The role of starting powder size on the compressive response of stand-alone plasma-sprayed alumina coatings

Cylindrical stand-alone tubes of plasma-sprayed alumina were tested in uniaxial compression at room temperature, using strain gages to monitor axial strains. The effect of lamella size on the mechanical response was investigated by employing different starting powders to fabricate samples. The average powder sizes investigated included 9 m, 19 m and 32 m alumina; the resulting effective lamella diameters were 10 m, 28 m, and 55 m, respectively. Similar stress-strain hysteresis was observed on unloading in all tubes, independent of lamella size. A strong correlation between the failure stress and the cumulative strain at failure was also observed for tubes fabricated from the three powders. For samples with approximately constant densities, tubes plasma sprayed with the 9 m powder exhibited greater moduli than tubes sprayed from either 19 or 32 m powders. This difference was attributed to the greater percentage of unmelted -Al₂O₃ in the coating.     

Effect of placing,removing and polishing of amalgam restorations on 24-h urinary mercury concentration

Twenty-four-hour urinary mercury concentration were assessed in 43 patients before and after removing old amalgam fillings (8 pts), placing (13 pts), and polishing of amalgam (22 pts). Baseline analyses 8 days before the treatments showed on average 18.5±7.2 g mercury mass excreted per 24-h urine samples. The removal of old fillings caused a total excreted mass of 56.3±32.3 g Hg, the placing of amalgam 45.9±26.2 g Hg, and the polishing 56.25±33.77 g Hg, respectively, one day after the treatments. When compared with the baseline values, the urinary mass excreted remained significantly elevated during the 8-day follow-up. However, all Hg values measured were below the WHO recommandations for the threshold limits for urinary mercury.     

Measurements of chemical potentials in superconducting tin whiskers

A superconductor / normal conductor potential probe pair was used to measure differences between the time-averaged electrochemical potentials _p of Cooper pairs and of quasiparticle excitations caused by a phase-slip center in several experimental situations. The results can only be understood by assuming that at a larger distance from the phase-slip center differs from the proposal of Skocpol, Beasley, and Tinkham by showing a swinging over or swinging below _p . We propose a modified slope of as a function of site. Possible explanations are discussed. The multiple-contact samples used also allow the study of the influence of phase-slip centers already present on the relaxation of nonequilibrium quasiparticles.     

Rheology of stimulated whole saliva in a typical pre-orthodontic sample population

The dynamic viscosity () of stimulated whole saliva in a typical pre-orthodontic sample population was characterized as a function of temperature (T). Samples were collected from 30 adolescents or young adults, after screening for factors that are known to have an effect on salivary viscosity. Using a cone and plate viscometer, 1.5 ml of stimulated whole saliva was evaluated at a constant shear rate of 450 s^-1 from T=20°C to T=40°C. Data from the -T plots showed a negative dependence of the form, =a–bT, over a range of from 1.08 to 2.45 centipoise (cps) at 34°C. Most of the samples fell into a narrow envelope, where the mean of the saliva samples ranged from 2.42±0.61 cps at 20°C to 1.57±0.32 cps at 37°C. With regard to sample stability, viscosity-time plots indicated that a small but predictable decrease in occurred during the 3 h period. The -T plots generated from fresh and frozen saliva samples demonstrated an appreciable change in as a result of refrigeration. With regard to sample reproducibility, viscometric data obtained from a typical pre-orthodontic patient over a 1-week period fluctuated within a fairly broad envelope of values.Presented, in part, at the 21st Annual Meeting and Exhibition of the A.A.D.R., Boston, Massachusetts, March, 1992.     

Absorption Spectrum of ZnO Precipitates in ZnSe

The absorption spectrum of ZnO precipitates in ZnSe saturated with oxygen is studied in the spectral range 500–2000 cm^–1 and is shown to correlate with the transmission spectrum of single-crystal ZnO. Saturation of ZnSe with oxygen in the course of growth leads to ZnO precipitation during cooling. The precipitates give rise to narrow absorption bands in the range 5.8–7.1 m, which correlate with the components of the multiphonon absorption spectrum of ZnO, formed by combinations of LO and TO phonons. The 2LO mode defines the long-wavelength transmission edge of ZnO. In addition, the spectrum shows strong absorptions due to the LO + TO(10.2 m) and 2TO (11.3 and 12.7 m) modes. The possible role of SeO₂ is discussed. It is suggested that ZnO with a high carrier concentration may act as a gray filter in the spectral range 2–9 m.     

A note on the similarity solutions for free convection on a vertical plate

Summary The similarity solutions for free convection on a vertical plate when the (non-dimensional) plate temperature is x and when the (non-dimensional) surface heat flux is –x are considered. Solutions valid for 1 and 1 are obtained. Further, for the first problem it is shown that there is a value ₀, dependent on the Prandtl number, such that solutions of the similarity equations are possible only for >₀, and for the second problem that solutions are possible only for >–1 (for all Prandtl numbers). In both cases the solutions becomes singular as ₀ and as –1, and the natures of these singularities are discussed.     

