Optical manipulation of photonic defect-modes in cholesteric liquid crystals induced by direct laser-lithography

Manipulation of photonic defect-modes in cholesteric liquid crystals (ChLCs), which are one-dimensional pseudo photonic band-gap materials have been demonstrated by an external optical field. A structural defect in which the pitch length of the ChLC in the bulk and the defect are different was introduced by inducing local polymerization in a photo-polymerizable ChLC material by a direct laser-lithography process, and infiltrating a different ChLC material as the defect medium. When an azobenzene dye-doped ChLC was infiltrated in the defect, the trans-cis isomerization of the dye upon ultraviolet (UV) exposure caused the pitch to shorten, changing the contrast in the pitch lengths at the bulk and the defect, leading to a consequent shifting of the defect-mode. The all-optical manipulation was reversible and had high reproducibility.     

Bioinspired supramolecular liquid crystals

A brief account on the historical events leading to the discovery of self-assembling dendrons that generate self-organizable supramolecular dendrimers, or supramolecular polymers, and self-organizable dendronized polymers is provided. These building blocks were accessed by an accelerated design strategy that involves structural and retrostructural analysis of periodic and quasi-periodic assemblies. This design strategy mediated the discovery of porous helical supramolecular structures that self-assembled from dendritic dipeptides. Helical porous columns are the closest mimics of biologically related structures, such as tobacco mosaic virus coat, porous transmembrane proteins, porous pathogens and antibiotics. It is expected that this concept will allow one to investigate the structural origin of functions in synthetic supramolecular materials.     

Resonant gratings in planar Grandjean cholesteric composite liquid crystals

We propose to induce a two-dimensional (2D) periodic modulation structure into a planar Grandjean cholesteric liquid crystal (CLC) to demonstrate the intrinsic 2D photonic crystal properties of such materials. The structure combines a thin transmission grating and a Bragg reflective grating. One advantage of using CLC is the intrinsic high quality Bragg structure, which can be modulated by an electric field: shifting the wavelength band edge by changing the applied field. Another interesting property is the polarization dependence. The main difference between using CLC Bragg instead of a linear grating is the need to operate with a circularly polarized light, because the CLC modes are circular in such a regime. We present preliminary results obtained with what we believe to be the first switchable photonic CLC (PCLC) sample, made up of a polymer CLC gel.     

Hydrodynamics of cholesteric liquid crystals in the coarse-grained limit

The hydrodynamical behaviour of cholesteric liquid crystals has been considered in the limit of low amplitude and low frequency distortions and motions. It is shown that there are interesting analogies with superfluid-hydrodynamics, such as the fountain effect, thermal superconductivity and temperature wave propagation. In certain situations, there is an unusual formation of a boundary layer at low velocities, and in certain others the properties resemble those of percolation in porous media. Results concerning some special phenomena peculiar to cholesteric liquid crystals are also presented. Finally it is pointed out that there should be two types of second sound in chiral smectic C.     

Bistable salt doped cholesteric liquid crystals light shutter

Liquid crystals have been used to make electrically switchable light shutters (windows), but most of them are monostable: opaque in the absence of applied voltage and transparent when a voltage is applied. Here we report a bistable switchable light shutter based on cholesteric liquid crystal doped with tetrabutylammonium bromide. The salt makes it possible for the liquid crystal to have different electro-optical responses to applied voltages with different frequencies. The shutter can be either transparent or opaque in the absence of applied voltage. It can be switched from the transparent state to the opaque state by applying a low frequency (60 Hz) voltage pulse and switched back to the transparent state by applying a high frequency (2 kHz) voltage pulse. Because of the bistability, it can be used for energy-saving switchable privacy control and architectural windows.     

