Spectral characterization and ASTER-based lithological mapping of an ophiolite complex: A case study from Neyriz ophiolite, SW Iran

The Neyriz ophiolite occurs along the Zagros suture zone in SW Iran, and is part of a 3000-km obduction belt thrusting over the edge of the Arabian continent during the late Cretaceous. This complex typically consists of altered dunites and peridotites, layered and massive gabbros, sheeted dykes and pillow lavas, and a thick sequence of radiolarites. Reflectance and emittance spectra of Neyriz ophiolite rock samples were measured in the laboratory and their spectra were used as endmembers in a spectral feature fitting (SFF) algorithm. Laboratory spectral reflectance measurements of field samples showed that in the visible through shortwave infrared (VNIR-SWIR) wavelength region the ultramafic and gabbroic rocks are characterized by ferrous-iron and Fe, MgOH spectral features, and the pillow lavas and radiolarites are characterized by spectral features of ferric-iron and AlOH. The laboratory spectral emittance spectra also revealed a wide wavelength range of SiO spectral features for the ophiolite rock units. After continuum removal of the spectra, the SFF classification method was applied to the VNIR + SWIR 9-band stack, and to the 11-band data set of SWIR and TIR data sets of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor, using field spectra as training sets for evaluating the potential of these data sets in discriminating ophiolite rock units. Output results were compared with the geological map of the area and field observations, and were assessed by the use of confusion matrices. The assessment showed, in terms of kappa coefficient, that the SFF classification method with continuum removal applied to the SWIR data achieved excellent results, which were distinctively better than those obtained using VNIR + SWIR data and TIR data alone.     

Lithological discrimination of the Phenaimata felsic–mafic complex,Gujarat, India,using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER)

This study deals with an evaluation of the efficacy of an Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) image for lithological mapping. ASTER level-1B data in the visible near-infrared (VNIR), short wave infrared (SWIR) and thermal infrared (TIR) regions have been processed to generate a lithological map of the study area in and around the Phenaimata igneous complex, in mainland Gujarat, India. ASTER band combinations, band ratio images and spectral angle mapper (SAM) processing techniques were evaluated for mapping various lithologies. The reflectance and emissivity spectra of rock samples collected from the study area were obtained in the laboratory and were used as reference spectra for ASTER image analysis. The original data in the scaled digital number (DN) values were converted to radiance and then to relative reflectance by using a scene-derived correction technique prior to SAM classification. The SAM classification in the VNIR–SWIR region is found to be effective in differentiating felsic and mafic lithologies. The relative band depth (RBD) images were generated from the continuum-removed images of ASTER VNIR–SWIR bands. Four RBD combinations (3, 5, 6 and 8) were used to identify Al-OH (aluminium hydroxide), Fe-OH (iron hydroxide), Mg-OH (magnesium hydroxide) and CO₃ (carbonate) absorption from various lithological components. ASTER TIR spectral emittance data and the laboratory emissivity measurements show the presence of a number of discrete Si-O spectral features that can differentiate mafic and felsic rock types reflecting the lithological diversity around the regions of Phenaimata igneous complex. SAM classification using emittance data failed to distinguish the felsic and mafic lithology due to the wider spectral bandwidth. The felsic class comprises the granitoid composition of rocks. RBD12 and 13 images in the TIR region were used to derive the mafic index (MI) and the silica index (SI). The MI shows the highest value in regions of gabbro–basalt occurrence, while the SI indicates regions of high silica content. The MI is lowest in regions where granophyres occur. The complimentary attributes based on the spectral reflectance and emittance data resulted in the discrimination of silica-rich and silica-poor lithologies.     