Single-Mode As–S Glass Fibers

Single-mode As–S glass fibers with a core diameter from 3 to 20 m and a clad diameter of 125 m are prepared by the double-crucible method. The cutoff wavelength of the fibers is 0.9–6 m. The lowest transmission losses in the fibers at 2.2–2.3 m are 100 dB/km, and their mean bending strength is 800–1000 MPa.     

Crystal growth of U2D2 solid3He

We have measured the growth rate of single crystal U2D2 solid³He in the superfluid B phase as a function of chemical potential difference between the solid and liquid for temperatures between 0.4 and 0.9 T_N. The growth rate was not proportional to , with very slow growth rates for less than about 10 erg/cm³. For larger values of the growth rate depended weakly on temperature and the growth was attributed to a quantum growth mechanism due to screw dislocations. The melting rate was too fast to be measured quantitatively, but was slower at higher temperatures.     

Surface study of liquid3He using surface state electrons

We have measured the mobility of surface state electrons (SSE) on liquid³He, 3, aiming to study the elementary surface excitations of the Fermi liquid. A gradual increase of 3 below 300 mK is attributed to the scattering of electrons by ripplons. Ripplons do exist in³He down to 100 mK. We observe an abrupt decrease of 3, due to the transition to the Wigner solid (WS). The dependences of the WS conductivity and mobility on temperature and magnetic field differ from the SSE behavior on liquid⁴He.     

Reissner-Sagoci problem for a non-homogeneous half-space with surface constraint

This paper deals with the problem of twisting of a non-homogeneous, isotropic, half-space by rotating a circular part of its boundary surface (0ra, z = 0) through a given angle. A ring (a<r<b, z = 0) outside this circle is stress-free and the remaining part (r>b, z = 0) is rigidly clamped. The shear modulus is assumed to vary with the cylindrical coordinates r, z by the power law ( = _, r z ). Such a dependence is of practical interest in the context of Soil Mechanics. The problem leads to a Fredholm integral equation of the second kind which is solved numerically, giving an evaluation of the influence of non-homogeneity on the torque at the surface and the stress intensity factor. The homogeneous case studied in [16] is recovered. Expressions for some quantities of physical importance such as the torque applied at the surface and stress intensity factor are obtained. It appears from our investigation that the influence of clamping dies out with increasing and . Quantitative evaluations are given and some curves for the relative increase, due to clamping, in the torque and in the stress intensity factor are presented.     

Ion-implantation technology for improved GaAs MESFETs performance

Electrical properties of Si-implanted and co-implanted with Mg or Be in semi-insulating GaAs was studied. The Si-implanted MESFETs with and without buried p-layer (formed by Mg or Be) have been fabricated and characterized by their d.c. and r.f. performance. The experimental results showed that the device with a buried p-layer can effectively suppress the substrate leakage current (thus good pinch-off characteristic) and obtained higher gain linearity than these without a buried p-layer. For 1 m×100 m MESFETs device with co-implantation of Si (8×10¹² cm^–2) and Be (6×10¹¹ cm^–2) demonstrated uniform transconductance (g_m) of 115 mS mm^–1 with the gate voltage ranging from –1 to 1 V and reduced pinch-off voltage compared to those with co-implantation of Si and Mg (6×10¹¹ cm^–2). The measured f_T and f_max of a 1 m×25 m MESFET with co-implantation of Si and Be are 10 and 39 GHz, respectively. However, FETs with increased Mg dose (from 6×10¹¹ cm^–2 to 2×10¹² cm^–2) in a buried p-layer can obtain higher transconductance and saturation current.     

Simulation of the Process of Water Freezing in a Round Pipe

The problem of freezing of pure water in a round pipe is treated with due regard for convection under asymmetric thermal boundary conditions in the absence of motion along the pipe. The problem is solved numerically using the control volume approach, SIMPLER algorithm, and the enthalpy method. Results are obtained for three Grashof (Gr) and six Biot (Bi) numbers: Gr = 1.55 × 10⁶, Bi = 0.305 (0 < ), Bi = 0.044 ( < 2); Gr = 1.24 × 10⁷, Bi = 0.610 (0 < ), Bi = 0.087 ( < 2); Gr = 9.89 × 10⁷, Bi = 1.220 (0 < ), Bi = 0.174 ( < 2). The correctness of calculation of the problem disregarding free-convection flows is analyzed.     

High-frequency magnetic properties of Co-Ti substituted barium ferrites prepared by modified chemical coprecipitation method

Co-Ti substituted barium ferrites were prepared by a modified chemical coprecipitation method. Microstructures and high-frequency magnetic properties were investigated by X-ray diffraction (XRD) transmission electron microscopy (TEM) scanning electron microscopy (SEM) and measurements of complex permeability spectra. Barium ferrites with Co-Ti substitution x=1.0 have the highest permeability and the lowest magnetic resonant frequency f_ros and f_ros can be changed continuously with changing Co-Ti substitution in the hyper-frequency region while keeps its high value at the same time. A higher sintering temperature corresponds to higher and lower f_ros due to the grain growth. The d.c. electrical resistivity for all samples was above 10⁸ cm.     