Going beyond the reflectance limit of cholesteric liquid crystals

Cholesteric liquid-crystalline states of matter are abundant in nature: atherosclerosis, arthropod cuticles, condensed phases of DNA, plant cell walls, human compact bone osteon, and chiral biopolymers. The self-organized helical structure produces unique optical properties. Light is reflected when the wavelength matches the pitch (twice periodicity); cholesteric liquid crystals are not only coloured filters, but also reflectors and polarizers. But, in theory, the reflectance is limited to 50% of the ambient (unpolarized) light because circularly polarized light of the same handedness as the helix is reflected. Here we give details of a cholesteric medium for which the reflectance limit is exceeded. Photopolymerizable monomers are introduced into a cholesteric medium exhibiting a thermally induced helicity inversion, and the blend is then cured with ultraviolet light when the helix is right-handed. Because of memory effects attributable to the polymer network, the reflectance exceeds 50% when measured at the temperature assigned for a cholesteric helix with the same pitch but a left-handed sense before the reaction. As cholesteric materials are used as tunable bandpass filters, reflectors or polarizers and temperature or pressure sensors, novel opportunities to modulate the reflection over the whole light flux range, instead of only 50%, are offered.     

Optical diffraction in nonuniform cholesteric liquid crystals: phase-grating mode.

We have worked out the diffraction pattern in the phase-grating mode of a cholesteric liquid crystal (cholesteric) with a pitch gradient. The pitch gradients considered are symmetric and asymmetric with respect to the sample center. For a uniform input beam, the intensity profile of each diffraction order becomes broad. Further, in the symmetric gradient, the profile of each order is irregular, while in the asymmetric gradient it is nearly flat. For a Gaussian input beam, for the symmetrically deformed structure the profile for each order is asymmetric, while for the asymmetrically deformed structure, the profiles just becomes broad. We find that even a 5% nonuniformity in the pitch can drastically alter the diffraction profiles.     

Extremely narrowed spontaneous emission spectrum induced by elliptically polarized light

Abstract

We demonstrate the control of spontaneous emission from a five-level atom embedded in a modified reservoir under the action of a single control beam with elliptical polarization. For different initial-state preparations, we take into account the influence of the phase difference between the two circularly polarized components of the control beam on the behavior of spontaneous emission. For the ground initial states, the spontaneous emission spectrum usually shows ultranarrow central lines which are greatly enhanced. In contrast, for the excited initial states, these enhanced ultranarrow lines are significantly suppressed due to the destructive quantum interference. Furthermore, our numerical simulations indicate that the multipeak structure appears in the presence of the elliptically polarized control beam and external magnetic field. Such a scheme for controlling spontaneous emission may find applications in high-precision spectroscopy.     

Fabrication of a simultaneous red-green-blue reflector using single-pitched cholesteric liquid crystals

A cholesteric liquid crystal (CLC) is a self-assembled photonic crystal formed by rodlike molecules, including chiral molecules, that arrange themselves in a helical fashion. The CLC has a single photonic bandgap and an associated one-colour reflection band for circularly polarized light with the same handedness as the CLC helix (selective reflection). These optical characteristics, particularly the circular polarization of the reflected light, are attractive for applications in reflective colour displays without using a backlight, for use as polarizers or colour filters and for mirrorless lasing. Recently, we showed by numerical simulation that simultaneous multicolour reflection is possible by introducing fibonaccian phase defects. Here, we design and fabricate a CLC system consisting of thin isotropic films and of polymeric CLC films, and demonstrate experimentally simultaneous red, green and blue reflections (multiple photonic bandgaps) using the single-pitched polymeric CLC films. The experimental reflection spectra are well simulated by calculations. The presented system can extend applications of CLCs to a wide-band region and could give rise to new photonic devices, in which white or multicolour light is manipulated.     

In-plane switching of cholesteric liquid crystals for visible and near-infrared applications

We have investigated the in-plane switching of cholesteric liquid crystals for reflective wavelength shifters for visible and near-infrared applications. These devices are based on the elongation of the cholesteric pitch by an electric field perpendicular to the helical axis. The transmission notch-reflection peak position can be tuned continuously to a longer wavelength (redshift) by application of an in-plane electric field. The helix is completely unwound when the electric field is higher than the cholesteric-to-nematic transition field, and the sample is transformed to a transparent state. We have investigated the electro-optic performance of in-plane switching of cholesteric samples and developed a simple phenomenological model to describe the underlying electro-optic phenomena.     