Integrating visible,near‐infrared and short wave infrared hyperspectral and multispectral thermal imagery for geologic mapping: simulated data

Hyperspectral and thermal infrared (TIR) multispectral remote sensing have great potential for surface geological mapping. This paper investigates the potential impact of combining these data on the comparative accuracy of different classification methods. A series of simulated datasets based on the characteristics of Airborne Visible/InfraRed Imaging Spectrometer (AVIRIS) and MODIS/ASTER Airborne Simulator (MASTER) sensors was created from surface reflectance and emissivity data derived from library spectra of 16 common minerals and rocks occurring in Cuprite, Nevada. System noise, illumination effects, the presence of vegetation, and spectral mixing were added to create the simulated data. Five commonly used classification algorithms, minimum distance, maximum likelihood classification, binary encoding, spectral angle mapper (SAM) and spectral feature fitting (SFF), were applied to all datasets. All the classification methods, excluding binary encoding, achieved nominal to significant improvement in overall accuracy when applied to the combined datasets in comparison to using only the AVIRIS dataset. Furthermore, certain classification methods of the combined datasets show a marked increase in individual rock or mineral class accuracies. Limestone, silicified and muscovite, for instance, show an improvement of almost 30% or greater in either producer's or user's accuracy using the combined datasets with SAM. SFF provides a great improvement in accuracy for limestone, quartz and muscovite. In terms of overall comparative accuracy for the individual and the combined datasets, maximum likelihood classification shows the best performance. For the simulated AVIRIS data, SFF was generally superior to SAM, although the accuracy of SAM applied to the combined datasets was slightly better than that of SFF. SAM applied to the combined datasets increases classification accuracy for some minerals and rocks which do not exhibit distinct absorption feature in the TIR region, while for SFF, only the accuracy of minerals and rocks with characteristic absorption features in the TIR region is improved.     

Detection of sandy soil surfaces using ASTER‐derived reflectance,emissivity and elevation data: potential for the identification of land degradation

Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) reflectance and emissivity data were used to discriminate nonphotosynthetic vegetation (NPV) from exposed soils, to produce a topsoil texture image, and to relate sand fraction estimates with elevation data in an agricultural area of central Brazil. The results show that the combination of the shortwave infrared (SWIR) bands 5 and 6 (hydroxyl absorption band) and thermal infrared (TIR) bands 10 and 14 (quartz reststrahlen feature) discriminated dark red clayey soils and bright sandy soils from NPV (crop litter), respectively. The ratio of the bands 10 and 14 was correlated with laboratory measured total sand fraction. When applied to the image and associated with topography, a predominance of sandy soil surfaces at lower elevations and clayey soil surfaces at higher elevations was observed. Areas presenting the largest sand fraction values, identified from ASTER band 10/14 emissivity ratio, were coincident with land degradation processes.     

Lithologic mapping in the Oscar II Coast area,Graham Land,Antarctic Peninsula using ASTER data

The results of the first attempt to use Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data for the purposes of lithologic mapping on the Antarctic Peninsula are presented for an area on the Oscar II Coast, eastern Graham Land. This study included undertaking laboratory reflectance spectroscopy of ～70 rock samples from the study area and spectral lithologic analysis of two ASTER scenes. Spectra of the granitoids, silicic volcanic/volcaniclastic and terrestrial sedimentary rocks in the study area display a limited range of absorption features associated with muscovite, smectite and chlorite that are generally present as the alteration products of regional metamorphism. ASTER data analysis was undertaken using the reflective bands of the Level 1B registered radiance at-sensor data and the standard thermal infrared (TIR) emissivity product (AST05). For both wavelength regions, standard qualitative image processing methods were employed to define image end-members that were used as reference within Matched Filter (MF) processing procedures. The results were interpreted with reference to existing field observations, and photogeologic analysis of the ASTER visible to near-infrared (VNIR)/shortwave infrared (SWIR) data was used to resolve ambiguities in the spectral mapping results. The results have enabled the discrimination of most of the major lithologic groups within the study area as well as delineation of hydrothermal alteration zones of propylitic, and argillic grades associated with the Mesozoic Mapple Formation volcanics. The results have extended the mapped coverage of the Mapple Formation into un-investigated regions further north and validated previously inferred geological observations concerning other rocks throughout the study area. The outcomes will enable important revisions to be made to the existing geological map of the Oscar II Coast and demonstrate that ASTER data offers potential for improving geological mapping coverage across the Antarctic Peninsula.     

