薄膜金属化低温共烧陶瓷基板的阻碍层对共晶焊的影响

讨论了低温共烧陶瓷基板薄膜金属化技术中,有效阻碍层的选择对基板共晶焊的剪切强度、互连阻抗、可焊性的影响。试验结果表明,Ti / Ni是一种高可靠性的阻碍层,且Ti / Ni / Au也是一种较理想的低温共烧陶瓷基板薄膜金属化结构。     

低温共烧陶瓷基板的薄膜金属化

就低温共烧陶瓷(LTCC)基板实用化过程中遇到的问题,研究了LTCC基板的薄膜金属化技术;经复合膜系Ti/Ni/Au薄膜金属化的LTCC基板可满足各项技术指标要求,通过考核证明了用此方法制得的基板可靠性高,完全满足使用要求。     

基于LTCC基板BCB/Cu薄膜混合多层互连技术研究

针对微系统小型化集成对高性能成膜基板需求,研究了基于LTCC基板的BCB/Cu薄膜多层互连关键技术及过程控制要求。提出一种高可靠"T"型界面互连方式的薄膜磁控溅射Cr/Cu/Cr和Cr/Pd/Au复合膜层结构及其制备方法。研究了LTCC基板收缩率偏差、LTCC-薄膜界面缺陷及粗糙度、BCB介质膜固化应力、介质膜金属化的应力等因素对厚薄膜混合基板质量的影响。制备的12层厚薄膜混合基板(10层LTCC基板,2层薄膜布线) 60片,100%全部通过GJB2438 C.2.7成膜基片评价考核要求,相比LTCC基板,布线密度提高4倍,尺寸缩小40%。     

LTCC基板上薄膜多层布线工艺技术

LTCC基板上薄膜多层布线工艺是MCM-C/D多芯片组件的关键技术。它可以充分利用LTCC布线层数多、可实现无源元件埋置于基板内层、薄膜细线条等优点,从而使芯片等元器件能够在基板上更加有效地实现高密度的组装互连。文章介绍了LTCC基板上薄膜多层布线工艺技术,通过对导带形成技术、通孔柱形成技术和聚酰亚胺介质膜技术的研究,解决了在LTCC基板上薄膜多层布线中介质膜"龟裂",通孔接触电阻大、断路,对导带的保护以及电镀前的基片处理等工艺难题。     

金凸点的打球法制作与可靠性考核

本文采用打球法在芯片上制作金凸点，并将凸点倒装焊接在Ti/Ni/Au多层金属化的LTCC基板上。利用扫描电镜观察凸点形貌，X射线透射研究倒装互连状况，并通过接触电阻和剪切强度对凸点倒装焊的可靠性进行了考核。     

一种LTCC基板上薄膜多层布线技术

LTCC基板上薄膜多层布线工艺是MCM—C／D多芯片组件的关键技术,它可以充分利用LTCC布线层数多、可实现无源元件埋置于基板内层、薄膜细线条精确等优点,从而使芯片等元器件能够在基板上更加有效地实现高密度的组装互连。本文介绍了在LTCC基板上薄膜多层布线工艺技术,通过对导带形成技术、通孔柱形成技术和聚酰亚胺介质膜技术的研究,解决了在LTCC基板上薄膜多层布线的工艺难题。     

氮化铝基板薄膜金属化工艺研究

氮化铝（ＡＩＮ）基板由于其优良的热性能和无毒性，成为一种重要的微电子材料。本文从以下三方面研究了氮化铝基板的薄膜金属化问题：（１）金属薄膜同ＡＩＮ基板的附着力；（２）ＡＩＮ基板上薄膜电阻的温度系数；（３）ＡＩＮ基板上ＮｉＣｒ薄膜电阻的功率密度。研究结果表明，氮化铝上薄膜金属化层的附着强度可以大于ＡＩＮ陶瓷本身。成功地将薄膜金属化氮化铝基板应用于功率混合电路和功率对晶体管模块中。     

基于LTCC基板的薄膜微带线制作技术

本文对厚、薄膜多层互连基板的发展进行了简单的分析，对基于LTCC基板的薄膜50Ω微带线的设计、制造、测试进行了介绍。结果表明LTCC基板表面实施薄膜工艺与厚膜工艺相比有利于获得更好的微波一致性。     