Structure and properties of injection-moulded nylon-6

The microstructure and morphology of injection-moulded nylon-6 has been studied using wide-angle and small-angle X-ray diffraction, optical microscopy and a density measurement technique. A non-spherulitic surface layer consisting of a metastable pseudohexagonal phase surrounds the moulding and the thickness of the layer is sensitive to mould temperature. This outer structure gives way to a monoclinic phase containing spherulites between 3 and 6 m diameter. The central core of the moulding consists almost entirely of the phase with spherulites 6 m diameter, approximately. Exposure of nylon-6 to boiling water had no significant effect on the morphology of the moulding but the phase in the surface layer was transformed to the monoclinic phase.     

Coaxial variable-length resonator for determining the electromagnetic parameters of materials at normal and higher temperatures

Conclusions It is possible by means of the above resonator, according to our analysis and in the absence of air gaps between the sample and the line, to evaluate the real components and of permeability and permittivity respectively in the range of 2 to 100 with an error between ±3% and ±10% in the temperature range from room temperature to +400°C, and the imaginary components and (for tan and tan in the range of 0.001 to 2) with an error of 7 to 20% over the same temperature range.     

Structure parameters of metal-fiber heat pipe wicks

The results of an experimental investigation of local and average values of permeability and effective pore diameter for metal-fiber wicks, using a laser-Doppler velocity measurement, are presented and discussed.Notation K permeability coefficient, m² - V filtration rate, m/sec - viscosity, N·sec/m² - dp/dx pressure gradient - rms deviation - f_i probability density distribution,m^–1 - D pore diameter,m - E excess - A asymmetry The 50-Year Anniversary of the Great October Socialist Revolution Kiev Polytechnic Institute.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 35, No. 5, pp. 777–781, November, 1978.     

Effect of filler content and size to properties of composite resins on microwave curing

The effect of filler content and size to property of composite resin using high purity spherical silica particles on microwave curing was examined by mechanical means and electron microscope observation to develop microwave-curing composite resin inlay. Increasing filler content in three kinds of filler particles (0.45, 0.96 and 1.46 m) resulted in increasing compressive strength, diametral tensile strength and knoop hardness and indicated the highest values at the operative mixing limit. The effect of particle size was that the mechanical property of the 0.96 m filled resin was highest, followed by 1.46 m and 0.45 m on the same filler content. The 0.96 m filled resin had about the same knoop hardness on both surfaces of the cured sample, which means that uniform polymerization occurred in the cured sample.With electron microscope observation, the bubbles of about 1.0 m and the cracks between the fillers and the matrix were observed in each cured resin. This is caused by the excessive absorption of microwave energy in fillers and surface treatment materials of fillers. Therefore, improvement of the composition of filler and surface treatment material of filler are needed, which makes it harder to absorb the microwave energy. ©©1999©Kluwer Academic Publishers     

Preparation of Si3N4 whiskers by reaction of wheat husks with NH3

-Si₃N₄ whiskers that are 1–10 mm long and 0.5–1.1 m thick were obtained by the reaction of wheat husks with NH₃ at 1250–1450 °C. A maximum whisker yield of about 30% was obtained at 1450 °C with the addition of an iron impurity. Whiskers with 1.3–2.2 m thickness (average 1.6 m) were obtained by the addition of an H₂S impurity. Thin whiskers with periodic thick and thin diameters were also obtained.     

Functional derivative ofT c with α2(ω)F(ω) for weak coupling anisotropic superconductors

Approximate analytic calculations of the functional derivative ofT _c with respect to ²()F() for anisotropic superconductors are presented, with the primary purpose of identifying the determining material parameters. The square-well model for the phonon-mediated electron-electron interaction, the weak coupling limit ( _c /2T _c 1), and separable anisotropy are used. The general behavior of T _c /²()F() is the same as that found in numerical calculations for the case of small anisotropy, a ²/(–*)1; the regime of * is also discussed.     

Structural properties and enumeration of quasi cyclic codes

Given any finite fieldF _q , an (N, K) quasi cyclic code is defined as aK dimensional linear subspace ofF _q ^N which is invariant underT ⁿ for some integern, 0 <n N, and whereT is the cyclic shift operator. Quasi cyclic codes are shown to be isomorphic to theF _q []-submodules ofF _q ^N where the product(gl)· is naturally defined as ₀ + ₁T ⁿ +...+ _m T ^mn if()= ₀ + ₁ +...+ _{m m} .In the case where (N/n, q)=1, all quasi cyclic codes are shown to be decomposable into the direct sum of a fixed number of indecomposable components called irreducible cyclicF _q []-submodules providing for the complete characterisation and enumeration of some subclasses of quasi cyclic codes including the cyclic codes, the quasi cyclic codes with a cyclic basis, the maximal and the irreducible ones. Finally a general procedure is presented which allows for the determination and characterisation of the dual of any quasi cyclic code.