ASTER spectral analysis of ultramafic lamprophyres (carbonatites and aillikites) within the Batain Nappe,northeastern margin of Oman: a proposal developed for spectral absorption

We developed a scientific proposal on spectral absorption in remote sensing and a new image-processing method that is purely based on multispectral satellite image spectra to map ultramafic lamprophyre and carbonatite occurrences. The proposed method provides a simple, yet efficient, tool that will help exploration geologists. In this proposal, in which the spectral absorption is applicable to all satellite images obtained in visible, reflected infrared, and thermal infrared spectral wavelength regions, we found that the carbonatites appear white in colour on a greyscale or RGB thermal infrared image obtained in the thermal infrared wavelength region (3–15 μm) due to molecular emission of thermal energy by such carbonate content, particularly the wavelength recorded by the sensor and that the variation of absorption in spectral bands of an outcrop is due to the differences in percentage of carbonate content or the spectral, spatial, radiometric, or temporal resolution of satellite data or the occurrences of carbonatites to incident energy. The results were confirmed by studying the spectral absorption characteristics of carbonatites in selected world occurrences including parts of Batain Nappe, Oman; Fuerteventura (Canary Islands), Spain; Mount Homa, Kenya; Ol Doinyo Lengai, Tanzania; Mount Weld region, (Laverton), Australia, and Phalaborwa region, South Africa, using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Landsat Thematic Mapper (TM) satellite data. A subsequent study of visible near-infrared (VNIR) and shortwave infrared (SWIR) ASTER spectral bands of Early Cretaceous alkaline ultramafic rocks of Batain Nappe, along the northeastern margin of Oman to map for the occurrences of carbonatite and aillikite (ultramafic lamprophyres) dikes and plugs, showed their detection mainly by the diagnostic CO₃ absorption (2.31–2.33 μm) in ASTER SWIR band 8. The results of image interpretations were verified and confirmed in the field and were validated through the study of laboratory analyses. A few more carbonatite dike occurrences were interpreted directly over the greyscale image of ASTER bands and true-colour interpretations of a Google Earth image along this margin. The carbonatites and aillikite occurrences of the area are rich in apatite, iron oxide, phlogopite, and REE-rich minerals and warrant new exploration projects.     

Combined use of ASTER and ALI data for hydrothermal alteration mapping in the northwestern part of the Kerman magmatic arc,Iran

The study area is located in the Kerman magmatic arc in southern Iran, which is known for its world-class porphyry-type deposits. The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Advanced Land Imager (ALI) visible–near-infrared to shortwave-infrared bands were used to investigate the spectral discrimination of hydrothermally altered rocks based on their mineral assemblages. Band ratioing, directed principal component analysis (DPCA), and the Spectral Angle Mapper (SAM) were applied on ASTER and ALI data for separating ferric iron-poor from ferric iron-rich phyllic alteration zones. The individual principal component images through DPCA could detect specific alteration zones dominated by minerals such as iron oxides, sericite, kaolinite, chlorite, and epidote. The phyllic zone associated with copper mineralization is generally rich in iron oxide minerals at the surface, which can be especially detected by ALI. The altered areas were sampled and studied using X-ray diffraction analysis, spectral measurements, chemical analysis, and thin-section studies. The results of this analysis have shown that more than 90% of the known copper mineralization falls within the ASTER/ALI-mapped alteration areas. These data can be useful for mapping alteration minerals related to porphyry deposits in other regions with similar geological settings.     

