Ti（C, N）基金属陶瓷刀具的高速切削性能与磨损机理

使用不同C与N摩尔比的Ti（C, N）固溶体粉末作为基体材料,采用真空烧结工艺研制两种Ti（C, N）基金属陶瓷刀片试样,并考察两种刀片试样和日本住友T1200A在不同的切削速度下干式车削20CrMn工件的切削性能。利用扫描电子显微镜分析刀具前、后刀面的磨损形态和显微结构,阐述Ti（C, N）基金属陶瓷刀具高速切削磨损机理。结果表明：高速切削时Ti（C, N）基金属陶瓷刀具的主要磨损形式是粘结、氧化和扩散磨损;减小Ti（C, N）固溶体中C与N的比值可改善Ti（C, N）基金属陶瓷刀具的耐磨性。     

Ti(C,N)基金属陶瓷刀具的切削性能

利用真空烧结工艺和表面氮化处理工艺制备纳米复合Ti(C,N)基金属陶瓷可转位刀片和功能梯度可转位刀片,并对刀片的切削性能进行分析。结果表明:切削正火态45#钢、淬火态45#钢和奥氏体不锈钢时,与YT15、YG8、TN20相比,制备的刀具皆表现出较优的切削性能和较高的耐磨性,表面经氮化处理后,刀具的表面硬度提高了HRA2.2,大幅度提高了刀具的抗热冲击性能。具有梯度结构的金属陶瓷刀片切削正火钢、铸铁和不锈钢时的切削性能比无梯度结构金属陶瓷刀片的切削性能优良,具有更高的耐磨性。     

渗硼对Ti(C,N)基金属陶瓷刀具性能的影响

采用粉末冶金法制备了Ti(C,N)基金属陶瓷,并用固体渗硼法对其进行了渗硼处理。研究了渗硼后金属陶瓷的微观组织和力学性能以及渗硼对切削性能的影响。结果表明:Ti(C,N)基金属陶瓷的渗硼层组织由硼化物层、扩散层和基体区组成。渗硼使金属陶瓷的表面硬度提高,抗弯强度降低。渗硼使金属陶瓷刀具在切削速度为200 m/min时的使用寿命提高约1倍;在300 m/min切削速度下,渗硼对延长金属陶瓷刀具的使用寿命没有明显作用;切削速度增至400 m/min时,渗硼使金属陶瓷刀具的使用寿命变短。强烈的热冲击是导致高速切削条件下渗硼层耐磨性降低的主要原因。渗硼层有效地减轻了金属陶瓷刀具表面发生的粘结,并抑制了刀具的扩散磨损和氧化磨损。     

后角对纳米TiN改性Ti(C,N)基金属陶瓷刀具磨损性能的影响

采用粉末冶金法制备了用纳米TiN改性的Ti(C,N)基金属陶瓷刀具。研究了后角对刀具使用寿命及前、后刀面磨损的影响。结果表明,后角为6°的刀具使用寿命最长,后角大于8°的刀具因崩刃而失效,这主要是由于切削刃强度降低和散热条件恶化所致。增大后角会使后刀面的边界磨损加剧,而过大的后角则使前刀面磨损加剧。纳米TiN改性Ti(C,N)基金属陶瓷刀具的后刀面磨损是磨粒磨损、氧化磨损、扩散磨损和黏着磨损共同作用的结果。     

Ti(C,N)基金属陶瓷刀具切削加工有限元模拟

介绍了本课题组研制的一种新的刀具材料--T(iC,N)基金属陶瓷的成分组成及其力学性能;基于大变形-大应变理论、增量理论以及更新拉格朗日算法、采用几何断裂分离准则,建立了二维弹塑性金属正交切削有限元模型,对金属正交切削过程进行了数值模拟;改变刀具前角,得出在不同的刀具前角下T(iC,N)基金属陶瓷刀具在正交切削过程中切削力以及刀具后刀面等效应力变化;分析了切削力、刀具表面等效应力对刀具磨损的影响;模拟结果与相关研究的实验数据吻合。本文的研究为后期研制新的刀具材料提供了理论依据,降低实验成本。     

N含量对超细Ti(C,N)基金属陶瓷显微组织和力学性能的影响

用扫描电子显微镜(SEM)、金相显微镜等观察手段研究了N含量对超细Ti(C,N)基金属陶瓷显微组织和力学性能的影响.结果表明N含量对超细Ti(C,N)基金属陶瓷显微组织和力学性能有显著的影响.随N含量增加,其晶粒尺寸细化,晶粒长大受到抑制,并且这种抑制作用非常显著.与此同时,组织中高的N含量也会导致烧结体中孔隙率增加,严重损害着横向断裂强度(TRS).高的N含量一方面能有效抑制晶粒长大,另一方面也促进N的分解.     

