple numerical method called alternative iteration between thermal resistance and temperature has been developed for the analysis of heat transfer between the PCM and HTF during charging and discharging cycles. Experimental arrangement has been designed and built to examine the physical validity of the numerical results. Comparison between the numerical predictions and the experimental data shows a good agreement. A detailed parametric study is also carried out for various flow parameters and system dimensions such as different mass flow rates, inlet temperatures of HTF, tube thicknesses and radii. Numerical study reveals that the contribution of the inlet temperature of HTF has much influence than mass flow rate in terms of storage operating time and HTF outlet temperature. Tube radius is a more important parameter than thickness for better heat transfer between HTF and PCM.     

Numerical study on thermal energy storage performance of phase change material under non-steady-state inlet boundary

Due to the solar radiation intensity variation over time, the outlet temperature or mass flow rate of heat transfer fluid (HTF) presents non-steady-state characteristics for solar collector. So, in the phase change thermal energy storage (PCTES) unit which is connected to solar collector, the phase change process occurs under the non-steady-state inlet boundary condition. In present paper, regarding the non-steady-state boundary, based on enthalpy method, a two dimensional physical and mathematical model for a shell-and-tube PCTES unit was established and the simulation code was self-developed. The effects of the non-steady-state inlet condition of HTF on the thermal performance of the PCTES unit were numerically analyzed. The results show that when the average HTF inlet temperature in an hour is fixed at a constant value, the melting time (time required for PCM completely melting) decreases with the increase of initial inlet temperature. When the initial inlet temperature increases from 30 °C to 90 °C, the melting time will decrease from 42.75 min to 20.58 min. However, the total TES capacity in an hour reduces from 338.9 kJ/kg to 211.5 kJ/kg. When the average inlet mass flow rate in an hour is fixed at a constant value, with the initial HTF inlet mass flow rate increasing, the melting time of PCM decreases. The initial inlet mass flow rate increasing from 2.0 × 10⁻⁴ kg/s to 8.0 × 10⁻⁴ kg/s will lead to the melting time decreasing from 37.42 min to 23.75 min and the TES capacity of PCM increasing from 265.8 kJ/kg to 273.8 kJ/kg. Under all the studied cases, the heat flux on the tube surface increases at first, until it reaches a maximum then it decreases over time. And the larger the initial inlet temperature or mass flow rate, the earlier the maximum value appearance and the larger the maximum value.     

Numerical simulation of a multi-layer latent heat thermal energy storage system

A computational model for the prediction of the thermal behaviour of a compact multi-layer latent heat storage unit is presented. The model is based on the conservation equations of energy for the phase change material (PCM) and the heat transfer fluid (HTF). Electrical heat sources embedded inside the PCM are used for heat storage (melting) while the flow of an HTF is employed for heat recovery (solidification). Parametric studies are performed to assess the effect of various design parameters and operating conditions on the thermal behaviour of the unit. Results indicate that the average output heat load during the recovery period is strongly dependent on the minimum operating temperature, on the thermal diffusivity of the liquid phase, on the thickness of the PCM layer and on the HTF inlet mass flowrate and temperature. It is, on the other hand, nearly independent of the wall thermal diffusivity and thickness and of the maximum operating temperature. Correlations are proposed for the total energy stored and the output heat load as a function of the design parameters and the operating conditions. © 1998 John Wiley & Sons, Ltd.     

A combined experimental and computational study on the melting behavior of a medium temperature phase change storage material inside shell and tube heat exchanger

A combined experimental and numerical study is performed aiming to understand the role of buoyancy-driven convection during constrained melting of phase change materials (PCMs) inside a shell and tube heat exchanger. A series of experiments is conducted to investigate the effect of increasing the inlet temperature of the heat transfer fluid (HTF) on the charging process (melting) of the PCM. The computations are based on an iterative, finite-volume numerical procedure that incorporates a single-domain enthalpy formulation for simulation of the phase change phenomenon. It was observed from experimental results that the melting front appeared at different times at positions close to the HTF tube and progressing at different rates outwards towards the shell. The computational results show that by increasing the inlet water temperature to 80 °C, the total melting time is decreased to 37%.     