Polarization characteristics of phase retardation defect mode lasing in polymeric cholesteric liquid crystals

We have studied the lasing characteristics of a dye-doped nematic layer sandwiched by two polymeric cholesteric liquid crystal (CLC) films as photonic band gap (PBG) materials. The nematic layer acts as a defect layer, the anisotropy of which brings about the following remarkable optical characteristics: (1) reflectance in the PBG region exceeds 50% due to the retardation effect, being unpredictable from a single CLC film; (2) efficient lasing occurs either at the defect mode wavelength or at the photonic band edge; and (3) the lasing emission due to both the defect mode and the photonic band edge mode contains both right- and left-circular polarizations, while the lasing emission from a dye-doped single CLC layer with a left-handed helix is left-circularly polarized.     

The preparation and characteristics studies of microencapsulated cholesteric liquid crystals (I)

Abstract

This paper deals with the enmicrocapsulation of cholesteric liquid crystals by the colloid coaversation process. This incident light reflection study reveals that the encapsulated liquid crystal films sustain highly sensitive and precise temperature gradients with responding abilities determined by their iridescent coloration.     

Rheological characterization and in-situ investigation of the time-dependent cholesteric based lyotropic liquid crystals

The impact of cell culture media on the rheology of liquid crystals is critical to developing liquid crystal (LC) based biosensors. The rheological properties of cholesteryl ester based lyotropic liquid crystals (LLC) were investigated in a rotational rheometer and using in-situ methods after incubation in cell culture media for periods of 24, 48 and 72 h. The results of the rheological experiments indicated that for incubation up to 48 h, LLC exhibited a linear viscoelastic behavior < 10% strain at low angular frequencies < 1 s^? 1 and an insignificant decrease in the complex viscosity. The in-situ experiments involved examining the response of the LLC to stresses generated by keratinocyte. It was found that cells induced deformations in the liquid crystal surfaces could be completely removed by disrupting the actin cytoskeletons of cells with cytochalasin-B after 48 h in culture media, but could only be partially removed after 48 h in culture media. In fixed stress experiments, it was found that LC deformation lengths remained constant over 72 h and exhibited a statistically insignificant decrease after 72 h in culture media. These later results indicate very little time related change of viscosity in the LLC. However, the in-situ rheological behaviors were in good agreement with the rheological results obtained from oscillatory tests for the LLC incubated up to 48 h. These results suggest that LLC coated substrates have viable physical properties within 48 h of incubation that can allow them to monitor cell-generated stresses in culture.     

Thermally tunable random laser in dye-doped liquid crystals

A thermally tunable random laser in dye-doped liquid crystals (DDLCs) is reported. The gain medium of PM597 dye-doped E7 nematic LC is injected into a glass cell. The experimental results show that the random lasing is still obtained when the cell temperature becomes higher, even above the nematic–isotropic transition, and that its polarization changes at the same time. Temperature has little effect on the full width at half maxiumum of the random lasing. The center wavelength of the random lasing shifts from 575.69?nm to 593.43?nm when the temperature increases from 25.5°C to 148°C. Meanwhile, a random laser based on a solution of laser dye is first reported in this article. The reasons are possibly that nanoparticles consisting of dye molecules provide a new scattering mechanism in both solution and isotropic phase.     

Photoelectron emission induced by radiation of a nitrogen laser

The photoionization of various technological materials under the action of a pulsed nitrogen laser has been studied. It is shown that the photoeffect is produced mostly via the mechanism of two-photon ionization. The maximum photoionization efficiency was observed for a magnesium cathode.     

Blue-light emission from porous silicon induced by laser irradiation

Porous silicon coated with silica gel emitted light with higher energy after it had been irradiated by a Nd:YAG laser. SEM and XRD measurements demonstrate no crystal-to-amorphous transformation under the irradiation, which is presumably because of good protection of the material by silica coat. FTIR results show that the blue-light emission obtained is due to the formation of Si–C and Si–O–C surface bonds under the laser treatment.