Assessment of image processing techniques and ASTER SWIR data for the delineation of evaporates and carbonate outcrops along the Salt Lake Fault,Turkey

The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) multispectral sensor allows a variety of minerals to be diagnosed with the availability of six shortwave infrared (SWIR) bands. The study area located in a semi-arid region in central Turkey was flanked by the Salt Lake Fault in the west. ASTER SWIR bands and the adopted image processing techniques such as decorrelation stretch, band ratio, and feature-oriented principle component selection (FPCS) were applied for mapping both gypsum and carbonate rocks in the study area. Initially, the application of the decorrelation stretch method with a novel band combination successfully delineated the gypsum and carbonate outcrops. In addition to that, the principle component 4 (PC4) image obtained from the FPCS technique applied to a new band selection of ASTER data distinguished explicitly the carbonate outcrops. The resultant images, consistent with the geologic map of the study area, were compared with another and demonstrated that the gypsum and carbonate rocks were clearly identifiable. In addition to that, quantitative analyses of parallelepiped supervised classification images, band 9/band 8 ratio, and PC4 images in particular, yielded very compatible results.     

Regional scale prospecting for non-sulphide zinc deposits using ASTER data and different spectral processing methods

ABSTRACT

The Ravar-Kuhbanan-Bahabad belt (RKBB) in Central Iran contains several carbonate-hosted non-sulphide Zn (zinc)-Pb (lead) deposits. The Gujer Zn mine area located in the middle of the RKBB was selected as the case study. Due to its large extent, dolomitic envelope in carbonate host rocks can be considered as a more appropriate exploratory target than small Zn-rich gossans or blind karst filling ore. Based on previous studies, the occurrence of red sandstone as a candidate of supplying metal for mineralization and evaporate as sulphate source for mineralized liquids in the vicinity of carbonate rocks can be important exploratory key in the RKBB. Non-sulphide Zn deposits were formed through oxidation of primary Mississippi Valley-type (MVT) deposits in the study area. Remote sensing studies were undertaken using visible to near-infrared (VNIR) and shortwave infrared (SWIR) bands of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) with the objective of lithological mapping. Five traverse lines containing a total of 81 samples were designed and followed with subsequent chemical analysis, thin section studies, and spectroscopy to verify the results. Two types of carbonates, namely, magnesian dolomite as host rock and surrounding calcitic limestone, were realized through using magnesium oxide (MgO) to calcium oxide (CaO) ratio. Based on spectroscopy studies, calcite and dolomite showed distinct absorption features at 2.35 µm and 2.32 µm, respectively, in ASTER band 8 while a shoulder at 2.25 µm was seen in ASTER band 7 for dolomite. Three image processing methods including spectral angle mapper (SAM), linear spectral unmixing (LSU), and mixture-tuned matched-filtering (MTMF) were applied to separate dolomite and limestone. The accuracy of image classification was numerically estimated using a confusion matrix. Limestone with the accuracy of 95.83% was more precisely enhanced using MTMF method compared to SAM and LSU methods. Highest accuracy of 75% for dolomite was obtained through using LSU method. Red sandstone and evaporate units were classified using MTMF and SAM/LSU methods, respectively. Rock units with the highest accuracy were selected and simply overlain on an image of ASTER in a GIS platform to create the potential map of the study area. Results showed that ASTER data can be successfully used to prepare a potential map for regional scale prospecting for carbonate-hosted non-sulphide Zn-Pb deposits in geological setting and climate condition similar to the RKBB.     

Atmospheric correction of optical imagery from MODIS and Reanalysis atmospheric products

