A semi-empirical analytic model for threshold voltage instability in MOSFETs with high-k gate stacks

n the threshold voltage and the induced trap density. The obtained model is also verified by extensive experimental data of trapping and de-trapping stress from different high-k gate configurations.     

高K栅堆叠结构MOSFET器件阈值电压不稳定度的半经验解析模型

A semi-empirical analytic model for the threshold voltage instability of MOSFET is derived from the Shockley-Read-Hall (SRH) statistics in this paper to account for the transient charging effects in a MOSFET high-k gate stack. Starting from the single energy level and single trap assumption, an analytical expression of the filled trap density in terms of the dynamic time is derived from the SRH statistics. The semi-empirical analytic model of the threshold voltage instability is developed based on the MOSFET device physics between the threshold voltage and the induced trap density. The obtained model is also verified by the extensive experimental data of the trapping and de-trapping stress from the different high k gate configuration.     

后栅工艺高k/金属栅结构NMOSFET偏压温度不稳定性特性研究

本文对后栅工艺高k/金属栅结构NMOSFET偏压温度不稳定性特性进行了研究。在加速应力电压和高温条件下,NMOSFET的阈值电压的退化与时间呈幂指数关系。然而幂指数随应力电压的增大而减小;在本文中,应力从0.6V到12V,幂指数则相应的由0.26减小到0.16。通过对应力前后器件的亚阈值特性分析,在应力过程中没有界面态产生。根据实验数据提取到数值为0.1eV的热激活能,表明偏压温度不稳定性是由栅介质中预先存在的陷阱俘获从衬底隧穿的电子造成的。恢复阶段的测试显示阈值电压的退化与对数时间呈线性关系,同时可以用确定的数学表达式来表明其与应力电压和温度之间的关系。     

Analytical 2D modeling for potential distribution and threshold voltage of the short channel fully depleted cylindrical/surrounding gate MOSFET

A two-dimensional analytical model for fully depleted cylindrical/surrounding gate MOSFET is presented. We used the evanescent mode analysis to solve the 2D Poisson's equation and to deduce analytically the surface potential and threshold voltage expressions of this device. Comparison with the other models reveals a good agreement.     

Annealing effect on the metal gate effective work function modulation for the Al/TiN/SiO2/p-Si structure

In this work, the thermal annealing effect on the metal gate effective work function (EWF) modulation for the Al/TiN/SiO₂/p-Si(1 0 0) structure was investigated. Compared with the sample of TiN/SiO₂/p-Si(1 0 0) structure, for the sample additionally capped with Al the flat band voltage has a very obvious shift as large as 0.54 V to the negative direction after forming gas annealing. It is also revealed that the thermal budget can effectively influence both the EWF of the gate electrode and the thickness of the gate dielectric layer when a post annealing at 600 °C with different soak times was applied to the samples with Al cap. Material characterization indicates that the diffusion of Al and the formation of Al oxide during annealing should be responsible for all the phenomena. The interface trap density Dit calculated from the high-frequency C-V and the laser-assisted high-frequency C-V curves show that the introduction of Al does not cause reliability problem in the Al/TiN/SiO₂/p-Si structure.     

Time-dependent degradation due to negative bias temperature instability of p-MOSFET with an ultra-thin SiON gate dielectric

This paper presents the time-dependence of the negative bias temperature instability (NBTI) degradation of p-MOSFETs with an ultra-thin silicon oxynitride gate dielectric. The concentrations of nitrogen in the gate dielectric were approximately 3% and 10%. The device with 10% nitrogen concentration had unique time-dependent degradation characteristics due to the nitrogen enhanced NBTI effect. It degraded significantly just after application of an NBTI stress. After this initial degradation, a fast and slow degradation followed in sequence. The initial, fast, and slow degradations appear to be associated with the deep donor effect of nitrogen, the diffusion of ionic and neutral hydrogen combined with Si-H bond breaking, and the diffusion of neutral hydrogen combined with O-H bond breaking, respectively. Owing to the slow down of the NBTI degradation after the initial and fast degradations, the lifetime for the device with 10% nitrogen concentration was three times longer than that with 3% nitrogen concentration.     