薄膜基板芯片共晶焊技术研究

共晶焊是微电子组装技术中的一种重要焊接工艺,在混合集成电路中得到了越来越多的应用。文章简要介绍了共晶焊接的原理,分析了影响薄膜基板与芯片共晶焊的各种因素,并且选用Ti/Ni/Au膜系和AuSn焊料,利用工装夹具在真空环境下通入氮、氢保护气体的方法进行薄膜基板芯片共晶焊技术的研究。试验证明:焊接基板金属化Au层厚度1.5μm,焊接压力为2kPa,焊接温度330℃,时间30s可有效地使空洞面积控制在10%以下。并在150℃高温贮存以及-65℃~150℃温度循环后对共晶焊接样品的剪切强度和接触电阻进行了试验。在可靠性试验后,样品的剪切强度满足GJB548B-2005的要求,接触电阻变化率小于5%。     

薄膜基板芯片共晶焊技术研究

共晶焊是微电子组装技术中的一种重要焊接工艺,在混合集成电路中得到了越来越多的应用。文中简要介绍了共晶焊接的原理,分析了影响薄膜基板与芯片共晶焊的各种因素,并且选用Ti/Ni/Au膜系和AuSn焊料,利用工装夹具在真空环境下通入氮、氢保护气体的方法进行薄膜基板芯片共晶焊技术的研究。     

用于半导体激光器热沉的金刚石膜/Ti/Ni/Au金属化体系的研究

提出了一种用于半导体激光器热沉的金刚石膜/ Ti/ Ni/ Au金属化体系.采用金属化前期预处理、电子束蒸镀技术和后续低温真空热处理,金属层和金刚石膜之间获得了良好的结合强度.AES分析表明Ti/ Ni/ Au金刚石膜金属化体系中,Ni层起到了良好的阻挡效果;XRD显示预处理过的金刚石膜,镀膜后经过6 73K,2 h低温真空热处理,Ti/金刚石膜界面形成Ti O和Ti C;RBS分析进一步证实该金属化体系在6 73K,1h真空加热条件下具有良好的热稳定性.采用完全相同的半导体激光器结构,金刚石膜热沉的热阻仅为氮化铝热沉的4 0 % .     

Silicon carbide pinch rectifiers using a dual-metal Ti-Ni/sub 2/Si Schottky barrier

The electrical characterization of dual-metal-planar Schottky diodes on silicon carbide is reported. The devices were fabricated on both 6H- and 4H-SiC by using titanium (Ti) and nickel silicide (Ni/sub 2/Si) as Schottky metals. These rectifiers yielded the same forward voltage drop as the Ti diodes and leakage current densities comparable to those of the Ni/sub 2/Si diodes. The reduction of the reverse leakage current density, with respect to that of the Ti diodes, was about three orders of magnitude in 6H and about a factor of 30 in 4H-SiC. All that results in a consistent reduction of the device power dissipation. Electrical characterization of the devices at different temperatures provided insight into the carrier transport mechanism. In particular, the electrical behavior of the system was explained by an "inhomogeneous" Schottky barrier model, in which the low Ti barrier determines the current flow under forward bias, whereas the high Ni/sub 2/Si barrier dominates the reverse bias conduction by the pinchoff of the low barrier Ti regions.     

Dual metal SiC Schottky rectifiers with low power dissipation

Nickel and titanium are the most commonly used metals for Schottky barrier diodes on silicon carbide (SiC). Ti has a low Schottky barrier height (i.e. 0.8 eV on 6H-SiC), whilst Ni has a higher barrier (i.e. 1.25 eV). Therefore, the first metal allows to achieve a low forward voltage drop V_F but leads to a high leakage current. On the other hand, the second one presents the advantage of a lower reverse leakage current but has also a high value of V_F. In this work, dual-metal-planar (DMP) Schottky diodes on silicon carbide are reported. The rectifying barrier was formed by using an array of micrometric Ti and Ni₂Si (nickel silicide) stripes. This low/high Schottky barrier allowed to combine the advantages of the two metals, i.e. to fabricate diodes with a forward voltage drop close to that of a Ti diode and with a level of reverse current comparable to that of a Ni₂Si diode. Under the application point of view, using this kind of barrier can lead to a reduction of the device power dissipation and an increase of the maximum operating temperature.     

