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熔融插层制备聚合物/层状粘土纳米复合材料研究进展 总被引:13,自引:0,他引:13
从流变性能、加工操作过程对熔融插层制备聚合物纳米复合材料的影响、分散机理的研究进展等方面对熔融插层制备聚合物 /层状粘土进行了综述 ,并对今后的研究提出了展望。 相似文献
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聚丙烯/蒙脱土纳米复合材料的研究进展 总被引:3,自引:0,他引:3
对聚丙烯(PP)/蒙脱土(MMT)纳米复合材料的国内外研究进展进行综述,介绍了PP/MMT纳米复合材料的制备原理和制备方法。包括原位插层聚合法、聚合物溶液插层法、聚合物熔融插层法、溶胶一凝胶法,重点介绍了聚合物熔融插层法的研究进展。聚合物熔融插层法具有操作简单、无需处理过多溶剂的优点,避免了环境和能源问题,更易于工业化。最后对PP/MMT纳米复合材料的未来发展进行了展望。 相似文献
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熔融插层法制备聚合物/纳米蒙脱土的研究进展 总被引:1,自引:0,他引:1
简要介绍了熔融插层法制备聚合物/纳米蒙脱土复合材料的研究进展。结合热力学和动力学的分析,概括了熔融插层法一些理论上的研究进展。总结了目前关于熔融插层法制备聚合物/纳米蒙脱土复合材料及其表征的最新研究成果。 相似文献
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在普通双螺杆挤出机上,基于未改性蒙脱土和聚酰胺6的直接熔融复合制备了纳米复合材料。通过插层剂的合理选择及不同插层剂的复配使用,可以得到具有插层刷离分散形态的聚酰胺6/未改性蒙脱土纳米复合材料。力学性能测试结果表明,有可能通过在聚酰胺6/未改性蒙脱土复合体系中插层剂的选择与调配实现同时增加聚酰胺6基体的强度和韧性的目的。在特定的插层剂复配条件下,复合材料的弯曲强度较基体增加20%,弯曲模量增加29%,同时干态冲击强度的增幅达70%以上。此外,还讨论了聚酰胺6/未改性蒙脱土复合体系的动态力学行为和流变性能。 相似文献
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采用密炼器熔融共混法,将聚乳酸(PLA)分别与碳酸钙(CaCO3)、蒙脱土(MMT)及滑石粉(Talc)共混制备成生物降解复合材料,研究了PLA/无机填料共混物的力学性能、断面微观结构及结晶性能。结果表明:CaCO3、MMT和Talc均降低了PLA的断裂伸长率;Talc和CaCO3对PLA的拉伸强度影响不大,MMT明显降低了PLA的拉伸强度;Talc和CaCO3相对MMT在PLA基体中的分散较均匀;CaCO3和MMT改善PLA结晶性能的效果不明显,而Talc大大提高了PLA的结晶性能使,PLA的结晶温度下降约20℃结,晶度提高近3%。 相似文献
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Improvements in carbon nanotube (CNT) dispersion and subsequent mechanical properties of CNT/poly(phenylsulfone) (PPSF) composites were obtained by applying the supercritical CO2 (scCO2)‐aided melt‐blending technique that has been used in our laboratory for nanoclay/polymer composite preparation. The preparation process relied on rapid expansion of the CNTs followed by melt blending using a single‐screw extruder. Scanning electronic microscopy results revealed that the CNTs exposed to scCO2 at certain pressures, temperatures, exposure time, and depressurization rates have a more dispersed structure. Microscopy results showed improved CNT dispersion in the polymer matrix and more uniform networks formed with the use of scCO2, which indicated that CO2‐expanded CNTs are easier to disperse into the polymer matrix during the blending procedure. The CNT/PPSF composites prepared with scCO2‐aided melt blending and conventional melt blending showed similar tensile strength and elongation at break. The Young's modulus of the composite prepared by means of conventional direct melt blending failed to increase beyond the addition of 1 wt% CNT, but the scCO2‐aided melt‐blending method provided continuous improvements in Young's modulus up to the addition of 7 wt% CNT. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers 相似文献
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Polyamide‐6 (PA‐6)/clay (modified montmorillonite) hybrid was synthesized by melt blending at high shear stress. 27Al‐NMR of solid state shows that the clay is not modified after melt blending. Using wide‐line 1H‐NMR and TEM, it is demonstrated that the nanocomposite exhibits mainly an exfoliated structure. It is shown that the modified montmorillonite induces the crystallization of PA‐6 predominantly in γ‐form. The presence of clay in PA‐6 increases the polymer crystallization temperature, and decreases its melting point. These phenomena show that a certain number of interactions develop near the reinforcing material, and that the latter plays a particular role of nucleating agent. However, the crystallization is not spherulitic and the assumption of macromolecular orientation in the vicinity of the clay is demonstrated by the observations carried out in DSC and AFM. These particular properties of orientation will have a particular importance on the mechanical behavior of the nanocomposite material. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2416–2423, 2002 相似文献