In this paper we analyze the differences obtained in the atmospheric correction of optical imagery covering bands located in the Visible and Near Infra-Red (VNIR), Short-Wave Infra-Red (SWIR) and Themal-Infrared (TIR) spectral regions when atmospheric profiles extracted from different sources are used. In particular, three sensors were used, Compact High Resolution Imaging Spectrometer (CHRIS), Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) and Landsat5 Thematic Mapper (TM), whereas four atmospheric profiles sources were considered: i) local soundings launched near the sensor overpass time, ii) Moderate Resolution Radiometer (MODIS) atmospheric profiles product (MOD07), iii) Atmospheric Correction Parameter Calculator (ACPC) generated by the National Center for Environmental Prediction (NCEP) and iv) Modified Atmospheric Profiles from Reanalysis Information (MAPRI), which includes data from NCEP and National Center of Atmospheric Research (NCAR) Reanalysis project but interpolated to 34 atmospheric levels and resampled to 0.5° × 0.5°. MODIS aerosol product (MOD04) was also used to extract Aerosol Optical Thickness (AOT) values at 550 nm. Analysis was performed for three test dates (12th July 2003, 18th July 2004 and 13th July 2005) over an agricultural area in Spain. Results showed that air temperature vertical profiles were similar for the four sources, whereas dew point temperature profiles showed significant differences at some particular levels. Atmospheric profiles were used as input to MODTRAN4 radiative transfer code in order to compute atmospheric parameters involved in atmospheric correction, with the aim of retrieving surface reflectances in the case of VNIR and SWIR regions, and Land Surface Temperature (LST) in the case of the TIR region. For the VNIR and SWIR region, significant differences depending on the atmospheric profile used were not found, particularly in the Visible region in which the AOT content is the main parameter involved in the atmospheric correction. In the case of TIR, differences depending on the atmospheric profile used were appreciable, since in this case the main parameter involved in the atmospheric correction is the water vapor content, which depends on the vertical profile. In terms of LST retrieval from ASTER data (2004 test case), all profiles provided satisfactory results compared to the ones obtained when using a local sounding, with errors of 0.3 K for ACPC and MAPRI cases and 0.7 K for MOD07. When retrieving LST from TM data (2005 test case), errors for MOD07 and MAPRI were 0.6 and 0.9 K respectively, whereas ACPC provided an error of 2 K. The results presented in this paper show that the different atmospheric profile sources are useful for accurate atmospheric correction when local soundings are not available. In particular, MOD07 product provides atmospheric information at the highest spatial resolution, 5 km, although its use is limited from 2000 to present, whereas MAPRI provides historical information from 1970 to present, but at lower spatial resolution.     

Identification of mineral components in tropical soils using reflectance spectroscopy and advanced spaceborne thermal emission and reflection radiometer (ASTER) data

Soil characteristics provide important support for understanding transformations that occur in environmental systems. Physical characteristics and chemical compositions of soils controlled by pedogenetic processes, climatic changes and land use imply different types of environmental transformations. Reflectance spectroscopy is an alternative soil mapping technique that uses spectral absorption features between visible (VIS) and short-wave infrared (SWIR) wavelengths (0.3-2.5 μm) for determining soil mineralogy. Soil analysis by means of reflectance spectroscopy and orbital optical sensors have provided favorable results in mapping transformation processes in environmental systems, particularly in arid and semiarid climates in extra-tropical terrains. In the case of inter-tropical environments, these methods cannot be readily applied due to local factors such as lack of exposed regolith, high amounts of soil moisture and the presence of dense vegetation. This study uses Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and reflectance spectroscopy data to map mineral components of soils covering a part of the state of São Paulo, Brazil, which could be linked to key aspects of environmental transformations in this tropical area (e.g., climate change, shifts in agriculture fronts, ph, and soil characteristics). We collected forty-two (42) soil samples at a depth of 0-20 cm, considering that this superficial layer corresponds to the highest correlation with soil properties detected by the ASTER sensor. These samples were measured using a FieldSpec FR spectrometer, and the derived spectra were interpreted for mineral composition. Interpretation was supported by X-ray diffraction analysis on the same samples. The spectral signatures were re-sampled to ASTER VNIR (AST1-4: 0.52-0.86 μm) and SWIR (AST5-9: 1.60-2.43 μm) spectral bandwidths and validated by comparing reflectance spectra of field samples with those extracted from atmospherically corrected and calibrated ASTER pixels. The agreement between spectral signatures measured from soil samples and those derived from ASTER imagery pixels proved plausible, with R² correlation values ranging from 0.6493 to 0.7886. This signifies that diagnostic spectral features of key minerals in tropical soils can be mapped at the spectral resolution of 9-band ASTER VNIR through SWIR reflectance. We used these spectral signatures as end-members in hyperspectral routine classifications adapted for use with ASTER data. Results proved possible the identification and remote mapping of minerals such as kaolinite, montmorillonite and gibbsite, as well as the distinction between iron-rich and iron-poor soils.     