Numerical and experimental investigation for heat transfer in triplex concentric tube with phase change material for thermal energy storage

This paper addresses a numerical and experimental investigation of a thermal energy storage unit involving phase change process dominated by heat conduction. The thermal energy storage unit involves a triplex concentric tube with phase change material (PCM) filling in the middle channel, with hot heat transfer fluid (HHTF) flowing outer channel during charging process and cold heat transfer fluid (CHTF) flowing inner channel during discharging process. A simple numerical method according to conversation of energy, called temperature & thermal resistance iteration method has been developed for the analysis of PCM solidification and melting in the triplex concentric tube. To test the physical validity of the numerical results, an experimental apparatus has been designed and built by which the effect of the inlet temperature and the flow rate of heat transfer fluid (HTF, including HHTF and CHTF) on the thermal energy storage has been studied. Comparison between the numerical predictions and the experimental data shows good agreement. Graphical results including fluid temperature and interface of solid and liquid phase of PCM versus time and axial position, time-wise variation of energy stored/released by the system were presented and discussed.     

Melting of PCM in a thermal energy storage unit: Numerical investigation and effect of nanoparticle enhancement

The present paper describes the analysis of the melting process in a single vertical shell‐and‐tube latent heat thermal energy storage (LHTES), unit and it is directed at understanding the thermal performance of the system. The study is realized using a computational fluid‐dynamic (CFD) model that takes into account of the phase‐change phenomenon by means of the enthalpy method. Fluid flow is fully resolved in the liquid phase‐change material (PCM) in order to elucidate the role of natural convection. The unsteady evolution of the melting front and the velocity and temperature fields is detailed. Temperature profiles are analyzed and compared with experimental data available in the literature. Other relevant quantities are also monitored, including energy stored and heat flux exchanged between PCM and HTF. The results demonstrate that natural convection within PCM and inlet HTF temperature significantly affects the phase‐change process. Thermal enhancement through the dispersion of highly conductive nanoparticles in the base PCM is considered in the second part of the paper. Thermal behavior of the LHTES unit charged with nano‐enhanced PCM is numerically analyzed and compared with the original system configuration. Due to increase of thermal conductivity, augmented thermal performance is observed: melting time is reduced of 15% when nano‐enhanced PCM with particle volume fraction of 4% is adopted. Similar improvements of the heat transfer rate are also detected. Copyright © 2012 John Wiley & Sons, Ltd.     

Heat transfer enhancement in medium temperature thermal energy storage system using a multitube heat transfer array

An experimental energy storage system has been designed using an horizontal shell and tube heat exchanger incorporating a medium temperature phase change material (PCM) with a melting point of 117.7 °C. Two experimental configurations consisting of a control unit with one heat transfer tube and a multitube unit with four heat transfer tubes were studied. The thermal characteristics in the systems have been analysed using isothermal contour plots and temperature time curves. Temperature gradients along the three directions of the shell and tube systems; axial, radial and angular directions have been analysed and compared. The phase change in the multitube system was dominated by the effect of convective heat transfer compared to conductive heat transfer in the control system. The temperature gradient in the PCM during phase change was greatest in the radial direction for both the control and multitube systems. The temperature gradients recorded in the axial direction for the control and multitube systems during the change of phase were respectively 2.5 and 3.5% that of the radial direction, indicating essentially a two-dimensional heat transfer in the PCM. The onset of natural convection through the formation of multiple convective cells in the multitube system significantly altered the shape of the solid liquid interface fluid flow and indicates the requirement for an in-depth study of multitube arrangements.     

Numerical simulation of a shell-and-tube latent heat thermal energy storage unit

A theoretical model was developed to predict the transient behavior of a shell-and-tube storage unit with the phase change material (PCM) on the shell side and the heat transfer fluid (HTF) circulating inside the tubes. The multidimensional phase change problem is tackled with an enthalpy-based method coupled to the convective heat transfer from the HTF. The numerical predictions are validated with experimental data. A series of numerical experiments are then undertaken to assess the effects of various thermal and geometric parameters on the heat transfer process and on the behavior of the system. Results show that the shell radius, the mass flow rate, and the inlet temperature of the HTF must be chosen carefully in order to optimize the performance of the unit.     

Thermal performance of myristic acid as a phase change material for energy storage application

Thermal performance and phase change stability of myristic acid as a latent heat energy storage material has been studied experimentally. In the experimental study, the thermal performance and heat transfer characteristics of the myristic acid were tested and compared with other studies given in the literature. In the present study is included some parameters such as transition times, temperature range, and propagation of the solid–liquid interface as well as heat flow rate effect on the phase change stability of myristic acid as a phase change material (PCM). The experimental results showed that the melting stability of the PCM is better in the radial direction than the axial direction. The variety of the melting and solidification parameters of the PCM with the change of inlet water temperature is also studied. The results show that the better stability of the myristic acid was accomplished at low inlet water temperature compared with the obtained results at high inlet water temperature. We also observed that while the heat exchanger tube is in the horizontal position, the PCM has more effective and steady phase change characteristics than in the vertical position. The heat storage capacity of the container (PCM tube) is not as good as we expected in this study and the average heat storage efficiency (or heat exchanger effectiveness) is 54%. It means that 46% of the heat acrually lost somewhere.     