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Vapor barrier properties of polycaprolactone montmorillonite nanocomposites: effect of clay dispersion 总被引:3,自引:0,他引:3
Giuliana GorrasiMariarosaria Tortora Vittoria Vittoria Eric PolletBénédicte Lepoittevin Michael AlexandrePhilippe Dubois 《Polymer》2003,44(8):2271-2279
Different compositions of poly(ε-caprolactone) (PCL) and (organo-modified) montmorillonite were prepared by melt blending or catalyzed ring opening polymerization of ε-caprolactone. Microphase composites were obtained by direct melt blending of PCL and sodium montmorillonite (MMT-Na+). Exfoliated nanocomposites were obtained by in situ ring opening polymerization of ε-caprolactone with an organo-modified montmorillonite (MMT-(OH)2) by using dibutyltin dimethoxide as an initiator/catalyst. Intercalated nanocomposites were formed either by melt blending with organo-modified montmorillonite or in situ polymerization within sodium montmorillonite. The barrier properties were studied for water vapor and dichloromethane as an organic solvent. The sorption (S) and the zero concentration diffusion coefficient (D0) were evaluated for both vapors. The water sorption increases with increasing the MMT content, particularly for the microcomposites containing the unmodified MMT-Na+. The thermodynamic diffusion parameters, D0, were compared to the value of the parent PCL: both microcomposites and intercalated nanocomposites show diffusion parameters very near to PCL. At variance exfoliated nanocomposites show much lower values, even for small montmorillonite content. In the case of the organic vapor, the value of sorption at low relative pressure is mainly dominated by the amorphous fraction present in the samples, not showing any preferential adsorption on the inorganic component. At high relative pressure the isotherms showed an exponential increase of sorption, due to plasticization of the polyester matrix. The D0 parameters were also compared to those of the unfilled PCL; in this case, both the exfoliated and the intercalated samples showed lower values, due to a more tortuous path for the penetrant molecules. 相似文献
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用熔融挤出的方法制备了聚碳酸酯(PC)/N烯腈-丁二烯-苯乙烯共聚物(ABS)/有机蒙脱土(OMMT)合金,考察了OMMT用量对PC/ABS合金力学性能和加工性能的影响,观察了其相分布和OMMT的分散情况以及冲击断面的形貌,并分析了机理。结果发现.ABS相分散在PC基体中.绝大部分的OMMT分散在ABS相中,且部分呈纳米级分散;固定PC/ABS质量比为70/30,加入OMMT后体系的拉仲强度变化不大,冲击强度降低较大;OMMT用量为2phr时,弯曲性能最佳;随着蒙脱土用量的增加,熔体质量流动速率(MFR)先增大后降低,在OMMT用量为5phr时.流动性最好。 相似文献
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SBS/蒙脱土复合材料的制备及其性能Ⅱ.复合材料的性能 总被引:3,自引:0,他引:3
分别采用大分子溶液插层法和大分子熔融插层法制备了苯乙烯-丁二烯-苯乙烯共聚物(SBS)/蒙脱土纳米复合材料.研究了材料的力学性能。纳米结构的形成对复合材料的性能产生显著影响,少量蒙脱士的引入可以明显改善SBS/蒙脱土复合材料的力学性能。无论溶液插层法制备的星型SBS/蒙脱土纳米复合材料,还是熔融插层法制备的线型SBS/蒙脱土纳米复合材料,其拉伸强度和断裂伸长率都同时增加。其中,溶液插层法制备的纳米复合材料的拉伸强度和断裂伸长率分别较纯SBS增加了75%和55%;熔融法制备的纳米复合材料的托伸强度和断裂伸长率分别较纯SBS增加了70%和18%。 相似文献