Evaluating spectral indices for burned area discrimination using MODIS/ASTER (MASTER) airborne simulator data

Wildland fires are an annually recurring phenomenon in many terrestrial ecosystems. Accurate burned area estimates are important for modeling fire-induced trace gas emissions and rehabilitating post-fire landscapes. High spatial and spectral resolution MODIS/ASTER (MASTER) airborne simulator data acquired over three 2007 southern California burns were used to evaluate the sensitivity of different spectral indices at discriminating burned land shortly after a fire. The performance of the indices, which included both traditional and new band combinations, was assessed by means of a separability index that provides an assessment of the effectiveness of a given index at discriminating between burned and unburned land. In the context of burned land applications results demonstrated (i) that the highest sensitivity of the longer short wave infrared (SWIR) spectral region (1.9 to 2.5 μm) was found at the band interval from 2.31 to 2.36 μm, (ii) the high discriminatory power of the mid infrared spectral domain (3 to 5.5 μm) and (iii) the high potential of emissivity data. As a consequence, a newly proposed index which combined near infrared (NIR), longer SWIR and emissivity outperformed all other indices when results were averaged over the three fires. Results were slightly different between land cover types (shrubland vs. forest-woodland). Prior to use in the indices the thermal infrared data were separated into temperature and emissivity to assess the benefits of using both temperature and emissivity. Currently, the only spaceborne sensor that provides moderate spatial resolution (< 100 m) temperature and emissivity data is the Advanced Spaceborne and Thermal Emission Radiometer (ASTER). Therefore, our findings can open new perspectives for the utility of future sensors, such as the Hyperspectral Infrared (HyspIRI) sensor. However, further research is required to evaluate the performance of the newly proposed band combinations in other vegetation types and different fire regimes.     

ASTER Level 1A数据产品文件解析及应用

深入解析了ASTER数据的结构,研究如何正确读取数据中卫星的位置、速度、时间、姿态角、姿态变化率等与影像定位有关的数据,并研究了这些数据的变化规律。根据ASTER数据的特点,给出了该数据在辐射校正及影像定位方面的应用方法,使得影像能更好的在这些方面得到应用。     

Validation of the North American ASTER Land Surface Emissivity Database (NAALSED) version 2.0 using pseudo-invariant sand dune sites

Knowledge of the Land Surface Emissivity (LSE) in the Thermal Infrared (TIR: 8-12 µm) part of the electromagnetic spectrum is essential to derive accurate Land Surface Temperatures (LSTs) from spaceborne TIR measurements. This study focuses on validation of the emissivity product in the North American ASTER Land Surface Emissivity Database (NAALSED) v2.0 — a mean seasonal, gridded emissivity product produced at 100 m spatial resolution using all Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) scenes from 2000 to 2008 over North America (http://emissivity.jpl.nasa.gov). The NAALSED emissivity product was validated over bare surfaces with laboratory measurements of sand samples collected at nine pseudo-invariant sand dune sites located in the western/southwestern USA. The nine sand dune sites cover a broad range of surface emissivities in the TIR. Results show that the absolute mean emissivity difference between NAALSED and the laboratory results for the nine validation sites and all five ASTER TIR bands was 0.016 (1.6%). This emissivity difference is equivalent to approximately a 1 K error in the land surface temperature for a material at 300 K in the TIR.     