High performance of high-voltage 4H-SiC Schottky barrier diodes

High performance of high-voltage rectifiers could be realized utilizing 4H-SiC Schottky barrier diodes. A typical specific on-resistance (R_on) of these devices was 1.4×10³ Ω cm³ at 24°C (room temperature) with breakdown voltages as high as 800 V. These devices based on 4H-SiC had R _on's lower than 6H-SiC based high-power rectifiers with the same breakdown voltage. As for Schottky contact metals, Au, Ni, and Ti were employed in this study. The barrier heights of these metals for 4H-SiC were determined by the analysis of current-voltage characteristics, and the reduction of power loss could be achieved by controlling the barrier heights     

缓冲层对铜催化生长碳管形貌和性能的影响

碳纳米管的生长通常使用Fe,Co,Ni作为催化剂,除此以外的一些过渡元素也能催化裂解生长碳管。其中用铜制备的碳管阈值电场低、发射电流密度大、发射均匀性好等等良好的场发射特性。铜与硅、或金属之间具有很强的的扩散特性,而碳管应用于场发射显示器必然使用玻璃、硅片作为衬底,所以需要一层缓冲层阻挡催化剂铜扩散入衬底。本文使用磁控溅射制备铜薄膜作为催化剂,化学气相沉积方法裂解乙炔生长碳管薄膜形成场发射阴极。并试验W,Ni,Cr和Ti作为铜薄膜的缓冲层,结果表明不同的金属阻挡特性不同,生长后碳管的形貌和特性都有差异。结果表明Ti和W能很好地阻挡铜的扩散,从而使铜催化裂解出附着性好、分布均匀、密度适中、场发射特性良好的碳管薄膜。对于Ni和Cr金属,由于生长的碳管与衬底结合差或者场发射能力差而不适合作铜的缓冲层。     

Schottky barrier heights of n-type and p-type Al0.48In0.52As

The authors report electrical measurements on four different metal contacts which formed Schottky barriers to lightly doped complementary n- and p-type Al_0.48In_0.52As epitaxial material grown by molecular beam epitaxy on semi-insulating InP substrates. The Schottky contact metals studied were Au, Al, Pt, and tri-layer Ti/Pt/Au. The Schottky barrier heights varied from 0.560 eV for Al on n-type AlInAs to 0.905 eV for Al on p-type AlInAs, with intermediate values for the other metals studied. The sum of n- and p-type Schottky barrier heights for each metal contact ranged from 1.440 to 1.465 eV, in good agreement with the accepted Al_0.48In_0.52As bandgap value of 1.45 eV     

Control of threshold voltage of AlGaAs/GaAs 2DEG FET's through heat treatment

Threshold voltage controls of Ni/Ti/Au gate and Ti/Au gate 2DEG AlGaAs/GaAs FET's through only heat treatment are investigated. Ni/Ti/Au gate FET's vary over quite a wide range from a depletion mode to an enhancement mode without degradation of FET characteristics after heat treatment at 300°C. The same experiment is made for Ti/Au gate FET's, but the threshold voltage change is negligibly small. It is confirmed that Ni/Ti/Au can be used as the gate metal for E-FET and Ti/Au as the gate metal for D-FET under simultaneous heat treatment. In addition, a mechanism for penetrating the barrier metal into the underlying layer is discussed.     

Leakage current reduction in pentacene-based thin film transistor using asymmetric source/drain electrodes

In this work, we propose the concept of achieving a lower off-current in organic thin film transistors (OTFTs) by asymmetric source/drain with low and high work-function metals. The artificial hole barrier height (h-BH) at the drain-channel junction formed by this method prevents hole carriers transport from source to drain through the pentacene layer during the off-state. On-current is not affected by this artificially formed h-BH because the effective h-BH is reduced in the on-state. As a result, in the asymmetric Ni–Ti and Ni–Al OTFTs, the off-currents are decreased by 12 and 18.3 times, respectively, compared to that in the symmetric S/D device.