Dynamic discharging characteristics simulation on solar heat storage system with spherical capsules using paraffin as heat storage material

The dynamic characteristics of solar heat storage system with spherical capsules packed bed during discharging process are studied. According to the energy balance of solar heat storage system, the dynamic discharging processes model of packed bed with spherical capsules is presented. Paraffin is taken as phase change material (PCM) and water is used as heat transfer fluid (HTF). The temperatures of PCM and HTF, solid fraction and heat released rate are simulated. The effects of inlet temperature of HTF, flow rate of HTF and porosity of packed bed on the time for discharging and heat released rate are also discussed. The following conclusion can be drawn: (1) the heat released rate is very high and decreases rapidly with time during the liquid cooling stage, it is stable at the solidification cooling stage, then it decreases to zero at the solid cooling stage. (2) The time for complete solidification decreases when the HTF flow rate increases, but the effect is not so obvious when the HTF flow rate is higher than 13 kg/min; (3) compared to the HTF inlet temperature and flow rate, the influence of porosity of packed bed on the time for complete solidification is not so significant.     

Thermal energy storage system using stearic acid as a phase change material

The thermal performance and phase change stability of stearic acid as a latent heat energy storage material has been studied experimentally. The thermal performance and heat transfer characteristics of the stearic acid were tested and compared with other studies given in the literature. In the present study, parameters such as transition times, temperature range and propagation of the solid–liquid interface as well as the effect of the heat flow rate on the phase change stability of stearic acid as a phase change material (PCM) were studied. The experimental results showed that the melting stability of the PCM is better in the radial direction than in the axial direction. The variation in the melting and solidification parameters of the PCM with the change of inlet water temperature is also studied. We observed that while the heat exchanger tube is in the horizontal position, the PCM has more effective and steady phase change characteristics than in the vertical position. The heat storage capacity of the container (PCM tube) is not as good as we expected in this study and the average heat storage efficiency (or heat exchanger effectiveness) is 50.3%. This indicates that 49.7% of the heat is actually lost somewhere.     

Experimental and computational evolution of a shell and tube heat exchanger as a PCM thermal storage system

A combined experimental and numerical study has been designed to study thermal behavior and heat transfer characteristics of Paraffin RT50 as a phase change material (PCM) during constrained melting and solidification processes inside a shell and tube heat exchanger. A series of experiments are conducted to investigate the effects of increasing the inlet temperature of the heat transfer fluid (HTF) on the charging and discharging processes of the PCM. The computations are based on an iterative, finite-volume numerical procedure that incorporates a single-domain enthalpy formulation for simulation of the phase change phenomenon. The molten front at various times of process has been studied through a numerical simulation. The experimental results show that by increasing the inlet HTF temperature from T_H = 70 °C to 75 and 80 °C, theoretical efficiency in charging and discharging processes rises from 81.1% to 88.4% and from 79.7% to 81.4% respectively.     

Experimental and numerical investigation of thermal energy storage with a finned tube

A latent heat thermal energy storage system using a phase change material (PCM) is an efficient way of storing or releasing a large amount of heat during melting or solidification. It has been determined that the shell‐and‐tube type heat exchanger is the most promising device as a latent heat system that requires high efficiency for a minimum volume. In this type of heat exchanger, the PCM fills the annular shell space around the finned tube while the heat transfer fluid flows within the tube. One of the methods used for increasing the rate of energy storage is to increase the heat transfer surface area by employing finned surfaces. In this study, energy storage by phase change around a radially finned tube is investigated numerically and experimentally. The solution of the system consists of the solving governing equations for the heat transfer fluid (HTF), pipe wall and phase change material. Numerical simulations are performed to investigate the effect of several fin parameters (fin spacing and fin diameter) and flow parameter (Re number and inlet temperature of HTF) and compare with experimental results. The effect of each variable on energy storage and amount of solidification are presented graphically. Copyright © 2005 John Wiley & Sons, Ltd.