Understanding reversal effects of metallic aluminum introduced in HfSiON/TiN PMOSFETs

We evaluate the insertion of metallic aluminum in TiN metal gate over HfSiON/SiON for a gate first CMOS integration with an equivalent oxide thickness of 15 Å. From capacitance versus voltage measurements, we report for the first time a non-linear Vfb shift associated to aluminum thickness variation (a). To understand this observation the metal gates have been reproduced on various dielectric stacks having either (b) beveled SiON or (c) 150 Å HfSiO. From beveled samples we extract the effective work function, which presents the same variations with aluminum thickness as in nominal devices (a). Aluminum diffusion at the bottom high-k interface is prevented in samples (c) thanks to thick HfSiO and leads to a negative Vfb shift. We conclude that the observed reversal shifts with metallic aluminum thickness in TiN are due to a +50 mV aluminum induced dipole at the HfSiON/SiON interface associated to an opposite metal work function decrease.     

TiN/TaN 厚度变化对nMOSCAP栅叠层有效功函数的影响

We evaluated the TiN/TaN/TiA1 triple-layer to modulate the effective work function （EWF） of a metal gate stack for the n-type metal-oxide-semiconductor （NMOS） devices application by varying the TiN/TaN thickness. In this paper, the effective work function of EWF ranges from 4.22 to 4.56 eV with different thicknesses of TiN and TaN. The thinner TiN and/or thinner in situ TaN capping, the closer to conduction band of silicon the EWF is, which is appropriate for 2-D planar NMOS. Mid-gap work function behavior is observed with thicker TiN, thicker in situ TaN capping, indicating a strong potential candidate of metal gate material for replacement gate processed three-dimensional devices such as FIN shaped field effect transistors. The physical understandings of the sensitivity of EWF to TiN and TaN thickness are proposed. The thicker TiN prevents the A1 diffusion then induces the EWF to shift to mid-gap. However, the TaN plays a different role in effective work function tuning from TiN, due to the Ta-O dipoles formed at the interface between the metal gate and the high-k layer.     

Top-TiN生长条件及TaN厚度对MOSCAP栅叠层有效功函数的影响

我们引入TaN/TiAl/top-TiN三层结构,通过变化TaN的厚度及top-TiN的生长条件来调节TiN-based金属栅叠层的有效功函数。实验结果显示：较薄的TaN和PVD-process生长的top-TiN组合可以得到较小的有效功函数(EWF),而较厚的TaN和ALD-process生长的top-TiN组合可以得到较大的有效功函数(EWF),文中EWF有从4.25eV to 4.56eV的变化。同时文中也给出了TaN厚度及top-TiN的生长条件调节有效功函数(EWF)的物理解释。与PVD-process在室温条件下生长TiN相比,ALD-process TiN是在400 ℃条件下生长的,400 ℃ ALD-process TiN 可以为整个工艺过程提供更多的热预算,从而促进更多的Al原子扩散进入top-TiN,导致扩散进入到bottom-TiN的Al原子数量减少。另外,厚的TaN也会阻止Al原子进入bottom-TiN。这些因素都减少了bottom-TiN中Al原子的数量,减弱了Al原子对有效功函数的调节作用,从而引起EWF的增加。     

High air stability of threshold voltage on gate bias stress in pentacene TFTs with a hydroxyl-free and amorphous fluoropolymer as gate insulators

We investigated the air stabilities of threshold voltages (V_th) on gate bias stress in pentacene thin-film transistors (TFTs) with a hydroxyl-free and amorphous fluoropolymer as gate insulators. The 40-nm-thick thin films of spin-coated fluoropolymer had excellent electrical insulating properties, and the pentacene TFTs exhibited negligible current hysteresis, low leakage current, a field-effect mobility of 0.45 cm²/Vs and an on/off current ratio of 3 × 10⁷ when it was operated at −20 V in ambient air. After a gate bias stress of 10⁴ s, a small V_th shift below 1.1 V was obtained despite non-passivation of the pentacene layer. We have discussed that the excellent air stability of V_th was attributed to the insulator surface without hydroxyl groups.     

低温退火对具有HfO2/TiN栅结构的MOS电容电学性能的影响

The effects of low temperature annealing,such as post high-k dielectric deposition annealing(PDA),post metal annealing(PMA)and forming gas annealing(FGA)on the electrical characteristics of a metal–oxide–semiconductor(MOS)capacitor with a TiN metal gate and a HfO2dielectric are systematically investigated.It can be found that the low temperature annealing can improve the capacitance–voltage hysteresis performance significantly at the cost of increasing gate leakage current.Moreover,FGA could effectively decrease the interfacial state density and oxygen vacancy density,and PDA could make the flat band positively shift which is suitable for P-type MOSs.