镍钴对超细Ti(C,N)基金属陶瓷性能的影响

研究了Co部分和全部代替Ni对超细Ti(C,N)基金属陶瓷性能的影响。采用X射线衍射仪对物相研究发现:金属相中w(Co)=10%和w(Co)=15%时,金属陶瓷中出现金属间化合物,并且有两种Co的同素异构体并存;力学性能测试表明:5%的Co取代5%的Ni可以明显提高金属陶瓷的抗弯强度、硬度和断裂韧性。金属相为10%Ni-5%Co时,材料的综合力学性能最好。     

Ti(C,N)基金属陶瓷的摩擦磨损研究

本文对Ti(C,N)基金属陶瓷材料的摩擦磨损行为及其磨损机理进行了研究.试验结果表明:与具有相同硬度的WC-Co合金和钢结硬质合金相比,Ti(C,N)金属陶瓷具有优异的耐磨性和较低的摩擦系数,其耐磨性随粘结相含量的增加而降低.Ti(C,N)基金属陶瓷磨损过程中,首先由表面微凸体间相互滑过,发生粘着,犁削,引起磨损,跑合一定时间后磨损由硬质相晶粒剥落控制.     

CO冷却对Ti(C,N)基金属陶瓷表层结构和切削性能的影响

为改善Ti(C,N)基金属陶瓷刀具的抗冲击性能,从烧结碳势对表层粘结相分布影响的角度出发,制备了不同压力CO冷却的Ti(C,N)基金属陶瓷刀片.借助扫描电镜和能谱仪研究了CO冷却下金属陶瓷表层的组织结构以及粘结相分布情况.对比了CO冷却和真空冷却对金属陶瓷刀片切削性能的影响.结果表明:CO冷却对金属陶瓷常规性能影响微小...     

Ti(C,N)_w/Ti(C,N)基金属陶瓷的组织与力学性能研究

采用Ti(C,N)晶须和颗粒复合粉末(Ti(C,N)w+Ti(C,N)p)制备Ti(C,N)w/Ti(C,N)基金属陶瓷。研究了复合粉末对金属陶瓷组织及性能的影响。结果表明,Ti(C,N)w的加入,金属陶瓷的各项力学性能都得到了提高。组织表现为环形相结构特征,与Ti(C,N)基金属陶瓷相比,双层环形相结构所占比例增大,且尺寸加厚。烧结组织中Ti(C,N)w的长径比大于临界长径比,在强化金属陶瓷方面起着重要的作用。环形相使Ti(C,N)w与基体界面结合紧密,增韧机制主要表现为裂纹桥联和裂纹偏转,拔出效应不明显。     

Evolution of Ti （C, N）-based cermet microstructures

Two series of Ti(C, N)-based cermet materials originating from the same chemical composition but with dif-ferent grain size distribution and sintered to different stages of the sintering cycle have been studied using SEM, TEM,EDX, and XRD. Much of the surrounding structure is formed during solid state sintering. During the solid state sintering, at first, the Mo and W rich (Ti, Mo, W)C inner rim is formed by the interaction among TiC, WC, and Mo2C; then the Mo and W lean (Ti, Mo, W)(C, N)outer rim is formed. During the liquid phase sintering, the outer rim of coarse grains grows rapidly throw a solution-reprecipitation process; aLso coarse grains grow by particle coalescence. The interface between coarse grain outer rim and binder is flat (crystal surface).     

Cutting performances, mechanical property and microstructure of ultra-fine grade Ti(C, N)-based cermets

The two cutting tools obtained from ultra-fine grade Ti(C, N)-based cermets were tested in the dry cutting of a medium carbon steel (AISI1045). Microstructure and mechanical properties were studied. Wear mechanisms (mainly diffusion and oxidation) were investigated in detail and compared each other in order to better understand key aspects due to thermal wear mechanisms. Comparing tool A with B, under the adopted cutting conditions, the tool A has a better resistance to oxidation deformation in machining medium carbon steel due to the higher hardness, although tool B has higher bending strength and fracture toughness.     

Effect of RE element Y on properties of Ti(C, N)-based cermet

The effect of RE element Y on the microstructure and properties of Ti(C, N)-based cermet has been investigated. Yttrium can refine the particles of carbide phase because it can purify the interface between binder phase and carbide phase, and increase the thickness of rim phase slightly. The effect is in the most evidence when the mass fraction of Y is 0.8% and when the transverse rupture strength and the hardness of Ti(C, N)-based cermet are maximal.     