Thermal infrared spectra and images of altered volcanic rocks in the Virginia Range,Nevada

Abstract

Airborne Thermal Infrared Multispectral Scanner (TIMS) data and laboratory thermal infrared reflectance spectra were collected from sites of hydrothermally altered andesitic volcanic rocks near Virginia City, Nevada. Alunitic, kaolinitic, illitic, and propylitic alteration types have distinct laboratory spectral curves, although the individual spectra are difficult to interpret mineralogically. TIMS emittance spectra show a general shift in the wavelength of the silicate emittance minima to shorter wavelengths with increasing intensity of alteration, owing to the increasing abundance of secondary framework and sheet silicate minerals. Strongly altered volcanic rocksare identifiable on TIMS radiance and emittance imagery.     

Mapping of hydrothermally altered rocks by the EO‐1 Hyperion sensor,Northern Danakil Depression,Eritrea

An EO‐1 Hyperion scene was used to identify and map hydrothermally altered rocks and a Precambrian metamorphic sequence at and around the Alid volcanic dome, at the northern Danakil Depression, Eritrea. Mapping was coupled with laboratory analyses, including reflectance measurements, X‐ray diffraction, and petrographic examination of selected rock samples. Thematic maps were compiled from the dataset, which was carefully pre‐processed to evaluate and to correct interferences in the data. Despite the difficulties, lithological mapping using narrow spectral bands proved possible. A spectral signature attributed to ammonium was detected in the laboratory measurements of hydrothermally altered rocks from Alid. This was expressed as spectral absorption clues in the atmospherically corrected cube, at the known hydrothermally altered areas. The existence of ammonium in hydrothermally altered rocks within the Alid dome has been confirmed by previous studies. Spectral information of endmember's mineralogy found in the area (e.g. dolomite) enables a surface mineral map to be produced that stands in good agreement with the known geology along the overpass. These maps are the first hyperspectral overview of the surface mineralogy in this arid terrain and may be used as a base for future studies of remote areas such as the Danakil.     

Thermal-infrared imaging of weathering and alteration changes on the surfaces of basalt flows,Hawai‘i,USA

Basaltic pahoehoe lavas weather on time scales of decades to millennia and are chemically altered by volcanic heat and gases on time scales of days to decades following their eruption. Despite differences in reactions and rates, the end products, viewed spectrally in the thermal infrared (TIR: 8–12 μm), are similar and distinctive: initial rinds of quickly cooled, disordered glass with broad emissivity minima at 9–11 μm devitrify to yield a sharper emissivity band at 9.1 μm; opaline rinds with a similar emissivity feature accrete and gradually transition to cryptocrystalline quartz with an emissivity minimum near 8.1 μm. Ultimately, exposed surfaces are oxidized and hydrated to palagonite, with a loss of spectral contrast and character. We have collected over 600 pahoehoe samples of different ages from seven sites on Mauna Loa and the south coast of Hawai‘i in order to measure hemispheric emissivity spectra and compare them to airborne and spaceborne TIR Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) AST05 emissivity images of Hawai‘i. ASTER, with five 90 m TIR bands, has operated over the 11 year period since launch in late 1999. Images and samples from some of the Hawai‘ian sites were collected repeatedly over a decade or more to study the rate of spectral change there. Continuing eruptions of Pu‘u ‘O‘o since 1983 offered an opportunity to study the effects of a persistent dousing of lavas by acidic rain and air (‘vog’), and older flows from Mauna Loa offered an opportunity to study the effects of weathering away from active vents. Weathering changes and rates quantified spectrally are helpful in mapping and assessing long-term environments on volcanoes.     

