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以对氯苯甲醛为原料,过氧化氢作氧化剂,在水作溶剂的碱性条件下,一步反应合成对氯苯甲酸。考察了碱的浓度、反应温度和物料摩尔比对反应产率的影响。实验结果表明:氢氧化钾浓度为40%,反应温度40℃,反应物质的量比n(对氯苯甲醛):n(30%过氧化氢)=1:4,对氯苯甲酸收率达89%。通过测熔点和红外光谱表征了目标产物对氯苯甲酸的结构。 相似文献
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以过氧化氢为氧化剂,十六烷基三甲基钨磷杂多酸铵为催化剂,催化氧化苯甲醛制苯甲酸.考察了反应温度、催化剂用量、30%过氧化氢用量和反应时间对苯甲酸产率的影响.结果表明:苯甲醛10.1 mL,30%过氧化氢11.5 mL,催化剂0.16 g,90℃下反应6 h,苯甲酸的产率可达到74.9%. 相似文献
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以4-氯甲基苯甲酸甲酯和亚磷酸三乙酯为起始原料,经Arbuzov反应后,再分别与4-甲酰基苯甲酸甲酯、苯甲醛、4-叔丁基苯甲醛、4-氯苯甲醛、2,4-二氯苯甲醛发生Wittig-Horner反应,成功合成出5种不同官能团的紫外线吸收剂,反应条件为:温度50 ℃,n(Wittig试剂)∶n(醛)=1∶1,在DMF/甲醇体系下反应30 min,产率分别是81.4%、76.7%、69.0%、57.0%、50.1%,目标产物均通过核磁共振氢谱和熔点确认,并用紫外光谱测试其性能. 相似文献
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以30%过氧化氢作为氧化剂,对苯二酚与甲醛、二乙胺的Mannich反应产物2,5-二(二乙氨基甲基)对苯二酚与钨酸钠为催化剂,研究了苯甲醇氧化制备苯甲酸的反应,2,5-二(二乙氨基甲基)对苯二酚的辅助催化性能优于对苯二酚。最佳反应条件为:40.5mmol苯甲醇,n(钨酸钠)∶n(2,5-二(二乙氨基甲基)对苯二酚)∶n(苯甲醇)∶n(30%过氧化氢)=0.405∶0.489∶40.5∶273,3mL0.1mol/L硫酸,于95℃反应8h,在无有机溶剂的条件下苯甲醇可以被氧化为苯甲酸,一次结晶率为76.9%,催化体系的重复使用性能不太理想。 相似文献
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以对羟基苯甲酸和乙酸酐为原料,采用对甲基苯磺酸作催化剂合成4-乙酰氧基苯甲酸,考察了反应温度、反应时间、催化剂用量对产品的影响。实验结果表明酰化反应的优化条件n(对羟基苯甲酸)∶n(乙酸酐)∶n(对甲苯磺酸)=1∶2∶0.025,反应时间30min,反应温度80~89℃,产率达91.63%。 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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D. G. Gordeev L. F. Gudarenko M. V. Zhernokletov V. G. Kudel’kin M. A. Mochalov 《Combustion, Explosion, and Shock Waves》2008,44(2):177-189
A semi-empirical equation of state for metals is described. Its capabilities are demonstrated by the example of the equation
of state for aluminum. New experimental data are presented on the location of the isentrope of aluminum for unloading from
the state at p = 229.71 GPa on the shock adiabat to an aerogel (SiO2) of density 0.08 g/cm3.
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Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 2, pp. 61–75, March–April, 2008. 相似文献
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A perturbation viscometer is a differential capillary viscometer that measures the logarithmic viscosity gradient of the viscosity-composition curve for gas mixtures. Measurements are made at different gas mixture compositions. Integration of the logarithmic viscosity gradients measured over the full composition range gives the mixture viscosity relative to the viscosity of one of the pure components of the gas mixture. This method is attractive because, for measurements of equal precision, integration of the gradients is potentially an order of magnitude more precise than measurement of the viscosities directly. It can also work at high and low temperatures and perhaps high pressures.The perturbation viscometer has been used to make measurements on ideal gas mixtures at ambient and elevated temperatures. The situation is more complicated when the gas mixtures are non-ideal. Extra effects due to density differences, molar volume change on mixing and differential thermal expansion may be measured in addition to the desired viscosity change producing systematic errors in the results. Thus, a more sophisticated apparatus is required. The standard perturbation viscometer has been modified to separate out the extra effects to permit measurement of the true change in viscosity. In addition, the theoretical operation of the modified apparatus has been revised to account for the design changes to permit calculation of the viscosity-composition profiles from the results.The apparatus has been tested using helium-HFC-125 mixtures and two new viscosity-composition profiles are presented for these mixtures at 23 and . Internal consistency tests have been used to confirm that the data produced are of high quality with an estimated uncertainty in the viscosity ratio data at of 0.9% and at of 1.5%. 相似文献
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Jorge Marcelo Romero Soledad Bustillo Hugo Enrique Ramirez Maisuls Nelly Lidia Jorge Manuel Eduardo Gómez Vara Eduardo Alberto Castro Alicia H. Jubert 《International journal of molecular sciences》2007,8(7):688-694
A thermochemical rather simple experimental technique is applied to determine the enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented with suitable theoretical calculations at the semiempirical and ab initio levels. A particular satisfactory agreement between both ways is found for the ab initio calculation at the 6–311G basis This set level. Some possible extensions of the present procedure are pointed out. 相似文献
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塔设备改造选型的分析 总被引:2,自引:0,他引:2
就当前扩产增容中塔设备设计和改造时板式塔和填料塔的选型问题加以分析。在评述目前国内常用的几种塔板和新型填料之后,着重介绍一种新型塔板(导向梯形浮阀塔板)和一种新型填料(波环填料——乾隆帕克)。 相似文献
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In the present article, chitin from crab shell was systematically deacetylated using a NaOH treatment with control of the reaction time. The degree of deacetylation, monitored using solid-state NMR, revealed that the reaction was pseudo-first order. Based on this, swollen and NaOH-saturated particles are proposed as the reaction system. The weight loss of the partially saponified and neutralized samples after HCl hydrolysis increased linearly with the degree of deacetylation. The crystallinity of the samples was found to increase after acid hydrolysis. According to conductimetric titration, the surface charge density of the crystallites, after acid hydrolysis, was found to increase with base treatment time. The effect of surface charge on the formation of a chiral nematic phase, due to the rodlike nature of the crystallites, was explored. These results show that because the contribution of charged particles to the ionic strength was significant the double layer compression was affected, especially since the surface charge density was close to the Manning limit. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 65:373–380, 1997 相似文献