Microstructural evolution and characteristics during sintering of submicron Ti(C,N)-based cermet

1　INTRODUCTIONThebasiccompositionofTi(C ,N ) basedcer metsisTi(C ,N)andNi.IthasbeenknownthattheadditionofMoorMo2 Cisnecessarytoensuregoodwettability[1] ,andWCorothercarbidesareoftenaddedtoimprovetheplasticityofhardgrainsandhothardnessofthecermets[2 ] .Ti(C ,N) basedcermetsconsistmainlyofcarbonitride grainsandmetalbinder.The“core rim”structurewithinthehardgrainsisthetypicalmicrostructureofcermets .Thecarbonitride phaseenrichedMoandW (therimphase)hasbeenfoundtosurroundthe Ti(C ,…     

Chemical precipitation of nickel nanoparticles on Ti(C,N) suspensions focused on cermet processing

Ti(C,N)-based cermets are currently used in high speed cutting tools industry due to its high thermal stability. In previous works, Fe was proposed as metal matrix, however the use of iron as continuous matrix strongly affects the processing due to the low wetting capability of molten Fe with the reinforcement phase, Ti(C,N). To solve this problem, the use of alloys such as FeNi has been proposed, where Ni improves the wettability between the ceramic and the metal phases. This work proposes a bottom-up approach to build the cermet microstructure through the synthesis of metal nanoparticles (NPs) on the surface of Ti(C,N) micrometric particles, creating Ti(C,N)-Ni core-shell structures. For that purpose, the in-situ synthesis of Ni NPs through the chemical reduction of a Ni precursor onto the surface of micrometric Ti(C,N) particles, previously stabilized in an aqueous suspension, was proposed. Core-shell structures were characterized by X-Ray Diffraction (XRD), scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM), scanning transmission electron microscopy (STEM), high resolution scanning electron microscopy (HRTEM), energy-dispersive X-Ray spectroscopy (EDX) and Raman Spectroscopy.     

纳米Ti(C,N)增强Ti(C,N)基金属陶瓷的研究

采用纳米Ti(C，N)粉末制备Ti(C，N)基金属陶瓷，研究了纳米粉末对金属陶瓷组织及性能的影响。结果表明，粉末冶金过程中，纳米Ti(C，N)粉末易于在粘结相中扩散与溶解及沿晶界分布，降低了硬质相在粘结相中的溶解度，抑制了晶粒长大，提高了材料的红硬性能。抗弯强度与晶粒尺寸满足于Hall-Perch公式，5wt％～l0wt％的纳米粉末加入量可使金属陶瓷的抗弯强度和切削性能得到较大的提高，但硬度变化不大。切削磨损主要表现为磨粒磨损和轻微的粘着磨损，磨痕细小均匀。     

超细WC-Co硬质合金及其磨损性能研究

采用低温化学镀方法在超细WC颗粒表面进行金属钴包覆,烧结包覆后的复合粉体制备新型硬质合金NYG（WC-3%Co）.研究了超细WC-Co硬质合金的力学性能、断口形貌和显微结构,在销盘式磨损试验机上进行干滑动磨损实验.结果表明,在硬质合金烧结过程中,沿WC晶界均匀分布的金属钴不仅起粘结剂作用,也起抑制剂作用阻碍晶粒的长大;新型硬质合金的抗弯强度、断裂韧性、硬度和耐磨性能均得到较大提高;在干滑动摩擦条件下,新型WC-Co硬质合金的失效以塑性变形及细小碳化钨相颗粒脱落为特征.     

Microstructure and shear strength of the brazed joint of Ti（C,N）-based cermet to steel

Firm joins were obtained between Ti(C,N)-based cermet and steel with Ag-Cu-Zn-Ni filler metal by vacuum brazing. The effects of technological parameters such as brazing temperature, holding time, and filler thickness on the shear strength of the joints were investigated. The microstructure of welded area and the reaction products of the filler metal were examined by scanning electron microscopy (SEM), metallographic microscope (OM), energy-dispersive X-ray analysis (EDS), and X-ray diffraction (XRD). The brazing temperature of 870°C, holding time of 15 min, and filler thickness of 0.4 mm are a set of optimum technological parameters, under which the maximum shear strength of the joints, 176.5 MPa, is achieved. The results of microstructure show that the wettability of the filler metal on Ti(C,N)-based cermet and steel is well. A mutual solution layer and a diffusion layer exist between the welding base materials and the filler metal.     

TiN/TiAlN涂层Ti(C,N)基金属陶瓷刀具的切削性能

采用多弧离子镀技术在Ti(C,N)基金属陶瓷基体上沉积了TiN/TiAlN多层涂层,通过扫描电镜、涂层附着力自动划痕仪对其显微组织形貌和涂层的结合强度进行了分析,并对涂层和未涂层金属陶瓷铣刀以及硬质合金铣刀进行了切削0Cr18Ni9钢的试验.结果表明,多弧离子镀TiN/TiAlN涂层均匀,TiN/TiAlN多层涂层与金属陶瓷之间的结合强度高达57.52 N.TiN/TiAlN涂层金属陶瓷的切削性能明显优于未涂层金属陶瓷和硬质合会YW2,其平均寿命为硬质合金刀具的2倍.TiN/TiAlN涂层金属陶瓷刀具的失效形式主要是磨损和崩刃,没有涂层剥落现象,TiN/TiAlN涂层与基体的结合强度很好.未涂层金属陶瓷刀具的磨损形式主要是磨损和粘着.