Evaluating Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data for alteration zone enhancement in a semi‐arid area,northern Shahr‐e‐Babak,SE Iran

The visible–near infrared (VNIR) and short wave infrared (SWIR) spectral bands of both the level 1B, radiance at sensor, and level 2, AST_07 surface reflectance data products of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument were evaluated and compared for mapping the alteration zones around porphyry copper deposits and occurrences at the northern Shahr‐e‐Babak, SE Iran. The level 1B data were converted to reflectance using internal average relative reflectance (IARR) method whereas the AST_07 dataset was processed as delivered. The porphyry copper mineralization occurs in Eocene, andesitic and basaltic rocks with zonal alteration patterns that are concentric and almost symmetrically arranged. The spectral signatures of alteration index minerals collected from field samples and the United States Geological Survey (USGS) spectral reference library, were considered in directed principal component analysis (DPCA) and spectral angle mapping (SAM) algorithms. Carrying out the DPCA method on three spectral bands enhanced the alteration haloes in the last principal component (PC) images. Generating RGB colour composite images using these PC images differentiated three alteration zones from the host rocks. The SAM results of the IARR calibrated dataset discriminated the propylitic, argillic and phyllic alteration zones. It is concluded that the higher spectral resolution of ASTER instrument is effective for mineral mapping. However, the method of conversion from radiance to reflectance is critical to the validity of the outputs and that the pseudo‐reflectance method using the IARR process may be more reliable than the standard reflectance product.     

Spectroscopic characterization of oils yielded from Brazilian offshore basins: Potential applications of remote sensing

Spectroscopy is the basis to detect and characterize offshore hydrocarbon (HC) seeps through optical remote sensing. Diagnostic spectral features of HCs are linked to their chemical composition and fundamental molecular vibrations (SWIR-TIR features), as well as overtones and combinations of these vibrations (VNIR-SWIR). These features allow for the characterization of oil, oil on water and emulsified oil. This work shows the results of lab and field spectral measurements of 17 petroleum samples yielded from key, oil-rich sedimentary basins in Brazil. Measurements comprised reflectance data (VNIR- SWIR), Attenuated Total Reflectance (ATR), Directional Hemispherical Reflectance (DHR), and emissivity data (TIR). These spectra were analyzed by multivariate techniques, such as Principal Components Analysis (PCA) and Partial Least-Square analysis (PLS). The experimental results indicate that for the VNIR-SWIR range: (i) spectral features can be recognized for crude oil, emulsified oil and oil on ocean water; (ii) different oil types can be qualitatively distinguished based on these features (i.e. light or heavy), even considering oil on water; (iii) the same applies for oil measurements simulated at the spectral resolution of hyperspectral (357-bands/ProSpecTIR) and multispectral (9-bands/ASTER) sensors. Within TIR wavelengths (3-14 μm), typical HC spectral features can also be resolved and oil types qualitatively discriminated using PCA/PLS, including both full-resolution spectra and spectra resampled to hyperspectral sensor (128-bands/SEBASS). However, despite the fact that oil emissivity is always lower than that of water, such separation seems unfeasible using 8-12 μm TIR features only; emissivity spectra are essentially flat for all samples in this interval. This research demonstrated that oil can be qualitatively distinguished based on both VNIR-SWIR and TIR spectroscopy data, with important implications for remote off-shore oil exploration and classification of oil leakages.     

Targeting key alteration minerals in epithermal deposits in Patagonia,Argentina, using ASTER imagery and principal component analysis

Principal component analysis (PCA) is an image processing technique that has been commonly applied to Landsat Thematic Mapper (TM) data to locate hydrothermal alteration zones related to metallic deposits. With the advent of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), a 14-band multispectral sensor operating onboard the Earth Observation System (EOS)-Terra satellite, the availability of spectral information in the shortwave infrared (SWIR) portion of the electromagnetic spectrum has been greatly increased. This allows detailed spectral characterization of surface targets, particularly of those belonging to the groups of minerals with diagnostic spectral features in this wavelength range, including phyllosilicates (‘clay’ minerals), sulphates and carbonates, among others. In this study, PCA was applied to ASTER bands covering the SWIR with the objective of mapping the occurrence of mineral endmembers related to an epithermal gold prospect in Patagonia, Argentina. The results illustrate ASTER's ability to provide information on alteration minerals which are valuable for mineral exploration activities and support the role of PCA as a very effective and robust image processing technique for that purpose.